CFS Environmental Clearance

M/S. CAMLIN FINE SCIENCES LTD.
FORM – 1
(I) BASIC INFORMATION
Sr.
Item Details
No.
1. Name of the Project M/s. Camlin Fine Sciences Ltd.
2. Sr. No in the schedule 5 (f)
3. Proposed capacity/ area/length/ 41900 MT/Annum of Products,
tonnage to be handled/command 1175 MT/Annum of Co-products and
area/ lease area / numbers of wells to 4.4 MW of Electricity
be drilled
4. New/ Expansion/ Modernization Modernization
5. Existing Capacity/ Area etc. Not Applicable
6. Category of the project i.e. ‘A’ or ‘B’ B
7. Does it attract the general condition? If No
yes, please specify
8. Does it attract the specific condition? If No
yes, please specify
9.  Location Part-II, Dahej SEZ
 Plot/ Survey/ Khasra` No. Plot No Z/96/D
Village
 Tehsil Vagra
 District Bharuch
 State Gujarat
10. Nearest Railway station / Airport Bharuch Railway station- Approx 40 Km.
along with distance in Kms.
11. Nearest Town, City, District Bharuch – Approx. 40 Kms.
Headquarters along with distance in
Kms.
12. Village Panchayat, Zilla Parishad, Post Office: Dahej
Municipal Corporation, Local Body Tehsil: Vagra
(complete postal addresses with Dist.: Bharuch
telephone numbers to be given).
13. Name of the Applicant Mr. A. S. Dukane
14. Registered Address F-11/12, WICEL, Opp. Seepz., Andheri
15. Address for Correspondence:
Name: Mr. A. S. Dukane
Designation (Owner/Partner/CEO): Sr. Global Vice President
Address: F-11/12, WICEL, Opp. Seepz. Main Gate,
Andheri(E), Mumbai
Pin Code: 400 065
E- mail: arjun.dukane@camlinfs.com
Telephone No.: 022 6700 1000
M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 1

16. Details of alternative sites examined, No alternate site is examined.

if any. Location of these sites should
be known on the Topo Sheet.
17. Interlinked Projects No
18. Whether second application of the Not Applicable
interlinked project has been
submitted?
19. If yes, Date of submission Not Applicable
20. If no, Reason Not Applicable
21. Whether the proposal involves
approval/clearance under: if yes,
details of the same and their status to No
be given.
 The Forest (Conservation) Act, 1980?
 The Wildlife (Protection) Act, 1972?
 Act, The C.R.Z Notification, 1991?
22. Whether there is any Government
Order/ Policy relevant/ relating to the No, it is GIDC Industrial Estate
site?
23. Forest Land involved (Hectares) No
24. Whether there is any litigation
pending against the project and/ or
land in which the project is proposed
to be set up?
 Name of the Court No
 Case No.
 Orders/ Directions of the Court, if
any and its relevance to the
proposed project

(II) ACTIVITY
1. Construction, operation or decommissioning of the Project involving actions,
which will cause physical changes in the locality (topography, land use, changes
in water bodies, etc)
Sr. Information / checklist Yes / Details thereof (with approximate
No. conformation. No. quantities/ rates, wherever possible)
with source of information data.
1.1 Permanent or temporary change in Yes Establishing New Manufacturing
land use, land cover or topography Activity in Open Plot.
including increase in intensity of land
use (with respect to local land use
plan.)
1.2 Clearance of existing land, vegetation Yes Plots are already marked by the
and buildings? GIDC Estate.
1.3 Creation of new land uses. Yes Plot will be developed for new
manufacturing activity.
1.4 Pre-construction investigations e.g. Yes Soil Test to be carried out
bore house, soil testing?
1.5 Construction works? Yes Construction will be carried out.
1.6 Demolition works? No Existing open plot.
1.7 Temporary sites used for No Local construction workers will be
construction works or housing of hired.
construction workers?
1.8 Above ground buildings, structures Yes Detailed Layout Plan from
or earthworks including linear Architecture attached as Annexure
structures, cut and fill or excavations. No. III-A and Site Plan is attached as
Annexure No. III-B
1.9 Underground works including No Not Applicable
mining or tunneling?
1.10 Reclamation works? No Not Applicable
1.11 Dredging? No Not Applicable
1.12 Offshore structures? No Not Applicable
1.13 Production and manufacturing Yes Attached Manufacturing Process
processes? details as Annexure No. VI
1.14 Facilities for storage of goods or Yes Provision of storages tanks or
materials? containers for storage of materials in
separate storage area.
1.15 Facilities for treatment or disposal of Yes The details of effluent treatment plant
solid waste or liquid effluents? are attached as Annexure No. VIII.
Hazardous waste details are given in
Annexure No. IX
1.16 Facilities for long term housing of No Plot will be utilized for industrial

operational workers? purpose only.

1.17 New road, rail or sea traffic during No The G.I.D.C Industrial Estate, Dahej
construction or operation? (SEZ) has well developed road
facility.
1.18 New road, rail, air waterborne or No The G.I.D.C Industrial Estate, Dahej
other transport infrastructure (SEZ) has well developed road
including new or altered routes and facility.
stations, ports, airports etc?
1.19 Closure or diversion of existing No Proposed project is located in
transport routes or infrastructure Notified area.
leading to changes in traffic
movements?
1.20 New or diverted transmission lines or No The proposed project is located in
pipelines? notified G.I.D.C. Industrial Estate.
1.21 Impoundment, damming, culverting, No Not Applicable
realignment or other changes to the
hydrology of watercourses or
aquifers?
1.22 Stream Crossing? No No such activity is involved in the
proposed project.
1.23 Abstraction or transfers of water No The unit will use water from G.I.D.C
form ground or surface waters? water supply system.
1.24 Changes in water bodies or the land No The proposed project is located in
surface affecting drainage or run-off? notified GIDC Estate.
1.25 Transport of personnel or materials Yes There will be routine movement of
for construction, operation or construction material, labor, raw
decommissioning? material to the site by road trucks.
1.26 Long-term dismantling or No This is green field project.
decommissioning or restoration
works?
1.27 Ongoing activity during No There will be no decommissioning
decommissioning which could have activity for the proposed project.
an impact on the environment?
1.28 Influx of people to an area in either No Local man power will be employed.
temporarily or permanently? The construction will be stage wise
and hence not more than 50 people
expected at a time.
1.29 Introduction of alien species? No No such activity is associated with
the proposed project.
1.30 Loss of native species or genetic No No such activity is involved which
diversity? can leads to loss of native species or

genetic diversity.
1.31 Any other actions? No Not required other action
2 Use of Natural resources for construction or operation of the Project (such as land,
water, materials or energy, especially any resources which are non-renewable or
in short supply):
Sr. Information / Checklist Yes / Details thereof (with approximate
No. conformation. No. quantities / rates, wherever possible)
2.1 Land especially undeveloped or No The proposed project is located in
agricultural land (ha) notified GIDC Industrial Estate, Dahej
(SEZ).
2.2 Water (expected source & competing Yes Details of water consumption and
users) unit: KLD waste water generation are attached
as Annexure No. VII.
2.3 Minerals (MT) No Not Applicable
2.4 Construction material – stone, Yes Materia Qty. Source
aggregates, sand / soil (expected l
source – MT) Bricks 100 Cu. Mt. From
Cement 5000 MT local
Sand 3600 Cu. Mt. supply
TMT 1800 MT
Steel
Gravel 7000 Cu. Mt.
Kapchi 1650 Cu. Mt.
Stone 2140 Cu. Mt.
2.5 Forests and timber (source - MT) Yes Small amount of wood will be
required for furniture in offices.
2.6 Energy including electricity and fuels Yes Details of Energy & fuel consumption
(source, competing users) Unit: fuel are attached as Annexure No. X.
(MT),energy (MW)
2.7 Any other natural resources (use No No other natural resources will be
appropriate standard units) used.
3 Use, storage, transport, handling or production of substances or materials, which
could be harmful to human health or the environment or raise concerns about
actual or perceived risks to human health.
No. Conformation. No. quantities / rates, wherever possible)
3.1 Use of substances or materials, which Yes List of raw materials and products as
are hazardous (as per MSIHC rules) per MSIHC rules is attached as
to human health or the environment Annexure No. XII.

(flora, fauna, and water supplies)

3.2 Changes in occurrence of disease or No Not Applicable. It is in the notified
affect disease vectors (e.g. insect or Area. (SEZ).
water borne diseases)
3.3 Affect the welfare of people e.g. by Yes New employeement will be
changing living conditions? generated.
3.4 Vulnerable groups of people who No There will be no such effects due to
could be affected by the project e.g. the proposed project.
hospital patients, children, the elderly
etc.,
3.5 Any other causes. No None.
4. Production of solid wastes during construction or operation or decommissioning
(MT/month).
4.1 Spoil, overburden or mine waste. Yes Handed over to notified authorized
agency.
4.2 Municipal waste (domestic and or Yes Use in vermiculture or similar
commercial wastes) composting facility.
Will be disposed off as per MSW
guide lines.
4.3 Hazardous wastes (as per Yes Details of hazardous waste
Hazardous Waste Management generation are attached as Annexure
Rules) No. IX.
4.4 Other industrial process wastes Yes Industrial Treated Effluent will be
disposed of in GIDC underground
drainage.
4.5 Surplus product No Not Applicable
4.6 Sewage sludge or other sludge from Yes 1. Sewage Sludge will be used in
effluent treatment. gardens as manure.
2. Effluent Sludge will be sent to
hazardous waste disposal facility.
4.7 Construction or demolition wastes Yes Any waste will be utilized in road
construction.
4.8 Redundant machinery or No Not Applicable
equipment.
4.9 Contaminated soils or other No New Project
materials.
4.10 Agricultural waste. No Notified SEZ Area.
4.11 Other solid wastes. No Nil
5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)


5.1 Emissions from combustion of fossil Yes Detail of flue gas emission is attached
fuels from stationary or mobile as Annexure No. XI.
sources
5.2 Emissions from Production Yes Detail of process emission is attached
Processes. as Annexure No. XI.
5.3 Emissions from materials handling Yes Adequate measures will be taken to
including storage or transport. control emissions from material
handling including storage or
transport.
5.4 Emissions from construction Yes Dust will be emitted from
activities including plant and construction activities which will be
equipment minimized by spraying of water,
barricading, etc.
5.5 Dust or odours from handling of Yes Dust will be emitted from
materials including construction construction activities which will be
materials, sewage and waste. minimized by spraying of water,
barricading, etc.
5.6 Emissions from incineration of waste. Yes There is a provision of hot gas filter in
plasma gasification stack.
5.7 Emissions from burning of waste in No No burning activity will be done in
open air (e.g. slash materials, the unit.
construction debris)
5.8 Emission from any other sources. No No other emissions from any other
source.
6. Generation of Noise and Vibration, and Emissions of Light and Heat:
6.1 From operation of equipment e.g. Yes Results of noise level monitoring will
engines, ventilation plant, crushers. be carried out during the construction
work.
6.2 From industrial or similar processes. Yes Noise proof equipments will be used
for industrial processes.
6.3 From construction or demolition. Yes Noise will be generated from some
activities such as drilling, digging,
grinding etc. during construction
which will be reduced by providing
barricades. It will be ensured that the
high noise creating activities will be

performed during the day only.

6.4 From blasting or piling. No Nil
6.5 From construction or operational No Adequate measures will be taken by
traffic. the unit.
6.6 From lighting or cooling systems. No Adequate measures will be taken by
the unit.
6.7 From any other sources. No No emission from any other sources.
7. Risks of contamination of land or water from releases of pollutants into the
ground or into sewers, surface waters, groundwater, coastal waters or the sea:
7.1 From handling, storage, use or Yes All the hazardous chemicals received
spillage of hazardous materials. will be stored in barrels in covered
godown. Adequate measures will be
taken during handling & use.
Spillages will be cleaned with
appropriate method and the waste
generated will be disposed off as
hazardous waste. PPE’s will be used
by the operators when handling
hazardous chemicals.
7.2 From discharge of sewage or other Yes Sewage will be treated in compact
effluents to water or the land sewage treatment plant. The treated
(expected mode and place of water from STP will be used for green
discharge) belt area.
7.3 By deposition of pollutants emitted to No Proper air pollution control measures
air into the land or into water are taken and thus their deposition on
land or water is not expected.
7.4 From any other sources. No No other sources will be there.
7.5 Is there a risk of long term build up No There will not be any long term build
of pollutants in the environment from up of pollutants in the environment
these sources? from these sources.
8. Risk of accidents during construction or operation of the Project, which could
affect human health or the environment.
8.1 From explosions, spillages, fires etc. Yes Adequate control measures will be
from storage, handling, use or provided. Proper on site and off site
production of hazardous substances. emergency plans will be prepared.
8.2 From any other causes No All the causes have been covered in

8.1
8.3 Could the project be affected by No Structures will be made earthquake
natural disasters causing proof and no possibility of flood is
environmental damage (e.g. floods, identified.
earthquakes, landslides, cloudburst
etc)?
9. Factors which should be considered (such as consequential development) which
could lead to environmental effects or the potential for cumulative impacts with
other existing or planned activities in the locality.
9.1 Lead to development of supporting Yes Local ancillary development like
localities, ancillary development or rewinding of motors, maintenance
development stimulated by the people, wiremen, etc. will be
project which could have impact on increased. It is the notified Industrial
the environment e.g.: Area.
• Supporting infrastructure (roads,

power supply, waste or waste water
treatment, etc.)
• housing development
• extractive industries
• supply industries
• other
9.2 Lead to after – use of the site, which No No negative impact identified.
could have an impact on the
environment.
9.3 Set a precedent for later No The project is not unprecedenent
developments.
9.4 Have a cumulative effect due to No It is in the industrial estate of SEZ
proximity to other existing or Dahej.
planned projects with similar effects.
(III) ENVIRONMENTAL SENSITIVITY.
Sr. Area. Name Aerial distance (within 15 km.)
No. / Proposed project location boundary.
Identi
ty
1 Areas protected under international No It is fully developed GIDC estate
conventions, national or local (SEZ).
legislation for their ecological,
landscape, cultural or other related
value.

2 Areas which are important or No The Narmada estuarine zone is

sensitive for ecological reasons - approximately 12 km away from
Wetlands, watercourses or other project site.
water bodies, coastal zone,
biospheres, mountains, forests.
3 Areas used by protected, important No It is fully developed GIDC estate
or sensitive species of flora or fauna (SEZ).
for breeding, nesting, foraging,
resting, over wintering, migration.
4 Inland, coastal, marine or No It is fully developed GIDC estate
underground waters (SEZ).
5 State, National boundaries. No It is fully developed GIDC estate
(SEZ).
6 Routes or facilities used by the public No It is fully developed GIDC estate
for access to recreation or other (SEZ).
tourist, pilgrim areas.
7 Defence installations. No It is fully developed GIDC estate
(SEZ).
8 Densely populated or built – up area. No Bharuch City is Approx. 40 Km. away.
9 Areas occupied by sensitive man- Yes Academic institutes and hospital are
made land uses (hospitals, schools, approximate 7km away from project
places of worship, community facilities) site.
10 Areas containing important, high No It is fully developed GIDC estate
quality or scare resources (ground (SEZ).
water, surface resources, forestry,
agriculture, fisheries, tourism, minerals)
11 Areas already subjected to pollution No Environment standards of GIDC
or environmental damage. (those estate (SEZ) are within the limits.
where existing legal environmental
standards are exceeded)
12 Areas susceptible to natural hazard No It is fully developed GIDC estate
which could cause the project to (SEZ).
present environmental problems
(earthquakes, subsidence, landslides,
erosion, flooding or extreme or adverse
climatic conditions)

“ I hereby given undertaking that the data and information given in the application and
enclosures are true to my best knowledge and belief and I am aware that if any part of the
data and information submitted is found to false or misleading at any stage, the project
will be rejected and clearance give, if any to the project will be revoked at our risk and
cost”.
Date:
Place:
Signature of the applicant

With full Name and Full address
(Project Proponent/ Authorized Signatory)
NOTE:
1. The projects involving clearance under Coastal Regulation Zone Notification, 1991
shall submit with the application a C.R.Z map duly demarcated by one of the
authorized agencies, showing the project activities, w.r.t. C.R.Z (at the stage of TOR)
and the recommendations of the State Coastal Zone Management Authority (at the
stage of EC). Simultaneous action shall also be taken to obtain the requisite clearance
under the provisions of the C.R.Z Notification, 1991 for the activities to be located in
the CRZ.
2. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere

Reserves, Migratory Corridors of Wild Animals, the project proponent shall submit
the map duly authenticated by Chief Wildlife Warden showing these features vis-à-vis
the project location and there commendations or comments of the Chief Wildlife
Warden thereon (at the stage of EC).
3. All correspondence with the Ministry of Environment & Forest including submission
of application for TOR/Environmental Clearance, subsequent clarifications, as may be
required from time to time, participation in the EAC Meeting on behalf of the project
proponent shall be made by the authorized signatory for the specific project.

ANNEXURE-I
PROPOSED TERMS OF REFERENCE
 Standard TOR of MoEF&CC for organic sector will be followed.

ANNEXURE-II
LIST OF DIRECTORS
Sr. Name of Directors Address & Contact Details

No.
1. Mr. Ashish S. Dandekar Flat No. 9, 9th Floor, Concord Apartment, Bullock
Road, Bandstand, Bandra (W).
Mumbai-400050
ashish.dandekar@camlinfs.com
Tel No.-67001000
2. Mr. Dilip D. Dandekar 6, Govind Sadan, Shivaji Park, Road No. 4, Dadar,
Mumbai-400028
dilipdandekar@kokuyocamlin.com
Tel No.-67001000
3. Mr. Pramod M. Sapre 401, Vaishali Apartments, 15/21 Janki Kutir, Juhu,
Mumbai-400049
pmsapre@yahoo.com
Tel No.-67001000
4. Mr. Abeezar E. 41, Mereweather Road, Jaiji Mansion, Ground Floor,
Faizullabhoy Mumbai-400039
Abeezar.faizullabhoy@hsalegal.com
Tel No.-67001000
5. Mr. Sharad M. Kulkarni 161/A, Twin Towers, V.S. Road, Prabhadevi,
Mumbai-400025
sharadkulkarni@mac.com
Tel No.-67001000
6. Mr. Bhargav A. Patel Nariman Building, First Floor, 136, Maharshi Karve
Road, Opp. Cooperage Bus, Mumbai-400020
bhargav@peass.com
Tel No.-67001000
7. Mr. Dattatraya R. Puranik Flat No. 6 Amber Palace Apts., Chittaranjan Road,
Vile Parle (E). Mumbai-400057.
d.puranik@camlinfs.com
Tel No.-67001000
8. Mrs. Leena A. Dandekar 13, S, Regency Terraces, Flat No. 504, Chitrakar
Dhurandar Marg, Khar West, Mumbai-400052
leena.dandekar@camlinfs.com
Tel No.-67001000
9. Mr. Atul R. Pradhan 32 Cherrysons 143/144 St. Crysl Road, Bandra West,
Mumbai-400050

Sr. Name of Directors Address & Contact Details

No.
a.r.pradhan@outlook.com
Tel No.-67001000
10. Mr. Nicola A. Paglietti Roma, Via Italio Panattoni, 93, Italy.
n.paglietti@stint.it
Tel No.-67001000
11. Mr. Nirmal V. Momaya Horizon View, Flat No. 5 Gen. J. Bhonsle Marg,
Mumbai-400021
nirmal.momaya@camlinfs.com
Tel No.-67001000
12. Mr. Ajit S. Deshmukh Sammarth Krupa, Ram Mandir Road, Vile Parle
(East), Mumbai-400057
ajit.deshmukh@equirus.com
Tel No.-67001000

ANNEXURE-III (A)
PLANT LAYOUT

ANNEXURE-III (B)
SITE PLAN
M/s. Camlin Fine Sciences Ltd.

ANNEXURE-IV
LIST OF PRODUCTS WITH THEIR PRODUCTION CAPACITY
Sr. Name of Products Proposed Proposed IUPAC Chemical

No. (MT/M) * (MT/A) Name of products
1. Diphenol (Hydroquinone 1636.364 18000 (Hydroquinone-
& Catechol) benzene-1,4-diol)
(Catechol:Benzene-
1,2-diol)
2. Guaiacol 727.27 8000 2-methoxyphenol
3. Guaethol 136.36 1500 2-ethoxyphenol
5. Tertiary Butyl 545.45 6000 2-(1,1-
Hydroquinone Dimethylethyl)-1,4-
benzenediol
6. Vanillin 545.45 6000 4-Hydroxy-3-
methoxybenzaldehyde
7. 4-Methoxy Phenol 181.81 2000 4-Methoxy Phenol
8. para Benzoquinone 36.36 400 Cyclohexa-2,5-diene-
1,4-dione
Total 3809.064 41900
9. Electricity 4.4 MW -- --
Co-products
1. Veratrole (Co- product of 36.36 400 1,2-
Guaiacol) Dimethoxybenzene
2. Ortho Diethoxy Benzene 6.82 75 1,2-Diethoxybenzene
(Co- product of Guaethol)
3. Di-tertiary Butyl 54.54 600.000 2,5-Di-tert-butyl-1,4-
Hydroquinone (Co- hydroquinone
product of tertiary Butyl
Hydroquinone)
Total 97.72 1175
*This is a continuous plant and it will run for 11 months in a year.
Note- There will be no change in product profile after EC Amendment.

ANNEXURE-V
LIST OF RAW MATERIALS
Sr. Product Production consumpt

No. Capacity Name of the raw material ion in Kg
(MT/Month) /Kg of
1. Diphenol 1636.364 Phenol product
1.150
Acetone* 0.01*
Hydrogen Peroxide (60%) 0.98
Methyl Isobutyl Ketone 0.003
Catalyst 0.001
Phosphoric Acid 0.001
2. Guaiacol 727.27 Catechol 1.050
Methanol (Fresh) 0.343
Recovered Methanol 1.539
Catalyst 0.001
3. Guethol 136.36 Catechol 1.050
Ethanol (Fresh) 0.299
Ethanol (Recovered) 2.701
Catalyst 0.001
4. Tertiary Butyl 545.45 Hydroquinone 0.706
Hydroquinone Toluene (Fresh) 0.064
(TBHQ) Toluene (Recovered) 3.156
Phosphoric Acid (Catalyst) 1.600
Make up Phosphoric Acid 0.003
(Catalyst)
Isobutylene 0.394
5. Vanillin 545.45 Guaiacol 1.080
Sodium Hydroxide 2.447
Glyoxalic Acid (50%) 1.300
Sulphuric Acid 2.140
Fresh Toluene 0.035
Recovered Toluene 1.685
Cupric Oxide/Cupric Acetate 0.001
Fresh Isopropyl Alcohol 0.010
Recovered IPA 0.461
6. 4-Methoxy 181.81 Hydroquinone 1.000
Phenol (MeHQ) Methanol (Fresh) 0.346
Methanol (Recovered) 2.440
p-Benzoquinone 0.100
Resin Catalyst 0.001

7. Para 36.36 Hydroquinone 1.05

Benzoquinone Methanol (Fresh) 0.040
(PBQ) Methanol (Recovered ) 1.960
Hydrogen Peroxide (50%) 0.746
Iodine 0.024
9. Electricity 4.4 MW Coal 100MT
/Day
*note-Acetone will be used as and when required to make specific quality of product. This
will be in exceptional case only.
Note- There will be no change in raw material consumption after EC Amendment.

ANNEXURE-VI
MANUFACTURING PROCESS
1. DIPHENOL (HYDROQUINONE & CATECHOL)
A) Brief Manufacturing Process:

Phenol is treated with Hydrogen Peroxide in presence of heterogeneous Catalyst. Mixture of
Hydroquinone & Catechol is formed. This is further separated by distillation. Pure Catechol obtained is
flaked &packed. Hydroquinone is crystallized to purify, dried and packed.
B) Chemical Reaction
Note: Excess Hydrogen Peroxide taken in the reaction is getting decomposed to water and oxygen. Extra hydrogen peroxide
requirement is necessary for completion of reaction.

B) Flow Chart

D) Material Balance (With Water as a solvent)

INPUT :-
Raw Material Input Qty. in Quantity
Kg per kg of (MT/Day)
Diphenol
Phenol 1.15 75.2675
Water with Phenol solution 0.43416 28.4161
Hydrogen peroxide (100%) 0.10391 6.80078
Water with Hydrogen peroxide 0.06923 4.53142
MIBK for Extraction 0.11064 7.24153
Water added for crystallization (Fresh) 1.87 122.392
Water from mother liquor 0.8 52.36
Water formed in reaction 0.27 17.6715
Total 4.808 314.680
OUTPUT :-
Raw Material Output Qty. Quantity
per kg/ (MT/Day)
diphenols
Product (Hydroquinone) 0.6 39.27
Product (Catechol) 0.4 26.18
Water from phenol solution 0.42548 27.8478
Water from hydrogen peroxide 0.06785 4.44079
Loss of water from phenol solution 0.00868 0.56832
Loss of water from hydrogen peroxide 0.00138 0.09063
Oxygen formed in reaction 0.028 1.8326
Water from extraction (crystallizer) 1.87 122.392
MIBK recovered 0.10843 7.0967
MIBK loss 0.00221 0.14483
Tar 0.22591 14.7857
Total 4.808 314.680

E) Material Balance (With Acetone as a solvent)

INPUT :-
Raw Material Input Qty. in Quantity
Kg per kg (MT/Day)
ofdiphenols
Phenol 1.15 75.2675
Water with Phenol solution 0.43416 28.4161
Hydrogen peroxide (100%) 0.10391 6.80078
Water with Hydrogen peroxide 0.06923 4.53142
MIBK for Extraction 0.11064 7.24153
Water added for crystallization (Fresh) 1.87 122.392
Acetone added for Reaction 0.21 13.74
Total 5.018 328.42
OUTPUT :-
Raw Material Output Qty. Quantity
per kg/ (MT/Day)
diphenols
Product (Hydroquinone) 0.45 29.4525
Product (Catechol) 0.55 35.9975
Acetone Recycled 0.2058 13.46961
Acetone loss 0.0042 0.27489
Water from phenol solution 0.42548 27.8478
Water from hydrogen peroxide 0.06785 4.44079
Loss of water from phenol solution 0.00868 0.56832
Loss of water from hydrogen peroxide 0.00138 0.09063
Oxygen formed in reaction 0.028 1.8326
Water from extraction (crystallizer) 1.87 122.392
MIBK recovered 0.10843 7.0967
MIBK loss 0.00221 0.14483
Tar 0.22591 14.7857
Total 5.018 328.42

2. GUAIACOL AND VERATROLE

Catechol is treated with Methanol in presence of a catalyst, when a mixture of Guaiacol and Veratrole is
formed in Methanol. Methanol is recovered & further fractional distillation is done to separate Guaiacol
and Veratrole.
C) Flow Chart

D) Material Balance
INPUT :-
Raw Material Input in Kg Qty.
per kg of (MT/Day)
Guaiacol
Catechol 1.05 28.000
Methanol 1.88 50.187
Catalyst 0.001 0.033
Total 2.93 78.220
OUTPUT :-
Product Streams Output in Kg Qty.
per kg of (MT/Day)
Guaiacol
Product (Guaiacol ) 1.00 26.667
Co Product (Veratrole) 0.05 1.333
Methanol (Recovered) 1.50 41.041
Water Generated (Waste Water) 0.17 6.747
Evaporation Loss 0.04 1.013
Solid Waste 0.17 1.413
Total 2.93 78.214
3. GUAETHOL AND OTHO DIETHOXY BENZENE

Catechol is treated with ethanol in presence of a catalyst, when a mixture of Guaethol and Ortho
Diethoxy Benzene is formed in ethanol. Ethanol is recovered & further fractional distillation is done to
separate Guaethol and Ortho Diethoxy Benzene.

C) Flow Chart
D) Material Balance
INPUT :-
Raw Material Input in Kg per Qty.
kg of Guathol (MT/Day)
Catechol 1.050 5.250
Ethanol (Fresh) 0.499 2.495
Ethanol (Recovered) 2.50 12.505
Catalyst 0.001 0.005
Total 4.051 20.255
OUTPUT :-
Product Stream Output in Kg per Qty.
kg of Guathol (MT/Day)
Product (Guaethol ) 1.000 5.000
Co Product (orthoDiethoxy Benzene ) 0.050 0.250
Ethanol (Recovered) 2.501 12.505
Total 4.051 20.255

4. TBHQ & D-TBHQ
A) Brief Manufacturing Process

Hydroquinone is reacted with Isobutylene in presence of a Phosphoric Acid & Toluene, when a mixture
of TBHQ and D-TBHQ is formed it is further treated to separate TBHQ and D-TBHQ.
C) Flow Chart

D) Material Balance
INPUT :-
Raw Material Input Qty. in Input Qty.
Kg per kg of (MT/Day)
TBHQ
Hydroquinone 0.706 14.120
Toluene (Fresh) 0.064 1.28
Toluene (Recovered) 3.156 63.120
Phosphoric Acid (Catalyst) 1.600 32.000
Isobutylene 0.394 7.876
Total 5.920 118.396
OUTPUT :-
Product Stream Output Qty. in Output
Kg per kg of Qty.
TBHQ (MT/Day)
Product (Tertiary Butyl Hydroquinone) 1.000 20.000
Co Product (Di-Tertiary Butyl 0.100 2.000
Hydroquinone)
Toluene (Recovered) 3.156 63.120
Phosphoric Acid (Catalyst - Recycled) 1.595 31.9
Total 5.920 118.508
5. VANILLIN
Guaiacol is treated with Glyoxalic Acid in presence of a Sodium Hydroxide & Sulphuric Acid. This
mass is then extracted with toluene to recover untreated Guaiacol. Aqueous layer further treated with
Sodium Hydroxide & Air in presence of catalyst here crude vanillin is obtained; mother liquor
(Aqueous Layer) of this stage is treated to get Sodium Sulphate as byproduct. Crude Vanillin is further
purified in Isopropyl Alcohol & Water; Pure Vanillin is dried and packed.

C) Chemical Reaction

C) Flow Chart
D) Material Balance
INPUT :-
per kg of (MT/Day)
Vanillin
Guaiacol 1.080 21.600
Water 20.8469 416.938
Sodium Hydroxide 2.447 48.940
Glyoxalic Acid (50%) 1.300 26.000
Sulphuric Acid 2.140 42.800
Toluene 1.720 34.400
Cupric Oxide/Cupric Acetate 0.001 0.020
Isopropyl Alcohol 0.471 9.420
Total 30.0059 600.118
OUTPUT :-

Product Stream Output in Kg Qty.

per kg of (MT/Day)
Vanillin
Product (Vanillin) 1.000 20.000
Toluene 1.6856 33.712
Isopropyl Alcohol 0.46158 9.2316
Sodium Sulphate (Byproduct) 2.803 56.06
Cupric Oxide/ Cupric Recovery 0.001 0.02
Water from sodium sulphate (90% 21.44781
Recovery) 428.9562
Solid waste 0.180 3.6
Evaporation loss (solvents) 0.04382 0.8764
Evaporation loss ( Water at sodium 2.38309 47.6618
sulphate recovery)
Total 30.0059 600.118
6.4-METHOXY PHENOL
Hydroquinone is treated with Methanol &para Benzoquinone in presence of a catalyst, when crude
MeHQ is formed in Methanol. Mass is filtered to recover catalyst. Methanol is recovered & further
distillation is done to purify MeHQ which is then flaked and packed.

C) Flow Chart
D) Material Balance
INPUT :-
per kg of (MT/Day)
MeHQ
Methanol ( Fresh) 0.356 2.373
p-Benzoquinone 0.100 0.667
Resin Catalyst 0.001 0.007
Total 3.887 25.915
OUTPUT :-
Product Stream Output in Kg Qty.
per kg of (MT/Day)
MeHQ
Product (4-Methoxy Phenol) 1.000 6.667
Total 3.887 25.917

7. PARABENZOQUINONE
Hydroquinone is treated with Hydrogen Peroxide in presence of Iodine & Methanol, Reaction mass is
crystallized & filtered to get wet para-benzoquinone which is further dried and packed.
C) Flow Chart
Solvent Recovery
& Residue
Separation

D) Material Balance
INPUT :-
Raw Material Input in Kg per kg Qty.
of (MT/Day)
Parabenzoquinone
Methanol (Fresh) 0.04 0.053
Hydrogen Peroxide (50%) 0.746 0.994
Iodine 0.018 0.024
Total 3.764 5.017
OUTPUT :-
Product Stream Output in Kg per Qty.
kg of (MT/Day)
Parabenzoquinone
Product (Parabenzoquinone) 0.950 1.333
Liquid Waste 0.733 0.977
Total 3.764 5.017

ANNEXURE-VII
DETAILS OF WATER CONSUMPTION AND WASTE WATER GENERATION
DETAILS OF WATER CONSUMPTION
Category Water Consumption Remarks

KLD
(A) Domestic 12 -
(B) Gardening 60 R Low TDS treated water from ETP
Plant: 50 KL
Treated water from STP: 10 KL
(C) Industrial -
Process (670) = 240 F+ 430 R Water Recovered from Sodium
Sulphate Recovery: 430 KL
Washing 5 -
Boiler 100 -
Cooling 250 -
Coal Handling 5R High TDS water from Boiler
System Blow down: 5 KL
Plasma System 30 -
Fly Ash 5R High TDS water from Plasma
gasification:5 KL
Industrial Total (1065) = (625 F + 440 R)
Total (A + B + C) 1137 (637 F + 500 R)
1) Total water requirement for the project: 1137 KLD

2) Quantity to be recycle: 500 KLD
3) Total fresh water requirement: 637 KLD
Note- There will be no change in water consumption after EC Amendment.

DETAILS OF WASTE WATER GENERATION
Category Waste water Remarks

generation in KLD
(A) Domestic 10 The domestic effluent is treated in compact
sewage treatment of 10 KLD capacity and the
treated waste water is sent for gardening purpose.
(B) Industrial
770 ( 430 High TDS+ The effluent from process is bifurcated into High
Process 290 Low TDS+ 50 for TDS and Low TDS streams. The high TDS
sodium sulphate stream is sent for Sodium Sulphate recovery,
recovery plant) Where as the low TDS stream is subjected to ETP
plant. 60 KL of treated Effluent from low TDS is
subjected for gardening use and rest is sent to
GIDC, Dahej drainage. 50 KLD sodium sulphate
recovery + 430 recycle into process
Washing 5 The effluent is treated with low TDS stream from
process and Cooling tower.
Boiler 5 The boiler blow down is sent for Coal Handling.
Cooling 62 The effluent is sent for treatment along with low
TDS water from process and washing.
Plasma 5 The effluent is sent directly to fly ash storage area
for sprinkling.
Total 847 (307 to ETP + 490 --
Industrial Recycle + 50 recovery
waste water of sodium sulphate
Total (A + B ) 857 (307 to ETP + 500 Only 307 KLD treated effluent will be sent to
Recycle + 50 recovery GIDC, Dahej drainage.
of sodium sulphate
Note- There will be no change in waste water generation after EC Amendment.

WATER BALANCE DIAGRAM
Total Water Consumption: 1137

KLD (637 KLD (Fresh) + 500
KLD (Recycled))
Water due to Water from Raw

Reaction: 75 Materials: 25
Coal Boiler: Cooling Process: Washi Plasma: Domes Fly Gardening:

handling 100 Tower: 670 ng: 5 30 tic: 12 ash: 60 (10 from
system: 250 5(R) STP + 50
5 (R) Low TDS
Blow Blow Effluent: Effluen Effluent: STP:

down: 5 down: 62 770 t: 5 5 10
High TDS: 480 Low TDS: 357
Recovery Recovery of
of water: Sodium 357 to ETP Plant Low TDS: 50 KLD
430 sulphate:
50
SEZ Part-II, Dahej

Drainage: 307
Recycled

ANNEXURE-VIII
EFFLUENT TREATMENT PLANT
EFFLUENT TREATMENT PROCESS DESCRIPTION
The wastewater coming from different operations (Process, cooling tower, washing) will be segregated
to two different streams such as:
 High TDS wastewater stream.
 Low TDS wastewater stream.
LOW TDS TREATMENT SCHEME
The Low TDS wastewater stream of 357 KLD will be treated in an Effluent Treatment Plant
Comprising of primary, secondary and tertiary treatment.
As depicted in the P & I D [ZTAP061/582/P & I D-01], the Raw Effluent is received in the
Equalization Tank [T-101] via Bar Screen Chamber [BS-101] and Oil & Grease Trap [O&G-101]
Continuous Air is provided in the Equalization Tank [T-101] through Blowers [BL-101 A/B] at the rate
of 150 M3/Hour and Pressure of 0.35 Kg/Cm2 for homogenized mixing of Raw Effluent. Further this
Effluent is pumped through Equalization Transfer Pumps [P-101 A/B] to first Compartment of
Reaction Tank [T-102] known as H2O2 tank, wherein H2O2 is added by the Dosing Pump DP-101
along with H2 SO4 by Dosing Pump [DP-104 A/B] via In-Line-Mixer [LM-101] and FeSO4 [Catalytic
Agent] by Dosing Pump-[DP-103 A/B]. The pH value is lowered to 3.0 to 3.5 by adding H2SO4 for
getting maximum reduction in Phenol and COD of the Raw Effluent.
The acidic effluent over flows to the next compartment of Reaction Tank [T-102] known as
Neutralization Tank where in NaOH is added by the Dosing Pump [DP-102 A/B] to adjust the pH 7.0
to 7.5.
For proper mixing in both the compartments, Agitators [AG-107 & AG-108] have been installed.
Overflow from the Neutralization Tank [T-102] flows to Primary Clarifier [PCLF-101] to settle the
formed sludge. The settled sludge at the bottom is transferred to Sludge Holding Tank [T-110]. The
clarified effluent from Primary Clarifier [PCLF-101]is admitted in to clarified effluent storage Tank
known as Primary Effluent Tank [T-103] from where it is pumped by Primary Transfer Pimps [P-102

A/B] to two stage activated process units comprising of Aeration Tank Stage I [T-104], Secondary
Clarifier Stage I [SCLF-102] Sludge Recycle Pump Stage I Pumps [P-103 A/B] and the Aeration Tank
Stage II [T-105], Secondary Clarifier Stage II [SCLF-103].
The Aeration Tank Stage I [T-104] Stage II [T105] receives air from Blowers BL-102 A/B/C at the rate
of 600 M3/Hr. and Pressure of 0.45 Kg/Cm2
The sludge collected at the bottom of both the Secondary Clarifiers [SCLF-102 & SCLF-103] is
pumped to Sludge Holding Tank [T-110] by the Sludge Recycle Pumps [P-103 A/B] & [P-104 A/B]
and also recycled to respective Aeration Tanks as per requirement.
The overflow of Aeration Tank Stage II [T-105] is taken to Secondary Clarifier Stage II [SCLF-103]
and the clarified effluent is transferred to Filter Feed Tank [T-106] The clarified/treated effluent is
pumped from Filter Feed Tank [T-106] and forced to flow through Pressure Sand Filter [PSF-101]
and Activated Carbon Filter [ACF-101] by the Filter Feed Pump [P-105 A/B] where suspended solids
are removed and also the part COD. The clarified effluent from Activated Carbon Filter [ACF-101] is
used to back wash both the Filters
The treated effluent now is finally received in Chlorine Contact Tank [T-108] where balance COD is
also removed and overflows to Treated Water Tank [T-109] from where this treated effluent is
disposed by Pumps [P-107 A/B] to the common effluent disposal system of SEZ-GIDC.
The Sludge collected at Sludge Holding Tank [T-110] is pumped to Filter Press [FP-101] by Filter
Press Feed Pumps [P-108 A/B] and the Filtrate is collected in the Filtrate Tank [T-111] from where the
same is pumped back to Equalization Tank [T-101] by the Filtrate Transfer Pumps [P-109 A/B]. The
dewatered Sludge is transferred to Sludge Drying Area for further disposal as appropriate.
DESIGN DATA OF EFFLUENT TREATMENT PLANT

Sr. No Description Volume Nos. MOC
1. BS-101 BAR SCREEN 1.8 m3 1 RCC + Epoxy
CHAMBER
2. O & G -101 OIL & GREASE 16.2 m3 1 RCC + Epoxy
TRAP
3. T-101 EQUALIZATION TANK 400 m3 1 RCC + Epoxy
4. T-102 A H2O2 TANK 62 m3 1 RCC + AR Tilling
5. T-102 B NEUTRALIZATION 62 m3 1 RCC + AR Tilling
TANK

Sr. No Description Volume Nos. MOC

6. PCLF-101 PRIMARY 45 m3 1 RCC
CLARIFIER -1
7. T-103 PRIMARY TREATED 18 m3 1 RCC
EFFLUENT TANK
8. T-104 AERATION TANK-1 350 m3 1 RCC
9. SCLF-102 SECONDARY 45 m3 1 RCC
CLARIFIER STAGE I
10. T-105 AERATION TANK-2 1030 m3 1 RCC
11. SCLF-103 SECONDARY 45 m3 1 RCC
CLARIFIER STAGE II
12. T-106 FILTER FEED TANK 22 m3 1 RCC
13. T-107 BACKWASH TANK 45 m3 1 RCC
14. T-108 CHLORINE CONTACT 72 m3 1 RCC
TANK
15. T-109 TREATED WATER 180 m3 1 RCC
TANK.
16. T-112 BUFFER TANK 98 m3 1 RCC
17. T-110 SLUDGE HOLDING 4 m3 1 RCC
TANK
18. T-111 FILTER PRESS 5.0 m3 1 RCC
FILTRATE TANK
19. FILTER PRESS SHED - 1 RCC/MS
20. BUILDING FOR MCC ROOM - 1 RCC/MS
AND CHEMICAL HOUSE
CHERICTERISTIC OF EFFLUENT TREATMENT PLANT

Sr. No. Parameter ETP Inlet ETP Outlet Result
1 pH 7.9 5.5-9.0
2 COD 1700-1800 250
3 BOD 500-600 100
4 TSS 100-200 100
5 TDS 100 --

ETP Flow Diagram

HIGH TDS TREATMENT SCHEME

The high TDS wastewater of 480 KLD is treated in sodium sulphate recovery plant. 9-10% Neutral
Sodium sulphate solution is filtered to remove any solid impurities. It is then evaporated to a
concentration of about 30% in multiple effect evaporator. The concentrated solution is cooled by
evaporative crystallization to 10-15 C. Glauber salt (Na2SO4.10H2O) crystals are formed and they are
centrifuged.
The depleted solution goes to mother liquor tank and the solid crystals go to a melter where the crystals
are heated to 50-70oC to melt them and slurry of anhydrous crystals is formed. The hot slurry is
centrifuged to obtain anhydrous sodium sulphate. The mother liquor is recycled. The sulphate crystals
are dried and packed.
The condensate obtained during evaporation can be recycled back to the process. There are no
inorganic impurities in it. There is no liquid effluent from the process.
Note: The cooling water circulation rate may be about 1500 m3/hr.
Large amount of cooling water has to be circulated and the blow down will be an effluent. Fresh
makeup water is also required. This can be reduced considerably by using air cooled condensers.
The sodium sulphate generated is market grade and the chemical properties are given below.
CHEMICAL PROPERTIES OF SODIUM SULPHATE
Properties of commercial Properties of isolated sodium sulfate
Sodium Sulphate
Chemical Na2SO4 Na2SO4
Formula
Molar mass 142.04 g/mol
Appearance White Crystalline Solid White to off white crystalline solid
Odor Odorless Odorless
Density 2.664 g/cm3 2.663 g/cm3
Melting Point 884°C --
Boiling Point 1429°C --
Solubility in 13.9 g/100 mL (20°C) 13.9 g/100 mL (20°C)
water
% purity 99.1 % 99.15%

SODIUM SULPHATE RECOVERY PLANT DIAGRAM
CW
Condenser
Condenser
Air or water
cooled Condensate
for recycle Steam Steam
Feed Evaporation Vaccum Glauber salt Glauber salt Anhydrous Sodium Storage
Evaporative Centrifuge Melter Centrifuge sulphate dryer
cooler/crystallizer
Steam
Mother
liquor

The recovered effluent is 430 KLD from sodium sulphate recovery plant.
WATER QUALITY FROM SODIUM SULPHATE RECOVERY
Sr. Parameters Water quality Water quality
No. needed for obtained from
Vanillin Plant recovering
Sodium Sulphate
1. pH 6.5-8.5 6-8
2. Total dissolved solids 394 mg/l 71 mg/l
3. Total suspended 110 mg/l 5 mg/l
solids
4. COD 21 mg/l 50 mg/l*
5. Hardness 212 mg/l 38 mg/l
*the value of COD will not impact the product quality or quantity as the recovered water
will be used in same product from where it is generated.
SEWAGE TREATMENT PLANT
PROCESS DESCRIPTION
After primary treatment the sewage water of 10 KLD from domestic purposes enters the “Biocask
treatment”. Fluidized Aerobic Bioreactor (FAB) is the latest technology in the aerobic wastewater
treatment field in which feed enters in the CSTR along with air bubbling at the bottom which tends to
mix the biomass with feed and gives degradation of organics. After bubbling the air at the bottom it
moves upward and trying to escape in the atmosphere as early as possible, due to which it provides
very less contact time with organics and hence low rate of oxygen transfer and efficiency.
The system adopted has much less moving parts (only pumps and blowers). Further there is no moving
part inside the bio-reactor. This gives the advantage of continuously running the bio-reactor system,
under widely fluctuating conditions. All the pumps / blowers are manufactured in India only, and hence
there is no problem of availability of spares. All the maintenance on the mechanical systems can be
done with normal skilled mechanics available. During monsoon this 10 KLD of water will be used for
washing purposes.

ANNEXURE-IX
DETAILS OF HAZARDOUS WASTE GENERATION & DISPOSAL
Catego Quantity
ry and (MT/Annum)
Type of Schedu Existi Prop Total
Sr. Source of
Hazardous le as ng osed Disposal Method
No. generation
Waste per
HW
Rules.
1. Discarded From Raw 33.1 3 -- 3 Collection,
Carboys of Material Decontamination within
Phosphoric Consumption company premises,
Acid transportation and send
to authorize recyclers.
2. Discarded From Raw 33.1 31 -- 31 Collection,
Barrels Material Decontamination within
Consumption company premises,
transportation and send
to authorize recyclers.
3. Discarded From Raw 33.1 6.3 - 6.3 In house gasification
Bags & Material
Liners Consumption
4 Spent Process 28.1 5.5 -- 5.5 In house gasification or
Carbon send to cement industries
for co processing.
5 Spent Waste Water 28.3 165 -- 165 In house gasification or
Carbon Treatment send to cement industries
from ETP Plant for co processing.
6 Spent Process 28.2 1245.6 -- 1245.6 Collection, storage,
Catalyst (Guaiacol, 4 4 transportation and
Guethol, disposal at TSDF site.
TBHQ)
7 Distillation Process 20.3 8770.8 -- 8770.8 In house gasification or
Residue (Guaiacol, 5 5 send to cement industries
Guethol, for co processing
TBHQ,
Vanillin, 4-
Methoxy
Phenol, Para
Benzoquinone
)
8 Used/Spent Lubrication, 5.1 5.5 -- 5.5 Collection, storage,
Oil Maintenance transportation and
of Gears & disposal by Sending to
Motors Registered Refiners.

9 Sodium Product -- 13750 -- 13750 Will be sold to the actual

sulphate (Vanillin) end users who are
authorized to receive the
Sodium sulphate as a raw
material.
10 ETP sludge Waste Water 35.5 -- 210 210 Collection, storage,
Treatment transportation and
Plant disposal at TSDF site.

ANNEXURE-X
ELECTRICITY & FUEL CONSUMPTION
Sr. Particulars Remarks

No.
FUEL
1. Type of Fuel Imported Coal
2. Consumption rate 150 MT/Day
3. Source of supply local purchase
ENERGY
1. Type of Energy Electricity
2. Connected Load 4.4 MW
3. Source of supply Captive power plant of 4.4
MW and Backup power
from Torrent power

ANNEXURE-XI
DETAILS OF STACK AND VENTS
FLUE GAS EMISSION
Sr. Stack Attached Stack Stack Stack Stack Exit Fuel Air Pollution Type Permissible
No. To Height Diameter exit gas gas Consumption Control of Limit
Velocity temperature System Emission
in(OC)
1. Boiler
Cyclone PM 150
(50 TPH) &
Imported Coal separator mg/NM3
Thermo pack 45 m 1.4 m 7 m/s 160
: 150 MT/Day followed by SO2 100 PPM
(10 million
E.S.P. NOx 50 PPM
Kcal/Hr.)
Note- There will be no change in Flue gas emission after EC Amendment.
PROCESS EMISSION
Sr. Stack Attached Stack Stack Stack exit gas Stack Exit gas Air Pollution Type of
No. To Height diameter Velocity temperature Control Emission
(m) System
1. Diphenol Plant 15 m 0.6 3 m/s Ambient temp Water scrubber VOC
followed by
2. Vanillin Plant 15 m 0.6 3 m/s Ambient temp Carbon VOC
adsorption
tower.
3. Guaiacol Plant 15 m 0.6 3 m/s Ambient temp VOC
4. TBHQ Plant 15 m 0.6 3 m/s Ambient temp VOC

5. MeHQ Plant 15 m 0.6 3 m/s Ambient temp VOC
6. Para 15 m 0.6 3 m/s Ambient temp VOC

Benzoquinone
Plant
7. Storage Area 15 m 0.6 3 m/s Ambient temp VOC
8. Plasma 20 m 0.6 6 m/s 120-140 Hot Gas Filter HCl, SO2, CO,
Gasification TOC, HF, NOx,
Total dioxins and
furans
Note- There will be no change in Process gas emission after EC Amendment.

ANNEXURE-XII
LIST OF HAZARDOUS CHEMICAL
Sr. Name of Chemical

No.
1. Phenol
2. Hydrogen Peroxide (H2O2)
3. Methanol
4. Phosphoric Acid
5. Toluene
6. KOH

ANNEXURE-XIII
DETAILS OF PLASMA GASIFICATION SYSTEM
The proposed waste disposal plant will consist of four (4) Plasma Reactors (PR) each capable
of processing 7.5 Ton/day of waste (at the rate of 4 x 375= 1500 kgs/hr). Each reactor will be
fitted with 3 nos of each of 100 kW (Subject to change during final configuration) non-
transferred arc plasma torch system. The waste will be shredded to a size that will facilitate
feeding of the waste in front of the plasma torch. The inorganic component of the waste will
be melted during this process and will be removed from the bottom of the PR as slag. The
synthesis gas (syngas) that is produced by the PR will consist predominantly of carbon
monoxide (CO) and hydrogen (H2). In addition to CO and H2, syngas which will exit from
PR will also consist of carbon particles and other pollutants in traces. Thus syngas from PR
will be treated in downstream syngas cleaning system consisting of hot gas filter.(In case of
Camlin, there would be no chlorine or sulphur in Syn gas since distillation residue (waste)
does not contain any chlorine or sulphur). Downstream ID Fan is provided to overcome
pressure drop across the entire system and to maintain negative pressure in PR. Clean Syngas
from ID Fan is collected in a Syn gas tank from which it can be used as a fuel for steam
generation in a syn gas fired boiler. Flue gas from syn gas boiler is passed through Bag Filter
for polishing treatment to final exhaust gas. Flue gas after bag filter is vented through stack.
Inorganic content in the PR is collected at vitrified slag from the bottom of PR which can be
used for land fill or for construction material. Details of major equipments are listed below.
LIST OF EQUIPMENT AT PLASMA SYSTEM

SR
NO NAME OF EQUIPMENT QTY.
1. DC Plasma Torch in Each Reactor 3
2. IGBT DC Power Supply 3
3. DC Plasma Reactor Shell 1X3
4. Reactor Refractory and crucible 1X3
5. Slag Tanks 2
6. Waste Slat Chain Conveyor 1
7. Waste Double Door Hopper 1

8. Waste Crusher 1
9. Waste Screw Feeder 1
10. Waste Valve 1
11. Structural work for DC Reactor 1
12. Everest Roots Blower with VFD 1
13. Water ring Vaccum for Starting Evacuation 1
WHRB boiler, D-Type Water Tube Boiler incl.
14. Economiser and Bag filter 1
15. Water tube oxygen fed boiler for CO2 generation 1
16. Oxygen generator and CO2 dryer 1
17. O2 and CO2 storage tanks 2
18. Emission Monitor incl. CO and H2 detector 4
19. PLC control and instrumentation 1
20. Stack 15 M height 1
ACCESSORIES
1. Oxygen, Carbon-di-Oxide and steam piping --
2. Ducting for Syngas and also flue gas --
3. Electrical distribution panel and wiring --
4. Drain valves --
5. Carbon-di-Oxide booster pump --
Cooling water system, water pumps, HDPE
6. piping, and SS valves --
7. Cooling Tower --
8. Pressure relief valve for reactor and slag tanks --
The design basis of gasification system is provided in table below. The waste characteristics
and operation (plasma technology) are given in table below.
DESIGN BASIS OF PLASMA GASIFICATION PLANT CAPACITY

Sl. DESCRIPTION CAPACITY
No.
1 Capacity of Plant, TPD 30 TPD
2 Design feed rate of waste, kg/hr 1500/ kg/hr
3 Design Feed Calorific Value of Avg 6,325 Kcal/kg
Waste
4 Syn Gas Utilization Steam Generation at boiler

WASTE CHARACTERISTICS
SR. DESCRIPTION
CHARACTERISTICS
NO.
Physical Form (Solid/Semi
1 Solid
Solid/sludge/liquid)
2 Feed Rate, kg/hr 1500
3 Design Calorific Value (Kcal/kg) Avg. 6325 kcal/kg
4 Bulk Density, kg/m3 100- 300
5 Waste Packing as received at site In Bulk
6 Typical Ultimate Analysis, % by wt
A Carbon as C 74.5
B Hydrogen as H 5.00
C Oxygen as O 19.7
D Nitrogen as N Nil
E Sulfur Nil
F Chlorine Nil
G Water as H2O 0.3
H Inorganic 0.5
I Hg, Cd, etc volatile heavy matter, ppm Nil
Total 100
7 Flash Point, 0C 150 0C
8 Boiling Point, 0 C More Than 350 0C

OPERATION (PLASMA TECHNOLOGY)

Plant internal power consumption 1500kW
Plasma Torch 3 x 5 x 100 kW (15nos)
Continuous Operation Approx. 20 Hrs per day
Approx. 300 days/Year
 Typical Syngas Flow Rate and Composition:

 CO = 2386 kgs/hr (93.3 wt%)
 H2 = 170 kgs/hr (6.7 wt%)
 Total = 2556 kgs/hr
 Volume flow rate will typically be 3817 Nm3/hr, with about 50 vol % each of CO
and H2.
 Syngas will be carried in a pipe of approx dia 500 mm from reactors to the boiler
 DETAILS OF SYN GAS STORAGE FACILITY:
The plasma unit will generate syn gas. After cleaning the syn gas, it will be stored in syn gas
storage tank as a buffer before feeding to boiler. The details of syn gas storage tank are
provided in below table.
SYN GAS HOLDER

1 Type Vertical cylindrical vessel
2 Duty To allow dampening of syn gas pulsation to
provide linear gas from to syn gas utilization
system
3 Syn Gas Flow Nm3/hr Operating: 1920
Design: 2400
3 Operating Temperature 50 deg C
4 Operating / Design 100 mmwc g / 2 kg/cm2 g
Pressure
5 Pressure Drop NA
6 Tank Volume 6,000 Litres

7 Quantity 1
8 Dimensions Shell Diameter 1,600 mm
Shell height 3,000 mm
9 End Dished end type
10 Material of Construction Shell and Dish: 6 mm thk SA516 Gr 70 steel
11 Support Supported on lugs provided from shell of
vessel
12 Note Bottom drains point to be provided for
removal of moisture from gas.
 SAFETY MEASURES PROVIDED AT SYN GAS STORAGE:
1. Tank is provided with emergency vent which is activated through a pressure relief valve. On
High set Point of pressure which exceeds 2 kg/cm2g, emergency vent opens and reduces the
pressure of tank to low pressure set point to less than 2 kg/cm2g. The excess Syn gas is vented
through flare provided in the plant to the stack.

\ ANNEXURE - XIV CTE Copy
GUJARAT POLLUTION CONTROL BOARD
PARYAVARAN BHAVAN
~ ,.,,.,. Sector 10-A, Gandhinagar 382 010

Phone
Fax
: (079) 23226295
(079) 23232156
GPCB Website: www.gpcb.gov.in
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PARYAVARAN BHAVAN
Sector 10-A, Gandhinagar 382 010
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150-9001-2008 & ISO-14oo1 - 2004 Certified Organisation
PARYAVARAN BHAVAN
Phone (079) 23226295
Fax (079) 23232156
GPCB Website: wwwgpcb.gov.in
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180-9001-2008 & 150-14001 - 2004 Certified Organisatkln
PARYAVARAN BHAVAN
Phone : (079) 23226295
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Website: www.gpcb.gov.in
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ISO-9001-2008 & IS0-14oo1 - 2004 Certified Organisation
PARYAVARAN BHAVAN
Sector lO-A, Gandhinagar 382 010
Phone : (079) 23226295
Fax . (079) 23232156
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180-9001-2008 & 180-14001 - 2004 Certified Organisation
PARYAVARAN BHAVAN
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ISO-9001-2008 & ISO-14oo1 - 2004 Certified Organisation
PARYAVARAN BHAVAN
Phone : (079) 23226295
Fax: (079) 23232156
01
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GUJARAT POLLUTION CONTROL BOARO
PARYAVARAN BHAVAN
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Phone
Fax:
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ISO-9001-2008 & 180-14001 - 2004 Certified Organisation
PARYAVARAN BHAVAN
Phone . (079) 23226295
Fax: (079) 23232156
01
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ISO-9001-2008 & 150-14001 - 2004 Certified Organisation

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M/S. CAMLIN FINE SCIENCES LTD.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 1

16. Details of alternative sites examined, No alternate site is examined.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 2

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 3

operational workers? purpose only.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 4

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 5

(flora, fauna, and water supplies)

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 6

Sr. Information / Checklist Yes / Details thereof (with approximate

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 7

performed during the day only.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 8

• Supporting infrastructure (roads,

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 9

2 Areas which are important or No The Narmada estuarine zone is

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 10

Signature of the applicant

2. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 11

PROPOSED TERMS OF REFERENCE

 Standard TOR of MoEF&CC for organic sector will be followed.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 12

Sr. Name of Directors Address & Contact Details

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 13

Sr. Name of Directors Address & Contact Details

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 14

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 15

M/s. Camlin Fine Sciences Ltd.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 16

LIST OF PRODUCTS WITH THEIR PRODUCTION CAPACITY

Sr. Name of Products Proposed Proposed IUPAC Chemical

*This is a continuous plant and it will run for 11 months in a year.

Note- There will be no change in product profile after EC Amendment.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 17

LIST OF RAW MATERIALS

Sr. Product Production consumpt

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 18

7. Para 36.36 Hydroquinone 1.05

Note- There will be no change in raw material consumption after EC Amendment.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 19

1. DIPHENOL (HYDROQUINONE & CATECHOL)

A) Brief Manufacturing Process:

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 20

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 21

D) Material Balance (With Water as a solvent)

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 22

E) Material Balance (With Acetone as a solvent)

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 23

2. GUAIACOL AND VERATROLE

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 24

3. GUAETHOL AND OTHO DIETHOXY BENZENE

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 25

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 26

4. TBHQ & D-TBHQ

A) Brief Manufacturing Process

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 27

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 28

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 29

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 30

Product Stream Output in Kg Qty.

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 31

M/s. Jyoti Om Chemical Research Centre Pvt. Ltd. 32