1018 결정학

I
t LESS THAN FREE 원자번호증가

of A0 M0
c쌌 m
combination
linear
A0
얪筑
electron
nearlyfree

ATOMS IN THE BOX

Diffraction
gap
empty shed
ourselves to a One dimensional crystal
For now limiting

cd i

7 ff 77 if
An VA periodic potential

빽
attraction
owing to the
btw ions valence electron

lattice
constant Toe
consider electrons
to Wavelength 大
筽 we number
入
If
Case a
 is very small
k湃 ii k
of these low k electrons
In this case the kinetic energy

辰二 뺢
Case玎 Air or Xia
CONDITION
BRAGG DIFFRACTION
K 쯠 2d sina.ME
x ray

electron diffraction
We're now looking at
STAN
閉幽 WAVE
In this case electron wave becomes
potential begin to be felt
The effect of the periodic

ELECTRON
NEARLY FREE
condition
the brass
according to ZONE
when k 士 式 BRILLWING
electrons difftact BOUNDARY

wave wave
At this boundary elton standing

traveling wave

Two possible standing waves

냐 et t Eihl 仁 土ㅠㅠ
At the zone boundary
 4 1기 205 펫 421기 2 isin 팟
八 sin 俓
뺘읇 ii 臍 tea a

4세
fihr
renren.ir
8_fn.ohefn.hn
4.1기

Mi__

h.hhiV
MlT
_ Ltfor
atom's electron in the boy

nucleus position
be exist
녀 electron cannot

the electrons to interact with the lattices

By allowing
ㅠㅠ
ENERGY GAP at kit

pit
 B
n electronic states
levels
No longer a continuous range of energy

electron dispersion the nearly

Comparison of the free
free electron dispersion

壞 i
瀛
躪 拇
region I how K

Dispersion is
based on Free electron

region
ㅍ i high k
that occurs
because of diffraction
standing wave states

from the lattice

interaction btw electrons lattices
This diffraction
creates a GAP at the Bt boundary

펗
Extended Zone scheme PETE

1
1
1
1

1 1
i iii 1gap 1
1
1
1 1
if
鳥
1 1 I
i
武
낲 갸

o o tici
o
ott o
o
悧
2차원 E
if
瓣
澁

o o o
o o o
옢
기
became longer
dy

실격자 t
band dispersion
Q 뺶자T 탸 diagram

A t BCC
Fa
설명