Iwa Mpt-1 - Chemistry - Que. & Sol.

PART – B
SECTION – 1 : (Maximum Marks : 80)

 This section contains TWENTY (20) questions.
 Each question has FOUR options (1), (2), (3) and (4) ONLY ONE of these four option is correct
 Marking scheme :
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases
  
31. Write the structure of alkane (MM = 72) having 1, 2,&3 carbon atoms
H3C  CH  CH2  CH3 CH3  CH  CH  CH2  CH3
(1*) | (2) | |
CH3 CH3 CH3
CH3  CH2  CH2  CH2  CH3

(3) CH3  CH2  CH2  CH2  CH3 (4) |
CH2
|
CH3
32. Give IUPAC name of

Me Et
(1) 2-ethyl-4-methyl pentane (2) 2-methyl-4-ethyl pentane

(3) 2, 4-Dimethyl pentene (4*) 2, 4-Dimethyl hexane
33. Bohr's theory is not applicable to :

(1) H (2) He+ (3) Li2+ (4*) H+
34. The correct expression for the energy of an electron in the nth energy level is for H-atom is :
2 2me 4K 2   2me 4K 2
(1) En  (2) E n 
n 2h 2 2n2h2
 2 me K
2 2 2
 2 2me 4K 2
(3) En  (4*) E n 
n 2h 2 n 2h 2
Sol. Theory based
35. Rearrange the following (I to IV) in the order of increasing masses :

(I) 0.5 mole of O3 (II) 0.5 mol of oxygen atoms
23
(III) 3.011 × 10 molecules of O2 (IV) 0.25 mole of CO2
(1*) II < IV < III < I (2) II < I < IV < III (3) IV < II < III < I (4) I < II < III < IV
36. The number of sodium atoms in 2 moles of sodium ferrocyanide (Na4[Fe(CN)6]) is

(NA = 6×1023) :
(1) 12 × 23 (2) 26 × 1023 (3) 34 × 1023 (4*) 48 × 1023
37. What is the total number of 2° Hydrogen atoms present in the given compound ?
(1*) 10 (2) 18 (3) 5 (4) 6
Reg. / Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
®
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
CIWAMPT102052021-1
Toll Free : 1800 258 5555 | CIN : U80302RJ2007PLC024029
38. 360 amu of Glucose (C6H12O6) contains :
(1) 2 moles of glucose molecules (2) 20 hydrogen atoms
(3) 12 moles of carbon atoms (4*) 2 glucose molecules
39. CH3–CH=CH–CCH has IUPAC name :

(1) Pent-2-ene-4-yne (2) Pent-4-yne-2-ene
(3) Pent-1-yne-3-ene (4*) Pent-3-ene-1-yne
40. The correct IUPAC name of following compound is :
(1) 1,3-Dihydroxypropane-1,3-diol (2) 2-formyl-3-Hydroxypropanoic acid

(3*) 3-Hydroxy-2-oxopropanoic acid (4) 2,3-Dioxopropane-1,3-diol
Sol.
3-Hydroxy-2-oxo propanoic acid
41. 0 and  are the threshold wavelength and wavelength of incident light respectively. The maximum
velocity of photo-electrons ejected from metal surface is:
2h 2hc 2hc   0 –   2h  1 1 
(1) ( 0 –  ) (2) ( 0 –  ) (3*)   (4)  – 
m m m   0  m   0  
Sol. As per Einstein's equation of photoelectric effect:
h = h0 + K.E.
1 2 hc hc
mv = h – h0 = –
2  0
1/ 2
 2hc   0 –  
v=   
 m   0 
42. Photons of frequency  are incident on metal surface having threshold frequency v 0, then
(1) All ejected electrons have the same kinetic energy ( h – h 0 )
(2) The most energetic electron have kinetic energy h
(3) The average kinetic energy of ejected electrons is ( h – h 0 )
(4*) The ejected electrons have a range of kinetic energy from zero to ( h – h 0 )
Sol. Maximum K. E. = h – h 0
Range of K.E. = 0 to K.E max.
(i.e. 0 to ( h – h 0 ))
43. Which pair of the following compound does not belong to same homologous series?
(1) and
(2) CH3–CH–COOH and CH3–CH2–CH2–COOH
O O
(3*) CH3 – CH2 –C– H and CH3 – CH2 – C – CH3
(4) and
®
CIWAMPT102052021-2
44. Correct IUPAC name for H3C–CH–CH–CH3
H5C2 C2H5
(1) 2-Ethyl-3-methylpentane (2*) 3, 4-Dimethylhexane
(3) 2-Sec-butylbutane (4) 2, 3-Dimethylbutane
45. Which graph shows how the energy E of a photon of light is related to its wavelength (  ) ?
(1) E (2) E
 
(3) E (4*) E
 
Sol. E
hc  E 1
 
46. The average molar mass CO2 & N2O can be

(1) 22 (2*) 44 (3) 46 (4) data is insufficient
47.
What is/are correct about the given structure?

(I) It has six D.U. (II) It has ten Sp2 hybrid C-atom
(III) It has ten Sp2 – Sp2 C – C  bond (IV) It has five   bond
(1) I, II only (2) I, II, III only (3) I, III, IV only (4*) Alll of these
48. Molecular formula of naphthaquinone
(1) C12H8O2 (2) C11H6O2 (3*) C10H6O2 (4) C10H8O2
49. 8 g of O2– ion has amount of charge equal to : (NA = 6.02 × 1023, e = – 1.6 × 10–19 C)
1
(1) 5 NAe (2) 2 NAe (3*) NAe (4) Ne
2 A
®
CIWAMPT102052021-3
50. For Selenium (Z = 34) how many electrons are present with magnetic quantum number= 2 ?
(1) 20 (2) 4 (3*) 2 (4) None of these
34 Se  [ Ar ]3d , 4s p
10 2 4
Sol.
SECTION – 2 : (Maximum Marks : 20)

 This section contains TEN (10) questions. The answer to each question is NUMERICAL VALUE with two
digit integer and decimal upto one digit. Candidates have to attempt any FIVE questions out of TEN.
 If the numerical value has more than two decimal places truncate/round-off the value to ONE decimal
placed.
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : 0 In all other cases
51. What is the total number of 2° Hydrogen atoms present in the given compound ?
Ans : 10.0
52. Maximum of how many quantum numbers can be different for any two electrons in the ground state
configuration of Na?
Ans : 04.00
Sol. This result follows from Pauli's exclusion principle.
1
53. Calculate the maximum total number of electrons in 31Ga, with spin  and which occupy orbitals
2
having minimum one radial node.
Ans : 07.00
54. Sum of moles of oxygen and hydrogen atoms in 1/2 mole of H2SO4 will be
Ans: 03.00
55. Calculate the degree of unsaturation (DU) at the given compound
Ans : 06.00
56. The number of de-Broglie waves made by a Bohr electron in an orbit of maximum magnetic quantum
number 3 is –
Ans : 04.00
Sol. No. of de-Broglie waves = n (Orbit number)
If mmax = 3
max = 3
n=4
57. What is the mass of carbon present in 0.5 mole of K4[Fe(CN)6]?

Ans : 36.00
Sol. 1 mole K4[Fe(CN)6] contain = 6 × 12 = 72 g carbon
0.5 mole K4[Fe(CN)6] contain = 72 × 0.5 = 36 g carbon
®
CIWAMPT102052021-4
58. A person adds 1.71 gram of sugar (C12H22O11) in order to sweeten his tea. The number of carbon atoms
added are y × 1022. Find the value of y - (molecular mass of sugar = 342, NA = 6×1023)
Ans : 03.6
59. In a sample of Na2CO3 .10H2O, 0.12 g of carbon is present, then find the ratio of moles of water
molecules to moles of sodium ions.
Ans : 05.0
60. Total number of nodal plane in px orbital is:

Ans : 01.00
Sol. yz plane
®
CIWAMPT102052021-5

Iwa Mpt-1 - Chemistry - Que. & Sol.

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Iwa Mpt-1 - Chemistry - Que. & Sol.

Uploaded by

Copyright:

Available Formats

PART – B

SECTION – 1 : (Maximum Marks : 80)

CH3  CH2  CH2  CH2  CH3

32. Give IUPAC name of

(1) 2-ethyl-4-methyl pentane (2) 2-methyl-4-ethyl pentane

33. Bohr's theory is not applicable to :

35. Rearrange the following (I to IV) in the order of increasing masses :

36. The number of sodium atoms in 2 moles of sodium ferrocyanide (Na4[Fe(CN)6]) is

(1*) 10 (2) 18 (3) 5 (4) 6

39. CH3–CH=CH–CCH has IUPAC name :

40. The correct IUPAC name of following compound is :

(1) 1,3-Dihydroxypropane-1,3-diol (2) 2-formyl-3-Hydroxypropanoic acid

3-Hydroxy-2-oxo propanoic acid

(2) CH3–CH–COOH and CH3–CH2–CH2–COOH

46. The average molar mass CO2 & N2O can be

What is/are correct about the given structure?

48. Molecular formula of naphthaquinone

(1) C12H8O2 (2) C11H6O2 (3*) C10H6O2 (4) C10H8O2

SECTION – 2 : (Maximum Marks : 20)

55. Calculate the degree of unsaturation (DU) at the given compound

57. What is the mass of carbon present in 0.5 mole of K4[Fe(CN)6]?

60. Total number of nodal plane in px orbital is:

You might also like