Daily Practice Problem

NVS Tutorials Suraj sir-988321963

1) When 1.80 g of non volatile compound dissolved in 25 g of acetone, the solution boils at
56.86 0C while pure acetone boils at 56.38 0C under the same atmospheric pressure.
Calculate the molar mass of compound. The molal elevation constant (Kb) for acetone is 1.72
(258 g mol-1)

2) On dissolving 3.24 g Sulphur in 40 g benzene, Boiling point of solution was higher than that
of benzene by 0.81 K. Kb value for benzene is 2.53 K kg mol-1. What is the molecular formula
of Sulphur? (Atomic mass of Sulphur = 32 g mol-1) (S8)

3) 0.90 g of non-electrolyte was dissolved in 87.90 g of benzene. This raised the boiling point of
benzene by 0.250C. If the molar mass of electrolyte is 103.0 g mol-1 , calculate the molal
elevation constant of Benzene.
(2.515 K kg mol-1)
-1
4) A solution of Glycerol (C3H8O3), Molar mass 92 g mol , in water was prepared by some
amount of glycerol in 500 g of water . This solution has boiling point of 100.420C. What mass
of glycerol was dissolved to make this solution? Kb of water is 0.512 K kg mol-1.
(37.7 g)

5) A solution is prepared by dissolving 1.25 g of oil of winter green (methyl salicylate) in 99.0 g
of benzene whose boiling point is 80.310C. Determine the molar mass of the compound
(Boiling point of pure benzene = 80.100C and Kb for benzene 2.53 0C kg mol-1)
(152 g mol-1)

6) A solution containing 34.2 g cane sugar dissolved in 500 cm3 of water froze at -0.3740C.
Calculate the freezing point depression Constant of water? (1.87 K molal-1)

7) 1.0 g none electrolyte dissolved in 50 g benzene lowered the freezing point of benzene by
0.40 K . The freezing point depression of benzene is 5.12 K kg mol-1. Find the molar mass of
solute? (256 g mol-1)

8) 45 g of ethylene glycol (C2H6O2) is mixed with 600 g of water.

(a) Calculate freezing point depression. (b) freezing point of the solution
(Kf of water = 1.86 K kg mol-1). (a)2.25 K (b)270.9K

9) A solution of urea in water has a boiling point of 100.1280C. Calculate the freezing point of
the same solution. Molal constatnt for water Kf and Kb are 1.860C and 0.5120C respectively.
(-0.4650C)

10) A solution of Organic compound is prepared by dissolving 34.20g in 500 g of water. calculate
the molar mass of the compound and the freezing point of solution. Given that Kb of water is
0.512 K molal-1and boiling point of solution =100.1040C, Kf for water 1.87 K molal-1
(342 g mol-1, -0.37 0C)

NVS Tutorial Girish park Suraj Sir- 9883219693