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SPECIAL SECTION FEATURE FEATURE BY THE NUMBERS


AIHce Recap Analysis of Metals Fume Hood Pneumoconiosis
and Metalloids Testing in the U.S.

August 2020

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FEATURES

24
WHAT’S ON YOUR WORKPLACE SURFACES?
SURFACE SAMPLING, CONSENSUS STANDARDS,
AND LABORATORY ANALYSIS
Recent developments have put greater emphasis on the
need for surface sampling and standard protocols for such
sampling. This article describes available surface sampling
methods, with a focus on consensus standards, as well as
caveats to consider when sending these samples to a
laboratory for analysis.
BY MIKE BRISSON AND KENN WHITE

30
MEASUREMENT OF TRACE METALS AND METALLOIDS
Pt Be
DELIBERATIONS FROM AN ASTM WORKSHOP
In light of impending reductions in limit values for metals
and metalloids such as antimony, beryllium, manganese,
and nickel, all aspects of validated measurement methods,
including sampling, sample preparation, and instrumental

Mn analysis, may need to be reviewed. To debate these issues,


an ASTM workshop on the measurement of trace metals
and metalloids at workplaces was held in October 2019.
BY STEVEN VERPAELE AND OWEN BUTLER

35
FUME HOOD PERFORMANCE TESTS
METHODS TO VERIFY PROPER FUNCTIONING
People working in laboratories rely on proper performance
of fume hoods as their primary means of protection from
overexposure to hazardous airborne chemicals generated
during scientific activities. This article describes methods
to verify that fume hoods are functioning properly.
BY THOMAS C. SMITH

CONTRIBUTORS
MIKE BRISSON, FEATURE AUTHOR STEVEN VERPAELE, FEATURE AUTHOR THOMAS C. SMITH, FEATURE AUTHOR
Michael J. (Mike) Brisson, MS, PMP, FASTM, is a fellow Steven Verpaele is an industrial hygienist with the Nickel Institute Thomas C. Smith is president of 3Flow in Cary, North Carolina,
technical advisor at Savannah River National Laboratory, in Brussels, Belgium, and a member of the AIHA Sampling and and a member of the ASHRAE 110, ASHRAE TC9.10, ASSE Z9, and
Aiken, South Carolina. Laboratory Analysis Committee. ASSE Z9.5 committees.

| August 2020 4
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AUGUST 2020

Volume 31 Number 7

EDITOR IN CHIEF
Ed Rutkowski: erutkowski@aiha.org

COLUMNS & DEPARTMENTS MANAGING EDITOR


Kay Bechtold: kbechtold@aiha.org

8 PRESIDENT’S MESSAGE 16 NEWSWATCH EDITORIAL ASSISTANT


Abby Roberts: aroberts@aiha.org
Reflections on Our First Virtual OEHS and Industry News
AIHce DESIGNER
BY LINDSAY COOK 20 ADVERTISERS’ INDEX Janelle Welch, 2 Hounds Media

9 LABORATORIES 39 PRODUCT FEATURES PRODUCTION MANAGER


Jim Myers: jmyers@aiha.org
AIHA LAP’s Response to COVID-19
BY CHERYL O. MORTON 40 COMMUNITY ADVERTISING REPRESENTATIVE
AIHA News MCI | USA
10 LABORATORIES Holly Klarman: holly.klarman@mci-group.com
Fixing Lab Safety Failures 42 BY THE NUMBERS
CHIEF EXECUTIVE OFFICER
BY JAMES STUBBS AND MAHDI FAHIM Pneumoconiosis Deaths in the
Lawrence D. Sloan, CAE: lsloan@aiha.org
United States
12 SPECIAL SECTION
AIHce EXP Goes Virtual The Synergist® is a copyrighted publication of the American Industrial
BY KAY BECHTOLD, ABBY ROBERTS, AND Hygiene Association, 3141 Fairview Park Drive, Suite 777, Falls Church,
VA 22042; (703) 849-8888; e-mail synergist@aiha.org. No part of The
ED RUTKOWSKI
Synergist may be reprinted without the express written consent of AIHA.
Submission of articles or letters to the editor are welcome, but AIHA
and The Synergist will determine what to publish and reserve the right to
edit all submissions for content, style, length and clarity.

The Synergist (USPS #009-332) is published monthly except a combined


June/July issue by the American Industrial Hygiene Association, 3141
Fairview Park Drive, Suite 777, Falls Church, VA 22042 for $50 per year
for members; nonmembers may subscribe for $315/yr. International
nonmembers may subscribe for $415/yr (U.S. funds). Periodicals
postage paid at Merrifield, Virginia, and additional mailing offices.
POSTMASTER: Send address changes to The Synergist, American
Industrial Hygiene Association, Attn: Customer Service, 3141 Fairview
Ü IN THE DIGITAL EDITION Ü ON AIHA.ORG Park Drive, Suite 777, Falls Church, VA 22042. ISSN 10667660.
See digital content at Latest news:
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Canadian addresses to PO Box 503, RPO West Beaver Creek, Richmond
Hill ON L4B 4R6.

EDITORIAL ADVISORY BOARD MEMBERS


COMING IN SEPTEMBER:
Jeff Behar, California Institute of Technology
Toxic Metals in the Workplace | Ethics and Credentials | PSX 2020 Preview Patricia Crawford, Consultant
M. Cathy Fehrenbacher, U.S. EPA
Don Garvey, 3M Co.
The Synergist’s mission is to provide AIHA members with news and information about
Stephen Hemperly, Western Digital Corporation
the occupational and environmental health and safety fields and the industrial hygiene Hank Muranko, Muranko & Associates
profession. The Synergist focuses on industry trends and news, government and regulatory Derek Popp, Wisconsin Occupational Health Laboratory
activities, key issues facing the profession, appropriate technical information and news on Doris Reid, Goodrich Corporation
association events and activities. John Rekus, John F. Rekus & Associates Ltd.
The Synergist’s objective is to present information that is newsworthy and of general
interest in industrial hygiene. Opinions, claims, conclusions, and positions expressed in this
publication are the authors’ or persons’ quoted and do not necessarily reflect the opinions
of the editors, AIHA, or The Synergist.

| August 2020 6
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PRESIDENT'S MESSAGE

LINDSAY COOK, CIH, CSP, FAIHA,


is retired senior vice president and now
Reflections on Our First
principal consultant at The EI Group, an
environmental health and safety consult-
ing firm in Morrisville, North Carolina.
Virtual AIHce
He can be reached at cook@ei1.com.
BY LINDSAY COOK, AIHA PRESIDENT

Send feedback to synergist@aiha.org.

T
he Board of Directors’ decision in April to convert AIHce EXP sions on June 2 and June 3 were deliv-
2020 from a live event to a virtual conference was likely one ered flawlessly. The June 1 sessions
of the most difficult decisions we’ll ever have to make as were scheduled to be rebroadcast. As
a Board. But we had no choice. At the time, the COVID-19 a thank-you to attendees for sticking
pandemic was spreading in many areas of the United States, with us, AIHA committed to delivering
Atlanta included. The AIHA staff had exhaustively considered access to AIHce OnDemand weeks
all options, including even cancellation, and recommended we move forward ahead of schedule, so anyone who was
with a fully virtual event. The decision was a calculated risk since we had never unable to attend the rebroadcast of the
before held a virtual event on such a scale. But considering our obligation to June 1 sessions wouldn’t have to wait
deliver quality education to our members, and with the health and safety of our long for the education they wanted.
attendees, exhibitors, and staff foremost in our minds, the decision to go fully
virtual was straightforward. EXCEEDING EXPECTATIONS
In a difficult year, AIHce EXP 2020 was
a significant success. We overcame
The challenges of an all-virtual AIHce in constant communication with our many challenges and fulfilled our obli-
were significant. Nothing like it had attendees and with our online learning gation to safely deliver high-quality
ever been attempted in our industry. vendor to troubleshoot the problem. education. I am deeply grateful to the
We overcame The educational program had to be But that afternoon, staff made the presenters for their openness to shar-
pared down to a manageable number difficult decision to call off the rest of ing their expertise in new ways, to staff
many challenges of sessions. The prerecording of ses- the day’s programming. for their hard work, to our exhibitors
and fulfilled our sions required arranging logistics Our attendees’ frustrations were for sticking with us, to the volunteers
obligation to with close to 200 presenters and an shared by the Board and staff. In some on the Conference Planning Commit-
safely deliver all-hands-on-deck effort from staff ways, we were victims of our own suc- tee for developing an excellent educa-
to conduct the recordings. The online cess. With no previous all-virtual AIHce tional program, and to the sponsors
high-quality delivery system needed to be prepared experience to draw from, staff had made whose commitment to our profession
education. for go-time on June 1. And it all had to an educated guess about the size of the makes AIHce possible.
be done in a matter of weeks. audience, but the number of attendees If you participated in our first-ever
far exceeded our expectations. A late fully virtual AIHce, I hope you found it
OVERCOMING CHALLENGES surge of registrations the final week- a worthwhile event. Preliminary data
The conference got off to a won- end before the conference resulted in from our post-conference survey indi-
derful start. Like many of you, I was a significantly larger audience than we cate that almost all attendees had a
delighted by René Rodriguez’s Opening had planned for: over 2,000 participants, positive experience. My hope is that I
Session address on Monday. René’s almost half of what we see at our face- will see you at an in-person conference
clever use of prerecorded segments to-face conferences! Unfortunately, the in Dallas next May. However, if circum-
demonstrated the potential of online online learning system buckled under stances require a continued virtual
education. the volume. approach, we are confident that we
As the day progressed, the system Thanks to some technical adjust- will continue to meet or exceed our
for submitting online credit was over- ments and the flexibility of staff and members’ expectations for timely, rel-
whelmed, and many attendees had presenters, we solved the problems. evant, and value-added educational
trouble joining sessions. Staff were The system was reworked, and ses- content.

| August 2020 8
LABORATORIES

CHERYL O. MORTON is managing


director of AIHA Laboratory Accreditation
AIHA LAP’s Response
Programs, LLC. She can be reached at
cmorton@aiha.org. to COVID-19
Send feedback to synergist@aiha.org.
BY CHERYL O. MORTON

M
ost occupational health and safety experts know the that certain AIHA LAP laboratories
importance of reliable data from accredited testing can analyze SARS-CoV-2 and related
laboratories. During the COVID-19 pandemic, OHS viruses, AIHA LAP has added anal-
professionals may require clinical testing or SARS-CoV-2 ysis of viruses using reverse tran-
testing of surfaces and air. Those experts relying on scription-polymerase chain reac-
laboratories accredited by AIHA Laboratory Accreditation tion (RT-PCR) to the Environmental
Programs should remain confident in the quality of our laboratories’ analysis. Below Microbiology Laboratory Accreditation
is information about how AIHA LAP has responded to COVID-19. Program’s Molecular Scope Category.
Some EMLAP labs that analyze viruses
on surfaces and in air and are already
Cancellation of on-site assessments. surveillances for all remote assess- accredited within the Molecular Scope
AIHA LAP’s priority is the health and ments so that we as an accreditation Category will soon add viruses to their
In early April, well-being of its staff, site assessors, and body can have even more confidence scopes. Contact Drake McGregor at
laboratory staff. In early April, AIHA LAP in the remote assessments conducted dmcgregor@aiha.org or (703) 846-
AIHA LAP can-
cancelled most on-site assessments for each accredited laboratory. 0739 for more information on how
celled most on-site and is now performing primarily remote Same technical rigor. Our goals to gain accreditation for analysis of
assessments and assessments. All of our site assessors are to have all AIHA LAP laboratories viruses under the EMLAP Molecular
is now performing and staff have been trained on newly accredited to the 2017 version of ISO/ Scope Category or for help in finding
released remote assessment proce- IEC 17025, General Requirements for a qualified microbiology lab that can
primarily remote
dures that can involve the use of web- the Competence of Testing and Calibra- conduct RT-PCR analyses for viruses.
assessments. based video technology (for example, tion Laboratories, by the end of the year COVID-19 webpage. Finally, AIHA
FaceTime, Zoom, GoToMeeting, WebEx) and, more importantly, to ensure that LAP has published a COVID-19 page
and document sharing software. Our AIHA LAP’s remote assessments are on our website at bit.ly/aihalapcovid
assessors also meet once a month to conducted with the same technical where you can find a Frequently Asked
exchange ideas on remote assessment rigor as our on-site assessments. Questions document (PDF, bit.ly/
techniques and best practices. Risk-based approach to resuming aihalapcovidfaq) and a video on remote
Readiness for assessment. Remote on-site assessments. As states and assessments (bit.ly/aihalapcovid
assessments are not performed auto- regions begin to reopen, AIHA LAP video) that can be accessed by our
matically. AIHA LAP laboratories are will resume some on-site assess- laboratories and other stakeholders.
screened to determine their readiness ments using a risk-based approach. We will continue to monitor the COVID-
for remote assessments. Laboratories Through a web-based survey, we will 19 situation and convey any updated
that are not prepared will have their collect exposure-related information information or our contingency plans
assessments postponed. from both the assigned site assessor for assessments on this page.
Confidence in assessments. Since and the laboratory. Decisions regard- Please feel free to contact me at
remote assessments are new to AIHA ing whether we can proceed with an cmorton@aiha.org or at (703) 846-0789
LAP, all site assessor reports from on-site assessment in whole or in part should you have any questions or need
remote assessments are undergoing will be made on a case-by-case basis. more information about remote assess-
review by members of our Technical RT-PCR analysis added to EMLAP ments or any of AIHA LAP’s actions
Advisory Panel. We are also scheduling scope. To make it clear to customers related to COVID-19.

9 www.aiha.org |
LABORATORIES

JAMES STUBBS is the associate director


of the EHS Department at the University of
Fixing Lab Safety Failures
Utah. He has over 25 years of experience
in IH and health and safety, including 20 BY JAMES STUBBS AND MAHDI FAHIM

years in an academic research laboratory


environment, and is the outgoing chair
of the AIHA Laboratory Health and Safety
Committee.

L
MAHDI FAHIM is the assistant direc-
tor-laboratory safety manager at North aboratory environ- barriers to its development still exist were originally designed as offices,
Carolina State University, Environmental ments challenge in the lab environment. Chief among classrooms, or computer labs. In such
Health and Safety Department. He is an industrial hygienists these is the lack of administrative spaces, fume hoods and other engi-
industrial hygienist with over 25 years of in ways unlike other support. For example, a recent safety neering controls are either nonexis-
experience in academic and industrial workplaces. While symposium at a major university held tent, poorly maintained, or improvised
research environments, specializing in the rapidly changing a session on field research safety. in ways that may introduce even more
chemical safety and laboratory exhaust research environment advances the The presentation introduced tools, hazards to the lab.
ventilation systems. He is an active frontier of scientific knowledge, inno- such as templates and guides, that A researcher at one of the authors’
member of AIHA, I2SL, and ACGIH. vation also introduces new hazards and researchers could use to compile institutions hired his brother-in-
risks to this unique work environment. a field research safety plan. The law, a handyman, to connect two
Send feedback to synergist@aiha.org. response to the session demon- fume hoods—which the department
strated the lack of safety culture at had received secondhand from an
It’s common knowledge in the industry the institution: at the end, the chair upgrade project in another building—
that there have been many significant of the biology department said that if to the building’s exhaust system using
lab incidents in the recent past, includ- the university made the tools manda- dryer vent hose. Because the enter-
ing the tragic death of UCLA gradu- tory, then researchers would choose prise saved money, the administra-
ate student Sheri Sangji in 2009, the to lie on the form rather than use tion praised the researcher—despite
2010 explosion at Texas Tech, and the the tools. Calling the safety culture the makeshift nature of the job, the
2016 explosion at the University of recommendations “ridiculous,” the uncertain condition of the hoods,
Hawaii. These incidents demonstrate department chair insisted that using and the fact that the scientist’s cya-
the need for robust, comprehensive the tools would take too much time. nide-based research warranted extra
safety programs in lab environments. This incident showed the other par- caution. Poor control mechanisms in
Evaluations of these recent events, and ticipants in the session that depart- the laboratory are a tangible result of
third-party reviews of safety programs, ment leadership did not support safety, an inadequate safety culture among
have revealed the failure points that and discouraged the development of department leadership. Combine a
contributed to the incidents, which, an effective safety culture. Leadership lack of proper controls, including PPE,
if ignored, will likely lead to more. must commit to the idea that good with highly hazardous research mate-
Researchers and IHs cannot rely on science is safe science. rials, and the consequences could be
Leadership must luck to prevent incidents in labs—we Poor control mechanisms. Often, devastating.
commit to the idea must diligently work toward safer labs. the lack of good control mechanisms Lack of resources. Researchers
that good science contributes to lab incidents. This often push back on the need to pur-
FAILURE POINTS phenomenon occurs in part because chase vital safety equipment, stating
is safe science.
The following failure points have been standard operating procedures are that their grant funds are restricted.
identified as contributing significantly rarely written down, and when they are, EHS programs are often understaffed
to lab incidents. they are often scavenged or borrowed and underfunded. IH and EHS pro-
Lack of a good safety culture, or from another source and are not cus- fessionals are very good at doing
presence of a poor safety culture. IHs tomized to the lab’s actual operations. more with less, but at some point,
have long discussed and promoted Also, physical space is limited at many the capacity of a system to make do
good safety culture—what it is, how to institutions, so often research labora- on limited resources becomes over-
achieve it, and so on—but significant tory operations move to spaces that loaded. Hazards go unmitigated and

| August 2020 10
LABORATORIES

people are put at risk. To prevent


accidents, organizational leadership
must step up, increase the capacity
of safety management systems, and
provide the resources researchers
need to maintain not only compliant
safety programs but those built on
industry best practices.
Lack of education. Training is
the fallback of every OSHA citation
abatement. What step do adminis-
trators claim to take to prevent the
accident from happening again?
Retrain all staff on relevant topics.
Training is important; relevant,
impactful training is even more so.
Good training is memorable, not
tedious, and it instills understanding,
not just of what must be done, but
why it must be done. Training is not
the endpoint of an OSHA citation but
the beginning of lab incident preven- the data used to predict outcomes Texas Tech is just one example of the The Synergist, AIHA’s Laboratory
tion. Employees who understand why in lab operations? If not, why do the impacts of a lab that neglects change Health and Safety Committee will
we have the programs we have and inspections at all? Are there better management, and of the need for present a series of articles with
why we need them have a different ways to provide oversight in the lab hazard analysis at every step in an information to help address these
mindset than employees who do not, environment? What about near-miss experimental process. failure points, including case studies,
and contribute to that overall goal reporting and other mechanisms? lessons learned, and novel concepts
of a positive safety culture. Training We need to ensure that oversight RESOURCES FOR LAB SAFETY and approaches, with the goal of pro-
does not prevent incidents, but good programs actually change behav- There are many failure points lead- viding resources to help implement
training does give employees tools ior and are not just checking a box ing up to lab safety incidents, but stronger safety programs up front.
that, when properly applied, prevent each year. those discussed above encompass As we have all heard, a penny of pre-
incidents. Lack of hazard review and man- many of them. In coming issues of vention is worth a pound of cure.
Lack of capable oversight. Lab agement of change. Often research-
inspections are the bread and butter ers perform experiments without
of lab safety programs. EHS depart- reviewing the hazards involved at RESOURCES
ments develop checklists, send tech- each step in the proposed proce- The Synergist: “Laboratory Chemical Safety Incidents, 2001–2018,” bit.ly/labsafety
nical experts into labs to conduct dure. Changes to a procedure are incidents (November 2018).
inspections, and collect mountains usually done on the fly without taking The Synergist: Letter from James A. Kaufman, bit.ly/labsafetyletter (November 2014).
of data, but then what? Does the time to consider their impacts and The Synergist: “Safety Test: What’s Behind the Rash of Incidents in Academic Labs?”
new data drive the programs? Is associated risks. The incident at (August 2014).

11 www.aiha.org |
Kesu01/DepositPhotos
AIHce EXP Goes Virtual
Forced Online by COVID-19, AIHce EXP 2020 Demonstrates
the Potential of Virtual Education
By Kay Bechtold, Abby Roberts, and Ed Rutkowski

O
n April 15, due to safety concerns stemming from the COVID-19
pandemic, AIHA’s Board of Directors announced that AIHce EXP
2020 would not be held in Atlanta as planned. Instead, the confer-
ence would be transformed into a fully virtual event to be broadcast online
June 1–3, the same days attendees were supposed to gather in Atlanta.

| August 2020 12
The decision spawned a mammoth effort from staff, prepared and being panicked,” he said. “If you just talk
volunteers, and presenters to convert the conference about how bad things are and don’t give me an actionable
program from face-to-face to virtual in a matter of weeks. thing to do, you’re just causing fear.”
Eighty-some sessions were prerecorded, while plans were
made to accommodate about 20 live broadcasts. Commit- HURDLES REMAIN FOR COVID-19 VACCINE
tee meetings and professional development conferences NIOSH Director Dr. John Howard summarized the cur-
were rescheduled. (See page 40 for more information rent state of knowledge regarding the COVID-19 pandemic
about the transformation of AIHce EXP 2020.) on June 1, addressing disease transmission, testing, mit-
Despite technical glitches that affected the submission igation strategies, and vaccine development. Howard’s
of course credits and forced the rescheduling of sessions message regarding a vaccine was hopeful but cautionary.
planned for the afternoon of June 1, the first fully virtual “Things are happening faster than we’ve ever seen
AIHce EXP exceeded expectations. Counting PDC and before,” Howard said of efforts around the world to
single-day attendees, more than 3,100 people experienced develop a vaccine. But given that development encom-
some or all of the conference. The decision to prerecord passes several phases with the last involving thousands
most presentations allowed presenters to add unexpected of volunteers, it is likely to take 12 to 18 months before
value by engaging in real-time chat with attendees while a vaccine is ready. Howard also reminded listeners that
their sessions were broadcast. And René Rodriguez book- resistance to vaccination has taken hold among people
ended the conference with opening and closing session who question the safety of vaccines. “It’s important to
addresses that made full use of the virtual format and remember even when we do get a vaccine” that convincing
demonstrated the potential of online-only conferences. people to take it will be a challenge, he said.
Howard emphasized the role of aerosols in trans-
THE COURAGE SCALE mitting COVID-19, explaining that infected individuals
Rodriguez, an author and speaker, opened AIHce EXP generate particles containing the virus when they cough,
2020 June 1 with a discussion of the central role occupa- sneeze, or speak. While the larger droplets fall to the
tional health and safety professionals can play in leading ground relatively quickly, smaller particles can stay
their organizations’ response to the COVID-19 pandemic. airborne for long periods. Recently published research
In a series of prerecorded vignettes, Rodriguez addressed indicates that even speech from asymptomatic people can
techniques leaders use to influence behavior, drawing transmit disease, Howard said.
lessons that have broad application but are particularly The virus can also be transmitted through contact with
resonant as countries around the world continue to deal surfaces that have infectious material, Howard said. The
with the COVID-19 pandemic. length of time the virus lasts on certain surfaces varies.
In a pandemic, leaders are under a microscope: their Serology testing, which detects the presence of anti-
every word and action will be judged, and they must set bodies, looks for evidence of prior infection but does not
examples for others to follow. “Right now is an opportu- identify whether people are protected from reinfection.
nity for you to really set the tone for what people around Howard said that experiments have shown that antibodies
you are thinking,” Rodriguez said. One of the ways that protect monkeys from reinfection, but scientists do not yet
leaders and others can achieve desired results is by affect- know how long this protection lasts.
ing what drives behavior—primarily people’s beliefs. But Mitigation strategies developed by CDC have attempted
rather than challenging others’ beliefs, Rodriguez encour- to address the many ways that people congregate at home,
aged the audience to approach change in a different way, at work, and during transport. While guidelines vary for
by causing an “inner shift” that affects behavior. different circumstances, the primary strategy, Howard
To help leaders gauge their effects on people, Rodriguez said, is to keep infected people away from the non-
discussed the work of the psychiatrist David R. Hawkins, infected. Studies show that stay-at-home orders have
whose 2013 book Power vs. Force posits a hierarchy of been very effective in reducing transmission.
consciousness that encompasses seventeen separate levels,
from feelings of shame, guilt, and apathy at the bottom SAMPLING IN AN ENGAGED COMMUNITY
to peace, love, and enlightenment at the top. In Hawkins’ An industrial hygienist from a consulting firm that par-
model, courage is midway between shame, the lowest ticipated in the sampling of ethylene oxide (EtO) in the
level, and enlightenment, the highest. Willowbrook, Illinois, community discussed his
Rodriguez encouraged attendees to think of Hawkins’
levels as a scale. Effective leaders, he suggested, are those
who help people reach the higher levels on this “courage
scale.” A leader’s goal should be to deliver information that More Conference News from the AIHce Daily
motivates positive action, Rodriguez said. And a leader Visit bit.ly/aihcedaily2020 for additional Synergist reporting
on AIHce EXP 2020.
must take care to project calm in times of crisis.
“We have to understand the difference between being

13 www.aiha.org |
experiences on June 1 as part of a prerecorded virtual ses- drawn the attention of organizations such as the American
sion. The presenter, Benjamin Chandler of GHD Services Chemistry Council and advocacy groups. Willowbrook res-
in North Little Rock, Arkansas, shed light on the sam- idents took a keen interest, filling meeting rooms for town
pling challenges associated with a case that drew national hall discussions.
attention and resulted in the shuttering of a Willowbrook By the time sampling concluded in August 2019, Chan-
facility. dler said his team had taken more than 200 ambient air
In August 2018, EPA released information indicating samples of indoor and outdoor environments, from areas
that residents of Willowbrook and surrounding areas were upwind and downwind of the Sterigenics facility. The
at increased risk of cancer from exposures to EtO. The team consistently found background levels of EtO above
gas was being emitted by Sterigenics, whose Willowbrook the EPA risk criteria up to three miles from the facility.
facility used EtO to sterilize medical devices. The com- Detectable levels of EtO were found inside residences and
munity was alarmed by EPA’s findings, and the Village of businesses.
Willowbrook formed a task force to investigate the issue. “Some of the data we collected ultimately was used to
The task force hired GHD to conduct sampling. issue a seal order to Sterigenics,” Chandler said. Not long
One challenge was identifying laboratory methods. Sev- after the sampling project ended, Sterigenics announced it
eral options exist for collecting air samples in workplaces, would permanently close its Willowbrook plant.
Chandler said, but criteria for community exposures were
much lower. REFOCUSING OPERATIONS DURING COVID-19
“We were unable to initially find a method with a labo- In June, General Motors was among the businesses
ratory that gave us a low enough detection limit,” Chandler already well into their response to COVID-19. Eltaneice
explained. Eventually, a few labs modified their methods Bolden, GM’s global manager for industrial hygiene,
and achieved a detection limit of around 0.02 parts per shared her company’s efforts to refocus operations during
billion, a level that allowed comparison to some existing the pandemic with AIHce EXP attendees in a prerecorded
limits corresponding to a 1-in-10,000 risk of cancer but session broadcast on June 3.
not low enough for EPA’s estimated 1-in-10,000 cancer As a global operation, GM had a preview of what was
risk level for EtO of 0.01 ppb. coming when its facilities in Asia were shut down by
Sample collection began in November 2018 following government order in the pandemic’s early days. Before
EPA TO-15, Determination of Volatile Organic Com- GM’s sites in North and South America shut down as well,
pounds (VOCs) in Air Collected in Specially-Prepared the company instituted visitor questionnaires that were
Canisters and Analyzed by Gas Chromatography/Mass eventually expanded for use by all employees. At the same
Spectrometry. By then, Chandler said, the project had time, GM fielded concerns about incoming materials from
suppliers around the world. The company began sani-
tizing shipments prior to arrival. Notices were placed on
the containers to indicate they had been sanitized so that
employees at GM’s assembly plants would be willing to
open them. The company eventually began recommending
THE FUTURE OF AIHA HAS ARRIVED. that anyone who could work from home should do so. In
mid-March, Bolden said, came the official shutdown of all
COME TAKE A LOOK. nonessential operations.
Essential employees continued to work, mostly from
Changes in our industry are inspiring changes at AIHA. We are dedicated to being a
forward-looking organization, working to advance the Occupational Health and Safety home, while several of the company’s U.S. sites remained
profession — enhancing our member services and recruiting the next generation of open to fill critical needs. GM formed a “COVID Team,”
professionals into our ranks.
comprising representatives from several departments.
All with a bold new look. Come see the future.
Medical staff developed guiding principles, interpreted
aiha.org
guidelines, and responded to cases of illness, while safety
and industrial hygiene personnel revised the respiratory
protection program and developed policies for face shields
AIHA Rolls Out New Brand and for sanitizing shared fall hazard equipment. Members
On June 1, prior to the Opening General Session, AIHA introduced of GM’s facilities team established stepped-up cleaning
a new logo and a new tagline. The logo incorporates a design that schedules, and engineering staff helped set up new pro-
evokes the “plan-do-check-act” process, which is a key component duction lines for some of GM’s COVID-19 response work,
of occupational health and safety management systems. AIHA’s particularly for mask production. The company also needed
tagline, previously “Protecting Worker Health,” is now “Healthier strategies and guidance for managing HVAC, cooling fans,
Workplaces. A Healthier World.” team rooms, and rarely used spaces. Operations personnel
As part of the new brand, AIHA will identify itself primarily by managed return-to-work requirements, facility entry points,
its acronym when communicating with outside audiences. For and social distancing. Chemical risk mitigation, purchasing,
more information, visit bit.ly/aihabrand.
and corporate communications were also critical to GM’s
response team, Bolden said.

| August 2020 14
GM also created a comprehensive “playbook” that NEUROLOGY FOR LEADERS
covered items like the company’s risk mitigation strat- Leadership—particularly leading people under stress—is
egy, communication and awareness efforts, sanitization a skill that takes years of trial and error to develop. In the
schedules, and approaches to social distancing and Closing Session, broadcast on June 3, René Rodriguez
ventilation. addressed a virtual audience on techniques based in neu-
“When the hourly workforce comes back, they’re going rology that leaders can use to exert influence.
to have nothing but questions and concerns, and we Drawing on the work of Dr. Paul MacLean, Rodriguez
know that,” Bolden said. “So it’s up to us . . . to know the illustrated the three systems within the brain: the “rep-
rules and understand them.” tilian” brain, or basal ganglia; the “mammalian” brain,
or limbic system; and the “human” brain, or cerebral
SINCLAIR LECTURE: RECYCLING IN CALIFORNIA neocortex.
Reporter Susie Neilson, a 2019 graduate of the University The reptilian brain oversees all autonomic functions,
of California-Berkeley’s School of Journalism, delivered such as breathing and heart rate—in other words, sur-
the 2020 Upton Sinclair Memorial Lecture on June vival. In times of extreme stress, this part of the brain
4. Neilson described a project she and her classmates takes control, to decide quickly between fight, flight, or
worked on during their second year. “Unseen: Living freeze responses. During this time, the systems in the
in the Shadows of the Golden State” focused on work- higher parts of the brain, including the limbic system,
ers who are at risk for injury, and who are often denied which governs memory and logic, and the neocortex,
healthcare, safety training, and legal protection, while which is responsible for planning and predicting out-
working in jobs not often under public scrutiny. comes, go dormant. People under extreme stress make
Neilson’s contribution to “Unseen,” titled “On the quick decisions to ensure their survival, not well-thought-
Line,” was an investigation of the state’s waste and out plans. Unfortunately, during the uncertainty of the
recycling workers. Her research revealed that recycling COVID-19 pandemic, many people’s brains are currently
facilities are tied for the fourth highest occupational operating in this state, Rodriguez said.
injury rate among all American industries. Neilson inter- A leader’s job, Rodriguez said, is to inspire a sense
viewed workers who spoke of having handled grenades of safety and allow people to engage the functions of
on the line, in addition to dealing with broken glass, dust, their limbic system and neocortex. Once a leader has
and toxic chemicals. assured people that their basic physical and social needs
Victoria Leon was one of the many people Neilson have been met, they are in a position to make logical,
interviewed over the course of her project. In 2016, Leon long-lasting decisions, he explained.
was injured on the job. That day, a doctor treated her To inspire change, according to Rodriguez, leaders
with pain relievers and minor physical therapy, but over need to appeal to others’ values and their desire for
time, Leon found herself increasingly incapable of per- community through effective communication. Rodriguez
forming her work. described a communication technique called “framing,”
According to Neilson, Leon asked multiple times to a way of answering questions or communicating infor-
see a doctor again, but her supervisor refused. Eventually mation that encourages the listener to make a personal
she was permitted to see a doctor, who dismissed her connection with the speaker.
injury without examining her and asserted that the injury “A powerful frame can cause an internal shift in us
was not work-related. A qualified medical evaluator for emotionally,” Rodriguez said. “If you could relate to that
the state of California later found that Leon’s injuries frame, if that triggers a value set inside you, [then] you’ve
were work-related and had left her partially disabled with connected.”
40 percent loss in upper body strength.
The lawyers who Neilson spoke with for the project WHAT HAPPENS NEXT YEAR?
stated that while most employers genuinely want their As this issue of The Synergist went to press, AIHA was
workers to be well, they are often concerned with con- preparing to hold AIHce EXP 2021 in Dallas, May 24–26.
trolling their company’s healthcare costs. California’s The health and safety of attendees is of paramount con-
progressive safety laws should protect workers at recy- cern, and plans may change as the conference draws
cling facilities but are grossly underenforced, Neilson closer. For the latest information, visit aihceexp.org.
said. She explained that most recycling facilities in the
state were not inspected during a four-year period from KAY BECHTOLD is managing editor of The Synergist. She
2014 to 2018, while between 2015 and 2017 the rate of can be reached at kbechtold@aiha.org.
injuries for recycling workers increased. Neilson said that
during the COVID-19 pandemic, recycling plant workers ABBY ROBERTS is AIHA’s editorial assistant. She can be
reached at aroberts@aiha.org.
have continued working in close quarters and handling
increased amounts of residential waste, some of it con-
ED RUTKOWSKI is editor-in-chief of The Synergist. He can
taminated, while lacking appropriate PPE. be reached at erutkowski@aiha.org.
Neilson’s project, and those of her classmates, can be
viewed at bit.ly/unseen-shadows. Send feedback to synergist@aiha.org.

15 www.aiha.org |
NEWSWATCH

CONSTRUCTION

Agencies Release COVID-19


Guidance for Construction
Editor’s note: Information about the COVID-19 pandemic is rapidly developing. The articles on these pages were current at time
BACTERIA AND VIRUSES of printing. Visit bit.ly/synergistcovid for the latest news and bit.ly/coronavirusresources for links to authoritative sources.
OSHA HIGHLIGHTS
CURRENT CORONAVIRUS

S
GUIDANCE eparate guidance re- present. The guidance also addresses CPWR, nearly 60 percent of construc-
As the U.S. economy began leased in May by CDC training topics and includes a lengthy tion workers in the U.S. are either
reopening in June, OSHA pub- and OSHA provides rec- section on the use of cloth face cov- over 65 or have medical conditions
lished a news release that sum- ommendations for pro- erings. or other risk factors that make them
marized the coronavirus-related tecting workers at construction sites CDC’s guidance includes recom- susceptible to COVID-19. Nearly 20
guidance currently available during the COVID-19 pandemic. The mendations for employers on reduc- percent of construction workers had
from the agency. OSHA’s guid- guidance acknowledges that con- ing disease transmission among a respiratory disease in 2019, and
ance on issues such as social struction workers, who were generally workers, maintaining a healthy work 25 percent had cancer, diabetes, or
distancing and identifying and considered essential and therefore not environment, and maintaining healthy heart, kidney, or liver disease. In 2018,
isolating sick workers is intend- subject to state stay-at-home orders, business operations. Like OSHA, more than 20 percent of construction
ed to complement guidelines may encounter additional exposure CDC recommends staggering work workers smoked cigarettes, compared
from the White House as well to the disease as other businesses shifts, physically separating workers, to 14 percent of workers in all U.S.
as the agency’s “Guidance on open and communities become more
Preparing Workplaces for COVID- active.
CDC’s recommendations for maintaining
19,” a set of recommendations OSHA stresses that its guidance
published in March and intended is non-binding and creates no new healthy business operations include
to help employers prevent or legal obligations. The guidance asso-
designating a “safety and health officer”
slow occupational spread of the ciates specific construction work tasks
disease. with the four levels of the agency’s at every job site.
OSHA recommends that “exposure risk pyramid,” which cat-
employers provide workers with egorizes tasks as lower risk, medium
refresher training and address risk, high risk, or very high risk. In restricting access to limit the number industries (PDF, bit.ly/cpwr2005data).
maintenance issues that may the context of COVID-19, lower-risk of workers in an area, reducing the Earlier in May, through the Back-
have been deferred during the tasks include those that allow employ- number of people at meetings, and toworksafely.org website, AIHA
shutdown. Employers should ees to remain at least six feet apart maintaining social distancing at choke released several guidance documents
also consult the agency’s and involve little contact with others. points such as hallways. that address return-to-work consid-
guidance related to coronavirus High-risk tasks require entering an CDC’s recommendations for erations for specific industries. The
testing, temperature checks and indoor work site occupied by people maintaining healthy business oper- AIHA guidance for construction (PDF,
health screenings, and the need suspected or known to have COVID-19. ations include designating a “safety bit.ly/btwsconstruction) identifies a
for personal protective equip- The agency does not identify tasks that and health officer” at every job site number of potential actions that are
ment during the pandemic. have a “very high” exposure risk for with responsibility for responding to not mentioned in either the CDC or
OSHA’s COVID-19 webpage at the disease. According to OSHA, this COVID-19 concerns and implementing OSHA documents, such as main-
bit.ly/oshacovidtopic collects category is not applicable for most sick leave policies. These recommen- taining daily “approved visitor” logs,
agency resources for employers construction work. dations do not appear in the OSHA considering four-day work weeks,
and workers about the coronavi- OSHA’s guidance recommends the guidance. and using color-coded access stick-
rus pandemic. use of engineering controls, such as The prevalence of COVID-19 among ers on work helmets to indicate which
plastic barriers to separate workers construction workers in the U.S. is employees can access certain areas
when working indoors, and admin- unknown, according to CPWR—The of a job site.
istrative controls, such as the use of Center for Construction Research CDC’s guidance for construction
screening questions to assess the and Training. In May, CPWR published workers is available at bit.ly/cdccon
risk of work assignments in indoor data on COVID-19 risk factors among struction. OSHA’s can be found at bit.
environments where others may be construction workers. According to ly/oshaconstruction.

| August 2020 16
NEWSWATCH

CONTROLS

OSHA Publishes FAQs on Cloth Face Coverings


A page added to the OSHA website against airborne transmissible infec- Respirators such as filtering
in June answers frequently asked tious agents, but OSHA states that facepieces are used to prevent work-
questions about cloth face coverings they can be “used to protect work- ers from inhaling airborne transmis-
in the workplace during the COVID- ers against splashes and sprays sible or aerosolized infectious agents
19 pandemic. OSHA clarifies that (i.e., droplets) containing potentially and other small particles.
cloth face coverings are intended infectious materials.” In this case, the Other topics addressed in OSHA’s BACTERIA AND VIRUSES
to contain the wearer's potentially EPA APPROVES TWO
infectious respiratory droplets and Because cloth face coverings are not DISINFECTANTS TESTED
to limit the spread of SARS-CoV-2. DIRECTLY AGAINST
The webpage explains that cloth face considered PPE, OSHA’s standards do SARS-COV-2
coverings are not personal protective not require employers to provide them. In early July, EPA approved label
equipment and “will not protect the claims for two surface disin-
wearer against airborne transmissible fectants’ effectiveness against
infectious agents due to loose fit and agency considers surgical masks as FAQ include whether employers need SARS-CoV-2 based on labora-
lack of seal or inadequate filtration.” PPE, and OSHA’s standards require to continue to ensure social distanc- tory testing conducted directly
Because cloth face coverings are not employers to provide necessary PPE ing measures are in place if workers against the virus. According to
considered PPE, OSHA’s standards to workers at no cost. However, if sur- wear cloth face coverings, and how the agency, Lysol Disinfectant
do not require employers to provide gical masks are being used only as to keep reusable cloth face coverings Spray and Lysol Disinfectant Max
them. source control, OSHA states that its clean. Cover Mist were the first prod-
Like cloth face coverings, surgical PPE standards do not require employ- View the FAQ page on OSHA’s web- ucts for which EPA had reviewed
masks will also not protect wearers ers to provide them to workers. site at bit.ly/clothcoveringfaq. testing data and approved label
claims against SARS-CoV-2. Both
BACTERIA AND VIRUSES
products were already included
on List N, EPA’s list of products
that meet the agency’s criteria
for use against the coronavirus
NIH Issues Alert on Preventing SARS-CoV-2 that causes COVID-19.
Eye Exposures EPA previously issued guid-
ance (see bit.ly/emergingpatho
A health and safety alert from the for when and where healthcare work- was also observed in some patients gens) regarding the process for
National Institutes of Health raises ers should use eye protection. OSHA’s during the Severe Acute Respiratory making claims of effectiveness
awareness about the need to protect standard for personal protective Syndrome outbreak in 2003. against emerging viral pathogens
workers’ eyes from exposure to SARS- equipment has been interpreted by No specific standard exists for the because novel viruses are typi-
CoV-2. The document describes the cally not immediately available
connection between the tear ducts and for laboratory testing. The guid-
the nasal cavity, which allows tears to Little guidance exists for when and ance allows product manufac-
drain into the back of the throat, the where healthcare workers should use turers to provide EPA with data
trachea, and then the lungs. Patients that shows their products are
with COVID-19 symptoms often have eye protection. effective against viruses that are
inflamed eyes or conjunctivitis, the harder to kill than SARS-CoV-2.
document notes. the agency to apply to biological haz- design or performance of goggles or All products on List N meet
Over 57 percent of all blood and ards such as SARS-CoV-2, according face shields for biological hazards, EPA’s criteria for use against
body fluid exposures to healthcare to Amber Mitchell, DrPH, MPH, CPH, Mitchell said, though an ANSI standard SARS-CoV-2. View the list at
workers involved the eyes, according who participated in an April 1 webi- is in development through the Interna- bit.ly/listnproducts.
to a surveillance system established nar on COVID-19 held by the National tional Safety Equipment Association.
by the International Safety Center. Institute of Environmental Health The standard will address biological
Only 6.4 percent of workers involved Sciences. “The eye is extremely rich hazards to the eyes and equipment that
in those incidents were wearing eye in blood vessels and mucous mem- can protect against them, Mitchell said.
protection. branes,” Mitchell said during her pre- A PDF of the alert is available on the
NIH notes that little guidance exists sentation. She noted that conjunctivitis NIH website at bit.ly/nihcovideyes.

17 www.aiha.org |
NEWSWATCH
BACTERIA AND VIRUSES
866-736-8347
www.RaecoRents.com
OSHA Addresses Reopening of
Rent
RentInstruments
Monitoring for Worker Safety Nonessential Businesses
Systems for All Your
Short-
Respirator orSystems
Fit Test Long-Term OSHA published guidance in June targeted to reopening businesses that were
Outdoor Projects deemed “nonessential” and shut down earlier in the COVID-19 pandemic.
Noise Dosimeters and The guidance supplements the agency’s previous guidance on preparing
Sound Level Meters
workplaces for COVID-19 and guidelines from the White House and CDC.
Perimeter Dust Studies The new guidance states that all phases of employers’ reopening plans
should include strategies for social distancing, identifying and isolating sick
Outdoor Noise Studies
employees, workplace controls, employee training, and hand hygiene, cleaning,
Fenceline Monitoring and disinfection. OSHA encourages employers to continue considering ways
to use remote work and alternative operations to conduct business.
Community Air Noise
Workers’ exposure risks to SARS-CoV-2 will depend on changing out-
Monitoring Programs break conditions in each community, OSHA says. The agency recommends
Heat Stress Monitors Dust
that employers develop policies and procedures that address preventing,
Hazardous Pollutant VOCs monitoring, and responding to emergences or resurgences of COVID-19 in
Monitoring workplaces or in communities.
Vibration “Employers should continue these practices to the extent possible to
Event Noise Monitoring help prevent COVID-19 from emerging or resurging in their workplace,” the
Silica Dust Sampling Kits
guidance states. “Such a resurgence could lead to increases in infected and
Daily, weekly, and long-term rentals. Free UPS Ground sick employees, the increased need for contact tracing of individuals who
round-trip shipping on every rental order $500 or larger. visited a workplace, enhanced cleaning and disinfection practices, or even a
temporary closure of the business.”
A PDF of the document is at bit.ly/oshareopening.

PERSONAL PROTECTIVE EQUIPMENT

Trusted for over 35 years by safety professionals studying for


their certification exams. NIOSH Publishes Instructions
for Preparing Solutions for
Qualitative Fit Testing
In June, the NIOSH National Personal Protective Technology Laboratory
(NPPTL) posted on its website instructions to make the OSHA-approved fit test
and threshold check solutions for the Saccharin Solution Aerosol Protocol,
Prepare for Your Future Bitrex (Denatonium Benzoate) Solution Aerosol Qualitative Fit Test Protocol,
and Isoamyl Acetate Protocol. These solutions are used in qualitative fit testing,
Certification Exam Prep. Self study programs for busy professionals.
Study at your own pace, when and where it’s convenient for you.
which relies on respirator wearers’ sensory detection of these test agents.
“The agents used in qualitative fit testing are usually available commer-
■ CIHprep ■ CSPprep ■ ASPprep cially in convenient, ready-to-use packaging that contains premade dilutions
■ CHMMprep ■ STSprep ■ CPEprep of the reagents,” NPPTL says. “When these ready-to-use packages are not
available, the [qualitative fit test] can be performed by using the required
■ OHSTprep ■ STSCprep ■ Safety in
solutions prepared from commercially available reagents.”
Numbers –
■ CHSTprep ■ CITprep reference manual NIOSH states that qualitative fit testing is the preferred method during the
COVID-19 pandemic because it can help slow the depletion of the inventory
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again after the test, whereas respirators used for a quantitative fit test must
be disposed of afterward because the quantitative method requires a hole
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www.datachemsoftware.com View the instructions at bit.ly/npptlqualfit.

| August 2020 18
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NEWSWATCH
BACTERIA AND VIRUSES

CDC: Quarantine, Distancing Helped Limit


COVID-19 Transmission at Basic Training
Professional Liability Insurance A U.S. Air Force base in Texas significantly limited The Lackland base instituted travel restrictions
Designed for Industrial Hygiene transmission of COVID-19 among cadets during and limited access to essential personnel, even
& Environmental Consultants basic training through nonpharmaceutical inter- for graduation ceremonies, which normally attract
ventions such as quarantine and social distancing, many visitors. When the first positive case in a
Coverage Highlights according to a CDC report released June 5. The trainee was confirmed on March 23, the base
- Professional Liability
report credits the interventions, implemented limited potential exposure by shortening the
- Pollution Liability
- Commercial General Liability over a seven-week period from March 1 through training schedule from eight and a half weeks
- Full & Part-Time Rates April 18, with limiting the number of COVID-19 to seven. Universal use of cloth face coverings
- Mold Liability Coverage cases at Joint Base San Antonio-Lackland to five was required beginning on April 6, and the base
- Exclusive Member-Only Rates out of a population of nearly 10,600 cadets for a stopped accepting recruits from areas with high
- Pandemic Endorsement
rate of 47 per 100,000 at a time when the overall community transmission of SARS-CoV-2.
($100K Sublimit) – E&O Only
rate of COVID-19 infections in the U.S. was 220 “Factors contributing to lack of transmission
Contact Us Today! per 100,000. likely included early implementation of mitigation
(855) 279-AIHA The training for incoming cadets includes strategies before the first case occurred, mobiliza-
https://AIHA.alliant.com classroom lectures, small group activities, and tion of nonmedical personnel to assist in symptom
AIHA.questions@alliant.com field exercises. Cadets are grouped into cohorts screening, and flexibility of the military training
of 50 who live in communal quarters and train staff to adjustments in programs and schedules,”
as a group. according to the report. The Lackland base had
Symptomatic trainees underwent nasopharyn- previously housed symptomatic passengers from
geal swabs, which were analyzed by polymerase cruise ships and therefore already had infrastruc-
chain reaction testing at a laboratory on base. ture in place for infected cadets.
Cadets who tested positive were isolated and The report (see bit.ly/mmwrlackland)
were not permitted to return to training until at acknowledges that the highly structured nature
least seven days after symptom onset and at least of the military base likely contributed to the suc-
three days without fever. cess of the interventions.

ADVERTISERS’ INDEX LEAD


ADVERTISER PAGE
ACS Badge 21
Alliant Insurance Services 20 EPA Rule Would Align Lead Clearance
ALS 5 Levels with Hazard Levels
Assay Technology, Inc. 19
EPA published a proposed rule in the Federal potential dilemmas for lead-based paint profes-
DataChem Software 18 Register on June 25 that would lower the clearance sionals. In the August 2019 Synergist, Kenn White
Inside Front levels for dust on floors and windowsills following and Derek Popp discussed situations where lead
EMSL Analytical lead removal activities from 40 µg of lead in dust dust in a building following abatement meets
Cover
per square foot to 10 µg/ft2 for floor dust and from the clearance level but exceeds the hazard level
Environmental Devices 250 µg/ft2 to 100 µg/ft2 for windowsill dust. The (bit.ly/synleadhazard). In such a situation, lead-
7
Corp. rule would align the clearance levels for floor dust based paint professionals may have a contractual
RAECO Rents LLC 18 and windowsill dust with new hazard levels that obligation to clear the space for occupancy even
went into effect in January 2020. though a lead hazard exists. The new rule would
RJ Lee Group Center Spread
The proposal does not address the clearance appear to address this potential conflict.
SGS North America 3 level for window troughs, which will remain 400 µg/ EPA Administrator Andrew Wheeler said the
Inside Back ft2. No EPA hazard level exists for window troughs. new proposed rule “aims to reduce one of the
SKC, Inc. Clearance levels define the maximum amount most common causes of elevated blood lead levels
Cover
of lead dust that may remain following abatement in children.”
Zefon International Back Cover activities. The discrepancy between the hazard The rule is available at bit.ly/epaleadclearance.
See this month’s Product Features on page 39. levels and the current clearance levels poses EPA is accepting comments until August 24, 2020.

| August 2020 20
NEWSWATCH
MINING
Toxic Vapor
NIOSH Reorganization Monitoring Badge
Addresses Changes in the
Mining Industry
A notice published in May by the Centers for Disease Control and Prevention
at bit.ly/reorgmining describes actions related to the reorganization of
NIOSH. According to CDC, the reorganization is intended to address changes
in the mining industry and stakeholder priorities. Seven organizational units
are eliminated entirely, including the Workplace Health Branch. The notice
also creates five new branches: the Health Hazards Prevention Branch; the
Mining Systems Safety Branch; the Human Systems Integration Branch; the
Miner Health Branch; and the Miner Safety Branch.
The purpose of the Health Hazards Prevention Branch will be to reduce
illnesses and injuries to mine workers through assessment and control of
respiratory and physical hazards. The Mining Systems Safety Branch will work • Results will be analyzed by an AIHA-LAP, LLC
to reduce accidents and injuries related to changing geological conditions and Accredited Laboratory
mine system technologies. The branch will also focus on preventing mine • Results in 72 hours
explosions, mine fires, and gas and water inundations. According to CDC’s • Chemicals such as: Formaldehyde, Xylene,
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will assess and track miner health and hazard exposures.

STANDARDS
Share your experience and knowledge
at AIHce EXP 2021!

ASHRAE Updates Legionellosis CALL FOR


Guideline PROPOSALS
In late May, ASHRAE updated its guideline on the control of legionellosis
associated with building water systems. The updated document, ASHRAE
Guideline 12-2020, is intended to help building owners and others involved
in the care of centralized building water systems manage the risk of legio-
nellosis associated with those systems.
ASHRAE notes that Guideline 12 can be useful in the implementation of
ANSI/ASHRAE Standard 188, which establishes minimum legionellosis risk
management requirements for building water systems.
A preview of Guideline 12-2020 is available on ASHRAE’s website at bit.
ly/standardsashrae.

MAY 24 - 26 | DALLAS, TX
Correction
On page 28 of the June/July 2020 Synergist, the article “The Marijuana Contribute to the conference and the profession
Dilemma” incorrectly attributes the resource “What You Need to and inspire and energize your colleagues by
Know About Marijuana Use and Driving” to the Canadian Center for submitting a presentation in your area of expertise.

www.AIHceEXP.org
Occupational Health and Safety. The fact sheet is a CDC publication.
The digital version of the article has been corrected.

21 www.aiha.org |
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THE LABS ISSUE

What’s on YOUR
Workplace Surfaces?
Surface Sampling,
Consensus Standards,
and Laboratory Analysis

T
he conduct of modern occupational health
and safety sampling can be divided into
three broad categories: sampling for con-
tents of or contaminants in ambient or
workplace air (air sampling); sampling of
solids, liquids, or solutions for content or
contamination (bulk sampling); and sampling for
materials or contaminants that have precipitated out
of the air or were purposefully or accidently distrib-
uted on surfaces (surface sampling).
Air sampling has been the field industrial
hygienist’s bread and butter when it comes to both
collecting samples for exposure assessment and
for compliance with limit values or action levels.
But some programs—EPA and U.S. Department of
Housing and Urban Development programs focused
on lead from lead-containing paint, for example—
require the collection of surface samples. In many
workplaces, samples from surfaces, when collected
at all, have often been for ancillary purposes such
as characterization of legacy facilities for cleanup.
Surface samples, particularly wipe samples, are
also useful for assessing the presence of surface
contamination in areas where workers may not be
adequately protected by personal protective equip-
ment (see the OSHA Technical Manual at bit.ly/
otmchapter2).
Recent developments have put greater emphasis
on the need for surface sampling and standard pro- BY MIKE BRISSON AND
tocols for such sampling. For example, ACGIH in
KENN WHITE
2019 established the Threshold Limit Value – Sur-
face Limit (TLV-SL) as a supplement to the airborne

| August 2020 24
TLV, particularly for substances that are dermal or
respiratory sensitizers or can be absorbed through
the skin. And this year, the COVID-19 pandemic has
created another need for surface sampling as OHS
practitioners and others study how long the SARS-
CoV-2 virus is viable on various surfaces—especially
Representations of in high-touch areas.
surfaces that may be
sampled in workplaces. Surface sampling can be a key component in OHS
assessments of risk or exposure. This article briefly
describes available surface sampling methods, with
a focus on consensus standards, as well as caveats to
consider when sending these samples to a laboratory
for analysis.

GENERAL GUIDANCE
Subcategories in surface sampling are defined by the
sampling media used: swab sampling (for small or
confined areas); vacuum sampling (using a personal
sampling pump or other such suction-producing
machine); tape lift sampling (using tape); and wipe
sampling (typically using a dry or premoistened
towelette).
Any effective sampling campaign begins with a
proper sampling strategy. Guidance on this topic can
be found in A Strategy for Assessing and Managing
Occupational Exposures from AIHA, Surface and
Dermal Sampling from ASTM International, and
the OSHA Technical Manual. OHS practitioners
should consider the purpose for sampling; any simi-
lar studies that have been published; the selection of
sampling locations; and data evaluation, including
outliers or results below reporting limits.
An article published in the October 2019 Synergist
on consensus standards and technology (see bit.ly/
synfirstchoice) discusses the benefits of using
standard sampling methods. OHS professionals
can use these methods to bolster consistency and
reproducibility, establish appropriate data quality
objectives, enhance data comparability, and build
defensibility. Consensus standards, including
ASTM, ANSI, and ISO standards, are developed by
a cross-section of OHS practitioners and subject
matter experts rather than by a single agency or
organization.
ma
ges As with any sampling program, taking time up
ty I
r/Get front to develop a good surface sampling strategy
o
oct
eD
rgu
jel,
Pla can help OHS practitioners anticipate potential
run
Pat issues. With vacuum sampling, for example, it may
Florin
,
art
alla
nsw be quite difficult (though not impossible) to collect
eekai,
nc,
cof
f
surface contaminants through a filter to obtain a
ivas
Vis
representative sample. Surfaces to be sampled may
not be readily accessible countertops, floors, and
tables and might include ductwork, ceilings, walls,

25 www.aiha.org |
or other hard-to-reach locations. Thinking about where on the surface. The OSHA Technical Manual also suggests
the sample may have deposited and how to collect repre- 100 cm2 since it is about the size of a worker’s palm.
sentative samples may be a three-dimensional exercise. Selection of wipe material is important, particularly
A free software tool that can help is the Pacific Northwest when it comes to the type of surface. For example, sam-
National Laboratory’s Visual Sample Plan, which is avail- pling a rough surface might require a different material
able at vsp.pnnl.gov. than a smooth or oily surface. The wipe material should
The amount of settled dust on the surface is another not have measurable amounts of the contaminant being
factor to consider. For large amounts of settled dust, measured. Specifications such as ASTM E1792 for lead
a bulk sampling technique may be more effective than and D7707 for beryllium address this in more detail.
other surface sampling methods. While a pre-wetted wipe Sampling technique is addressed in ASTM E1728/
substrate is usually preferred, a dry wipe or swab may be E1728M; ASTM D6966, Standard Practice for Collection
more appropriate if the surface is oily. of Settled Dust Samples Using Wipe Sampling Methods
For metals and metalloids, ASTM D7659 provides for Subsequent Determination of Metals; and NIOSH
guidance for the development of sampling plans and data Method 9102, “Elements on Wipes,” among others. These
quality objectives, selection of methods for sampling and describe the use of an “S” or “Z” pattern to ensure wiping
laboratory analysis, and evaluation of the data. A similar of the entire area being sampled, as well as the impor-
ASTM guidance document for selected organic contami- tance of folding the wipe to prevent sample loss.
nants is under development. A variety of standard wipe sampling methods is avail-
able. A partial list is provided in Table 1.
WIPE SAMPLING
What do we mean by a wipe sample? EPA’s regulation on SWAB AND TAPE LIFT SAMPLING
lead-based paint poisoning prevention in certain residen- Sterile swabs are most often used to collect biological
tial structures (40 Code of Federal Regulations 745.63) materials such as powders or fungal material from sur-
defines lead sampling as “a sample collected by wiping faces. ASTM International has two standard methods.
a representative surface of known area, as determined ASTM D7789 was developed for swab sampling for
by ASTM E1728 [now E1728/E1728M]…or equivalent fungal materials and can be used for analysis by direct
method, with an acceptable wipe material as defined in microscopy, culture, or biochemical analysis. ASTM
ASTM E1792.” This definition encompasses some key E2458 addresses swab sampling of nonporous surfaces
aspects that define the sampling area, the sampling sub- for “residual suspicious powders that are suspected bio-
strate, and the sampling technique. logical agents and toxins from solid nonporous surfaces.”
For beryllium, lead, and several other substances, In addition, NIOSH has posted a swab sampling proce-
the sampling area is defined by regulation, but in any dure for use in collecting culturable samples for Bacillus
event the sampling area should be predetermined and anthracis spores at bit.ly/nioshbacillus.
consistent. Checking for regulation is always a worth- Prepared swabs, as test kits, can be useful when col-
while search. The sampling area may also depend on lecting a sample of or for testing for contaminants in small
the amount of settled dust on the surface. ASTM E1728/ or hard-to-reach places. Swab testing kits for lead and
E1728M, Standard Practice for Collection of Settled Dust other metals and drugs are commercially available, and
Samples Using Wipe Sampling Methods for Subsequent a web search for the analyte of interest as a test kit could
Lead Determination, suggests a range of 100 cm2 (10 produce an appropriate product. For example, when deal-
cm by 10 cm) to 1 ft2 (12 inches by 12 inches), but adjust- ing with lead-based paint and lead-based paint hazards,
ments may be needed based on the amount of visible dust see bit.ly/epatestkits for the list of EPA-recognized test
kits.
Tape lift sampling is typically used for microscopic
examination rather than instrumental analysis. Standard
Table 1. Standard Wipe Sampling Methods methods include ASTM E1216, which focuses on sampling
for particulate contamination by tape lift, and ASTM
Standard ID Contaminant(s) Surface(s)
D7910. ASTM E1216 can be used for microscopic exam-
ASTM D6480 Asbestos General ination of metal, metalloid, or organic particulates, while
ASTM D6661 Organics Smooth ASTM D7910 is used for fungal materials.
ASTM D6966 Metals/Metalloids Smooth/Hard
VACUUM SAMPLING
ASTM D7296 (Dry Wipe) Beryllium Oily/Fragile
Vacuum sampling is often a good choice for obtain-
ASTM D7822 Metals/Metalloids Dermal ing samples from carpeted floors and similar surfaces,
ASTM E1728/E1728M Lead Smooth/Hard and for collecting bulk samples. Standardized vacuum
NIOSH 9102 Metals/Metalloids Smooth/Hard sampling protocols include ASTM D7144, which uses a
personal sampling pump for micro-vacuum sampling on
NIOSH 9111 (Gauze Wipe) Methamphetamine General
soft surfaces including carpets, and ASTM D5438, which
OSHA ID-125G and ID-206 Metals/Metalloids Smooth/Hard/Dermal uses a modified stand-up “high-volume sampler” (HVS)

| August 2020 26
vacuum cleaner to perform carpet sampling. Collection the qRT-PCR procedure is semi-quantitative at best, and
efficiencies of both methods have been investigated and studies should be performed to improve knowledge in this
performance data published in peer-reviewed literature area. Swabs are currently scarce due to the pandemic and
(see two articles from the Journal of Occupational and wipes can cover much greater areas, potentially improving
Environmental Hygiene in the resources section on page the sensitivity. Research into suitable wiping procedures
28 for more information). is ongoing. See the U.S. Food and Drug Administration’s
In ASTM D7144, dust collected is captured in a sample frequently asked questions on testing for SARS-CoV-2 at
cassette fitted with a collection nozzle. The collection bit.ly/sarscov2fda for information regarding SARS-
efficiency varies widely with the surface being sampled; CoV-2 test kits.
also, material gets caught in the collection nozzle. Despite
these limitations, micro-vacuum sampling is viewed as a WHAT THE LAB NEEDS TO KNOW
practical design-based method that enables data compar- Communication with the lab is key to the success of the
isons if the standard method is used. Collection efficiency sampling program. It’s important that the OHS practi-
of the D5438 method is enhanced due to high sampling tioner understands what the lab can and cannot do; the
flow rate and rigorous agitation of the surface, is demon- lab knows what it is getting and the desired data quality
strably high (overall mean 88 percent), and supports the objectives; and the OHS practitioner understands what
ASTM standard. the data from the lab mean. Thus, the lab needs to know:
• What is the target analyte?
DERMAL SAMPLING • How well do you need it done? (Here, screening meth-
A number of dermal sampling techniques are outlined in ods may be faster and cheaper than methods with all the
ISO Technical Report 14294, Workplace Atmospheres “bells and whistles” that come with accreditation.)
— Measurement of Dermal Exposure — Principles and • What else is in the sample that might impact or interfere
Methods. The report describes methods such as wiping with handling and the analysis? For example, are there
using a cotton fabric; dermal patches for selected organ- other sample components that may interfere with the
ics; smear tabs for polychlorinated biphenyls, or PCBs; target species? Are there any regulatory considerations?
and in situ methods using clothing as the collection Does the sample require special handling? What about
medium. Gloves have also been used to collect the sample the disposal of the residual and waste?
by intercepting it before it reaches the hand. Most of • What is the sample matrix? (Note that some media are
these methods have not been validated. more difficult to dissolve/digest/extract than others.)
ASTM D7822, which applies to sampling for metals Wipe material is especially important for the labora-
and metalloids, is based on methodologies developed by tory. Certain wipe materials may not be compatible with
NIOSH and utilizes a wipe (either premoistened or moist- some methods used in the laboratory, so it is important to
ened in the field) with a wiping pattern starting from the check in advance to make sure the laboratory can handle
perimeter and moving to the interior of the area being what you plan to send. In return, the lab should provide:
sampled. It includes a protocol for estimating the surface • how much it will and did cost
area of a hand when the entire hand is being wiped. • how long it will and did take
• what method is to be and was used
SARS-COV-2 CORONAVIRUS • how sensitive the method is given a sample size and was
Surface sampling for viruses, including the new SARS- given the sample size as received
CoV-2 virus (cause of COVID-19), has typically been done • how much of the target species (reporting limit) can be
in the same way as sampling for fungi and bacteria: with and was found
a pre-wetted swab. The wetting agent is often phosphate • how the data will be reported
buffered saline. Analysis is by reverse transcription • the data
polymerase chain reaction (RT-PCR) in which a specific Call the lab! They are there to help. (Editor’s note:
ribonucleic acid (RNA) sequence is converted to DNA More tips for improving collaboration between field IHs
for amplification and detection. RT-PCR can be used to and laboratory professionals can be found in an article
indicate just presence/absence, but it may also be used from the August 2016 Synergist at bit.ly/syn1608.)
quantitatively (qRT-PCR) to track the rate of amplifica-
tion. The swab should be analyzed very quickly as RNA is MORE TO COME
not as stable as DNA. Some protocols require overnight- A full-day professional development course titled “Surface
ing refrigerated samples; others require placing the swab Sampling – Issues, Methods, and Strategy for Metals,
in a viral transport medium or chaotropic lysis buffer in Metalloids, Organics, and Biologicals” was presented at
the field, the latter being preferred for long-term storage. AIHce EXP 2019 and included much of the information
While data on the limits of quantitation is available contained in this article with more detail and discussion.
for analytical procedures, no data exists regarding the The PDC was accepted for this year’s conference, but it
efficiency or uncertainty in the transfer of virus from was not presented online at AIHce EXP 2020 because it
different surfaces to swab, or the stability, recovery, or does not lend itself to virtual presentation. The same PDC
uncertainty of the transfer from swab to analyzer. Hence, will be proposed for AIHce EXP 2021. In addition,

27 www.aiha.org |
ysis Committee, serving as chair of the Environmental Lead
a Sampling Quality Assurance Manual compiled by the
Subcommittee. He can be reached at kennwhite@cox.net.
AIHA Sampling and Laboratory Analysis Committee is
scheduled for release next year. The following applies to Mike Brisson: This manuscript
has been authored by Savannah River Nuclear Solutions
MICHAEL J. (MIKE) BRISSON, MS, PMP, FASTM, is a fellow (SRNS), LLC under Contract No. DE-AC09-08SR22470
technical advisor at Savannah River National Laboratory, with the U.S. Department of Energy (DOE) Office of Envi-
Aiken, South Carolina. He is a past chair of the AIHA Sam-
ronmental Management (EM).
pling and Laboratory Analysis Committee, on the Board of
Directors of ASTM International and past chair of Com-
mittee D22 (Air Quality), chair of ISO Technical Committee Disclaimer: The United States Government retains and
146, Subcommittee 4, on Air Quality General Aspects, and the publisher, by accepting this article for publication,
convener of four ISO working groups. He can be reached at acknowledges that the United States Government retains
mike.brisson@srnl.doe.gov. a non-exclusive, paid-up, irrevocable, worldwide license
to publish or reproduce the published form of this work,
KENNETH T. (KENN) WHITE, MS, MM, CIH, CSP, FAIHA, or allow others to do so, for United States Government
FASTM, is the principal of Consultive Services in Virginia
purposes.
Beach, Virginia. He is a three-time recipient of the AIHA
Edward J. Baier Technical Achievement Award, chair of the
ASTM International Subcommittee D22.12 on Sampling Acknowledgements: The authors gratefully acknowledge
and Analysis of Lead for Exposure and Risk Assessment, Eric Esswein, Lisa Rogers, and Martin Harper for provid-
and a member of the AIHA Sampling and Laboratory Anal- ing their valuable inputs.

RESOURCES
ACGIH: Annual Reports of the Committees on TLVs and BEIs for ASTM International: ASTM D7822, Standard Practice for Dermal NIOSH Manual of Analytical Methods: Method 9102, “Elements
Year 2018. Wipe Sampling for the Subsequent Determination of Metals on Wipes,” bit.ly/niosh9102 (PDF, March 2003).
AIHA: A Strategy for Assessing and Managing Occupational and Metalloids (2018). NIOSH Manual of Analytical Methods: Method 9111,
Exposures, 4th edition, bit.ly/exposures4thed. ASTM International: ASTM D7910, Standard Practice for Collec- “Methamphetamine on Wipes by Liquid Chromatography/
ASTM International: ASTM D5438, Standard Practice for Collec- tion of Fungal Material from Surfaces by Tape Lift (2014). Mass Spectrometry,” bit.ly/niosh9111 (PDF, October
tion of Floor Dust for Chemical Analysis (2017). ASTM International: ASTM E1216, Standard Practice for Sam- 2011).

ASTM International: ASTM D6480, Standard Test Method for pling for Particulate Contamination by Tape Lift (2011). OSHA: Method ID-125G, “Metal and Metalloid Particulates
Wipe Sampling of Surfaces, Indirect Preparation, and Analysis ASTM International: ASTM E1728/E1728M, Standard Practice in Workplace Atmospheres (ICP Analysis),” bit.ly/metho
for Asbestos Structure Number Surface Loading by Transmis- for Collection of Settled Dust Samples Using Wipe Sampling did125g (September 2002).
sion Electron Microscopy (2019). Methods for Subsequent Lead Determination (2020). OSHA: Method ID-206, “ICP Analysis of Metal/Metalloid
ASTM International: ASTM D6661, Standard Practice for Field ASTM International: ASTM E1792, Standard Specification for Particulates from Solder Operations,” bit.ly/methodid206
Collection of Organic Compounds from Surfaces Using Wipe Wipe Sampling Materials for Lead in Surface Dust (2016). (May 1991).
Sampling (2017). ASTM International: ASTM E2458, Standard Practices for Bulk OSHA: OSHA Technical Manual, Section II, Chapter 2, “Surface
ASTM International: ASTM D6966, Standard Practice for Collec- Sample Collection and Swab Sample Collection of Visible Contaminants, Skin Exposure, Biological Monitoring and
tion of Settled Dust Samples Using Wipe Sampling Methods Powders Suspected of Being Biological Agents and Toxins Other Analyses,” bit.ly/otmchapter2 (February 2014).
for Subsequent Determination of Metals (2018). from Nonporous Surfaces (2017). Pacific Northwest National Laboratory: Visual Sample Plan,
ASTM International: ASTM D7144, Standard Practice for ISO: Technical Report 14294, Workplace Atmospheres — Version 7.13, vsp.pnnl.gov.
Collection of Surface Dust by Micro-Vacuum Sampling for Measurement of Dermal Exposure — Principles and Methods The Synergist: “First Choice: Consensus Standards, Tech-
Subsequent Metals Determination (2016). (2011). nology, and the IH Professional,” bit.ly/synfirstchoice
ASTM International: ASTM D7296, Standard Practice for Journal of ASTM International: Selected Technical Papers (October 2019).
Collection of Settled Dust Samples Using Dry Wipe Sampling STP1533, “Surface and Dermal Sampling,” bit.ly/stp1533 U.S. Department of Housing and Urban Development: Policy
Methods for Subsequent Determination of Beryllium and (PDF). Guidance Number 2017-01 Rev 1: “Revised Dust-Lead Ac-
Compounds (2018). Journal of Occupational and Environmental Hygiene: “Evaluation tion Levels for Risk Assessment and Clearance; Clearance
ASTM International: ASTM D7659, Standard Guide for Strategies of a Standardized Micro-Vacuum Sampling Method for of Porch Floors,” bit.ly/huddustlead (PDF, 2017).
for Surface Sampling of Metals and Metalloids for Worker Collection of Surface Dust” (March 2007). U.S. Government Publishing Office: 40 CFR Part 745, Lead-
Protection (2015). Journal of Occupational and Environmental Hygiene: “House Dust Based Paint Poisoning Prevention in Certain Residential
ASTM International: ASTM D7707, Standard Specification Collection Efficiency of the High Volume Small Surface Structures, bit.ly/40cfr745.
for Wipe Sampling Materials for Beryllium in Surface Dust Sampler on Worn Carpets” (June 2006).
(2016). NIOSH: Surface Sampling Procedures for Bacillus anthracis
ASTM International: ASTM D7789, Standard Practice for Collec- Spores from Smooth, Non-Porous Surfaces, bit.ly/nioshba
tion of Fungal Material from Surfaces by Swab (2012). cillus (April 2012).

| August 2020 28
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THE LABS ISSUE

Pt Be

Mn
Measurement
of Trace Metals
and Metalloids
Deliberations from
an ASTM Workshop
Ni
N
ew and revised (downward) occupational exposure limit values
are emerging for metals and metalloids such as antimony, beryl-
lium, manganese, and nickel. Validated measurement methods
for workplace air measurements, based around the use in labora-
tories of the widely available inductively coupled plasma-atomic
emission spectrometric (ICP-AES) technique for multi-elemental analy-
sis, have long since been codified at a national level (for example, with
NIOSH Method 7302 and OSHA Method ID-125G) and more recently
at an international level (ASTM D7035 and ISO 15202 parts 1, 2, and
3). However, in light of these impending reductions in limit values, all
aspects of such methods, including sampling, sample preparation, and
instrumental analysis, may need to be reviewed. To debate these issues,
a workshop on the measurement of trace metals and metalloids at work-
places, sponsored by ASTM International Committee D22 on Air Quality,
was held in October 2019 in Houston, Texas. The event attracted 24
stakeholders interested in improving the science of measuring metals in
workplace air. This article summarizes deliberations from this meeting.

BY STEVEN VERPAELE AND OWEN BUTLER

| August 2020 30
OEL SETTING AND COMPLIANCE and added to a filter sample for analysis. However, this
Those responsible for setting exposure limit values for can be a laborious procedure. In recent years, an elegant
carcinogens, including several commonly used metals solution has evolved in the form of acid-soluble capsules
and metalloids, now recognize the concept of a thresh- designed to capture all particles entering a sampling device
old for carcinogenic effects and a risk-based concept for and which are readily digestible for subsequent metal anal-
non-threshold carcinogens. (See bit.ly/echanickelannex ysis. A new variant of these capsules was presented at the
for the European Chemicals Agency Risk Assessment Com- workshop, the disposable inhalable sampler (DIS), which is
mittee opinion on OELs for nickel and its compounds; and based upon the ubiquitous IOM inhalable sampler. A metal-
bit.ly/bauatrgs910, in which the German Ministry of sampling version employs a cellulose capsule bonded to a
Labour and Social Affairs defines the concept of “accept- 25-mm diameter mixed cellulose ester (MCE) filter, and a
able cancer risks” for a number of metals and metalloids.) polyvinyl chloride-based (PVC) version is available if grav-
A great deal of epidemiological and toxicological evidence imetric determinations are required (as PVC media exhibit
exists for metals and metalloids from studies within many better weight stability than MCE media).
metal processing workplaces from which new or revised Comparative studies in assessing the performance of
limit values have been derived. personal samplers have been undertaken, but given the
There are new requirements for sampling specific numerous types of personal samplers in use, more such
particle size fractions (for example, in cases where a new studies are needed. Impending new exposure limits will
respirable limit value has been added for an agent that require both the collection of new exposure data and the
previously had only an inhalable limit value). These situ- sharing of existing data, hence a need for comparability.
ations require new exposure datasets, which has spurred In April 2018, the Nickel Institute, a global association of
development of samplers that can simultaneously sample primary nickel producers, proposed a new study be under-
inhalable and respirable fractions (discussed below). taken to assess sampler performance in both laboratory
Many inhalable exposure datasets already exist, and some and field settings. The Institute is in the process of reaching
researchers have investigated the possibility of extrapo- out to relevant stakeholders to ascertain their interest in
lating likely respirable exposures from such data—that is, participating. (For more information about this project,
by deriving a respirable-to-inhalable mass ratio. In the contact Steven Verpaele at sverpaele@nickelinstitute.
absence, at this time, of suitable respirable exposure data, org.)
there are merits in this approach, but ratios derived in With reductions in exposure limits requiring reliable
one work setting may not be translatable over time or to measurement of potentially smaller sample masses, focus
another work setting. Particle size distributions can vary has shifted to minimizing both the potential for sample
greatly and depend on factors such as the workplace opera- contamination and ensuring that sufficient sample is
tions that generate such particles, whether those processes collected for analysis. Endeavors here involve the devel-
remain stable over time, and whether the composition and opment of the “single-use” sampler, as exemplified by
morphology of materials remain constant. At the work- the DIS. Other designs are in the offing as exemplified by
shop, representatives from the European metal industry a presentation at the workshop on the development of a
presented results from workplace surveys that involved the new inhalable sampler. To collect sufficient sample mass,
use of cascade impactor sampling to derive metal-mass-to- samplers operating at high flow rates (around 10 liters per
particle-size data. minute) are available, but work to develop new samplers,
running at even higher flow rates, was suggested in the
SAMPLING CONSIDERATIONS workshop.
Ongoing air sampling challenges include dealing with “wall Several researchers have proposed the simultaneous
losses” (particles not collected on the filter but deposited sampling of inhalable and respirable fractions using foams
on some other part of the sampler inlet). Emerging chal- to perform the desired particle size selections. Indeed, a
lenges arising from new or reduced exposure limits include dual-fraction IOM sampler that employs a foam separator
the previously mentioned need for simultaneous sampling is now commercially available. At the workshop, a new
of different health-related fractions and the increased variant of the DIS, equipped with a foam insert that allows
potential for cross-contamination if smaller sample masses the respirable fraction to be collected on the filter and the
are collected. extra-respirable component of an inhalable sample to be
A paper published in the Journal of Occupational and trapped in the foam, was presented. Also presented was
Environmental Hygiene in 2015 has shown that, by wiping the nanoparticle respiratory deposition sampler (NRD),
interior surfaces of samplers, wall losses can be recovered designed to sample those sub-micron metal particulates

31 www.aiha.org |
digestion procedures. In summary, effective and consis-
tent digestions can be performed. A microwave-assisted
digestion procedure, based on EPA Method 3052, was
incorporated into the published ISO 15202-2 standard.
Presentations at the workshop detailed work being under-
taken to include microwave-assisted digestions in future
iterations of German and U.S. national standard methods.

INSTRUMENTAL ANALYSIS
Multi-Element Analysis
Currently ICP-AES, which is codified in several national

Antoine2K/Getty Images
and international standards, is the technique of choice in
most occupational hygiene laboratories for the multi-
element analysis of air filter samples. There are concerns,
however, that the sensitivity of the ICP-AES technique
may be insufficient to quantify certain metals at proposed
new reduced exposure limits as alluded to, for example,

Emerging challenges in a survey of laboratories that offered nickel assays (see


Detection Limits in Air Quality and Environmental Mea-

include the need for


surement, ASTM International, 2019). Complimentary
standards such as ASTM D7439-14 and ISO 30011
now exist, which advocate the use of the more sensitive

simultaneous sampling of inductively coupled plasma-mass spectrometry (ICP-


MS) technique. As reported at the workshop, efforts are

different health-related
ongoing to incorporate ICP-MS into revisions of national
standards and in particular for the analysis of elements
such as antimony, beryllium, and platinum where ICP-

fractions. AES indeed lacks the required sensitivity. In summary,


the main challenge is potentially an economic one—that
is, procurement of new ICP-MS capabilities to supplement
existing ICP-AES capabilities in occupational hygiene
laboratories.

that deposit deep in the lung, which now also uses foams Single-Element Analysis
to select the required particle sizes. However, further Workshop participants also discussed requirements for
studies on the utility of such samplers would be welcome, sampling, sample preparation, and analytical determina-
and there are plans to include such samplers in the com- tions of beryllium, hexavalent chromium, nickel species,
parability study proposed by the Nickel Institute. and platinum.
Findings from an inter-laboratory study published
SAMPLE PREPARATION REQUIREMENTS in the Journal of Environmental Monitoring in 2012
An inherent challenge with ICP-based methodologies is demonstrated that either a high-boiling point acid (such
that they typically require a sample to be presented for as sulfuric acid) or hydrofluoric acid was required to read-
analysis in the form of a solution (that is, via digestion ily dissolve beryllium oxide phases present in beryllium
of an air filter sample in strong mineral acid). While the processing facilities. Requisite analyst skill sets have been
requisite procedures are codified in relevant standards, mentioned previously but there remain concerns whether
their correct use nevertheless still relies heavily upon the some laboratories use appropriate digestion methods and,
skill and experience of the analyst, especially those pro- if so, whether they follow the prescribed recipe completely
cedures that involve the use of hotplates and open beaker (that is, use the recommended acid mixtures). An over-
digestions. The use of the closed-vessel pressurized micro- view of a sensitive fluorescence-based beryllium assay,
wave-assisted digestion option has emerged as the method developed for both filter and swab samples and described
of choice for many laboratories undertaking trace metal in a 2017 paper in the International Journal of Analytical
analysis. Pressurized digestions enable acids to be heated Chemistry, was presented at the workshop. This assay is
to temperatures above their nominal boiling points and so now available as ASTM D7202 and NIOSH 7704, and is
allow samples to be digested most efficiently. Microwave as sensitive, if not more so, than ICP-MS. Usefully, it can
ovens are microprocessor controlled, allowing a safe, be made portable, so enabling timely measurements to be
automated, and highly repeatable operation. Furthermore, performed close to the workplace.
microwave power considerably shortens sample dissolu- Sensitive spectrophotometric protocols, discussed
tion times when compared to more traditional hotplate at the workshop, for the determination of hexavalent

| August 2020 32
chromium are available, such as ASTM D6832 and ISO welding fume on filter samples, concluded that, despite
16740. Nevertheless, analytical challenges remain, such as the availability of standard methods, use of inappropriate
extracting insoluble hexavalent chromium species and the or incorrectly performed digestions was indeed a major
omnipresent potential for species interconversion between source of analytical bias, which remains apparent to this
hexavalent and trivalent chromium forms during filter day.
extraction. These considerations were detailed in a useful If available, analysis of matrix reference materials
2003 review paper in the Journal of Environmental Moni- (RMs), with a known elemental composition, could help
toring and remain relevant to this day. laboratories determine whether they are following a
The assessment of health risks in the metal producing published procedure correctly or verify whether the perfor-
industry ideally requires the ability to distinguish quanti- mance of their in-house digestion method is satisfactory.
tatively between different forms of a metal that could exist Ideally such RMs would be representative of the wide
in workplace dusts. In one endeavor, the Zatka protocol—a range of dusts and fumes encountered in the workplace
sequential leaching method described in a 1992 paper in and preferably are available as particle-on-filter samples.
Environmental Science and Technology—was developed Producing large batches on near-identical RM filters, how-
to provide a laboratory-based assay that could differentiate ever, remains challenging, and to date, as far as is known,
between “soluble,” “sulphidic,” “metallic,” and “oxidic” only two metal-on-filter RMs have been produced, a weld-
nickel forms present in dusts within refineries that pro- ing fume material certified only for its chromium content
cessed sulphidic-based nickel ores. In this approach, labile and a beryllium oxide material.
nickel forms are sequentially removed (and analyzed) by At the workshop, endeavors in developing new RMs
subjecting air filter samples to leaching agents of increas- were presented. These included a new approach for pro-
ing strength, thereby exploiting solubility differences ducing metal oxide on filter materials (described in two
between nickel compounds. In a workshop presentation, publications in the journal Gefahrstoffe - Reinhaltung
use of this same sequential leaching approach to elucidate der Luft) and the development and validation of two bulk
the possible forms of nickel present in particles within a welding fume RMs, characterized for elements such as
stainless-steel mill was presented. Here both the original chromium, iron, manganese, nickel, and zinc, detailed in a
Zatka protocol and a modified version were utilized along- 2014 publication in the Journal of Occupational and
side instrumental particle characterization techniques Environmental Hygiene.
such as X-ray diffraction (XRD), X-ray absorption near
edge structure (XANES), and Quantitative Evaluation of EMERGING MEASUREMENT SCIENCE
Materials by Scanning Electron Microscopy (QEMSCAN). A widely shared aspiration is the development of field-based
Given the diverse particle morphologies and sizes that methods for the determination of metals and metalloids
could be encountered in metal-handling workplaces, an in the workplace. While analyzing air filter samples at the
approach employing a battery of analytical techniques not workplace is currently possible—for example, through use of
only better characterizes workplace particles but can ascer- portable X-ray fluorescence (XRF) analyzers—new portable
tain whether the use of sequential leach-type procedures in instruments that can sample and quantify airborne elemen-
other work settings has merit. tal concentration data in near real time are ideally required.
The International Platinum Group Metal Association At the workshop, emerging research into the development
(IPA) has published a harmonized methodology for the of a portable spark emission spectrometer was presented.
sampling of platinum in workplace atmospheres that Ongoing endeavors such as development of new air sampler
subsequently involves the extraction of filter samples in designs; new filter digestion approaches; approaches to
dilute hydrochloric acid for determining the soluble plati- boost the sensitivity of the ICP-AES technique (for example,
num fraction. Researchers at the University of Wisconsin, through use of high efficiency nebulizers); and evaluation of
working on behalf of IPA, presented their highly sensitive new ICP-MS technologies (such as new triple-cell systems
ICP-MS assay for measurements at concentrations less for the improved removal of isobaric interferences) will, in
than 1 ng/m3. Purity of reagents and cleanliness of appara- time, feed into future iterations of national and international
tus are critical in achieving such sensitivities. (ASTM and ISO) standards.

QUALITY ASSURANCE AND CONTROL REQUIREMENTS STEVEN VERPAELE is an industrial hygienist with the
Proficiency testing (PT) allows a laboratory to compare Nickel Institute in Brussels, Belgium, and a member of the
its analytical performance against those of its peers and AIHA Sampling and Laboratory Analysis Committee. He
demonstrate that it can obtain reliable results. While the can be reached at sverpaele@nickelinstitute.org.
performance of laboratories analyzing simulated (spiked
OWEN BUTLER is an analytical chemist and proficiency
aqueous metal solutions) test filters remains satisfactory,
testing specialist with the U.K. Health and Safety Executive
such samples may not provide a realistic examination in Harpur Hill, Buxton, United Kingdom.
because they are not truly representative of air filter sam-
ples collected from many workplaces. Indeed, a 2008 Acknowledgment: The authors thank the ASTM workshop
paper in The Annals of Occupational Hygiene, drawing delegates for their contributions, without which this sum-
upon results from a PT scheme that offered realistic mary report would not have been possible.

33 www.aiha.org |
RESOURCES
American Industrial Hygiene Association Journal: “Development ASTM International: “Size Selective Personal Air Sampling Us- Journal of Environmental Monitoring: “Development of an
of Respirable Aerosol Samplers Using Porous Foams” ing Porous Foams,” presented at ASTM Johnson Conference: International Standard for the Determination of Metals and
(November 1998). Workplace Aerosol Sampling to Meet ISO Size Selective Metalloids in Workplace Air Using ICP-AES: Evaluation of
Annals of Work Exposures and Health: “Comparison of Criteria (presentation by C. Mohlman and others, July 2007). Sample Dissolution Procedures through an Interlaboratory
Microwave-Assisted Digestion and Consensus Open-Vessel Atomic Spectrometry: “Standardization of Sample Preparation for Trial” (January 1999).
Digestion Procedures for Evaluation of Metalliferous Trace Element Determination through Microwave-Enhanced Journal of Environmental Monitoring: “Evaluation of Sequential
Airborne Particulate Matter” (October 2019). Chemistry” (March 1998). Extraction Procedures for Soluble and Insoluble Hexavalent
The Annals of Occupational Hygiene: “A Collaborative European BAuA (German Federal Institute for Occupational Safety and Chromium Compounds in Workplace Air Samples” (February
Study of Personal Inhalable Aerosol Sampler Performance” Health): TRGS 910, “Risk-Related Concept of Measures for 2009).
(April 1997). Activities Involving Carcinogenic Hazardous Substances,” Journal of Environmental Monitoring: “Preparation, Certification
The Annals of Occupational Hygiene: “A Simple and Disposable bit.ly/bauatrgs910 (2014). and Interlaboratory Analysis of Workplace Air Filters Spiked
Sampler for Inhalable Aerosol,” bit.ly/annalssampler Environmental Science and Technology: “A Personal Nanoparticle with High-Fired Beryllium Oxide” (February 2012).
(March 2016). Respiratory Deposition (NRD) Sampler” (August 2011). Journal of Environmental Monitoring: “Sampling and Analysis
The Annals of Occupational Hygiene: “Aerosol Evaluation Environmental Science and Technology: “Chemical Speciation of Considerations for the Determination of Hexavalent Chromi-
Difficulties Due to Particle Deposition on Filter Holder Inner Nickel in Airborne Dusts: Analytical Methods and Results of um in Workplace Air” (2003).
Walls” (August 1990). an Interlaboratory Test Program” (January 1992). Journal of Environmental Monitoring: “Sampling and Charac-
The Annals of Occupational Hygiene: “Applications of Low-Cost, European Chemicals Agency: “Annex 1: Background Document terization of Individual Particles in Occupational Health
Dual-Fraction Dust Samplers” (January 2001). in Support of the Committee for Risk Assessment (RAC) for Studies” (August 1999).

The Annals of Occupational Hygiene: “Development and Testing of Evaluation of Limit Values for Nickel and its Compounds in Journal of Occupational and Environmental Hygiene: “Acid-Soluble
a New Sampler for Welding Fume” (June 1997). the Workplace,” bit.ly/echanickelannex (PDF, 2018). Internal Capsules for Closed-Face Cassette Elemental
Gefahrstoffe - Reinhaltung der Luft: “Means of Converting the Sampling and Analysis of Workplace Air” (June 2013).
The Annals of Occupational Hygiene: “Performance of Laborato-
ries Analysing Welding Fume on Filter Samples: Results Concentration of Inhalable to Respirable Dust” (September Journal of Occupational and Environmental Hygiene: “Comparison
from the WASP Proficiency Testing Scheme,” bit.ly/ 2019). of a Wipe Method with and Without a Rinse to Recover Wall
annalswasp (June 2008). Gefahrstoffe - Reinhaltung der Luft: “Reproducible Loading Losses in Closed Face 37-mm Cassettes Used for Sampling
of Membrane Filters with Airborne Metals to Carry Out Lead Dust Particulates” (October 2015).
Applied Occupational and Environmental Hygiene: “Application of
Porous Foams as Size Selectors for Biologically Relevant Proficiency Testing – Part I” (2016). Journal of Occupational and Environmental Hygiene: “Concerning
Samplers” (April 1993). Gefahrstoffe - Reinhaltung der Luft: “Reproducible Loading Sampler Wall Deposits in the Chemical Analysis of Airborne
of Membrane Filters with Airborne Metals to Carry Out Metals” (September 2007).
Applied Occupational and Environmental Hygiene: “Field Compar-
ison of 37-mm Closed-Face Cassettes and IOM Samplers” Proficiency Testing – Part II” (2018). Journal of Occupational and Environmental Hygiene: “Laboratory
(March 2002). Institute for Reference Materials and Measurements: “Certified Comparison of New High Flow Rate Respirable Size-Selec-
Reference Material BCR 545 Welding Dust Loaded on a tive Sampler” (October 2018).
Applied Occupational and Environmental Hygiene: “Notice of
Intended Change—Appendix D—Particle Size-Selective Filter.” Journal of Occupational and Environmental Hygiene: “Perfor-
Sampling Criteria for Airborne Particulate Matter” International Journal of Environmental Analytical Chemistry: “Op- mance of Prototype High-Flow Inhalable Dust Sampler in a
(September 1991). tical Molecular Fluorescence Determination of Ultra-Trace Livestock Production Facility” (May 2017).

ASTM International: “Differences Between Samplers for Re- Beryllium in Occupational and Environmental Samples Using Journal of Occupational and Environmental Hygiene: “Preliminary
spirable Dust and the Analysis of Quartz—An International Highly Alkaline Conditions” (March 2017). Studies on the Use of Acid-Soluble Cellulose Acetate
Study” (February 2014). International Platinum Group Metal Association: "Harmonized Internal Capsules for Workplace Metals Sampling and
Methodology for the Sampling of Platinum in Workplace Analysis” (July 2012).
ASTM International: “Impact of the Detection and Quantitation
Limits on the Analytical Feasibility of Measuring the Atmospheres,” bit.ly/ipaplatinum (PDF, April 2016). Journal of Occupational and Environmental Hygiene: “Preparation
European Chemicals Agency Risk Assessment Committee’s Journal of Analytical Atomic Spectrometry: “Measurement of and Certification of Two New Bulk Welding Fume Reference
Recommendations for Occupational Exposure Limit Values Elemental Concentrations of Aerosols Using Spark Emission Materials for Use in Laboratories Undertaking Analysis of
for Nickel and Its Compounds in the Workplace,” in Spectroscopy” (July 2012). Occupational Hygiene Samples” (September 2014).
Detection Limits in Air Quality and Environmental Measure- Journal of Environmental Monitoring: “A Comparison of Portable Pure and Applied Chemistry: “Sampling and Chemical Character-
ment (2019). XRF and ICP-OES Analysis for Lead on Air Filter Samples ization of Aerosols in Workplace Air,” bit.ly/pacaerosols
ASTM International: “Opportunities for Standardization of from a Lead Ore Concentrator Mill and a Lead-Acid Battery (December 1993).
Beryllium Sampling and Analysis,” in Beryllium: Sampling Recycler” (March 2006).
and Analysis (2006).

| August 2020 34
THE LABS ISSUE

Fume Hood
Performance Tests
Methods to
Verify Proper
Functioning

BY THOMAS C. SMITH

P
eople working in laboratories rely on
proper performance of fume hoods
as their primary means of protection
from overexposure to hazardous air-
borne chemicals generated during
scientific activities. Fume hood performance is
defined as the ability to protect people through
containment, capture, and removal of airborne
hazards generated within the fume hood enclo-
sure. Results from thousands of performance
tests by my company, 3Flow, indicate that 15
percent to 30 percent of fume hoods do not
meet performance criteria described in ANSI/
AIHA/ASSP Z9.5-2012, Laboratory Ventila-
tion. (More information is available in my paper
“The Unintended Practice of Using Employee
Health as an Indicator of Laboratory Hood Per-
formance” in the January/February 2004 issue
of Chemical Health and Safety Journal.)
zilli/Getty Images

35 www.aiha.org |
performance under prevailing operating conditions.
Evaluation of prevailing operating conditions includes
the following methods:
• fume hood and lab inspection
• face velocity measurements
• VAV face velocity control test
• VAV response test
• cross-draft velocity tests (optional)
Methods for evaluating containment performance under
prevailing operating conditions are:
• flow visualization (smoke) test
• tracer gas containment test
To conserve energy, fume hoods are being operated at
lower average velocities and equipped with complex VAV
systems. The VAV systems are intended to modulate flow
to a minimum when the sash is closed or when the hood
is unoccupied, and increase flow in proportion to the sash
opening area or when the hood is occupied with the sash
open. Most organizations employ measurement of average
face velocity, but the introduction of more complex VAV
systems requires additional testing. While face velocity
measurements are applicable when the sash is open, special
airflow tests are required to evaluate proper operation of
In the ASHRAE 110 test method, a mannequin is used to simulate a hood the VAV flow control systems. The VAV face velocity con-
user standing in front of the hood opening. trol tests and VAV response tests are conducted to verify
proper modulation and control of flow across the range of
The factors that affect safety performance are numerous operating modes from minimum to maximum flow.
and generally associated with the aerodynamic design of According to ANSI/AIHA/ASSP Z9.5-2012, the VAV
the fume hood, the operation of the airflow systems, the controls should be capable of modulating flow in less than
configuration of the laboratory environment, and the work 5 seconds following movement of the sash and preventing
practices of the hood user. These factors are further exac- flow variations in excess of 10 percent from the design
erbated as laboratory hood systems become increasingly specifications at each sash configuration or operating
more complex with the introduction of unique features mode. Measurement of face velocity alone will not ensure
and variable air volume (VAV) systems that modulate flow proper functioning of VAV controls, and performance can
to conserve energy. Since fume hood systems are installed be compromised by slow response and unstable flow con-
for the sole purpose of protecting people, proper testing is trol. These systems are also susceptible to degradation over
critical to ensure proper performance before people place time, which may lead to more frequent testing and mainte-
their health at risk using hazardous chemicals. nance efforts.
OSHA’s Occupational Exposure to Hazardous Chem- In addition to problems caused by improper modu-
icals standard (29 CFR 1910.1450) requires all facilities lation of exhaust flow, fume hood performance can be
to ensure the proper functioning of fume hoods through dramatically affected by the velocity and direction of room
appropriate testing and maintenance. The current stan- air currents near the hood opening. Issues can arise if air
dard in the United States for verifying proper functioning supply diffusers are located too close to the fume hood or
of fume hood systems is ANSI/ASHRAE 110-2016, Method the air supply flow produces detrimental cross-draft veloc-
of Testing Performance of Laboratory Fume Hoods. ities near the opening. ANSI/AIHA Z9.5 recommends that
ASHRAE 110 provides quantitative and qualitative test cross-draft velocities be maintained at less than 50 percent
methods to evaluate containment performance under of the average face velocity. However, the performance of
prevailing operating conditions. The standard describes a some fume hoods may be more susceptible to cross-drafts
series of tasks that include inspection of the hood, evalua- than others. High-velocity cross-drafts can also create
tion of the lab environment, airflow measurements, airflow turbulence at the plane of the sash and affect the accuracy
visualization tests, and tracer gas containment tests. The of face velocity measurements. At a minimum, this can
tests are conducted to verify containment performance and lead to improper calibration and tuning of the airflow con-
document the prevailing operating conditions. trols; at worst, cross-drafts can adversely affect fume hood
containment and safety performance. For these reasons,
TEST METHODS AND APPLICATION cross-draft velocities should be measured across the range
The test methods described in the ASHRAE 110 standard of operating modes to evaluate and reduce the impact of air
can be divided into two sections: evaluation of prevail- supply on hood performance.
ing operating conditions, and evaluation of containment To assess the impact of these operational factors on

| August 2020 36
Mannequin
Tracer Gas Ejector
Tracer Gas Detector

Computerized Data
Collection System

Face Velocity Probe

Cross-Draft Velocity
Probe

Figure 1. Photo of experimental setup during ASHRAE 110 fume hood performance tests.

hood containment performance, ASHRAE 110 describes and tests must be conducted periodically to verify proper
application of qualitative flow visualization tests and functioning of the flow control systems. Refer to Figure 1
quantitative tracer gas containment tests. During flow for a photo of the test apparatus used during ASHRAE 110
visualization tests, a visible source of smoke is generated fume hood tests.
in the hood to observe airflow patterns and qualitatively Due to the number of factors that can influence hood
assess hood containment. During tracer gas tests, the gas containment, ASHRAE 110 tests can be conducted “as man-
sulfur hexafluoride (SF6) is discharged from a special ejec- ufactured” (AM), “as installed” (AI), and “as used” (AU):
tor located inside the fume hood to simulate a hazardous AM tests are conducted before purchase of the hood
emission, and a mannequin is used to simulate a hood to help evaluate the impact of hood design on performance
user standing in front of the hood opening. A tracer gas and establish an operational performance envelope.
detector is placed in the mannequin’s breathing zone to AI tests are conducted during commissioning of the
quantitatively assess containment for use in rating fume newly installed fume hood system to evaluate performance
hood performance. The tracer gas is generated at a rate of in the actual lab under the prevailing operating conditions.
4 liters per minute through the ejector located in the hood The AI tests should be conducted before occupancy to
directly downstream of the mannequin. With the sash in document the operating conditions and verify safety perfor-
the design opening configuration, the detector samples mance before people are potentially exposed to hazardous
concentrations at a rate of 1 hertz in the mannequin’s airborne chemicals.
breathing zone for a period of 5 minutes and at a minimum AU tests are conducted after installation and setup of
of three locations across the opening (that is, at the left, experimental apparatus to evaluate the potential impact of
center, and right sides of the opening). Special tests are the procedures on containment and help determine work
also conducted with the mannequin placed at the center of practices that may help further mitigate risk of exposure.
the opening to evaluate containment during three cycles The need for AU tests is often subject to the level of risk
of opening and closing the sash. These tests are called associated with the work in the hood and applied at the
sash movement effect tests and are intended to evaluate discretion of the chemical hygiene officer.
potential for escape as a function of sash movement and Once operating and in service, all fume hoods should be
VAV flow response and stability. Improper operation of the tested periodically (at least annually) to verify proper oper-
VAV controls can dramatically affect hood performance, ation. Routine operating tests should include, at a

37 www.aiha.org |
minimum, inspection of the hood and lab, cross-draft alternative test method using IPA provided generally com-
tests, face velocity tests, VAV response tests, and qual- parable results to the current ASHRAE 110 method using
itative flow visualization tests. It may not be necessary SF6; dramatically reduced the impact on the environment;
to conduct periodic tracer gas tests where operation is and was simpler and less costly to conduct. As a greenhouse
demonstrated to be equivalent to conditions prevailing gas, IPA is reported to be 0.5 times better than CO2 and
during the AI commissioning tests. However, should any 48,000 times better than SF6. The results indicate that use
significant changes be made to the design or operation of IPA or other alcohol mixtures as a tracer together with
of the fume hood system or the laboratory environment, PIDs may provide a suitable and environmentally attractive
the AI tests should be conducted again to validate perfor- alternative to SF6.
mance and benchmark the new operating conditions. Although the alternative test method is still under
review by ASHRAE, a new method that uses a more envi-
RECENT DEVELOPMENTS ronmentally friendly tracer and is simpler and less costly
Tens of thousands of fume hoods have been tested to chal- to conduct may result in broader application of ASHRAE
lenge and quantify hood containment using the ASHRAE 110 performance tests. This may in turn lead to further
110 test methods. The results have been used to improve improvements in fume hood performance and better pro-
safety and reduce energy consumption by enabling better tection for people working with airborne chemical hazards.
performance of fume hoods, laboratories, and ventilation In addition, the new methods may also be applicable to
evaluating performance of other types of exposure control
systems, leading to greater safety and better protection
for all people working in or around labs and critical
Fume hood performance can be workspaces.

dramatically affected by the CHALLENGE AND CONFIRM

velocity and direction of room air Due to the critical importance of fume hoods as a primary
safety device when working with chemicals and the large

currents near the hood opening. number of variables that can affect containment, appropri-
ate tests are required to evaluate fume hood performance
and ensure proper functioning. Systems are becoming
systems. In the original ASHRAE standard published in increasingly more complex. Fume hoods must be tested
1985, dichlorodifluoromethane (refrigerant 12) was spec- across the range of operating modes (open and closed
ified as the tracer gas. Refrigerant 12 was later identified sashes, occupied and unoccupied operation). The introduc-
as a potential environmental pollutant that contributed tion of new operating modes results in even more factors
to ozone depletion. To reduce generation of potential air- that can affect fume hood performance and user safety.
borne pollutants, the ASHRAE standard switched to SF6 Face velocity measurements alone are no longer ade-
in 1995. Unfortunately, SF6 has now been identified as quate to evaluate modern fume hood systems. Tests such
an extremely potent greenhouse gas and reported to be as VAV response and stability tests must be conducted in
24,000 times worse than carbon dioxide. Organizations addition to face velocity tests to verify proper fume hood
around the world are discouraging use of SF6 as an air operation. Furthermore, test procedures and performance
tracer, and California has banned it for “as used” fume criteria must be specified that are appropriate to challenge
hood tests. In addition, the high cost, complexity, and and confirm performance at all operating modes. When
limited availability of SF6 tracer gas detectors has limited establishing the test methods required to verify proper per-
the application of ASHRAE 110 tests. Even considering the formance, consider all the components that could influence
thousands of tests conducted, it is estimated that less than performance and verify proper function over the range of
10 percent of the nearly 1.4 million fume hoods in the U.S. operating modes.
have been subject to quantitative tracer gas tests.
In keeping with commitments to occupational safety THOMAS C. SMITH is president of 3Flow in Cary, North
and environmental health, ASHRAE undertook a research Carolina, and a member of the ASHRAE 110, ASHRAE
project to determine a more environmentally friendly TC9.10, ASSE Z9, and ASSE Z9.5 committees. He can be
alternative to SF6. The investigation included a review of reached at tcsmith@3flow.com.
available background literature; characterization of the Send feedback to synergist@aiha.org.
ASHRAE 110 ejector for SF6; determination of alternative
tracer generation, delivery, and detection systems; and a
series of tests to evaluate the similarity of results. The work RESOURCES
revealed that isopropyl alcohol (IPA) and other alcohol ASHRAE: ANSI/ASHRAE 110-2016, Method of Testing Performance of Laboratory Fume
mixtures can be vaporized, mixed with air, discharged Hoods (2016).
from the ASHRAE 110 outlet diffuser, and detected using Chemical Health and Safety Journal: “The Unintended Practice of Using Employee Health
simple, low-cost, and readily available photoionization as an Indicator of Laboratory Hood Performance” (January/February 2004).
detectors (PIDs). Hundreds of tests revealed that the

| August 2020 38
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COMMUNITY

INSIDE AIHCE EXP 2020

O
AIHA Honors n April 15, AIHA’s for launch on Monday, June 1. rest of Monday’s programming. An
Recipient of 2020 Board of Directors The conference started on a high email was sent to attendees apolo-
President’s Award announced that due note. Opening Session speaker René gizing for the difficulties and explain-
to the COVID-19 pan- Rodriguez playfully exploited the vir- ing that the day’s sessions would be
In late May, AIHA announced
demic, AIHce EXP 2020 would not be tual format, creating the illusion that rebroadcast at later dates.
that Perry W. Logan, PhD, CIH,
held in Atlanta as planned. To protect he was in several places at once. On the morning of June 2, staff sent
is the recipient of the 2020
the health and safety of attendees, His message about leadership in new instructions to attendees. A dif-
President’s Award. The accolade
the conference would be entirely the time of the COVID-19 pandemic ferent procedure for obtaining credit
is presented annually to an
virtual, and it would be held on the generated enthusiasm on the live was put in place, and attendees were
individual, task force, special
same dates, June 1–3, reserved for chat board, where attendees reacted provided direct links to the session
interest group, or local section
the live event. The challenge facing in real time. recordings. “It was the best thing we
to recognize outstanding
conference staff was to reimagine an But when the session ended, the could do to be sure that we were actu-
contributions related to efforts
event that had always been rooted in comments quickly turned sour. Many ally delivering the education when we
to achieve AIHA's mission.
the real world as an entirely virtual attendees experienced errors with said we were going to,” Manning said.
Kathleen S. Murphy, CIH, AIHA
experience. They had six weeks to the credit submission mechanism, The changes worked. Attendees
president for 2019–2020,
get it done. which was supposed to record their reported few problems for the rest
chose to honor Logan for his
It helped that staff had thoroughly attendance so they could receive cer- of the conference, and staff reflected
contributions to AIHA and the
explored all possibilities, according tification maintenance points. on what was ultimately a successful
profession of industrial hygiene,
to Bethany Chirico, AIHA’s managing AIHA’s online learning vendor, virtual event, the first of its kind ever
including the academic study
director of global meetings and busi- Freestone, told Manning that the attempted in the occupational health
and application of leadership to
ness development. The Board, she system was overloaded. and safety industry.
IH roles.
said, was “willing to take a calculated “You’ve got 2,000 people all trying “The decision [to hold a virtual
“Dr. Logan’s success can not risk knowing that we had done our to submit for credit simultaneously,” conference] was based on what we
only be attributed to his vast homework.” Manning explained. “It takes a few thought was best for our audience,
experience and technical Part of that homework involved extra seconds, so they hit refresh. So but also knowing that we have an obli-
knowledge, but also his ability gauging speakers’ interest in convert- a volume of 2,000 can easily become gation to deliver education in the best
to influence and inspire indus- ing their presentations to an online a volume of 4,000.” format we can,” Chirico said. “And
trial hygienists to think outside format. By the time of the Board’s The root of the problem was the aside from the technical glitches, I
the box and pursue continued announcement, AIHA’s online learn- sheer size of the audience. Since a think we did that in spades.”
learning,” Murphy said. ing team was poised to hit the ground fully virtual AIHce had never been The experience will prove invalu-
Read more in AIHA’s press running. “Almost immediately after attempted, projections of attendance able for next year’s conference, which
release at bit.ly/2020 that decision became official, we went had been educated guesses. “Within is scheduled for May 24–26, 2021,
presaward. straight into prerecording sessions,” just those last three weeks, four in Dallas. Provided that conditions
said Colleen Manning, eLearning pro- weeks, the numbers skyrocketed,” allow a live event to be held safely,
gram director. Chirico said. “They jumped almost one option under consideration is a
Manning and eLearning Coordina- 500 people in the weekend right hybrid conference “that encourages
tor Fatima Khan had experience with before we went live.” the virtual audience to participate in
virtual events, but AIHce EXP 2020 As Monday wore on, staff realized many of the things that are actually
would be on a vastly greater scale. with dismay that the system wasn’t happening in person, outside of just
They recruited other staff to help recovering. Attendees were being the education,” Chirico said.
record and edit presentations, and denied access to sessions. By early For more information about AIHce
they readied the online classrooms afternoon, staff decided to cancel the EXP 2021, visit aihceexp.org.

| August 2020 40
COMMUNITY

A Tribute to Eula Bingham, 1929–2020


BY ROBERT LIECKFIELD, JR., AND BARBARA COHRSSEN

We are sad to report that one of Safety and Health from 1977 until hazards in the workplace. The pro- Students Recognized for
the titans of modern-day industrial 1981 under President Jimmy Carter gram served as a model for the Best-in-Show Posters
hygiene and occupational health, and was the first woman to lead the National Cancer Institute and the
Congratulations to the students whose
Eula Bingham, passed away June agency responsible for ensuring National Institute of Environmental
posters were selected as best in show
13, 2020, at the age of 90. She began the health and safety of millions of Health Sciences in training their
during Virtual AIHce EXP 2020. Li Liao
her career in industrial hygiene at American workers. workers and communities.
of Purdue University came in first
the University of Cincinnati College During her OSHA tenure, she led The occupational health and
place with the poster “Size-Selective
of Medicine in 1961 as a researcher the agency on what was termed a safety profession salutes and cel-
Bioaerosol Sampler Combined With an
doing pioneering work on chemical set of “common sense priorities” ebrates Eula and her accomplish-
Adenosine Triphosphate (ATP) Biolu-
carcinogens. Eula was an author- focusing on serious problems in ments. We owe a debt of gratitude
minescence Assay.” The second-place
ity on occupational disease and on the workplace, helping small busi- to her and all the other health and
winner was the University of Washing-
cancer-causing substances. Over nesses comply with OSHA rules, safety pioneers who helped pave
ton’s Hannah Echt, whose poster was
her lifetime, she contributed more and clarifying and simplifying the path for worker safety and
titled “Characterization of Alpha Dike-
than one hundred peer-reviewed safety rules. She led the charge to health.
tone Emissions and Exposures During
articles on occupational and envi- improve American worker health, Continue reading this tribute and
Coffee Production.” Kathryn Crawford
ronmental respiratory hazards, issuing many new health standards leave your memories of Eula on Syn-
of the University of Iowa placed third
chemical carcinogenesis, and for toxic chemicals and establish- ergistNOW: bit.ly/eulabingham.
for her poster “Simulations of Control
occupational and environmental ing the “New Directions Training Robert Lieckfield, Jr., CIH, FAIHA,
Strategies to Reduce Sound Exposures
health policy. Program,” which created grants and Barbara Cohrssen, CIH, FAIHA,
of Music Instructors.”
Eula served as the Assistant for small businesses and worker are members of the Yuma Pacific
Secretary of Labor for Occupational groups to improve education about Southwest Section.
Present at AIHce EXP 2021
AIHA Accolades As the status of the current health
crisis continues to fluctuate, AIHA is
In May, Barbara Dawson, CIH, CSP, manufacturing industry’s environ- Safety Professionals in May. ASSP’s
planning to host an in-person event for
FAIHA, an Environmental, Health, mental, health, safety, and security highest honor recognizes society
AIHce EXP 2021 in Dallas, Texas, with a
and Safety Fellow at DuPont, performance initiative. Read more members who have made significant
robust virtual program. The submission
received the American Chemistry at bit.ly/respcare2020. contributions to the occupational
portal for the 2021 conference is now
Council 2020 Responsible Care AIHA Fellows Zack Mansdorf, safety and health profession. More
open, and proposals for professional
Employee of the Year Award. The PhD, CIH, CSP, QEP, and James information about Mansdorf’s and
development courses, educational
award recognizes Dawson’s “exem- Thornton, MS, CIH, CSP, were Thornton’s careers can be found
sessions, professional posters, and
plary leadership” in the Responsible among five safety experts honored in ASSP’s press release at bit.ly/
presentations of case studies and
Care program, which is the chemical as Fellows of the American Society of asspfellows.
scientific research will be accepted
through Sept. 23, 2020. Student poster
Dates and Deadlines and presentation submissions will be
due on March 16, 2021. Learn more at
AUG. 20 SEPT. 23 AUG. 21–26, 2021
bit.ly/aihce2021proposals.
AIHA webinar: “Fighting the Risk of Deadline to submit proposals for New dates for IOHA 2021, the 12th
Worker Fatigue in a 24/7 Workplace.” AIHce EXP 2021. Visit bit.ly/aihce IOHA International Scientific Con-
Visit bit.ly/aihawebinars. 2021proposals. ference, in Daegu, South Korea. Visit Guidance on Surface
ioha2020.org. Disinfection Practices
SEPT. 15–16 SEPT. 29
A new white paper developed by mem-
2020 AIHA-Rocky Mountain Section AIHA webinar: “How to Organize and
bers of AIHA's Nonionizing Radiation
Fall Technical Conference in Arvada, Win: Essentials for Effective Public
Committee addresses occupational
Colorado. Visit aiha-rms.org/events. Policy Advocacy Strategies.” Visit bit.
exposures to UV light from artificial
ly/aihawebinars.
sources. "Occupational Safety and
SEPT. 15–17
Health Guide for Surface Disinfection
Virtual PSX 2020 (formerly the Prod- OCT. 19–21
Practices Using Germicidal Ultraviolet
uct Stewardship Conference). Visit AIHA’s “Exposure and Chemical
Radiation" is freely available
bit.ly/psx2020. Monitoring - Beyond IH Fundamen-
as a PDF on AIHA's website at
tals” course in Westerville, Ohio. Visit For a complete list of events, visit
bit.ly/aihasurfaces.
bit.ly/aihamonitoring. www.aiha.org/calendar.

41 www.aiha.org |
BY THE NUMBERS

PNEUMOCONIOSIS DEATHS IN THE


UNITED STATES
From “Trends in Pneumoconiosis Deaths
— United States, 1999–2018”:
“Despite the decline in mortality
and updated regulatory actions
addressing occupational A CDC report published in June indicates that deaths attributable to pneumoconiosis
exposures to hazardous dusts, declined during 1999–2018 but calls for increased focus on pneumoconiosis attributable
pneumoconiosis-associated deaths to "other inorganic dusts" such as aluminum, bauxite, beryllium, iron, and tin oxide. Deaths
continue to occur, underscoring from pneumoconiosis attributed to “other inorganic dusts” increased significantly during the
the need for maintaining exposure period studied, CDC has found. Pneumoconioses attributable to other inorganic dusts include
prevention measures and continued berylliosis and pulmonary siderosis, a disease most common in workers exposed to metal
surveillance. Recent reports indicate fumes during welding. Information from the report is presented below.
the re-emergence of progressive
massive fibrosis… [and] new tasks
and occupations (e.g., quartz
countertop installation and hydraulic
fracturing) that put workers at an 1999 2018
increased risk for silicosis.”

Number of deaths
1,002 associated with coal workers’
COAL DUST

pneumoconiosis in 1999.

Number of deaths associated with coal workers’


305 pneumoconiosis in 2018—a nearly 70-percent
decrease from 1999.

Number of deaths associated with


185 silicosis in 1999.
SILICA DUST

Number of deaths associated with silicosis in


87 2018—a nearly 53-percent decrease from 1999.
SOURCE
CDC: Morbidity and Mortality Weekly
Report, “Trends in Pneumoconiosis
Deaths — United States, 1999–2018,”
bit.ly/mmwrinorganicdusts
(June 2020).
Number of pneumoconiosis deaths attributed to
12
OTHER INORGANIC

other inorganic dusts in 1999.


DUSTS

Number of pneumoconiosis deaths attributed


25 to other inorganic dusts in 2018—an increase
of more than 108 percent.

| August 2020 42

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