Goaph): valume of L,trO s

(V

Volume o k,1,0 (oval

Gyraph 2: %lume at kaCr,0- Vs

AE/av.

Volune of k,(r,0-1 (mi

 3) Estimation oarous ron by
potivctiomctric TeBalion.

Ain
To estimdte ta amouwit of rous iren (
powseit in looml at te giren doluctin pstantiomdtsia
.A dtandand Boluction e p5tamuum dickromáte
fBtungtt o.iN pkovded.
Pinuple
otatiomcoulc titweaion depads on measuouniria
m f betiuean sulaoceuto lechcode aud an
indicaton oucoode, wlun a 6olrtiton af fvwous iren
eatud wth dlutiovn ot pstasiuun dichocomate,
a

the ollouing rdexc ueactovn takes plate

6F
6F+Cr, 0 +l4H
26A+2CY+7H%0.
Desung tes trtuartionFeis
Covnnattud irto
Fowhose ContesTtoation incomeases .At
tie nd poist,
thiaoe uLl he a dharp change due to dudden
Piemoval of all Fe?2 Lons.

The cell dtup by Connerting the owdoe

lhctocode wth a talomel olucbode a

grcaph etuwen mf measuoaa aganst

tha oluume of Cr0- addeds draun and the
&nd Point s nstad ron the
O A12
guapla.
 Table T.
kaCrs07 é Tron doltion.
OLL fuow on oluction =20ml

S 6lme g
Kabn0(mly Ef(vaks ) AF vo) Av4 4E
h(ml)
1

sh
Matioias PLeauioed
. .Dpstactiomzar .1

2 pt elatbode
3 Gutuoatad colonel aud aecbode
A) dtd. k,cv, 0, oltion.

5 Gqivn erous an olction.

6 Buocctte, and pipcte.
D H30
814 Distlod uster
Ponaceduwe
The given fvvous bon oluctiovn es toanslpved.
icto tooml daundavd lask and ade upsto the
Zero mank using dlstalled uwaton .20ml of teis
made p doku i pipatad ooct in erun elan
looml eakeo . Abovct to ml f del. Hasoand
20 ml of distillid usaher oe added in &.

pletinun olecrade i diepacd into uain T

elactoiode then Coupled uastk a datrouted
eells acoduced
Calomel lkcbode and the
vco potevtiometre cercet,
Tetvtion-T:
The burete ashed ell uwdtk
uwatio aud insedth tta ginn b2 tr Oy
Qolution .t thn elld a te auma upo
ZAvO man Lnd ttated against the rrous o n
ouction takn n te touical flask.
lolo
he addtton tasodd ouct by addig dtaudod
k,CrOy Goln in portiovn of 1ml aud te remf f ta
tha
cell
Cell miasuwed ot tte ath addelon. Ta addeeion
aCr0 eadelea oln in portions
eml aud the mf f cell mtasuoeed aptar
Aach addetton. poit es is found oct ey

plotti'rg valuwne gf Ecry,o7 addad against enf.

Caluulaton a amud ot woLus ibon

The aumoutt ot woous von pueeu in

tooe m
the dolucion

The amount dsiss iun peut &

tDo m ot the aven o
dolutton "

Looo
Twtion-TT
Ansther tivetomàCanoad otyadkin
dandand k,tr oy alutdon in potctiovno. m
ha t t tand e eun the cel
maaed an atlh addako The adlition
cro tinud wn atr tha ed poit

rti lml.The attwata ud point &

deemind b prting AE/, V volume kaer0
added.Fown d d t , the hungt o fevrous
s n avd buue samout takeuletd.

T amouwt oferrous on pockut in tooml

doletion m.