11 Chemical Equilibrium Solution

SOLUTION : CHEMICAL EQUILIBRIUM
EXERCISE # S-I
11 1
1. (a) QC = 2
= = 25
(0.2) 0.04
QC > KC , backward shift
2  (1)2 2
(b) QP = 2
=
(3) 9
QP < KP , forward shift
11
(c) QP = =
1
QP < KP , forward shift
(d) Since initially only reactants are present, so reaction will shift to forward
2. If K is large. Then tendency of reaction to convert in product will be more
Kf
3. KC =
Kb
Kf
4. KC =
Kb
5. (i) Amount if  formed = 2 × amount of A reacted

 n=2
 2B
(ii) A 
[B]2 (0.6) 2
K= = = 1.2
Nucleus Education-(NURTURE_(UNACADEMY)
[A] 0.3
6.  2NO(g)
N2(g) + O2(g)  KC = 0.5×10–9
 N2(g) + O2(g) 1

2NO  KC = 9
= 2×109
0.5 10
7.  ClF(g) + F2(g)

ClF3(g) 
Pi 0.15 0 0
Peq 0.15 – x x x
x2
0.2 =
0.15  x
x = 0.01
C.O.: NAIVEDHYAM, Plot No. SP-11, Old INOX, Indira Vihar, Kota (Raj.) 324005 Phone: 0744-2799900 Online Partner UNACADEMY 52
8.  PCl3 (g) + Cl2 (g)
PCl5 (g) 
Ceq 0.5×10–3 1.5×10–2 3×10–2
1.5 102  3 102
KC = = 0.9
0.5 103
9.  2HI(g)
H2(g) + I2(g) 
Ci 0 0 4.8×10–3
–3
Ceq 0.4×10 0.4×10–3 4×10–3
(4 103 )2
KC = = 100
0.4 103  0.4 103
10. KP = PH O = 0.2463
2
KP = KC(RT)2
0.2463
KC = = 0.01
0.0821 300
11. If KC is very large, extent of reaction is almost 100%.
12.  2O3 (g) KC = 8×10–55

3O2 (g) 
Ceq 8×10–3 x
x2
8×10–55 =
(8 103 )3
x2 = 8×10–55 × (8)3 × 10–9
x2 = (8)4 × 10–64
x = 64 × 10–32
13.  2C
A + B 
ni 2 3 0
neq 2–x 3–x 2x
4x 2
4=
(2  x)(3  x)
x = 1.2
14.  CS2(g) + 4H2(g)

CH4(g) + 2H2S(g) 
3 4 3 3
0.3  (0.3) 4
QC =
0.3  (0.4) 2
8110 4 81
= 2
= ×10–2
16 10 16
15.  CO(g) + 3H2(g)
H2O(g) + CH4(g) 
0.03 M 0.05 M 0.15 M 0.2 M
0.15  (0.2) 3
QC = = 0.8
0.03  0.05
QC < KC , forward shift
16. N2(g) +  2NH3(g)

3H2(g) 
0.036 M 0.15 M x
2
x
0.29 =
0.036  (0.15)3
x = 5.9×10–3
17.  2NO(g)

N2(g) + O2(g) 
Ci 1.5 1.5 0
Ceq 1.5–x 1.5–x 2x
(2x) 2
KC = = 16
(1.5  x)(1.5  x)
2x
=4
(1.5  x)
x=1
18.  PCl3(g) + Cl2(g)

PCl5 (g) 
Ci 0.1 0 0
Ceq 0.1–x x x
x2
= 10–2
0.1  x
x = 0.027
2 2
19. KC = =4
1
 B(g) + C(g)
A(g) 
Ceq 0.5–x 1+x 1+x
(1  x) 2
=4
0.5  x
x = 0.16
4 2
20. KP = .P
1  2
 
2
4  14 4 2
2 × 1.5 = × 10
    2
1 41 1
4  0.01
= ×10 = 0.4
1  0.01
21.  2NO2(g)

N2O4 (g) 
2 4 2 1
= ×
3 1  2
2
 2
1
=
1  2 3
42 = 1
1
2 =
2
22.  2NO(g) + Br2(g)

2NOBr(g) 
ni a 0 0
2a a a
neq
3 3 6
Peq 0.16 0.8 0.4
(0.8) 2  0.4
KP = = 0.1
(0.16) 2
(0.1) 2 4
24. KP = ×4=
1  (0.1) 2
99
1
25 × P = 4
1  1 25 99
96
P= = 0.97 atm
99
25.  PCl3(g) + Cl2(g)

PCl5 (g) 
2
KP = ×P
1  2
2
0.178 = ×1
1  2
 = 0.8
208.5
Mmix = = 115.83
1.8
1115.83
d= = 2.7 g/L
0.0821 523
92
26. 69 =
1 
1
=
3
4 1 4
9 ×5 = 9 ×5
KP =
1  19 8
9
20
= = 2.5
8
230 92
=
3 1 
 = 0.2
1 4
20
= 25 .P
8 1  125
P = 15 atm
46
27. 30 =
1 
46
1+=
30
 = 0.53
28. KP = KC
 H2S(g)
H2(g) + S(s) 
ni 0.2 1 0
neq 0.2–x 1–x x
x
6.8×10–2 =
0.2  x
x = 0.0127
29.  CS2(g)

S2(g) + C(s) 
Pi 2 0
Peq 2–x x
x
=9
2x
11x = 18
18
x=
11
30.  CaO(s) + CO2(g)
CaCO3(s) 
KP + PCO = 4×10–2
2
4 102  0.521
n CO2 =
0.0821 1000
= 4×10–4
nCaO = n CO = 4×10–4
2
WCaO = 4×10–4× 56 g
= 0.4×56 g
= 22.4 mg
31.  CaO(s) + CO2(g)

CaCO3(s) 
neq 0.2×0.75
0.2  0.75  0.0821 1000
KP = PCO = 2
15
KP = 0.821
32.  NiCO(g)

Ni(s) + 4CO(g) 
x x
x
= 0.125
x4
1
= 0.125
x3
x=2
PT = 4 atm
1
33. KP = = 6.4×1085
(PH2O )6
1 1
(PH2O )6 = = 10–85 = ×10–84
6.4 64
1
PH2O = ×10–14 = 5×10–15
2
34. KP = (PH O )2 = 2.25×10–4

2
PH2O = 15×10–3 = 1.5×10–2

1.5 102
R.H. = ×760×100
22.8
= 50 %
If RH < 50% reaction will shift forward
36. (a) Forward shift

No of moles of H2O will decrease
(b) For ward shift  moles of H2O will decrease
(c) Forward shift  moles of HCl will increase
(d) Backward shift  moles of Cl2 will increase
(e) Backward shift  partical pressure of each goes will increase
(f) No change
(g) H > 0, T, KC
(h) T, forward shift [HCl]
(i) At constant volume – no change
37. On increasing temperature reaction will shift towards endothermic direction and on increasing
pressure reaction will more towards lesser number of gaseous moles.
38. Decreasing volume of container

Increasing temperature
Addition of N2
Addition of H2
40. (b)
(i)  CH3OH (g)
2H2(g) + CO(g) 
conc.    
(ii) conc.    
 (iii) conc.   
(iv) conc.   
(v) conc.    
0.29
44. Keq at 1400 K =
1.1106
2.9
= × 105
1.1
= 2.6×105
1.3
Keq at 1500 K =
1.4 105
1.3
= × 105
1.4
= 0.92×105
T, Keq e×0
45. Keq at 2000 K
(iii) = –[2(i) + (ii) ]
1
K=
(4.4)  5.311010
2
1010
=
(4.4)2  5.31
Keq at 1000 K
K = 2.24 × 22
T, K e×0
47.  A(g) B(s) + C(g)

X(s) 
P1 + P2 P1
 D(g) + A(s) + E(s)
Y(s) 
P2 P2 + P1
P1 (P1 + P2) = 500
P2 (P1 + P2) = 2000
P1 + P2 = 50
P1 = 2×50 = 100 atm
49.  NH3(g) + H2S (g)

NH4HS(s) 
1–x 1
  N2(g) + 3 H2(g)
NH3(g) 
2 2
x 3x
1–x
2 2
x
= 0.25  x = 0.5
2
EXERCISE # S-II
1. N2O4(g)  2 NO2(g)
ni 1 0
neq 0.8 0.4
P1 P
 2
n1T1 n 2T2
1 P2

1 300 1.2  600
P2 = 1.2 × 2
= 2.4 atm
2. NH2COONH4 (s)  2 NH3(g) + CO2(g)

nI, eq 2P P
nII, eq 3P P1
2 1 2
(3P) × P = (2P) × P
4P
P1 =
9
(PT )II,eq 31

(PT )I,eq 27
3. NH4HS (s)  NH3(g) + H2S(g)

0.5 + P P
0.5 + 2P = 0.84
P = 0.17
Kp = 0.67 × 0.17
= 0.1139
4. A(g) + 2B(g)  C(g) + D(g)

ni 0.5 1 0.5 3.5
neq x 2x 1 4
1 4
1012 =
4x3
–12
3
x = 10  x = 10–4
[B] = 2 × 10–4
5. H2(g) + I2(g)  2HI(g)

ni 1.5a a 0
neq 1.5 a–x a–x 2x
ax 1

2x 18
x = 0.9a
1.8 1.8
KC = = 54
0.6  0.1
6. 2H2O (g) + 2Cl2(g)  4HCl(g) + O2(g)
pi 2 2 2 2
peq 0.5 x 6 3
64  3
12 × 108 =
(0.5)2  x 2
x = 3.6 × 10–3
7. X(s)  A(g) + C(g) K P1 = 400

P1 P1 + P2
Y(s)  B(g) + C(g) KP2 = 900
P2 P1 + P2
(a) P1(P1 + P2) = 400 P2(P1 + P2) = 900
P1 + P2 = 10 13
n A PA 4
(b)  
n B PB 9
(c) PT = 2(P1 + P2) = 20 13 atm
8. A(g)  B(g) + C(g)

1–x x+y x–y
C(g)  D(g) + B(g)
x–y y y+x
nT at eq = 1 – x + x + y + x–y+y
=1+x+y
pi 1 ni 1 1
  
peq 2 n eq 1  x  y 2
1+x+y=2
[C]eq x  y 1
   5x – 5y = x + y
[B]eq x  y 5
4x = 6y
y = 0.4
x = 0.6
0.4 1
KC2
 0.5  4
KC1 1 0.2
0.4
EXERCISE # O-I
3. At equilibrium conc. Becomes constant.
4. rf = rb
5. NH3, ND3, NH2D, NHD2, N2, H2, H-D, D2
Kf
6. Keq =
Kb
1
7. K2 =
1
(K1 )
2
1
8. K2 =
K12
9. K3 = K1 × K2
(iii) = (i) + (ii)
11. S + S2–  S22– K1 – 12

2S + S2–  S32– K2 = 132
S + S22–  S32– K3
(iii) = (ii) – (i)
K
K3 = 2
K1
12. KC depends only only on temp
ng
 mol 
18. KC =  
 L 
1
 mol 
=  = mol L–1
 L 
19. KP = (a/m)ng
[B]
20. Keq =
[A]
[B]e K
KC = = f  [A]e = Kf Kb–1 [B]e
[A]e Kb
21. KP = KC(RT)ng
KP
22. log + log RT = 0
KC
KP
= (RT)–1  ng = – 1
KC
KP
23. = (RT)ng
KC
24. KP = KC(RT)1
1
RT = 1 T= K
R
2
 48 
 80  0.6  0.6
27. KC =   = = 30
2
 12.8   9.6 0.2  0.2  0.3
 64  32
 
28.  PCl3(g) + Cl2(g)

PCl5 (g) 
neq 0.1 0.2 0.2
0.2 0.2

KC = 10 10 = 0.04
0.1
10
29. PCl5(g)  PCl3(g) + Cl2(g)

X PCl3 = 1 – 0.4 – 0.3 = 0.3
30.  3R(g) + s(g)

2P(g) + O(g) 
ni 2 2
neq 2(1–x) 2–x
moles of Q > moles of P
[Q] > [P]
32.  C(g) + D(g)

A(g) + B(g) 
Ci 3n n 0 0
Ceq 3n–x n–x x x
n–x=x
n
x=
2
35. 
N2(g) + O2(g)  2 NO(g)
ni 2 4 0
neq 1.5 3.5 1
1
[No] = = 0.4
2.5
36. 
3A (g) + B(g)  2C (g)
neq 2 2 2
–2
1
2
2
9=  
2 2  V 
3
V = 9 × 22 V = 6 L
2
38. 
A(g) + 2B(g)  C(g)
ni a 4 0
neq a-1 2 1
1
0.25 = 5
a 1  2 
2

5  5 
1
0.25 =  25
(a  1)  4
a = 26
40. 
H2(g) + I2(g)  2HI(g)
Ci a a 0
Ceq a–x a–x 2x
(2 x)2
Kf = Kb Kc = 1 =1
(a  x)(a  x)
2x = a – x
a
x=
3
41. 
C2H5OH (l) + CH3COOH(l)  CH3COOC2H5(l) + H2O(l)
ni a a 0 0
2a 2a a a
neq
3 3 3 3
aa
· 1
KC = 3 3 =
2a 2a 4
·
3 3
44. 
2SO2(g) + O2(g)  2SO3(g)
nSO2 = nSO3  PSO2 = PSO3
2
PSO
4= 2 3
PSO2  PO2
1
PO2 =
4
46. 
N2(g) + 3H2(g)  2NH3(g)
ni a 3a 0
neq a–x 3(a–x) 2x
n H 2 = 3 n N2
P
PH2 = 3 PN2 = 3 × =P
3
2P
PNH3 = 2P – (P + P/3) =
3
48. KP = KC ng = 0

A(g) + 2B(g)  3C(g)
Pi 1 2 0
Peq 1–x 2(1–x) 3x
(3x)3
= 2 × 10–3
(1  x)  4(1 – x) 2
3x
= 2 × 10–1
1– x
x = 0.0625
49. 
H2(g) + CO2(g)  CO(g) + H2O(g)
ni 0.25 0.25 0 0
neq 0.25–x 0.25–x x x
KP = KC
x2
0.16 =
(0.25  x)2
x 1
= 0.4 x=
0.25  x 14
54. 
A3(g)  3A(g)
Ci a 0
Ceq a(1–x) 3ax
nT = a(1 – x) + 3ax
= a+ 2ax
56. 
PCl5  PCl3(g) + Cl2(g)
ni 4 0 0
neq 2 2 2
nT = 6
57.  2SO2(g) + O2(g)

2SO3(g) 
ni 1 0 0
neq 1–  
2
1
2 .  2  1 
KP = . 
(1  )2  1   
 2
3  2
= 2 .P
(1  ) 2 (2  )
3
Kp = .P
(1  ) 2 (2  )
58.  H2 (g) + I2 (g)

2HI(g) 
neq 1–  
2 2
 .
0
2 2 . P 
(1  )2  1 
KP =
2
KP =
4(1  ) 2
4 2
59. KP = .P
1  2
2
60. KP = .P
1  2
2 1
  << 1
1  2
P
1

P
46
63. 30 =
1 
46
= – 1 = 0.533
30
2
64. KP = .P
1  2
2
9= .7
1  2
7 2 = 9 – 9 2
3
16 2 = 9 = = 0.75
4
70 70
Mmix = = = 40
1  0.75 1.75
8.5
65. 6=
1 
8.5
1+=
6
 = 0.4166
40
66. 35 =
1  0.5
40
1 + 0.5 =
35
 = 0.28
208.5
67. Mmix = = 139
1.5
PMmix 2 139
dmix = =
RT 0.0821 800
= 4.23 g/L
P
69. PNH3 = PH2S =
2
P P P2
KP = . =
2 2 4
71.  2CO(g)
C(s) + CO2(g) 
Pi P 0
P
Peq P
2
PCO2 = 4 atm PCO = 8 atm
(8) 2
KP = = 16
4
73.  NH3(g) + H2S(g)

NH4HS(s) 
0.6atm 0.6atm
KP = 0.6×0.6
= 0.36 atm2
1
77. 
P
1 P
 2
2 P1
P
1 1 1
 16  =
2 P 2 4
83.  C(graphite)

C(diamond)  H = –ve
d d
High T and high pressure
85.  2C (g)

2A(g) + B(g)  H = –ve
On increasing pressure equilibrium will shift to forward direction low temperature high
pressure
89. KE depends only on temperature
90.  Au()

Au(s)  H = +ve
d d
92.  H2O()

H2O(s)  H = +ve
d d
high temperature and high pressure
97. If CO is introduced
 PCl5(g) 
  PCl3(g) + Cl2(g)
 COCl2(g) 
  CO(g) + Cl2(g)
98.  2NH3(g) + CO2(g)

NH2COONH4 (s)  K P1
 CaO(s) + CO2(g)
CaCO3 (s)  K P2
K P2 = K CO2
K P1 = (PNH3 )2 . PCO2
PCO2 and PNH3 remains constant at new equilibrium
EXERCISE # O-II
12. KP = KC (RT)ng
ng = 0
KP = 49
13. H2(g) + I2(g)  2HI(g)

neq 0.5–x 0.5–x 2x
2
(2x)
 49
(0.5 – x)(0.5  x)
2x
7
0.5 – x
x = 0.38
1 0.0821 700
P=
7
= 8.21 atm
14. mole of I2, eq. = 0.5 – 0.38

= .012
2  0.38  0.0821 700

15. PHI =
7
= 6.385 atm
EXERCISE # JEE MAINS
1. In this reaction the ratio of number of moles of reactants to products in same i.e., 2 : 2, hence
change in volume will not alter the number of moles .
3. The conversion of SO2 to SO3 is an exothermic reaction, hence there is no need to increase the
temperature. There is also a decrease in volume or moles in product side. Thus the reaction is
favoured by low temperature and high pressure. (Le-Chatelier’s principle).
4. C[ N2O4 ] = 4.8 × 10–2 mol L–1, C[ NO2 ] = 1.2 × 10–2 mol L–1
[ NO2 ]2 1.2 102 1.2 103
Kc   2
= 0.3 × 10–2 = 3 × 10–3 mol L–1
[ N2O4 ] 4.8 10
[NO]2
5. 
N2(g) + O2(g)  2NO(g) ; Kc =  4 104
[N 2 ][O2 ]
1 1 [N2 ]1/2 [O2 ]1/2 1 1 1 100
 N2(g) + O2(g) ; Kc 

NO(g)     2
  50
2 2 [NO] Kc 4 10 4 2 10 2
6. What is the equilibrium expression for the reaction P4(s) + 5O2(g)  P4O10(s)?[AIEEE-2004]
(1) KC = [P4O10] / [P4] [O2]5 (2) KC = [P4O10] / 5 [P4] [O2]
5
(3) KC = [O2] (4) KC = 1 / [O2]5
7. 
CO(g) + CI2(g)  COCI2(g)
Kp 1
n = 1 – 2 = – 1; Kp = Kc (RT)n   ( RT )1 
Kc RT
8. Kp = Kc (RT)n n = 3 – 2 = 1.
1
Kp = Kc (0.0821 × 457) . Kp > Kc.
9. 
Cl2(g) + 3F2(g)  2CIF3(g) ; H = – 329 kJ. Favourable conditions:
(i) Decrease in temperature, (ii) Addition of reactants, (iii) Increase in pressure i.e., decrease in
volume.
11. Given : 

PCI5(g)  PCI3(g) + CI2(g)
t=0 1 0 0
teq 1–x x x
Total number of moles = 1 – x + x + x = 1 + x
 x 
Thus partial pressure of PCl3 =   P.
 1 x 
12. 
SO3(g)  SO2(g) + O2(g)
[ SO2 ][O2 ]1/2
= KC = 4.9 × 10–2 ...........(i)
[ SO3 ]

SO3(g) + 1/25 O2(g)  SO3(g) ...........(ii)
[SO3 ] 1 
= K'C = For 2SO2(g) + O2(g)  2SO3(g)
[SO2 ][O2 ]1/2
4.9 10–2
[ SO3 ]2 1 10000
= KC2 = 4
= = 416.49
2
[ SO2 ] [O2 ] 4.9  4.9 10 24.01
13. X 
 2Y Z 
 P + Q
1– 2 1–  
2
 2α   α  α 
 1+ α PT1   1+ α PT2   1+ α PT2 
Kp =   Kp =   
1
 1- α  2
 1- α 
 1+ α PT1   1+ α PT2 
   
2
 2α   1- α 
 PT1   PT2 
K P1
= 
1+ α 
×  1+ α 
K P2  1- α   α  α 
 1+ α PT2   1+ α PT2   1+ α PT2 
    
1 4PT1 PT1 1
= ; =
9 PT2 PT2 36
14. 
CO2(g) + C(s)  2CO (g)
0.5 atm
0.5–p 2p
Total pressure = 0.5 – P + 2P = 0.8
P = 0.3
2
PCO (2P) 2 (0.6) 2
Kp = = =
PCO2 (0.5 - P) (0.5  0.3)
Kp = 1.8
Kp = Kc  RT
ng
22.
1
ng = –
2
24. A + B 
 C + D
t=0 1 1 1 1
teq 1–x 1–x 1+x 1+x
(1  x) 2
1 x
 = 100  = 10
(1  x)2 1 x
 1 + x = 10 – 10x  11x = 9
9
   x=
11
9
 [D] = 1 +
11
 [D] = 1.818
H 1
25. ln K = ln A – ·
R T
Reaction is exothermic (i.e. H = –ve) so slope
1
of the curve between lnK and will be positive .
T
[AB]2
26. K1 = ... (1)
[A 2 ][B2 ]
[A2 ]3[B2 ]3
K2 = ... (2)
[AB]6
 K2 = K1–3
27. 1. N2 + O2  2NO
ng = 0
Kp = Kc(RT)ng
Kp
=1
Kp
2. N2O4  2NO2
Kp
=(RT)1 = 24.62
Kc
Kp 1
3. = (RT)–2 = = 1.62 × 10–3
Kc (24.62) 2
28. 
NH4HS(s)  NH3(g)  H2S(g)
5.1
Number of mole of given NH4HS = = 0.1 mole
51
0.1 30
moles of NH3 formed = = moles of H2S
100
0.03  0.0821 600
pressure of NH3 = = pressure of H2S = 0.492
3
 Kp = PNH  PH S = 0.492 ×0.492 = 0.242 atm2
3 2
29. N2 + 3H2  2NH3

t=0   P
teq P 3p x
x2
Kp =
p  (3p)3
x = (Kp × 27 p4)1/2
x = (27)1/2 Kp1/2 P2
PT = 4P
PT
P=
4
33/2 K1/2 2
p PT
X=
16
30. A (s)  B(g) + C(g) K P1 = x atm2

P1 P1 + P2
D(s)  C(g) + E(g) KP2 = y atm2
P2+P1 P2
P1 (P1 + P2) = x
P2 (P1 + P2) = y
P1 + P2 = xy
Total pressure = 2 (P1 + P2)
= 2 x  y atm
31. A + 2B  2C + D
Ci a 1.5a 0 0
Ceq a–x 1.5a – 2x 2x x
[A]eq = [B]eq
a–x = 1.5a – 2x
x = 0.5a
[C]2 [D] a 2  0.5a
KC = = =4
[A] [B]2 0.5a  (0.5a) 2
1
32. Equation 1: S(s) + O2 (g)  SO2 (g) : K1 = 1052
2
Equation 2 : 2S(s) + 3O2(g)  2SO3(g) : K2 = 10129
Equation 2 – 2 × Equation 1 gives,
2SO2(g) + O2(g)  2SO3(g) : K
K 2 10129
  K= =  1025
(K1 )2 10104
33. On addition of catalyst value of equilibrium constant does not change.
34. As, Kp = Kc (RT)ng Kp Kc if ng  o

1. 2 HI(g)  H2 (s) + I2(g), ng = 0 kp = kc
2. NO2(g) + SO2(g)  NO(g) + SO3(g) , ng = 0 kp kc
3. 2C(s) + O2 (g)  2CO(g) , ng = 1  kp  kc
4. 2NO(g)  N2(g) + O2(g), ng = 0 kp = kc
EXERCISE # JEE ADVANCED
5. (D) With change of pressure, x will change in such a way that Kp remains a constant.
6. N2O4 (g) 2NO2.

moles t=0, 1 0
moles at eq. 1– 2
2
 2 
 (1  )  P 
 = 4 × P.
2
KP = 
1–  1 – 2
P
1 
Let total pressure at eq. = P.
4 2
or KP = × P.
1 – 2
When volume is halved, P is double.
 a will change as KP is independent of pressure change.
8. (A) H2 – H1 = CP (rxn) (T2 – T1)

and Cp depends on temperature. Hence enthalpy also depends on temperature.
(B) CaCO3(s) CaO(s) + CO2(g) Kp = ( PCO2 )at equlibrium
For a given reaction.
Keq. depends only on temperature.
(C) Keq depends only on temperature.
(D) Enthalpy of reaction is independent of the catalyst. Catalyst generaly changes activation
energy.
9. (8.92 or 8.93)
Sol. Equal volumes of both the reactant are taken so, initial concentrations will be halved.

Fe2+ (aq) +S2–(aq)   FeS (s)
t = 0 0.03M 0.1M
teq. x 0.07M since KC is very high
1 1
KC = 2
= = 1.6 × 1017
[Fe ][S ]2–
x  0.07
x = 8.928 × 10–17
So, Y = 8.92 (after truncate) or 8.93 (after round off).

11 Chemical Equilibrium Solution

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11 Chemical Equilibrium Solution

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SOLUTION : CHEMICAL EQUILIBRIUM

2. If K is large. Then tendency of reaction to convert in product will be more

5. (i) Amount if  formed = 2 × amount of A reacted

 N2(g) + O2(g) 1

7.  ClF(g) + F2(g)

11. If KC is very large, extent of reaction is almost 100%.

12.  2O3 (g) KC = 8×10–55

14.  CS2(g) + 4H2(g)

16. N2(g) +  2NH3(g)

17.  2NO(g)

18.  PCl3(g) + Cl2(g)

21.  2NO2(g)

22.  2NO(g) + Br2(g)

25.  PCl3(g) + Cl2(g)

29.  CS2(g)

31.  CaO(s) + CO2(g)

32.  NiCO(g)

34. KP = (PH O )2 = 2.25×10–4

PH2O = 15×10–3 = 1.5×10–2

36. (a) Forward shift

38. Decreasing volume of container

45. Keq at 2000 K

47.  A(g) B(s) + C(g)

49.  NH3(g) + H2S (g)

2. NH2COONH4 (s)  2 NH3(g) + CO2(g)

3. NH4HS (s)  NH3(g) + H2S(g)

4. A(g) + 2B(g)  C(g) + D(g)

5. H2(g) + I2(g)  2HI(g)

7. X(s)  A(g) + C(g) K P1 = 400

8. A(g)  B(g) + C(g)

5. NH3, ND3, NH2D, NHD2, N2, H2, H-D, D2

11. S + S2–  S22– K1 – 12

28.  PCl3(g) + Cl2(g)

29. PCl5(g)  PCl3(g) + Cl2(g)

30.  3R(g) + s(g)

32.  C(g) + D(g)

57.  2SO2(g) + O2(g)

58.  H2 (g) + I2 (g)

73.  NH3(g) + H2S(g)

83.  C(graphite)

85.  2C (g)

89. KE depends only on temperature

90.  Au()

92.  H2O()

98.  2NH3(g) + CO2(g)

13. H2(g) + I2(g)  2HI(g)

14. mole of I2, eq. = 0.5 – 0.38

2  0.38  0.0821 700

11. Given : 

29. N2 + 3H2  2NH3

30. A (s)  B(g) + C(g) K P1 = x atm2

33. On addition of catalyst value of equilibrium constant does not change.

34. As, Kp = Kc (RT)ng Kp Kc if ng  o

6. N2O4 (g) 2NO2.

8. (A) H2 – H1 = CP (rxn) (T2 – T1)

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