Appendix A

8.3 Notes for use in qualitative analysis

Tests for anions
anion test test result
2–
carbonate (CO ) 3 add dilute acid effervescence, carbon dioxide
produced
chloride (Cl –) acidify with dilute nitric acid, then add white ppt.
[in solution] aqueous silver nitrate
iodide (I –) acidify with dilute nitric acid, then add yellow ppt.
[in solution] aqueous silver nitrate
nitrate (NO3–) add aqueous sodium hydroxide, then ammonia produced
[in solution] aluminium foil; warm carefully
sulfate (SO42–) acidify, then add aqueous barium nitrate white ppt.
[in solution]

Tests for aqueous cations

cation effect of aqueous sodium hydroxide effect of aqueous ammonia
3+
aluminium (Al ) white ppt., soluble in excess giving a white ppt., insoluble in excess
colourless solution
ammonium (NH4+) ammonia produced on warming –
calcium (Ca2+) white ppt., insoluble in excess no ppt. or very slight white ppt.
copper (Cu2+) light blue ppt., insoluble in excess light blue ppt., soluble in excess,
giving a dark blue solution
iron(II) (Fe2+) green ppt., insoluble in excess green ppt., insoluble in excess
iron(III) (Fe3+) red-brown ppt., insoluble in excess red-brown ppt., insoluble in excess
2+
zinc (Zn ) white ppt., soluble in excess, giving a white ppt., soluble in excess,
colourless solution giving a colourless solution

Tests for gases

gas test and test result
ammonia (NH3) turns damp red litmus paper blue
carbon dioxide (CO2) turns limewater milky
chlorine (Cl 2) bleaches damp litmus paper
hydrogen (H2) ‘pops’ with a lighted splint
oxygen (O2) relights a glowing splint

Cambridge IGCSE Chemistry 0620. Syllabus for examination in 2015. 37