WORKSHEET (S.No. 1.

5)

SOLUTIONS

Q1) Increasing the temperature of an aqueous solution will cause: [CBSE 2021]

a) Increase in molarity b) Increase in molality

c) Decrease in molarity. d) Decrease in molality

Q2) Pure water boils at 373.15 K and nitric acid boils at 359.15 K. An azeotropic mixture of water and
nitric acid boils at 393.55 K. Distilling the azeotropic mixture will cause: [CBSE 2021]

a) Pure nitric acid to distil over first b) Pure water to distil over first

c) One of them to distil over with a small amount of the other

d) Both of them to distil over in the same composition as that of the mixture being distilled.

Q3) a) Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.

b) Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

c) Assertion is correct but Reason is incorrect

d) Assertion is incorrect but Reason is correct

Assertion: 0.1 M solution of KCl has greater osmotic pressure than 0.1 M solution of glucose at same
temperature.

Reason: In solution, KCl dissociates to produce a greater number of particles. [CBSE 2020]

Q4) 10 mL of liquid A was mixed with 10 mL of liquid B. The volume of the resulting solution was found
to be 19.9 mL. Comment on the type of deviation from Raoult’s law with explanation. [CBSE 2018]

Q5) Calculate the freezing point of a solution containing 60 g of glucose in 250 g of water. Kf of
water=1.86 K kg mol⁻¹. (Ans. 270.67 K) [CBSE 2018]

Q6) Derive the expression for Raoult’s law when the solute is non-volatile. [CBSE 2013]

Q7) A 0.01 m aqueous solution of AlCl₃ freezes at −0.068⁰C. Calculate the percentage of dissociation. Kf
of water=1.86 K kg mol⁻¹. (Ans. 88.5%) [CBSE 2020]

Q8) A solution containing 15 g urea (molar mass = 60 g/mol) per litre of solution in water has the same
osmotic pressure (isotonic) as a solution of glucose in water. Calculate the mass of glucose present in
one litre of its solution. (Ans. 45 g) [AI 2014]

Q9) A solution prepared from 1.25 g of oil of wintergreen in 90 g of benzene has a boiling point of
80.31⁰C. Determine the molar mass of this compound if the boiling point of pure benzene is 80.10⁰C. Kb
for benzene = 2.53⁰C kg mol⁻¹. (Ans. 167.328 g/mol) [CBSE 2019]

Q10) Why are aquatic species comfortable in cold water than warm water? [CBSE 2018]