For Ba(N01h-8ertum Ntrm

AIM-To analyze the given salt fOf' one anion and one c.1tion presmt in it_

Material reqwed - Boihns tubes, test tubes, test tube holder, test t ~ stand, delivery tube, corks, filter
papers, reasmts
Prcllmlnlry tests

Colour at the salt -white, lustrous crystals

Smell (Odour) - Odourless

Solublllty- Soluble n water

Dry Helltlnc Tnt - Brown fumes are evolved, CoUect the fumes in test tube and add Freshly Prepared FeSO,
Solution - Colour becomes Bladt

Flame tat (Paste of salt with-. HCJJ - Crimson red flame

ForaddkrlldlQI-

S.No. uperlment
1. Observation lnferax:e
Treated 0.1 g of salt with 1 mt dilH,SO, and
w=d No effervescence and c0s,. _. soi,..., s2- ,
No,-
2. evolution al vapours. , Of,COO- absent.
Heated 0.1 g of s.ilt with 1 ml cone. H,SO, Brown fumes are No,- Maybe
3. evolved
On heating the reaction minure after addition of Brown Fumes become
copper turnings NO, - Confirmed
derue
And the colour of
4. solution changes to blue
Take salt solution in a test tube and add small
amount of diphenylamine Deep blue colouration is No,- Confirmed
5. obtained
Take aqueous solution of salt and add 'Sfflall
Brown ring appeared on NO,- Confirmed
quantity of freshly p.repared FeSO~ solution add
small quantity of cone.. H,SO, the junction of liquids

For Basic Radical -

S.N o. Experiment
1. Observ.t1on Inference
Heated 0.1 e of salt with 2 ml NaOH solution
No smell is obtained Ntt.• Absent (Zero
2. Oiswlve the salt in di! . HCJ Group absent)
3. Passed H,S gas throueh No precipitate formed Group-I Absent
one portion of the No precipitate formed
solution Group-II Absent
4.
Heat with cone. HNO,, Add about 0.2 8 of solid
ammonium chloride and then added excess of No precipitate formed Group--111 Absent
ammonium hydroxide to the solution
5. Paned H,S gas through the above solution
6. No precipitate formed
Add Ammonium chloride In salt solution and heat Group-IV Absent
White precipitate Group-v P~nt
then add l!Xcess of ammonium hydroxide solution
formed
 to the orisinal solution and then added 05 8 of
ammonium carbonate
7. Dissolve the white precipitate by boilins with White precipitate Is oa•2 Confirmed
dilute acetic acid and divide the solution into obtained
three parts
•To the first part add ammonium sulphate
8. Potassium Chromate test - Dissolve die white 'fellow precipitate is ea•2 Confirmed
precipitate by boiAns with dilute acetic acid. then formed
add small quantity of pot:assium chromate
sohnion

Note - Preserve a small amount of the precipitate for flame test.

Result-
The given salt contains-Anionic Radical - N01- 2 &.Cationic Radical - Ba •J

And the formula of sett will be - Ba(NOJ)2

Reactions for Nitrate Ion -

N01 - + H1SO, HSO,- + HN01 (Vapours)

4HN03 + Cu Cu(NOJh + 2N02 (Brown Vapours)

6Feso. + 3H2SO• + 2HN03 3F~(S04h + 4H 20 + 2NO

FeS04 + NO + SH20 (Fe(NO)(H20h)S04 (Brown Ring)

Reactions for Barium Ion -

Ba• 2 + NH, C01 BaC01 (White ppt.) + NH..'

BaC03 + 2CH 3COOH (CH1COO)i8a + H20 + CO2

Ba• 2 + K2Cr0• BaCrO. (Yellow ppt.) + 2K'