SET C

1. A 3.952 g sample of hydrated magnesium bromide, MgBr2 x H2O, is dried in an oven. When
the anhydrous salt is removed from the oven, its mass is 2.263g. What is the value of x?
a. 8 b. 1 c. 12 d. 3 e. 6

2. Chlorophyll, the substance responsible for the green color of leaves, has one magnesium
atom per chlorophyll molecule and contains 2.72% magnesium by mass. What is the molar
mass of chlorophyll?
a. 8.94 g/mol b. 20.2 g/mol c. 894 g/mol d. 24.3 g/mol e. 2020 g/mol

3. The activity of 3 µg of Cm-247 is 1.8 nCi. Calculate the disintegration rate constant of 247Cm.
a. 2.1x10^-15 s^-1 b. 7.8x10^-15 s^-1 c. 1.9 x10^-15 s^-1 d. 9.1 x10^-15 s^-1

4. The activity of 3 µg of Cm-247 is 1.8 nCi. Calculate the half-life of 247Cm.

a. 4.2x10^6 years b. 2.4x10^6 years c. 4.2x10^7 years
d. 2.4x10^7 years e. none of the above

5. 10.0 g of ice at 0.00°C is mixed with 25.0 g of water at 53.00°C in a coffee-cup calorimeter.
What is the final temperature of the mixture?
a. 47.8degC b. 5.22degC c. 0.00degC d. 15.0degC e. 2.24degC

6. Red phosphorus reacts with liquid bromine in an exothermic reaction.

2P(s) + 3Br2(l) -> 2PBr3(g) ∆H = -243 kJ
Calculate the enthalpy change when 2.63g of phosphorus reacts with an excess of bromine in
this way.

Ans:

7. Hydrazine reacts with chlorine according to the equation

N2H4 (l) + 2Cl2(g) -> 4HCl(g) + N2(g) ∆H = -420 kJ
Calculate the enthalpy change when
a.) 25.4g of hydrazine reacts with excess chlorine
b.) When 1.45 mol of HCl(g) is generated by this reaction

Ans:

8. A solution of hydrogen peroxide is 15.2% by mass. What is the molarity of the solution?
Assume that the solution has a density of 1.01g/mL.
a. 3.72M b. 6.02M c. 5.00M d. 4.95M

9. How many milliliters of a 5.0MCuSO4 solution are needed to prepare 0.350L of

0.500MCuSO4?
a. 0.035mL b. 35mL c. 0.0714mL d. 7.14mL e. 3.5mL
10. What is the molality of a solution made by adding 9.5g of NaCl to 300g of water?
a. 1.24m b. 0.24m c. 1.84m d. 0.54m e. 2.54m

11. What is the molarity of a solution containing 750ml of solution containing 35g of MgCO3?
a. 1M b. 0.25M c. 0.35M d. 0.75M e. 0.55M

12. How many ml of water are needed to dilute 65ml 7M KCl to 2M?
a. 227.5mL b. 0.0044mL c. 22.75mL d. 227.5mL e. 18.75mL

13. You are presented with a solution that has a pOH of 2.13. What is the pH of this solution?
a. (10)-2.13 b. 2.13 c. (10)2.13 d. 6.57 e. 11.87

14. What is the pH for a 0.05M solution of hydrochloric acid?

a. 6.95 b. -0.3 c. 0.05 d. 1.3

15. Hydrofluoric acid has a Ka value of 7.2x 10-4. What is the pH of a 0.04M solution of
hydrofluoric acid?
a. 4.5 b. 11.7 c. 2.3 d. 1.4

16. What is the pH of a 0.02M ammonia solution if its Kb value is 1.8 x 10-5?
a. 12.3 b. 7.6 c. 3.2 d. 10.8

17. What is the pOH of a solution containing a hydrogen ion concentration of 1 x 10-8M?
a. 6 b. -8 c. cannot be determined d. 8 e. 0.8

18. Given 100.0mL of a buffer that is 0.50 M in HOCl and 0.48M in NaOCl, what is the pH after
10.0mL of 1.0M NaOH has been added? (Ka for HOCl = 3.5 x 10-6)
a. 7.54 b. 7.62 c. 7.46 d. 7.29 e. 7.43

19. Which of the following group compounds does not contain a carbonyl group?
a. ester b. organic acid c. ketone d. ether

20. Very fine suspended and colloidal impurities are removed by a process called
a. softening b. disinfection c. coagulation d. plain sedimentation

21. Aeration of water is done to remove

a. suspended impurities b. floating impurities c. dissolved salts d. dissolved gases

22. The process of killing infective bacteria in water is called

a. sterilization b. disinfection c. coagulation d. sedimentation

23. Esters are formed from condensation reactions between

a. alcohols and aldehydes b. aldehydes and acids
c. ethers and acids d. alcohols and acids
24. How many sigma and pi bonds are in C2H2 in which two carbon atoms are adjacent and
each carbon has one hydrogen?
a. three sigma bonds and one pi bonds b. one sigma and one pi bonds
c. two sigma and one pi bonds d. three sigma bonds and two pi bonds

25. It is obtained from the milky secretion of various plants such as the tree Hevea Brasiliensis
a. natural rubber b. PAI c. xenoy d. collagen

1. A; 2. A; 3. D; 4. B; 5. E; 6. -10.31 kJ; 7. a.) -333.38 kJ; b.) -152.25 kJ; 8. D; 9. B; 10. D; 11. E; 12. A; 13. E; 14. D;
15. C; 16. D; 17. A; 18. A; 19. D; 20. C; 21. D; 22. A; 23. D; 24. D; 25. A;