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  • Mass and Heat Transfer - Aula 31 01 23

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    Priscila Auad
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    The document describes mass transfer in two dimensions within a laminar liquid film. It discusses the momentum balance and mass balance equations for the system. The momentum balance equation accounts for molecular transport of momentum via viscosity and convective transport via fluid movement. The mass balance equation uses Fick's law of diffusion to model mass transfer. The document presents the partial differential equation derived from the mass balance and proposes a variable substitution solution approach involving exponential functions.

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    The document describes mass transfer in two dimensions within a laminar liquid film. It discusses the momentum balance and mass balance equations for the system. The momentum balance equation accounts for molecular transport of momentum via viscosity and convective transport via fluid movement. The mass balance equation uses Fick's law of diffusion to model mass transfer. The document presents the partial differential equation derived from the mass balance and proposes a variable substitution solution approach involving exponential functions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    8 views55 pages

    Mass and Heat Transfer - Aula 31 01 23

    Uploaded by

    Priscila Auad
    The document describes mass transfer in two dimensions within a laminar liquid film. It discusses the momentum balance and mass balance equations for the system. The momentum balance equation accounts for molecular transport of momentum via viscosity and convective transport via fluid movement. The mass balance equation uses Fick's law of diffusion to model mass transfer. The document presents the partial differential equation derived from the mass balance and proposes a variable substitution solution approach involving exponential functions.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 55

    Chemical Engineering Program

    COPPE – Federal University of Rio de Janeiro

    January / 2023

    Module I: Fundamentals of Chemical


    Engineering

    Heat and Mass Transfer

    Prof. Cristiano Borges


    Mass transfer in two dimensions

    Mass Transfer in two dimensions


    Following liquid film in laminar flow

    Liquid B # Gas A has low solubility in liquid B

    # Developed velocity profile


    Gas A
    # Equilibrium at gas/liquid interface
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid
    film Liquid in Momentum balance

    Reser-
    voir
    Velocity (profile)
    Diretion of
    gravity

    Length: L
    Width: W
    Thickness: d
    Mass transfer in two dimensions

    Following liquid film in laminar flow


    Momentum balance

    Liquid
    film Liquid in
    Velocity (profile)
    Reser-
    voir

    Diretion of
    gravity

    Length: L
    Width: W
    Thickness: d
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Momentum by
    molecular transport

    Newton’s Law of
    viscosity
    Mass transfer in two dimensions

    Momentum by
    molecular transport

    Newton’s Law of
    viscosity
    Mass transfer in two dimensions

    Momentum by
    molecular transport
    Mass transfer in two dimensions

    Momentum by convective
    transport

    Fluid movement

    Velocity: v (x,y,z)

    Momentum by fluid
    movement: r.v

    velocity . (mass flux):


    v(r.v)
    Mass transfer in two dimensions

    Momentum by convective
    transport

    Fluid movement
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:

    Rate of momentum at z = 0
    Rate of momentum at z = L
    Rate of momentum at x
    Rate of momentum at x + Dx
    Gravity force (field)
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:

    Dividing by LWDx
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:

    rvzvz z=0 = rvzvz z=L p z=0 =p z=L


    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Momentum balance:
    Mass transfer in two dimensions

    Mass Transfer in two dimensions


    Following liquid film in laminar flow

    Liquid B
    # Gas A has low solubility in liquid B

    # Developed velocity profile


    Gas A
    # Equilibrium at gas/liquid interface
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B Momentum balance:

    Gas A
    Mass transfer in two dimensions

    Liquid B

    Gas A

    Mass balance:

    Dividing by ΔV=Δx.Δz.w Δx→0, e Δz→0


    Mass transfer in two dimensions

    Liquid B

    Gas A

    Mass balance:
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Direction x

    Mass transfer model (FICK):


    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Direction x

    Mass transfer model (FICK):


    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Direction x

    Mass transfer model (FICK):

    xA is small
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Direction x
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Direction z

    diffusion << convection


    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Direction z

    diffusion << convection


    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Direction z

    diffusion << convection


    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Direction z

    diffusion << convection


    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Direction z
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Liquid B
    Mass balance:

    Gas A
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):

    Variable substitution
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    1 h ¶f h 2 ¶2f
    -Uz,max = DAB 2 2
    2 z ¶h x ¶h
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    1 h ¶f h 2 ¶2f
    -Uz,max = DAB 2 2
    2 z ¶h x ¶h

    ¶2f ¶f
    + 2h =0
    ¶h 2
    ¶h
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    ¶2f ¶f
    + 2h =0
    ¶h 2
    ¶h
    df dy dy ln y = -h 2 + C1
    =y + 2hy = 0 = -2hdh
    dh dh y y = C1.exp(-h 2 )
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    ¶2f ¶f
    + 2h =0
    ¶h 2
    ¶h

    df
    y = C1.exp(-h ) 2
    = C2 exp(-h 2 )
    dh
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    ¶2f ¶f
    + 2h =0
    ¶h 2
    ¶h

    df
    y = C1.exp(-h ) 2
    = C2 exp(-h 2 )
    dh
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    ¶2f ¶f
    + 2h =0
    ¶h 2
    ¶h
    Boundary
    conditions
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    ¶2f ¶f
    + 2h =0
    ¶h 2
    ¶h
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    ¶2f ¶f
    + 2h =0
    ¶h 2
    ¶h
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Solution (maths):
    Mass transfer in two dimensions

    Following liquid film in laminar flow


    Mass transfer in two dimensions

    Following liquid film in laminar flow

    DAB= 1 x 10-5 cm/s2


    Umax = 10 cm/s
    Mass transfer in two dimensions

    Following liquid film in laminar flow

    Molar flux of A: Interface (x=0)

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