90 G.R.B. Inorganic Chemistry forC.

for Competitin
HNO HON
XX

XX
x

0X H-0-N=0
0
HPO4
H O P 0 H

xX X XX
H-0-P-0
xx 0
NO 0NO
X*

XX
0-N=0 H H
protons from HjPO4 molecule
K X Note: For PO remove
xX
Note: Remove XX

proton from HNO, molecule.

xx x Xx
XX

HNO
[NOZ
H0N:0
xx
XX H-0-N=0
HAP07 H0P:0%PXOXH H-0-p-0-
XXX XX x XX
A-0-P-0-P-0-H
0NO 0-N=0
Note: Remove
XX
H H H H
proton from HNO2 molecule.
xx . Note: For Pz07 remove protons
from H4P207 molecule
sO2
0:s:00
XX 0-S-0 H
X XX
Note: On the basis KX

of overlapping and hybridization concept, the HOP0H H-0-P 0-H

HPO3 xx XX
structureofsO, is, S{ i.e.,octetrule is not followed.
XX
XX

SO3 0:S*o 0-S=0

XX
CI CI CI
XX
Al Al
Note: On the basis
AlCl .

of overlapping and hybridization concept, (Anhydrous)

structure ofSO3 is, CI: CI:
O=§=0,i.e., octet rule is not followed.

XX
Ck C
0:
XX XX C
HSO4 H0S0H XX XX
H-0-$-0-H Note: Anhydrous aluminium chloride is a dimer.
KX

KX

XX XX
:0
So O
XX
SxO
XX
0--0 XX

CIx Cl
XXXXx
XX

Note: Remove protons from H,S0, molecule.

SOClh 0:S:0O 0-S-0
XXXXX
Xx XX
CI
XX
C
HSO3 HOS0:H H-0-S-0-H XX XX
XX XX
SOCh 0SCIXXx XX
0-$-C1
XX C1
XX
XX Xx

so 0S O O-S-0 HIO
Xx XX

XX
HOXI0x H-0--0

xx
0
XX

from H2SOg molecule. Note: For 107 remove

Note: Remove protons proton from HIO molecule.
 Inorganic
tor CCompetitiong
Chemistryfor
C.R.B.

90
X

HNO H:0N:0: H-0-N=0

HPCO4
H0:P 0 H
H-0-P-0-H
H
[NO oN0 X
0-N-0
protons
from H,PO molecule
remove

Note: For POj

Note: Remove proton from HNO, molecule.

XX
HP07 H
O:P:0P<O*H

xxX X*X
HH0-P-0-P-0-
X*
H-0-P-0

HNO2 H0 N:0* XX
H-0-N=0
O 0
XX
H H
[NO oN:o o-N-O] HH
XX
from H,P20, molecule
Note: Remove proton from HNO molecule. Note: For P0 remove protons
H
SO o:S:0:
XX
0-S-0
HOP 0 H H-0-P-0-H
Note: On the basis of overlapping and hybridization concept. the
H3PO Xx

structure ofSO, is, S ,ie..octetrule is not followed.

XX

SO3 O:So O-S-0O C1. :C1

O Al
xx
AlCl
Note: On the basis of overlapping and hybridization concept. the (Anhydrous) C1
:Ci
structure ofSso, is. O=$=0,.ie,octet rule is not followed. C
XX

CI a
XX

HSO4 HOS:0H XX
H-0-S-0-H Note: Anhydrous aluminium chloride is a dimer.
XX

XX

Os : o

XX

so 0 S0 0-$-0
XX XX

O
C
Xx x Xx
XX
sO2Ch X0:S:O0x O-S-0
XX X XX
Note: Removeprotons from H2SO4 molecule.
CI C
XX XX XX

H2SO3 H0S:0H H-0-S-0-H

XX Xx

O
SOClh 0:S:C X XX
0-$-C1
:0
XX CI
XX
C
xX XX

so 0S0
XX
0-S-0o
HIO3 HOI:0
XX

H-0--0
Xx XX
O
xx

Note: Remove protons from H,SOj molecule. Note: For 103 remove proton from HIOg molecule.