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TME 213
2 Thermodynamics
Properties of
Pure Dr S.K. Fasogbon & Dr Temilola T. Olugasa
Substances
University of Ibadan
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Examples:
Water (solid, liquid, and vapor phases)
Mixture of liquid water and water vapor
Carbon dioxide, CO2
Nitrogen, N2
Mixtures of gases, such as air, as long as there is no
change of phase.
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Phase-change Processes
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This constant
pressure heating
process can be
illustrated as:
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Property Diagram
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Property Diagram
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Saturation
Saturation is defined as a condition in which a mixture
of vapor and liquid can exist together at a given
temperature and pressure.
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Latent Heat
Latent heat: The amount of energy absorbed or
released during a phase-change process.
Latent heat of fusion: The amount of energy absorbed
during melting. It is equivalent to the amount of energy
released during freezing.
Latent heat of vaporization: The amount of energy
absorbed during vaporization and it is equivalent to the
energy released during condensation.
At 1 atm pressure, the latent heat of fusion of water
is 333.7 kJ/kg and the latent heat of vaporization is
2256.5 kJ/kg.
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Quality
masssaturated vapor mg
x
masstotal m f mg
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Quality
Moisture Content
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Moisture Content
Take specific volume as an example. The specific volume of the
saturated mixture becomes
v (1 x )v f xv g
The form that is most often used
v v f x(v g v f )
Let Y be any extensive property and let y be the corresponding
intensive property, Y/m, then
Y
y y f x( yg y f )
m
y f x y fg
where y fg y g y f 18
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Property Table
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Property Table
If the answer to the first question is yes,
the state is in the compressed liquid
region, and the compressed liquid table is v vf
used to find the properties. (or using
saturation temperature table)
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Property Table
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Example 2.1
Determine the saturated pressure, specific volume, internal energy
and enthalpy for saturated water vapor at 45oC and 50oC.
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Example 2.2
Determine the saturated pressure, specific volume, internal energy
and enthalpy for saturated water vapor at 47⁰ C .
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Solution:
T Psat v u h
45 9.5953 15.251 2436.1 2582.4
47 Psat v u h
50 12.352 12.026 2442.7 2591.3
Psat 9.5953 47 45
12.352 9.5953 50 45 Interpolation Scheme for Psat
Psat @ 47 10.698 kPa
Exercises
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Example 2.3 Is v v f ? No
Determine the enthalpy of 1.5 Is v f v v g ? Yes
kg of water contained in a Is v g v ? No
volume of 1.2 m3 at 200 kPa.
Find the quality
Solution: v v f x (v g v f )
v vf
Specific volume for water x
vg v f
Volume 12. m3 m3 0.8 0.001061
v 0.8
mass 15
. kg kg 0.8858 0.001061
From table A-5: 0.903 (What does this mean?)
The enthalpy
v f 0.001061 m3
kg
h h f x h fg
vg 0.8858 m3
kg 504.7 (0.903)(2201.6)
kJ
2492.7
kg 26
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Example 2.4
Determine the internal energy of refrigerant-134a at a temperature
of 0C and a quality of 60%.
Solution:
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Example 2.5
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Solution:
State 2:
Theoretically:
v2 v1 Information :
P2 8 MPa v2 0.031 mkg
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Exercises
1. Four kg of water is placed in an enclosed volume of 1m3.
Heat is added until the temperature is 150°C. Find ( a )
the pressure, ( b )the mass of vapor, and ( c ) the volume
of the vapor.
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Exercises
3. For a specific volume of 0.2 m3/kg, find the quality of steam
if the absolute pressure is (a) 40 kPa and ( b ) 630 kPa. What
is the temperature of each case?
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Important Definition
o Critical point - the temperature and pressure above which there
is no distinction between the liquid and vapor phases.
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Important Definition
o Critical point - the temperature and pressure above which there
is no distinction between the liquid and vapor phases.
Triple point - the temperature and pressure at which all three phases
can exist in equilibrium. For water, the triple-point temperature and
pressure are 0.01°C and 0.6117 kPa, respectively
o Sublimation - change of phase from solid to vapor.
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This diagram is often called the phase diagram since all three phases are separated
from each other by three lines. 34
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V1 T1 P1 T1
or
V2 T2 P2 T2
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( RU ) air 8.3144
Rair 0.2871kJ / kg.K
( M ) air 28.96
u h
Cv and C P
T v T P
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h u Pv
dh du RT
CP dt CV dt RdT
CP CV R
CP
k
Cv
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u u 2 u1 C v (T2 T1 )
h h2 h1 C P (T2 T1 )
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Example 2.8
An automobile tire with a volume
of 0.6 m3 is inflated to a gage
pressure of 200 kPa. Calculate the
mass of air in the tire if the
temperature is 20°C.
Solution: From ideal-gas law:
given
PV
state1 m
RT
P 200 100 kPa
300 103 mN3 0.6m2
T 20 273K 293 K
287 kgNm.K 293K
2.14 kg
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Supplementary Problems
1. The pressure in an automobile tire depends on the temperature of the air
in the tire. When the air temperature is 25°C, the pressure gage reads 210
kPa. If the volume of the tire is 0.025 m3, determine the pressure rise in
the tire when the air temperature in the tire rises to 50°C. Also, determine
the amount of air that must be bled off to restore pressure to its original
value at this temperature. Assume the atmospheric pressure is 100 kPa.
[ 26 kPa, 0.007 kg]
2. A 1-m3 tank containing air at 25°C and 500 kPa is connected through a
valve to another tank containing 5 kg of air at 35°C and 200 kPa. Now
the valve is opened, and the entire system is allowed to reach thermal
equilibrium with the surroundings, which are at 20°C. Determine the
volume of the second tank and the final equilibrium pressure of air.
[ 2.21 m3, 284.1 kPa]
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