APSAC Badin Cantt

FIRST TERM EXAMINATION

Class: XII HB Subject: Chemistry

Max Time: 03 Hours Max Marks: 85

Name: _____________________ Teacher: Mr: Arsalan Akram
Section: ___________________ Date:______________________

Instructions

1. Write your name, section and date clearly in the space provided.
2. Carefully read through the complete paper.
3. Space has been provided for objective.
4. Do not copy the question on the answer sheet.
5. Re. checks your work before handing it over at the end of the examination.
6. The marks for each question in the paper are given in brackets.
7. Use separate answer sheet for subjective part.
8. Attach the rough work sheet along with the answer sheet.

Sections Section-A Section-B Section-C Total Marks

Q. No 1 2 3 --

Max Marks 17 40 28 85

Marks Obtd
Ans. Sheets

Marked by: ___________________ _____ Sign:________________________ Dated:_____________

Counter-Checked by:__________________ Sign:_________________________ Dated:___________

 SECTION A (Marks 17)
MULTIPLE CHOICE QUESTIONS (MCQ’s)
Time allowed: 20 Minutes Marks = 17
NOTE: Section-A is compulsory. All parts of this section are to be answered on the in Answer sheet the first
20 minutes. Deleting/overwriting is not allowed. Do not use lead pencil.
Q.1 Circle the correct answer a / b / c /d by filling the relevant bubble for each question on the Answer
sheet instructions given there. Each option carries one mark.
i. Hydrogen resemble with alkali metals in:
a. Electronic configuration c. Electropositive character
b. Valence d. all of them
ii. Hydrogen element is.
a. Divalent c. Trivalent
b. Monovalent d. None of these
iii. Hydrogen react with electronegative elements to form:
a. Ionic compound c. Covalent compound
b. Mendeleev’s periodic table d. none of these
iv. When elements are arranged in the increasing of atomic mass, the properties are the periodic function
of their atomic mass is the law called:
a. Mendeleev’s periodic table c. Modern periodic law
b. Lother Mayer’s Law d. none of these
v. What is the number of periods in the original periodic table of Mendeleev’s?
a. 12 c. 8
b. 18 d. 9
vi. The elements called alkali metals are:
a. Br and Cl c. N and S
b. Na and K d. none of these
vii. Methyl alcohol react with steam to produce.
a. Methane and Alcohol c. Carbon dioxide & Hydrogen gas
b. Methane and Water d. Alcohol and Water
viii. Hydrogen resemble with alkali metals in:
a. Electronic configuration c. Electropositive character
b. Valency d. all of them
ix. Hydrogen element is:
a. Divalent c. Trivalent
b. Monovalent d. None of these
x. Hydrogen react with electronegative elements to form:
a. Ionic compound c. Covalent compound
b. Metallic bond d. None of these
xi. An isomer of ethanol is:
a. Dimethyl ether c. methanol
b. Diethyl ether d. All of these
xii. Name the hydrocarbon gas that is applied as general anesthesia.
a. Ethyne c. ethane
 b. Natural gas d. ethylene
xiii. Further nitration of nitro benzene will be at which position.
a. Ortho c. Meta
b. Para d. All of these
xiv. Benzene is an aromatic compound obtain from
a. Petrol c. coal
b. Coal tar d. All of these
xv. Tetraethyl lead is use as:
a. Knocking agent c. catalytic agent
b. Anti-knocking agent d. reforming agent
xvi. When sodium benzoate is treated with caustic soda it is converted into
a. Hexane c. cyclohexene
b. Cyclohexane d. benzene
xvii. when ethylene is react sulphur mono chloride it produce very poisonous is known as

a. thionyl gas c. chloride gas

b. Mustard gas d. All of these

Section-B (Marks 40)

Q.2: Answer any EIGHT (08) of the following parts each part carries 5 marks. [8×5=40 ]

I. Ionization potential decreases from lithium to cesium.

II. How does ionic radius of elements change in a period and a group?
III. Why electronic configuration of each period start from ns 1 and ends at ns2 np6?
IV. How can you justify a separate position of hydrogen in the periodic table of elements?
V. Write chemical properties of NaOH.
VI. Why the second ionization enthalpies of alkali metals are higher than second ionization enthalpies of alkaline
earth metals?
VII. Explain the preparation of ethane.
VIII. Explain the refining of petroleum.
IX. Write the Structural formula of the following.
i) 3-methyl hexane
ii) 2-methyl-1-butene
iii) 1,3-pentadiyne
iv) 4-hexene-1-ene

x. Derive the structure of all isomers of pentane (C5H12) and name them by the I.U.P.A.C system.

xi. Define the following: (i) Catenation (ii) Isomerism

 Section-C (Marks 28)

Q.3 Answer any TWO of the following questions in detail each question carries 14 marks.
[2 ×14=28]

I. a) Write chemical properties of methane?

b) Which alkane may be obtained by the reduction of
1) 2 bromo propane. 2) Secondary butyl bromide. 3) Isopropyl bromide

II. a) Explain the classification of organic compounds.

b) Explain polymerization and its types.

III. Explain electrophilic substitution of benzene with mechanism (any three).