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Level # 1 .................................................................................... 75
Level # 2 .................................................................................... 37
Level # 3 .................................................................................... 64
Level # 4 .................................................................................... 34
Q.2 Which of the following set of elements obeyes Q.9 Modern periodic table is based on atomic no.
Newland’s octave rule - experiments which proved importance of at no.
(A) Na, K, Rb (B) F, Cl, Br was -
(C) Be, Mg, Ca (D) B, Al, Ga (A) Braggs work on X-ray diffraction
(B) Moseleys work on X-ray spectrum
Q.3 Which of the following is/are Doeberiners (C) Mulliken’s oil drop experiment
triad - (D) Lother meyer curve plotted between at vol. &
(i) P, As, Sb (ii) Cu, Ag, Au at wt.
(iii) Fe, Co, Ni (iv) S, Se, Te
Correct answer is - Q.10 Atomic no. is the base of -
(A) (i) and (ii) (B) (ii) and (iii) (i) Lother meyer curve
(C) (i) and (iv) (D) All (ii) Newland octave rule
(iii) Modern periodic table
Q.4 Which is not anomalous pair of elements in the (iv) Doeberiener triad rule
Medeleeves periodic table - (v) Long form of periodic table
(A) Ar and K (B) Co and Ni (A) (i), (ii), (iv) (B) (iii), (v)
(C) Te and I (D) Al and Si (C) (i), (iv) (D) (i), (iii), (v)
Q.5 Which are correct match - Q.11 Atomic wt. or Cl = 35.5 and of I = 127. According to
doeberiner triad rule, At. wt. of Br will be -
(i) Eka silicon – Be
(A) 80.0 (B) 162.5 (C) 81.25 (D) 91.5
(ii) Eka aluminium – Ga
(iii) Eka mangenese – Tc Q.12 The elements of groups, 1, 2, 13, 14, 15, 16 and 17
(iv) Eka scandium – B are collectively called -
(A) (ii) & (iii) (B) (i), (ii) & (iv) (A) Noble gases
(C) (i) & (iv) (D) All (B) Representative or normal elements
(C) Transition elements
Q.6 The places that were left empty by Mendeleef were, (D) Inner transition elements
for -
(A) Aluminium & Silicon Q.13 Justification of putting H in VII A group is -
(B) Gallium and germinium (A) H is gas
(C) Arsenic and antimony (B) H is non metal
(D) Molybdenum and tungsten (C) It form NaH like salt
(D) It has ortho and para allotropes
Q.7 Which of the following pairs of elements do not
Q.14 The discovery of which of the following group of
follow octave rule -
elements gave a death blow to the Newlands Law -
(A) Na, K (B) Ca, Sr
(A) Inert gases (B) Alkali metals
(C) F, Cl (D) O, S
(C) Transuranic element (D) Halogens
Q.15 Which of the following pair of elements follows Q.24 Atomic number of Ag is 47. In the same group the
Newland’s octave rule - atomic number of elements placed above and below
(A) Ne, Ar (B) C, N (C) Na, K (D) P, S Ag will be -
(A) 37, 67 (B) 29, 79
Q.16 238 234
changes to 90 Th by emission of - (C) 39, 69 (D) 29, 65
92 U (IIIB)
particle. Daughter element will be in -
(A) IIIB (B) IB (C) VB (D) IIA Q.25 Atomic number 15, 33, 51 represents the following
family -
(A) Carbon family (B) Nitrogen family
Q.17 From the list given below, elements which belongs
to the same group or sub-group are - (C) Oxygen family (D) None
(A) Atomic number = 12, 20, 4, 88
(B) Atomic number = 8, 16, 34, 2 Q.26 The atom having the valence shell electronic
configuration 4s2 4p2 would be in -
(C) Atomic number = 11, 18, 27, 5
(A) Group II A and period 3
(D) Atomic number = 24, 47, 42, 55
(B) Group II B and period 4
(C) Group IV A and period 4
Q.18 The name ‘Rare earths’ is used for -
(D) Group IV A and period 3
(A) Lanthanides only
(B) Actinides only
Q.27 The number of elements know at that time when
(C) Both lanthanides and actinides
Mendeleev arranged them in the periodic table was-
(D) Alakaline earth metals
(A) 63 (B) 60
(C) 71 (D) 65
Q.19 Z/e ratio for N3–, O2– and F– respectively will be -
(A) 0.7, 0.8 and 0.9 (B) 0.9, 0.8 and 0.7
Q.28 As applied to periodic table, which of the following
(C) 7, 8 and 9 (D) 9, 8 and 7 sets include only magic numbers -
(A) 2, 8, 20, 28, 50, 82, 126
Q.20 There are 10 neutrons in the nucleus of the element (B) 2, 8, 8, 18, 18, 32
19
zM . It belongs to - (C) 2, 2, 8, 8, 18, 32
(A) f-block (B) s-block
(D) 2, 8, 18, 18, 32, 32
(C) d-block (D) None of these
Q.33 The screening effect of d-electrons is - Q.41 Arrange the elements in increasing order of
(A) Equal to the p-electrons atomic radius Na, Rb, K, Mg -
(B) Much more than p-electrons (A) Na < K < Mg < Rb
(C) Same as f-electrons (B) K < Na < Mg < Rb
(D) Less than p-electrons (C) Mg < Na < K < Rb
(D) Rb < K < Mg < Na
Q.34 In which of the following compounds manganese
show maximum radius - Q.42 Which of the following sequences is correct for
(A) MnO2 (B) KMnO4 decreasing order of ionic radius -
(C) MnO (D) K3[Mn(CN)6] (A) Se–2 > I– > Br – > O–2 > F–
(B) I– > Se–2 > O–2 > Br– > F–
Q.35 Arrange in the increasing order of atomic radii of (C) Se–2 > I– > Br– > F– > O–2
the following elements O, C, F, Cl, Br - (D) I– > Se–2 > Br– > O–2 > F–
(A) F < O < C < Cl < Br
(B) F < C < O < Cl < Br Q.43 The order of size is -
(C) F < Cl < Br < O < C (A) S–2 > Cl – > O–2 > F–
(D) C < O < F < Cl < Br (B) Cl – > S–2 > O–2 > F–
(C) S–2 > O–2 > Cl– > F–
Q.36 The correct order of size would be - (D) S–2 > O–2 > F– > Cl –
(A) Ni < Pd ~ Pt (B) Pd < Pt < Ni
(C) Pt > Ni > Pd (D) Pd > Pt > Ni Q.44 Arrange the following in order of increasing
atomic radii Na, Si, Al, Ar -
Q.37 Which group of atoms have nearly same atomic (A) Na < Si < Al < Ar
radius - (B) Si < Al < Na < Ar
(A) Na, K, Rb, Cs (B) Li, Be, B, C (C) Ar < Al < Si < Na
(C) Fe, Co, Ni (D) F, Cl, Br, I (D) Na < Al < Si < Ar
Q.45 Consider the isoelectronic series : Q.52 The correct order of stability of Al+, Al+2, Al+3 is-
K+, S2– , Cl – and Ca 2+, the radii of the ions (A) Al+3 > Al+2 > Al + (B) Al+2 > Al+3 > Al +
decrease as - (C) Al+2 < Al+ > Al+3 (D) Al+3 > Al+ > Al+2
(A) Ca2+ > K+ > Cl– > S2–
(B) Cl– > S2– > K+ > Ca2+ Q.53 The ionization energy of sodium is 495 kJ mol–1.
(C) S2– > Cl– > K+ > Ca2+ How much energy is needed to convert atoms
(D) K+ > Ca2+ > S2– > Cl – persent in 2.3 mg of sodium into sodium ions -
(A) 4.95 J (B) 49.5 J (C) 495 J (D) 0.495 J
Q.46 Which of the following is not isoelectronic series-
(A) Cl–, P3–, Ar (B) N3–, Ne, Mg+2 Q.54 Ionisation energy increases in the order -
(C) B+3, He, Li+ (D) N3– , S2–, Cl – (A) Be < B < C < N (B) B < Be < C < N
(C) C < N < Be < B (D) N < C < Be < B
Q.47 In the isoelectronic species the ionic radii (Å) of
N3–, Ne and Al+3 are respectively given by - Q.55 Mg forms Mg(II) because of -
(A) 1.36, 1.40, 1.71 (B) 1.36, 1.71, 1.40 (A) The oxidation state of Mg is +2
(C) 1.71, 1.40, 1.36 (D) 1.71, 1.36, 1.40 (B) Difference between I.P1 and I.P2 is greater
than 16.0 eV
(C) There are only two electrons in the outermost
Ionisation Potential energy level of Mg
(D) Difference between I.P1 and I.P2 is less than
Q.48 Correct orders of Ist I.P. are - 11 eV
(i) Li < B < Be < C
(ii) O < N < F Q.56 IP1 and IP2 of Mg are 178 and 348 K.cal mol–1.
The enthalpy required for the reqction
(iii) Be < N < Ne
Mg Mg2+ + 2e– is -
(A) (i), (ii) (B) (ii), (iii)
(A) + 170 K.cal (B) + 526 K.cal
(C) (i), (iii) (D) (i), (ii), (iii)
(C) – 170 K.cal (D) – 526 K.cal
Q.49 The maximum tendency to form unipositive ion Q.57 Highest ionisation potential in a period is shown
is for the elment with the electronic configuration-
by -
(A) 1s2, 2s2, 2p6, 3s2 (A) Alkali metals
(B) 1s2, 2s22p6, 3s23p1
(B) Noble gases
(C) 1s2, 2s22p6, 3s23p2
(C) Halogens
(D) 1s2, 2s22p6, 3s23p3
(D) Representative elements
Q.7 The correct order of decreasing first ionization (C) Energy is absorbed in both the processes
energy is - (D) Energy is released in both the processes
(A) Si > Al > Mg > Na
Q.13 The order of first ionisation enthalpies of the
(B) Si > Mg > Al > Na
elments Li, Be, B, Na is -
(C) Al > Si > Mg > Na
(A) Li > Be > B > Na (B) Be > B > Li > Na
(D) None of these
(C) Na > Li > B > Be (D) Be > Li > B > Na
Q.8 Which of the following transitions involves Q.14 Arrange the elements S, P, As in order of
maximum amount of energy - increasing ionization enthalpy -
(A) M–(g) M(g) (B) M(g) M+(g) (A) S < P < As (B) P < S < As
(C) M+(g) M2+
(g) (D) M2+ 3+
(g) M (g) (C) As < S < P (D) As < P < S
Q.15 The correct order of second ionization potential Q.22 The electron affinityes of , O, S and Cl are such
of C, N, O and F is - that -
(A) C > N > O > F (B) O > N > F > C (A) N < O < S < Cl
(C) O > F > N > C (D) F > O > N > C (B) O < N < Cl < S
(C) O Cl < N S
Q.16 First, second and third IP values are 100eV, 150eV (D) O < S < Cl < N
and 1500eV. Element can be -
(A) Be (B) B (C) F (D) Na Q.23 The correct order of electron affinity of B, C, N,
O is -
Q.17 M+(g) + e–, H = 100 eV
M(g) (A) O > C > N > B (B) B > N > C > O
M2+(g) + 2e–, H = 250 eV
M(g) (C) O > C > B > N (D) O > B > C > N
Which is incorrect statement ?
(A) IE1 of M(g) is 100 eV Q.24 The correct order of electron affinity for the
different families is -
(B) IE1 of M+(g) is 150 eV
(A) Halogen > carbon > nitrogen > oxygen
(C) IE2 of M(g) is 250 eV
(B) Halogen > oxygen > nitrogen > carbon
(D) IE2 of M(g) is 150 eV
(C) Halogen > nitrogen > carbon > oxygen
(D) Halogen > oxygen > carbon > nitrogen
Q.18 I.P. of sodium is 5.14 eV. then I.P. of potassium
will be -
(A) Equal to sodium (B) 5.68 eV Q.25 Highest electron-affinity is associated with the
configuration -
(C) 4.34 eV (D) 10.28 eV
(A) 2s2, 2p0 (B) 2s2, 2p2
2
(C) 2s , 2p 3 (D) 2s2, 2p1
Q.19 The correct values of ionization enthalpies (in kJ
mol–1) of Si, P, Cl and S respectively are -
(A) 786, 1012, 999, 1256 Q.26 Adding electron a neutral gaseous atom usually
leads to -
(B) 1012, 786, 999, 1256
(i) Liberation of energy
(C) 786, 1012, 1256, 999
(ii) Formation of anion
(D) 786, 999, 1012, 1256
(iii) Proton/electron ratio decrease
(iv) Proton/electron ratio increase
Q.20 Consider the following changes -
Code in -
A A+ + e– : E1 and A+ A2 + e– : E 2
(A) (i), (iv) (B) (ii), (iii), (iv)
The energy required to pull out the two electrons
are E 1 and E 2 respectively. The correct (C) (i), (ii), (iv) (D) (i), (ii), (iii)
relationship between two energies would be -
(A) E1 < E 2 (B) E1 = E 2 Q.27 Which statement is correct -
(C) E1 > E 2 (D) E1 E 2 (A) The E.A. of carbon is greater than oxygen
(B) The E.A. of sulphur is less than oxygen
Q.21 Electron affinity is a - (C) The E.A. of iodine is greater than bromine
(A) Relative strength to attract the shared (D) The E.A. of bromine is less than chlorine
electron pair
(B) Necessary energy required to remove the Q.28 Fluorine has low electron affinity than chlorine
electron from the ultimate orbit because of -
(C) Energy released when an electron is added (A) Smaller radius of fluorine, high density
to the outermost shell (B) Smaller radius of chlorine, high density
(D) Energy released when an electron is added (C) Bigger radius of fluorine, less density
to the inner shell (D) Smaller radius of chlorine, less density
Q.29 Which of the following element is expected to Q.33 The correct set of decreasing order of
have highest electron gain enthalpy - electronegativity is -
(A) 1s22s22p63s23p5 (B) 1s22s22p3 (A) Li, H, Na (B) Na, H, Li
2 2
(C) 1s 2s 2p 4 (D) 1s22s22p5 (C) H, Li, Na (D) Li, Na, H
Q.16 Strongest reducing agent among the following is - Q.25 Which of the following properties is nearly same
(A) F– (B) Cl– (C) Br– (D) I– for two families -
Family-1 Be, Mg, Ca, Sr........
Q.17 Which of the following statements are correct ? Family-2 He, Ne, Ar, Kr........
(A) Tl3+ salts are oxidising agents (A) EN (B) EA
(B) Ga+ salts are reducing agents (C) IP (D) OS (oxidation state)
(C) Pb4+ salts are better oxidising agents
(D) All of these Q.26 Match list-I with list-II and choose the correct
answer from the code given below:
Q.18 Which statement is correct ? List-I List-II
(A) Sn4+ is more stable than Sn 2+ (a) Strongest reductant i. Aurum
(B) Pb2+ is more stable than Pb4+
(b) Half filled d-orbital ii. cerium
(C) Both (A) and (B)
(c) Coinage metal iii. chromium
(D) None of these
(d) Lanthanide iv. iodide ion
Q.19 The size of the species, Pb, Pb2+, Pb4+ decreases Code is -
as - (a) (b) (c) (d)
(A) Pb4+ > Pb2+ > Pb (A) iv iii i ii
(B) Pb > Pb2+ > Pb4+ (B) i ii iii iv
(C) Pb > Pb4+ > Pb2+ (C) iv i iii ii
(D) Pb4+ > Pb > Pb2+ (D) ii iii i iv
Q.29 Match list-I (atomic number of element) with list- Q.34 The correct decreasing order of ionic radius is -
II (position of elements in periodic table) and (A) C4– > N3– > O2– > F–
select the corect anwer using the codes given (B) F– > O2– > N3– > C4–
gelow the lists :
(C) O2– > F– > C4– > N3–
List-I List-II
(D) N3– > O2– > F– > C4–
(a) 19 i. p-block
(b) 22 ii. f-block
Q.35 Lanthanoids are -
(c) 32 iii. d-block
(A) 14 elements in the seventh period (Atomic
(d) 64 iv. s-block no. = 58 to 71) that are filling 4f subshell
Codes - (B) 14 elements in the sixth period (atomic no.
(a) (b) (c) (d) = 90 to 103) that are filling 4f subshell
(A) i ii iii iv (C) 14 elements in the seventh period (atomic
(B) iv iii i ii no. = 90 to 103) that are filling 5f subshell
(C) iv i iii ii (D) 14 elements in the sixth period (atomic no.
(D) ii i iii iv = 58 to 71) that are filling 4f subshell
Q.7 Which one of the following sets of ions represents Q.13 Pick out the isoelectronic structure from the
the collection of isoelectronic species ? following :
I. +CH3 II. H3O+ III. NH3 IV. CH3–
(A) K+, Cl–, Mg2+, Sc3+ (B) Na+, Ca2+, Sc3+, F– (A) I and II (B) III and IV
(C) K+, Ca2+, Sc3+, Cl– (D) Na+, Mg2+, Al3+, Cl– (C) I and III (D) II, III and IV
Q.14 The lanthanide contraction is responsible for the Q.2 The decreasing order of the second ionization energy
fact that of K, Ca and Ba is (At. Nos. K = 19, Ca = 20, Ba = 56)
(A) Zr and Y have about the same radius
(B) Zr and Nb have similar oxidation state (A) K > Ca > Ba (B) Ca > Ba > K
(C) Zr and Hf have about the same radius (C) Ba > K > Ca (D) K > Ba > Ca
(D) Zr and Zn have the same oxidation state
Q.3 Element Hg has two oxidation states Hg+1 & Hg+2.
Q.15 Which of the following factors may be regarded The right order of radii of these ions -
as the main cause the lanthanide contraction ?
(A) Hg+1 > Hg+2 (B) Hg+2 > Hg+1
(C) Hg+1 = Hg+2 (D) Hg+2 Hg+1
(A) Poor shielding of one of 4f electron by
another in the subshell
Q.4 Which has most stable + 2 oxidation state :
(B) Effective shielding of one of 4f electrons by
another in the subshell
(C) Poorer shielding of 5d electrons by 4f (A) Sn (B) Pb (C) Fe (D) Ag
electrons
(D) greater shielding of 5d electrons by 4f Q.5 Moving from right to left in a periodic table, the
electrons atomic size is-
(A) Increased (B) Decreased
Q.16 The increasing order of the first ionization (C) Remains constant (D) None of these
enthalpies of the elements B, P, S and F (lowest
first) is –
(A) F < S < P < B (B) P < S < B < F Q.6 The increasing order of electronegativity in the
(C) B < P < S < F (D) B < S < P < F following elements-
(A) C, N, Si, P (B) N, Si, C, P
Q.17 Which one of the following sets of ions represents (C) Si, P, C, N (D) P, Si, N, C
a collection of isoelectronic species ?
Q.7 One element has atomic weight 39. Its electronic
(A) N3–, O2–, F–, S2– (B) Li+, Na+, Mg2+, Ca2+ configuration is 1s2, 2s2 2p6, 3s2 3p6 4s1. The true
(C) K+, Cl–, Ca2+, Sc3+ (D) Ba2+, Sr2+, K+, Ca2+ statement for that element is-
(A) More (IE)1
Q.18 lanthanoid contraction is caused due to - (B) Transition element
(C) Isotone with 18Ar38
(A) The same effective nuclear charge from Ce to (D) Stable oxide M2O
Lu
(B) The imperfect shielding on outer electrons by
4f electrons from the nuclear charge Q.8 The number of paired electrons in oxygen is -
(C) The appreciable shielding on outer electrons
by 4f electrons from the nuclear charge (A) 6 (B) 16 (C) 8 (D) 32
(D) The appreciable shielding on outer electrons
by 5d electrons from the nuclear charge Q.9 Which of the following oxide is neutral ?
LEVEL # 2
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. B B D A D C B D B B B D B C A A C B C A
Q.No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37
Ans. C A C D B D D A A A A C C A D D A
LEVEL # 3
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. D B B B D C C C A C D D C A C D D C B C
Q.No. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. C C A A B A C C B D C A D A D D C D B A
Q.No. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. B A B A A B D C A D B A C C B C C D C A
Q.No. 61 62 63 64
Ans. C A C A
LEVEL # 4
SECTION - A
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Ans. A B B B A A C A D A B A D C C D C B
SECTION - B
Q.No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
Ans. C A A B A C C A A D B B B A B A