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2. Picric acid is to be extracted with benzene from its solution. If the aqueous solution contains 0.2 mol of picric acid per liter, calculate the 2.5
volume of benzene with which 1 liter of the solution must be extracted in order to form a benzene solution containing 0.02mol of picric acid
per liter. Also calculate the percentage recovery of picric acid from the aqueous solution.
K = distribution coefficient = 0.505 ,CE =concentration of picric acid in benzene, mol per liter of solution, CR =concentration of picric acid in
water, mol per liter of solution.
3. Define liquid extraction & state briefly the fields of application of extraction. 2.5
7. A distillation column separates 10,000kg/h of a benzene-toluene mixture as shown in the figure below. In the figure xF,xD, and xw represent 5
the weight fraction of benzene in the feed, distillate, and residue, respectively. Find the Reflux Ratio.
GOVERNMENT POLYTECHNIC BARAUNI
CLASS TEST -2023
Semester – 5th Branch: - Chemical engg.
Subject: - C.R.E. (2014502) Full marks: - 20
Q.NO. QUESTION MARKS
GROUP – A (5)
I) The fractional volume change of the system for the isothermal gas phase 1
reaction, A 3B, between no conversion and complete conversion is
(a) 0.5
(b) 1
(c) 2
(d) 3
ii) What is the order of a chemical reaction, A + 2B C, if the rate of 1
formation of 'C', increases by a factor of 2.82 on doubling the concentration
of 'A' and increases by a factor of 9 on trebling the concentration of 'B'?
(a) 7/2
(b) 7/4
(c) 5/2
(d) 5/4
iii) A first order reaction requires two equals sized CSTR. The conversion is 1
(a) less when they are connected in series.
(b) more when they are connected in series.
(c) more when they are connected in parallel.
(d) same whether they are connected in series or in parallel.
iv) Reaction with high activation energy is – 1
(a) Very temp. sensitive
(b) Temp. insensitive
(c) Always irreversible
(d) Always reversible
v) A back-mixes reactor- 1
(a) Is same as P.F.R
(b) Is same as ideal C.S.T.R
(c) Employs mixing in axial direction only
(d) Is most suitable for gas phase reaction
GROUP – B (answer any two) (5)
2. Define order of reaction and describe which variable affecting the rate of reaction. 2.5
4. Explain Arrhenius theory for temperature dependency of reactions rate constant. 2.5
5. Derive the performance equation for a steady state plug flow reactor in term of 5
conversion?
6. Explain the step involved in solid catalyzed gas phase reactions? 5
7. Define space time and space velocity. Derive the performance equation for CSTR. 5
GOVERNMENT POLYTECHNIC BARAUNI
CLASS TEST -2023
Semester – 5th Branch: - Chemical engg.
Subject: - Petrochemical Technology (1614504) Full marks: - 20
Q.NO. QUESTION MARKS
GROUP – A (5)
2. Define: - 2.5
(i) Octane number (ii) Cetane number
3. Write the definition and significance of following: Flash and Fire Point. 2.5