JEE ADVANCED PAPER-I

Time Duration: 3 Hours Maximum Marks : 183

 PHYSICS

SECTION - 1
1. A block M hangs vertically at the bottom end of a uniform rope of constant mass per unit length.
The top end of the rope is attached to a fixed rigid support at O. A transverse wave pulse (Pulse 1)
of wavelength 0 is produced at point A (Pulse 2) without disturbing the position of M it takes time
TAO to reach point O. Which of the following options is/are correct?

(A) The velocities of the two pulses (Pulse 1 and Pulse 2) are the same at the midpoint of rope
(B) The velocities of any pulse along the rope is independent of its frequency and wavelength
(C) The wavelength of Pulse 1 becomes longer when it reaches point A
(D) The time TAO = TOA
1. , d l eku j S
f[ kd ?kur koky s(uniform mass per unit length) Å/okZ /kj Mksj dsfupy sfl j si j , d xq VdkM y Vdkgq vk
gSA Mksj dk nwl j k fl j k n`<+vk/kkj (fca
nqO) l sl a y Xu gSAr j a
x&nS/; Z0 dhvuq i zLFk r j a
x Li a
n (Li a
n 1, Pulse 1) fcanqO
i j mRiUu dhxbZgS A ; sr j a
x Li an fca
nqO l sfca nqA r d TOA l e; esai gq ¡pr hgSA xq VdsM dksfcuk fo{kksfHkr fd; sgq , fca
nq
A i j fuekZ
. k dhxbZr j a x&nS /; Z0 dhvuq i zLFk r j a
x Li a
n (Li a
n 2, pulse 2), fca nqA l sfca nqO r d TAO l e; esai gq
¡pr hgS
A
fuEu esal sdkS u l k(l s) dFku l ghgS @gSa
\

(A) Mksj dse/; fca

nqi j Li a
n 1 (pulse 1) , oaLi a
n 2 (pulse 2) dk osx l eku gS
A
(B) Mksj dsvuq
fn' k i zsf"kr fdl hHkhLi a
n dk osx ml dhvkof̀Ùk , oar j a
x nS
/; Zi j fuHkZ
j ughagS
A
(C) Li a
n 1 (pulse 1) dhr j a
x&nS
/; Zfca
nqA r d i gq
¡pusesay Echgkst k, xhA
(D) l e; TAO = TOA
1. B,D

T (M  x)g
vA = = ;  = mass per unit length
 g
 v depends on x
hence, A,D & B is theoretical
2. A circular insulated copper wire loop is twisted to form two loops of area A and 2A as shown in the
figure. At the point of crossing the wires remain electrically insulated from each other. The entire

loop lies in the plane (of the paper). A uniform magnetic field B points into the plane of the
paper. At t = 0, the loop starts rotating about the common diameter as axis with a constant
angular velocity  in the magnetic field. Which of the following options is/are correct?

(A) The net emf induced due to both the loops is proportional to cos t
(B) The rate of change of the flux is maximum when the plane of the loops is perpendicular to
plane of the paper
(C) The amplitude of the maximum net emf induced due to both the loops is equal to the
amplitude of maximum emf induced in the smaller loop alone
(D) The emf induced in the loop is proportional to the sum of the areas of the two loops
2. , d xksy kdkj fo| q r &j ks/khr kezr kj (insulated copper wire) dksA , oa2A oky snks{ks=kQy ksadsoy ; ksaesaO ; kofr Z
r fd; k
x; kgS A r kj ksadsvfr Øe.kfca nqfo| qr j ks/khj gr sgS(t S
l kfp=kesan' kkZ
; kx; kgS)A l a
iw
. kZoy ; dkxt dsr y esafLFkr gS A dkxt

dsr y dsvfHky Ecor ~fLFkj r Fkk , d l eku pq Ecdh; {ks=k B l oZ
=k mi fLFkr gS
A oy ; vi usl keq nkf; d O
; kl ksal scusv{k ds
i fj r %l e; t = 0 l s dks.kh; osx (angular velocity) l s?kw euk' kq: dj r kgSA fuEu esal sdkS
u l k(l s) dFku l ghgS @gSa
\

(A) nksuksaoy ; ksal smRiUu dq

y i zsf"kr fo| q
r okgd cy cos t l sl ekuq
i kr h gS
A
(B) t c oy ; ksadk r y dkxt dsr y l svfHky a
c fn' kk esagksrk gSr c vfHkokg dsi fj or Z
u dhnj vf/kdr e gksrhgS
A
(C) nks
uksaoy ; ksal
smRiUu vf/kdr e dq
y i zsf"kr fo| q
r okgd cy dkvk; ke] NksVsoy ; esamRiUu vf/kdr e i zsf"kr fo| q
r okgd
cy dsvk; ke dscj kcj gksxkA
(D) i zsf"kr fo| q
r okgd cy oy ; ksads{ks=kQy ksads; ksx dsl ekuq
i kfr d gS
A
2. B,C
induced current is both loops in opposite directions;
enet = e2 – e1 1
2 = 2BA cost
1 = BA cost
2
d2
e2 = – = 2BA sint
dt
e1 = BA sint
enet = e2 – e1 = BA sint

3. A block of mass M has a circular cut with a frictionless surface as shown. The block rests on the
horizontal frictionless surface of a fixed table. Initially the right edge of the block is at x = 0, in
a co-ordinate system fixed to the table. A point mass m is released from rest at the topmost point
of the path as shown and it slides down. When the mass loses contact with the block, its position
is x and the velocity is v. At that instant, which of the following options is/are correct?

2gR
(A) The velocity of the point mass m is : v 
m
1
M

mR
(B) The x component of displacement of the center of mass of the block M is ; 
Mm

mR
(C) The position of the point mass is : x =  2
Mm

m
(D) The velocity of the block M is : V   2gR
M
3. oÙ̀kkdkj pki oky s, d xq
VdsdknzO ; eku M gSA ; sxq
Vdk, d ?k"kZ. kj fgr est i j fLFkr gS Aest dsl ki s{; (in a coordinate
system fixed to the table) xq Vdsdk nkfguk dksj (right edge) x = 0 i j fLFkr gS A nzO
; eku m oky s, d fca nqd.k
(point mass) dksoÙ̀kkdkj pki dsmPpr e fca nql sfoj kekoLFkk l sNksM+k t kr k (released from rest) gS A ; sfcanqd.k
oÙ̀kkdkj i Fk i j uhpsdhvksj l j dr k gS
A t c fcanqd.k xqVdsl sl a i dZfoghu gkst kr k gS ] r c ml dhr kR{kf.kd fLFkfr x vkS
j
xfr v gS A fuEu esal sdkS
u l k (l s) dFku l ghgS @gS
a
\
 2gR
(A) fca
nqd.k (m) dk osx v  gS
A
m
1
M

mR
(B) xq
Vds(M) dsl a nzdsfoLFkki u dk x ?kVd (x co-ordinate) 
gfr dsa gS
a
Mm

mR
(C) nqd.k (m) dk LFkku x =  2
fca gS
A
Mm

m
(D) Vds(M) dk osx V  
xq 2gR gS
a
A
M
3. A,B
Let wedge shifts by x.
R

m
v M v

(0,0)
x
mR
xCM = 0  M (–x) + m (R – x) = 0  x =
mM
Then mechanical energy conservation

1 1
mv
v2 + Mv2 = mgR, R = h
2 2
& momentum conservation
mv = MV

2gR
v= m
1
M

4. A flat plate is moving normal to its plane through a gas under the action of a constant force F. The
gas is kept at a very low pressure. The speed of the plate v is much less than the average speed
u of the gas molecules. Which of the following options is/are true?
(A) The pressure difference between the leading and trailing faces of the plate is proportional to uv
(B) At a later time the external force F balances the resistive force
(C) The resistive force experienced by the plate is proportional to v
(D) The plate will continue to move with constant non-zero acceleration, at all times
4. , d l i kV IysV (flat plate) vYi ncko dsxS l (gas at low pressure) esavi usr y dhvfHkya c fn' kk esa
] cká cy F ds
i zHkko esavxzl fj r gSA Iy sV dhxfr v, xS l v.kq v ksadsvklSr xfr u l scgq r de gS
A fuEu esal sdkS
u l k (l s) dFku l ghgS
@gS
a
\
(A) i z fr xkeh, oavuq xkehi `"B dsncko dk va r j uv dsl ekuq i kr h gS
A
(B) dq N l e; dsckn cká cy F vkS j i zfr j ks/k cy l arqfy r gkst k, xsa
A
(C) Iy s V } kj k vuq Hko gqv k i zfr j ks/kd cy v dsl ekuq i kr h gS
A
(D) Iy s V l oZ nk ' kq
U; srj fLFkj Roj .k (constant non-zero acceleration) l spy r h j gsxhA
4. A,B,C

v v

Leading
face
v'
u

Before After
Collision Collision

v ' v
1  v '  u  2v
vu
 p = m v' – m(–u) = mv' + mu
= 2m (u + v)
 FL  A (u + v)2

Rear
v v
face
u
v'

Before After
Collision Collision

v  v'
1=  v' = 2v - u
uv
 P = mv' – mu = 2m (v-u)
 FR  A (v-u)2
 Force difference = FL – FR  uv
 FRes = k u v

dv dv
F – FRes = (M)  F – k u v = M
Fres dt dt

5. In the circuit shown, L = 1 H, C = 1 F and R = 1 k. They are connected in series with an a.c.
source V = V0 sin t as shown. Which of the following options is/are correct?

(A) The current will be in phase with the voltage if = 104 rad.s–1
(B) At  >> 106 rad.s–1, the circuit behaves like a capacitor
(C) The frequency at which the current will be in phase with the voltage is independent of R
(D) At  ~ 0 the current flowing through the circuit becomes nearly zero.
5. fp=k esafn[ kk; sx, i fj i Fk esaL = 1 H, C = 1 F r Fkk R = 1 k gS
A , d i fj or hZoksYVr k (V = V0 sin t) L=kksr l s
Js.khl aca
/k gSA fuEu esal sdkS u l k (l s) dFku l ghgS
@gS
a
\

(A) t c = 104 rad.s–1 gksxhr c fo| q r /kkj k (electric current) oksYVr k dhl edy k esagksxhA
(B) t c  >> 106 rad.s–1, i fj i Fk l a /kkfj =k (capacitor) dhr j g O
; ogkj dj r k gS
A
(C) t c fo| q
r /kkj k oksYVr k dhl edy k esagksxhr ksog vkofr ZR i j fuHkZj ughadj sxhA
(D) t c  ~ 0 gks xhr c i fj i Fk esacgr h /kkj k ' kw
U; dsfudV gksxhA

5. C,D

1
0   106
LC
 A & B incorrect
C & D correct – Theoretical

6. For an isosceles prism of angle A and refractive index , it is found that the angle of minimum
deviation m = A. Which of the following options is/are correct?
(A) At minimum deviation, the incident angle i1 and the refracting angle r1 at the first refracting
surface are related by r1 = (i1/2)

1 
(B) For this prism, the refractive index  and the angle of prism A are related as A cos1  
2 2
(C) For the angle of incidence i1 = A, the ray inside the prism is parallel to the base of the prism
(D) For this prism, the emergent ray at the second surface will be tangential to the surface when

1
 2 A

the angle of incidence at the first surface is i1  sin sin A 4 cos  1  cos A 
 2 
6. , d l ef} ckgqfi zTe dk fi zTe dks.k A gS(isosceles prism of angle A)A bl fi zTe dk vi or Z uka
d  gSA bl fi zTe dk
U; w
ur e fopy u dks.k (angle of minimum deviation)m = A gS A fuEu esal sdksS
u l k (l s) dFku l ghgS@gS
a\
(A) U; w
ur e fopy u esavki fr r dks.k i1 , oai zFke vi or Z
d r y dsvi or Z
d dks.k r1 = (i1/2) } kj k l a
ca
f/kr gS
A

1 
(B) fi zTe dk vi or Z d  , oafi zTe dks.k (A), A 
uka cos1   } kj k l a
ca
f/kr gS
A
2 2
(C) t c fi zTe dk vki r u dks.k i1 = A gSr c fi zTe dsHkhr j i zd k' k fdj .k fi zTe dsvk/kkj dsl ekukUr j gksxhA

1
 2 A

(D) t c i gy sr y i j vki r u dks.k i1  sin sin A 4 cos  1  cos A  gS
] r c bl fi zTe dsfy , f} r h; r y
 2 
l sfuxZ
r fdj .k fi zTe dsi `"B l sLi ' khZ
; gksxhA (tangential to the emergent surface)
6. A,C,D

i e
r1 r2

At minimum deviation
r1 = r2 = A/2 & i = e, m = A
sm = i + e – A = A  i = A = e

  A  m  
 sin  sin A

Also,  =   2  = A = 2 cos A
A  sin 2
sin 2
 2 
 

i e=90°
r1 r 2

sin i =  sin r1 &  sin r2 = sin 90°

1
1
 sin r2 = = 2 cos A

2

& cos r2 = 1  sin2 r2

A
4 cos2 1
2
= A
2 cos
2

Then, sin i =  sin (A – r2)

A
= 2 cos [sin A cos r2 – cos A sin r2]
2

A
= sin A 4 cos2  1 – cos A
2
7. A human body has a surface area of approximately 1 m2. The normal body temperature is 10 K
above the surrounding room temperature T0. Take the room temperature to be T0 = 300 K. For T0
= 300 K, the value of T04 = 460 Wm–2 (where  is the Stefan-Boltzmann constant). Which of the
following options is/are correct?
(A) If the surrounding temperature reduces by a small amount t0 << T0, then to maintain the
same body temperature the same (living) human being needs-to radiate W = 4T03T0 more
energy per unit time
(B) Reducing the exposed surface area of the body (e.g. by curling up) allows humans to main-
tain the same body temperature while reducing the energy lost by radiation
(C) If the body temperature rises significantly then the peak in the spectrum of electromagnetic
radiation emitted by the body would shift to longer wavelengths
(D) The amount of energy radiated by the body in 1 second is close to 60 Joules
7. ekuoh; i `"Bh; {ks=kQy y xHkx 1 m2 gksrk gS A ekuo ' kj hj dk r ki eku i fj os'k dsr ki eku l s10 K vf/kd gksrk gS
A i fj os'k
r ki eku T0 = 300 K gS ] bl i fj os'k r ki eku dsfy , T0 = 460 Wm gS
4 –2
A t gk¡  LVhQku&cksYV~
t eku fu; r ka d
(Stefan-Boltzmann constant) gS A fuEu esal sdkS u l k (l s) dFku l gh gS @gS
a
\
(A) i fj os
' k r ki eku vxj T0 l sdVr k gS (t0 << T0) r c ekuo ds' kj hj dksr ki eku dk vuq j {k.k dj usdsfy ,
W = 4T03T0 vf/kd Åt kZfofdfj r dj uh i M+ r hgS
A
(B) i `"Bh; {ks=kQy ?kVkus(t S
l s%fl dq
M+usl s) l sekuo vi us' kj hj l sfofdfj r Åt kZ?kVkr sgS, oavi us' kj hj dk r ki eku
vuqj f{kr dj r sgS
A
(C) ekuoh; ' kj hj dsr ki eku es
avxj l kFkZ
d of̀) gksr c i zd k' kpq
Ecdh; fofdj .kLi S
DVªe dhf' k[ kj r j a
x nS
/; Z(peak in the
electromagnetic spectrum) nh?kZr j a x&nS/; Zdhvksj foLFkkfi r gksrhgS A
(D) ekuoh; ' kj hj l s1 l sd s.M esafudVr e fofdj r Åt kZ60 t w y (60 Joules) gS A
7. A,B,D
A = 1 m2
T04 = 460
4eA T03 ×(T)

SECTION - 2
0.1
8. A drop of liquid of radius R = 10-2 m having surface tension S  Nm1 divides itself into K
4
identical drops. In this process the total change in the surface energy U = 10-3J. If K = 10 then
the value of  is
0.1
8. i `"B r uko (surface tension) S  Nm1 dsæo ds, d cw
Un dh f=kT; k R=10-2 m gS
] ft l sK l e: i cw
Unksaesa
4
foHkkft r fd; k x; k gS
A i `"B&Åt kZdk cny ko U = 10-3J gS
A ; fn K = 10 gSr c  dk eku gksxk &
Sol. 6
0.1
s R = 10-2
4
4 4
(102 )3  k  r3
3 3

106
K
r3

102
r
k1 / 3

102  104 k1 / 3  1

101 = k1 /3
K = (101)3
10 = (10)6
=6
9. A monochromatic light is travelling in a medium of refractive index n = 1.6. It enters a stack of
glass layers from the bottom side at an angle  = 30°. The interfaces of the glass layers are
parallel to each other. The refractive indices of different glass layers are monotonically decreas-
ing as nm = n – mn, where nm is the refractive index of the mth slab and n = 0.1 (see the
figure). The ray is refracted out parallel to the interface between the (m–1)th and mth slabs from
the right side of the stack. What is the value of m?
, do.khZi zd k' k (monochromatic light) vi or Z uka
d n = 1.6 oky sek/; e esai zxkehgS A ; g i zd k' k dk¡p dhphr h(stack
of glass layers) i j fupy sl r g l s = 30° dks . k i j vki fr r gksrk gS
A (t S
l k fd fp=k esan' kkZ
; k x; k gS
A) dk¡pksadsLr j
i j Li j l ekUr j gS
A dk¡p dsphr hdsvi or Z uka
d , dfn"V nm = n – mn, Øe l s?kV j gsgS A ; gk¡m Lr j dkvi or Z uka
d nm
gSvkS j n = 0.1 gS A i zd k' k fdj .k (m–1) , oam Lr j dsi `"Br y l sl ekUr j fn' kk esankabZvkS j l sckgj fudy r k gS Ar c
m dk eku gks xk?
m
m-1

3
2
1

Sol. 8
n  (m  1)n
sin C 
n  mn
n sin  = (n–mn) sin 90°
1
1.6× = (1.6–m(0.1))1
2
0.8 = 1.6 – 0.1m
0.1 m = 0.8
m=8

10. 131
I is an isotope of Iodine that  decays to an isotope of Xenon with a half-life of 8 days. A small
amount of a serum labelled with 131I is injected into the blood of a person. The activity of the
amount of 131I injected was 2.4×105 Becquerel (Bq). It is known that the injected serum will get
distributed uniformly in the blood stream in less than half an hour. After 11.5 hours, 2.5 ml of
blood is drawn from the person's body, and gives an activity of 115 Bq. The total volume of blood
in the person's body, in liters is approximately (you may use ex  1 + x for |x| << 1 and In 2  0.7).
vk; ksMhu dk l eLFkkfud (isotope)131I ft l dhv/kZ &vk; q8 fnu gS] -{k; dsdkj .k t sukW u (Xenon) dsl eLFkkfud esa
{kf; r gksrk gS
A vYi ek=kk dk 131I fpfUgr (labelled) l hje (serum) ekuo ' kj hj esavUr % f{kIr (inject) fd; k x; k] ft l
ek=kk dhvW fDVor k (activity) 2.4×105 csd sjy (Becquerel) gS A ; g l hje : f/kj /kkj k esavk/ks?k.Vsesa, dl eku for fj r
gksrk gSA vxj 11.5 ?k.Vsckn, 2.5 ml j Dr 115 cS d sjy dhvW fDVor k n' kkZ
r k gS] r c ekuo ' kj hj esaj Dr vk; r u (y hVj esa
)
gSA (vki e  1 + x for |x| << 1 , oaIn 2  0.7 dk mi ; ksx dj l dr sgS
x
A).
Sol. 5
A = A0e–t
0.7  11.5 
115 2.4  105  
8  24 

3
 e
2.5  10 V
0.7  11.5 
  115V
8  24 

e 
2.4  2.5  102
e–0.0419 = 19.167×10-2
1 – 0.0419 = 19.167×10-2 V
0.95  100
V = 5 Litre
19.167
11. An electron in a hydrogen atom undergoes a transition from an orbit with quantum number ni to
another with quantum number nf. Vi and Vf are respectively the initial and final potential energies
Vi
of the electron. If V  6.25, then the smallest possible nf is
f

, d gkbMªkst u i j ek.kqdk , d by sDVªkW

u ni Doka
Ve l a
[ ; k (quantum number) oky sd{k l snf Doka
Ve l a
[ ; k (quantum
V i
number) dsd{k esai zos'k dj r k gS
A Vi r Fkk Vf i zkFkfed , oavfUr e fLFkfr t Åt kZ A ; fn V  6.25, r c nf dhU; w
, gS ur e
f

la
Hkkohl a
[ ; k (smallest possible nf) gS A
Sol. 5
Vi
 6.25
Vf

Z2
13.6
n2
n2f n
2
 6.25  f  2.5
ni ni
Min. value of nf = 5

12. A stationary source emits the sound of frequency f0 = 492 Hz. The sound is reflected by a large
car approaching the source with a speed of 2 ms–1. The reflected signal is received by the source
and superposed with the original. What will be the beat frequency of the resulting signal in Hz?
(Given that the speed of sound in air is 330 ms–1 and the car reflects the sound at the frequency
it has received)
12. , d fLFkj L=kksr f0 = 492 Hz dh/ofu mRl ft Z r dj r k gS
A 2 ms–1 dsxfr l svi xeuhdkj l s; g /ofu i j kofr Z r gksrhgS
A
/ofu L=kksr i j kofr Z
r la
d sr dksi zkIr dj dsew
y la
d sr i j v/; kj ksfi r (superpose) dj r k gS
A r c i fj .kkeh fl Xuy dh
foLi a
n&vkof̀Ùk (beat frequency) gS&
(/ofu dh xfr 330 ms–1 gS A dkj /ofu dksml dhi zkIr gq
bZvkof̀Rr i j i j kofr Z
r dj r hgS
)
Sol. 6

v0=2m/s=vc

f0 = 492 Hz
f0=492 Hz
S
SC
 v  v0 
f = f0  v 
 
Now, C  S
 v  v0 
f' = f  v  v 
 s 

 v  v0   v0 
f' = f0  v   
v  v 
   0 

 330  2   330 
f' = 492  330   330  2 
   
= 486 Hz
Beat frequency = 492 – 486 = 6 Hz
 SECTION-3
Paragraph-I
A charged particle (electron or proton) is introduced at the origin (x = 0, y = 0, z = 0) with a
  
given initial velocity  . A uniform electric field E and a uniform magnetic field B exist every--

  
where. The velocity  , electric field E and magnetic field B are given in columns 1,2 and 3

respectively. The quantities E0, B0 are positive in magnitude.

, d pkt Z
;q
Dr d.k (by sDVªkW fHkd xfr  l sew
u ; k i zksVksu) vkj a y fca
nq(x = 0, y = 0, z = 0) i j i zLr q
r (introduced)
  
gksrkgS
A fLFkj r Fkk, dl eku fo| q
r {ks=k E , oapq
Ecdh; {ks=k B l oZ Ad.kdhxfr  , fo| q
=kmi fLFkr gS r {ks=k E r Fkkpq
Ecdh;

{ks=k B fuEu dkW
y eksa1,2 , oa3 Øe' k%n' kkZ
; sx; sgS
A E0, B0 dseku /kukRed gS
A
Column-1 Column-2 Column - 3

 E0  
(I) Electron with   2 B x̂ (i) E  E0ẑ (P) B  B0x̂
0

 E0  
(II) Electron with   B ŷ (ii) E  E0ŷ (Q) B  B0x̂
0

  
(III) Proton with   0 (iii) E  E0x̂ (R) B  B0ŷ

 E0  
(IV) Proton with   2 B x̂ (iv) E  E0x̂ (S) B  B0ẑ
0

dkW
y e-1 dkW
y e-2 dkW
y e- 3

 0 E  
(I) u   2 B x̂ l s
by sDVªkW (i) E  E0ẑ (P) B  B0x̂
0

0 E  
(II) u   B ŷ l s
by sDVªkW (ii) E  E0ŷ (Q) B  B0x̂
0

 
(III) i zksVksu   0 l s (iii) E  E0x̂ (R) B  B0ŷ

 0 E  
(IV) i zksVksu   2 B x̂ l s (iv) E  E0x̂ (S) B  B0ẑ
0

13. In which case will the particle move in a straight line with constant velocity ?
(A) (IV) (i) (S) (B) (III) (ii) (R) (C) (II) (iii) (S) (D) (III) (iii) (P)
13. fdl fLFkfr esad.kvpy xfr l sl h/kkj s[keksapyu dj r kgS\
(A) (IV) (i) (S) (B) (III) (ii) (R) (C) (II) (iii) (S) (D) (III) (iii) (P)
Sol. C
 E0  
Electron (II) v  B ŷ (III) E  E0x̂ (S) B  B0ẑ
0

Electric force on electron is along +x-axis FE = –e (E0 x̂) = eE0 x̂ & magnetic force on electron,
 
FM = –e (v  B)

 E0 
= – e  B  B0 (ŷ  ẑ) = – eE0 x̂
 0

14. In which case will the particle describe a helical path with axis along the positive z-direction ?
(A) (IV) (i) (S) (B) (II) (ii) (R) (C) (III) (iii) (P) (D) (IV) (ii) (R)
14. fdl fLFkfr esad.k +z-v{k vuq
fn' k dq
. Mfy uhi Fk (helical path along positive z-axis) dk vuq
l j .k dj sxk \
(A) (IV) (i) (S) (B) (II) (ii) (R) (C) (III) (iii) (P) (D) (IV) (ii) (R)
Sol. A

 E0  
(IV) Proton v  2 B x̂ (i) E  E0ẑ (S) B  B0ẑ
0

 
FE  eE  eE0ẑ

    2E0 
& FM = e(v  B) = e  B  B0 (x̂  ẑ)
 0 

Initial magnetic force = –2eE0 ĵ

15. In which case would the particle move in a straight line along the negative direction of y-axis
(i.e., move along - ŷ ) ?
(A) (III) (ii) (R) (B) (IV) (ii) (S) (C) (III) (ii) (P) (D) (II) (iii) (Q)
15. fdl fLFkfr esad.k l h/khj s[kk esa_ .kkRed y-v{k (negative y-axis) dhfn' kk esapy sxk \
(A) (III) (ii) (R) (B) (IV) (ii) (S) (C) (III) (ii) (P) (D) (II) (iii) (Q)
Sol. A
Electric force along -y aixs
& magnetic force is zero.
Initial value = 0. So particle will move along -y-axis
Paragraph - II
An ideal gas is undergoing a cyclic thermodynamic process in different ways as shown in the
corresponding P - V diagrams in column 3 of the table. Consider only the path from state 1 to
state 2. W denotes the corresponding work done on the system. The equations and plots in the
table have standard notations as used in thermodynamic processes. Here  is the ratio of heat
capacities at constant pressure and constant volume. The number of moles in the gas is n.
, d vkn' kZxS
l (ideal gas) fofHkUu pØh; m"ei kfr d i zØeksl sxq t j r k gS
A ; g fuEu dkW
y e 3 esaP - V vkj s[k } kj k n' kkZ
;k
x; k gS
A dsoy fLFkfr 1 l sfLFkfr 2 t kusoky si Fk dhvksj /; kj nsa
A bl i Fki j fudk; i j gqv k dk; ZW gS(work done on
the system)A ; gk¡ fu; r nkc , oafu; r vk; r u m"ek&/kkfj r kvksdkvuq i kr gS(ratio of the heat capacities)AxS l
dseksy ks(moles) dhl a [ ; k n gS
A
column-1 column-2 column- 3

P
1 2

1
(I) W12 =
 1
(P2V2 – P1V2) (i) l er ki h; (Isothermal) (P)

P
1

(II) W12 = –PV2 + PV1 (ii) l evk; r fud (Isochoric) (Q)

2

P 1
2

(III) W12 = 0 (iii) l enkch; (Isobaric) (R)

P
1

 V2 
(IV) W12 = –nRT ln  V  (iv) : /kks"e (Adiabatic) (S) 2
 1

v
16. Which of the following options is the only correct representation of a process in which U = Q – PV ?
(A) (II) (iii) (P) (B) (II) (iii) (S) (C) (III) (iii) (P) (D) (III) (iv) (R)
16. fuEu fn, fodYi ksesadkS
ul k l a
; kst u U = Q – PV i zfØ; k dk vdsy sl gh i zfr fuf/kRo dj r k gS?
(A) (II) (iii) (P) (B) (II) (iii) (S) (C) (III) (iii) (P) (D) (III) (iv) (R)
Sol. A

17. Which one of the following options is the correct combination ?

(A) (II) (iv) (P) (B) (IV) (ii) (S) (C) (II) (iv) (R) (D) (III) (ii) (S)
17. fuEu fodYi ksesadkS
ul k l a
; kst u l ghgS\
(A) (II) (iv) (P) (B) (IV) (ii) (S) (C) (II) (iv) (R) (D) (III) (ii) (S)
Sol. D

18. Which one of the following options correctly represents a thermodynamic process that is used as
a correction in the determination of the speed of sound in an ideal gas ?
(A) (III) (iv) (R) (B) (I) (ii) (Q) (C) (IV) (ii) (R) (D) (I) (iv) (Q)
18. fuEu fod Yi ksesal sdkS
ul k l a
; kst u vkn' kZxsl esa/ofu d h xfr dheki dsl a
' kks/ku esai z; q
Dr Å"ekxfr d i zfØ; k d ksl gh
n' kkZ
r k gS\
(A) (III) (iv) (R) (B) (I) (ii) (Q) (C) (IV) (ii) (R) (D) (I) (iv) (Q)
Sol. D
 CHEMISTRY

19. An ideal gas is expanded from (p1,V1, T1) to (p2, V2, T2) under different conditions. The correct
statement (s) among the following is (are)
(A) The work done by the gas is less when it is expanded reversibly from V1 to V2 under adiabatic
conditions as compared to that when expanded reversibly from V1 to V2under isothermal conditions
(B) The change in internal energy of the gas is (i) zero, if it is expanded reversibly with T1 = T2,
and (ii) positive, if it is expanded reversibly under adiabatic conditions with T1  T2
(C) If the expansion is carried out freely, it is simultaneously both isothermal as well as adiabatic
(D) The work done on the gas is maximum when it is compressed irreversibly from (p2, V2) to
(p1, V1) against constant pressure p1
19. , d vkn' kZxS
l dks(p1,V1, T1) l s(p2, V2, T2) r d fofHkUu voLFkkvksadsv/khu QS
y k; k x; k gA fuEufy f[ kr fodYi ksaesal s
l ghdFku gS @gS a\
(A) t c V1 l sV2 r d #) ks "e voLFkk dsv/khu bl dk mRØe.kh; (reversibly) QS y ko fd; k t k; sr ksxS
l } kj k fd; k x; k
dk; ZV1 l sV2 r d l er ki h(isothermal) voLFkkvksadsv/khu mRØe.kh; QS y ko esafd; sx; sdk; Zdhr q y uk esade gS A
(B) xSl dhvka r fj d Åt kZea scny ko (i) ' kw
U; gS; fn bl sT1 = T2 dsl kFk QS y ko mRØe.kh; (revesible) r j hdsl sfd; k
t k, vkSj (ii) /kukRed gS A ; fn bl sT1  T2 dsl kFk #) ks"e (adiabatic) i fj fLFkfr ; ksadsv/khu mRØe.kh; (reversible)
QSy ko fd; k t k; sA
(C) ; fn QS y ko eq Dr : i l sfd; k t k; sr ks; g l kFk&l kFk nksuksal er ki h(isothermal) , oa#) ks"e (adiabatic) gS A
(D) t c bl svuq RØe.kh; r j hdsl s(irreversibly) (p2, V2) l s(p1, V1) r d fLFkj nkc p1 dsfo: ) nck; kt kr kgSr ksxS l
dsÅi j fd; k x; kk dk; Zvf/kdr e gksrk gS A
Sol. A, C, D
P1V1T1 P2V2, T2

PV°

isothermal
(A) Wisothermal  Wadiabatic
adiabatic

(B) (i) zero T1 = T2 = T = constant. E = ncv T = 0

(ii) positive T1  T2 (During adiabatic expansion internal energy decrease)

(C) Pext = 0 isothermal  E = 0  q= 0

W = 0 adiabatic  q = 0  E = 0
(D)

20. The IUPAC name(s) of the following compound is(are)

(A) 4-methylchlorobenzene (B) 4-chlorotoluene

(C) 1-chloro-4-methylbenzene (D) 1-methyl-4-chlorobenzene
20. fuEufy f[ kr ; kS
fxd dk ¼
ds½vkbZ
-; w
-i h-, s-l h- (IUPAC) uke gS%

(A) 4-eS
fFky Dy ksjkscS
a
t hu (B) 4-Dy ks
j ksVksy q
bu
(C) 1-Dy ks
j ks-4-eSfFky cSa
t hu (D) 1-eS
fFky -4-Dy ksjkscS
a
t hu
Sol. B, C

1-chloro-4-methylbenzene & 4-chlorotoulene

21. For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the mole
fraction of M in solution is shown in the following figure. Here x1 and xM represent mole fraction of
L and M, respectively, in the solution. The correct statement(s) applicable to this system is(are)

Z
pL

1 xM 0
(A) The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed from xL
= 0 to xL = 1
(B) Attractive intermolecular interactions between L–L in pure liquid L and M-M in pure liquid M
are stronger than those between L–M when mixed in solution
(C) The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed when xL  0
(D) The point Z represents vapour pressure of pure liquid L and Raoult's law is obeyed when xL  1
21. L vkS
j M nzoksadsfeJ.k} kj kcuk; s, d foy ; u esanzo M dsxzke v.kq d fHkUu (mole fraction) dsfo: ) nzo L dsok"i nkc
dksfp=k esafn[ kk; k x; k gS
] ; gkax1 r Fkk xM dsØe' k%xzke v.kq
d fHkUuksadksfu: fi r dj r sgS
A bl fudk; dk¼
ds½mi ; q
Dr l gh
dFku gS
¼
gSa
½

Z
pL

1 xM 0
(A) fca
nqZ Øe' k%nzo M dsok"i nkc dksfu: fi r dj r k gSvkSj xL = 0 l sxL = 1 r d j kmYV dk fu; e (Raoult's Law)
dk i ky u gksrk gS
(B) ' kq) nzo L esaL-L dschp esavkSj ' kq
) M esaM-M dschp esava r j k&v.kq
d fØ; k, aL-M dschp esava
r j k v.kq
d fØ; kvksa
l si zcy gSt c mUgsfoy ; u esafefJr fd; k t kr k gS
A
(C) fcU nqZ ' kq
) nzo M dsok"i nkc dksfu: fi r dj r k gSvkS
j t c xL  0 r ksj kmYV dk fu; e (Raoult's law) dk i ky u
gksrk gSA
(D) fcU nqZ ' kq
) nzo L dsok"i nkc dksfu: fi r dj r k gSvkS
j t c xL  1 r ksj kmYV dk fu; e (Raoult's law) dk i ky u
gksrk gSA
Sol. B,D

22. The correct statement(s) for the following addition reaction is (are)

(i)

(ii)
(A) (M and O) and (N and P) are two pairs of enantiomers
(B) Bromination proceeds through trans-addition in both the reactions
(C) O and P are identical molecules
(D) (M and O) and (N and P) are two pairs of diastereomers
22. fuEufy f[ kr l a
d y u vfHkfØ; kvksa(addition reaction) dsfy , l ghdFku gS@gS
a\

(i)

(ii)

(A) (M vkS j O) vkSj (N vkS j P) , uUVhvksesjks(enantiomers) dsnks; qxy gS A

(B) nks
uksavfHkfØ; kvksaesaczksfefudj .k Vªka
l la d y u } kj k c<+
r k gS
A
(C) O vkS j P l e: i v.kqgS A
(D) (M vkS j O) vkSj (N vkS j P) vkbZLVhfj vksesjksa(diastereomers)dsnks; q
xy gS
A
Sol. B, D

CH3 CH3

H3C H Br2/CHCl3 H Br Br H
Anti add.
+
H CH 3 H Br Br H
Trans
CH3 CH3
(M) (N)
[Erythene]
[Trans-Anti-Erythro]

Identical

CH 3 CH3

CH 3 CH3 Br2/CHCl3 H Br Br H
+
Anti add.
H H Br H H Br
Trans
CH 3 CH3
(O) (P)
[Erythene]
[Cis-Anti-Threo]

Enantiomerl

Ans. (B) Anti addition takes place.

(D) (M and O) and (N and P) are two pairs of diasteromers

23. Addition of excess aqueous ammonia to a pink coloured aqueous solution of MCl2.6H2O (X) and
NH4Cl gives an octahedral complex Y in the pressure of air. In aqueous solution, complex Y
behaves as 1 : 3 electrolyte. The reaction of X with excess HCl at room temperature results in the
formation of a blue coloured compelx Z. The calculated spin only magnetic moment of X and Z is
3.87 B.M., whereas it is zero for complex Y.
Among the following options, which statement(s) is(are) correct ?
(A) The hybridization of the central metal ion in Y id d2sp3
(B) Addition of silver nitrate to Y gives only two equivalents of silver chloride
(C) When X and Z are in equilbrium at 0°C, the coloured of the solution is pink
(D) Z is a tetrahedral complex
23. , d xqy kch j a
x oky sMCl2.6H2O (X) vkS j NH4Cl dst y h; foy ; u veksfu; k dsfey kusi j ] ok; qdh mi fLFkfr esa, d
v"VQy dh; l a d j (octahedral complex) Y nsrk gS A t y h; foy ; u esal a
d j Y, 1 : 3 fo| q
r vi ?kV~
; (electrolyte)
dhr j g O ; ogkj dj r k gS A l kekU; r ki i j vf/kD; HCl dsl kFk X dhvfHkfØ; k dsi fj .kkeLo: i , d uhy sj a x dk l adj Z
cur kgSA X vkS j Z dki fj dfy r i zpdj .kek=kpq Ecdh; vk?kw. kZ(spin only magnetic moment) 3.87 B.M. gS ] t cfd
;gl ad j Y dsfy , ' kw U; gS A fuEu esal sdkS ul k@l sfodYi l ghgS @gSa\
(A) Y es adsUnzh; /kkr qvk; u dk l a d j .k (hybridization) d2sp3 gS A
(B) Y ea sfl Yoj ukbVªsV fey kusi j fl Yoj Dy ksjkbM dsdsoy nksl er q Y; fey kr sgS
a
A
(C) t c 0°C i j X vkS j Z l kE; koLFkk easgS
ar ksfoy ; u dk j ax xqy kchgS
A
(D) Z , d pr q "Qy dh; (tetrahedral) l a d j gSA
Sol. A, C, D
Cobalt salts are pink in anhydrous & blue in hydated form.

(x) (z)
EX HCl
COCl2. 6H2O [CO(H2O)4]Cl2
Pink Blue

NH4Cl NH4OH
(O)

[Co(NH3)6]Cl 3
(y)
24. The Correct statement(s) about the oxaacids, HCIO4 and HCIO, is (are)
(A) The central atom in both HCIO4 and HCIO is sp3 hybridized
(B) HCIO4 is formed in the reaction between Cl2 and H2O
(C) The conjugate base of HCIO4 is weaker base than H2O
(D) HCIO4 is more acidic than HCIO because of the resonance stabilization of its anion
24. HCIO4 vkS
j HCIO dsckj sesal ghdFku gS
¼
gSa
½
(A) HCIO4 r Fkk HCIO nksuksesadsUnzh; i j ek.kqsp3 l a
d fj r gS
A
(B) Cl2 dh H2O dsl kFk vfH kfØ; k gksusi j HCIO4 cukr k gS A
(C) HCIO4 dk l a ;q
Xeh{kkj (Conjugate base) H2O l snq cZ
y {kkj gS
A
(D) _ .kk; u dsvuq ukn fLFkj hdj .k (Resonance stabilization) dsQy Lo: i HCIO4, HCIO l svf/kd vEy h; gS
A
Sol. A, C, D

OH

Cl sp3 H—O—Cl
(A)
O O
O
3
sp

+
HClO4 + H2O ClOH– + H3O
strong weak acid weak base Strong
(C)
acid and strong (Resonance stable) acid
base More stable

O–

Cl
(D)
O O
O

25. The colour of the X2, molecules of group 17 elements changes gradually from yellow to violet
down the group. This is due to
(A) Decrease in *-O* gap down the group
(B) Decrease in ionization enrgy down the group
(C) The physical state of X2 at room temperature changes from gas to solid down the group
(D) decrease in HOMO-LUMO gap down the group
25. l ew
g 17 dsr RoksadsX2 v.kq
v ksadk j a
x budsoxZesauhpst kusi j i hy sj a
x l s/khjs&/khjscS
a
xuhj a
x esacny r k gS
A ; g fuEu esa
l sfdl dsQy Lo: i gS\
(A) oxZesauhpst kusi j *-O* dk va r j ?kVr k gS
(B) oxZesauhpst kusi j vk; uu Åt kZ?kVr hgS A
(C) l kekU
; r ki i j oxZesauhpst kusi j X2 dhHkkS fr d voLFkk xS
l l sBksl esacny r hgS
A
(D) oxZes auhpst kusi j HOMO-LUMO dk va r j ?kVr k gS
A
Sol. A, D
According to M.O.T

26. The sum of the number of lone pairs of electrons on each central atom in the following species is
[TeBr6]2–, [BrF2]+, SNF3, and [XeF3]–
(A) Atomic numbers: 7, F = 9, S = 16, Br = 35, Te = 52, Xe= 54)
26. fuEufy f[ kr oxZ(Species) esai zR; sd dsUnzh; i j ek.kqi j , dkdhby sDVªkW
u ;q
Xeksadhl a
[ ; k dk ; ksx gS%
&
[TeBr6]2–, [BrF2]+, SNF3, and [XeF3]–
(A) i j ek.kql a
[ ; k: 7, F = 9, S = 16, Br = 35, Te = 52, Xe= 54)
Sol. 6
2–
Br +
Br Br F
Te , Br
Br Br F
Br
lone pair in C.A. is 1 lone pair = 2
F F
F Xe—F
F F
lone pair of electron = 0 lone pair of electron = 3

Total sum is 0+1+2+3=6

27. Among the following the number of aromatic compound(s) is

27. fuEufy f[ kr esal s, j ksesfVd ; kS

fxd ¼
; kS
fxdksa
½dhl a
[ ; k gS%
&

Sol. 5

28. Among H2, He2+, Li2, Be2, B2, C2, N2, O2– and F2 the number of diamagnetic species is
(Atomic numbers: = 1, He = 2, Li=3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9)
28. H2, He2+, Li2, Be2, B2, C2, N2, O2– vkS j F2 esai zfr pq
Ecdh; Li h'kht (Diamagnetic species) dhl a
[ ; k gS
%
&
(i j ek.kql a
[ ; k: = 1, He = 2, Li=3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9)
Sol. 5 or 6
Diamagnetic species are
C2, H2, Li2, N2, F2, Be2 → (does not exist)
29. A crystalline solid of a pure substance has a face-centred cubic structure with a cell edge of 400
pm. If the density of the substance in the crystal is 8 g cm–3, then the number of atoms present
in 256 g of the crystal in N×1024. The value of N is
29. , d ' kq
) i nkFkZds, d fØLVy h; Bksl dhQy d&dsfUnzr ?ku (face-centred cubic) l a j pukdsl kFkdksfLBdk dksj (cell
edge) dhy EckbZ400 pm gS A ; fn fØLVy dsi nkFkZdk ?kuRo 8 g cm gS
–3
] r ksfØLVy ds256 g esami fLFkr i j ek.kq
v ksa
dhdq y la[ ; k N×10 gS
24
AN dk eku gS% &
Sol. 2
FCC a = 400 pm

zFcc  GMM
dfFcc = NA  a3

4  GMM
8g/ml = N  64  1024
A

GMM = 128 × NA × 10–24

NA
= 128  N  1024 × 256
A

N = 2 Ans.

30. The conductance of a 0.0015 M aqueous solution of a weak monobasic acid was determined by
using a conductivity cell consisting of platinized Pt electrodes. The distance between the electrodes
is 120 cm with an area of cross section of 1 cm2. The conductance of this solution was found to
be 5 × 10–7 S. The pH of the solution is 4. The value of limiting molar conductivity ( 0m ) of this
weak monobasic acid is aqueous solution is Z × 102 S cm–1. The value of Z is
30. , d nqcZu , d{kkj dh; vEy ds0.0015 M t y h; foy ; u dhpky dr k (conductance) , d Iy kfVfudr̀ Pt (Platinized
Pt) by sDVªkW
Moky spky dr kl Sy dkmi ; ksx dj dsfu/kkZ
fj r dhx; hA 1 cm2 vuqi zLFkdkV ds{ks=kQy oky sby sDVªkW
Mksdschp
dhnw j h120 cm gS A bl foy ; u dhpky dr k dk eku 5 × 10 S i k; k x; kA foy ; u dk pH 4 gS
–7
A bl nqcZ
y , d{kkj dh;
vEy dht y h; foy ; u esal hekUr eksy j pky dr k (limiting molar conductivity ( 0m )) dk eku Z × 102 S cm–1
gS
A Z dk eku gS
A
Sol. 6
Concentration = 0.0015 M
[HA]
 = 120 cm G = 5 × 10–7 S = R × A/
A = 1 cm 2

PH = –log(H+) = – log(0.0015 ) = 4

1
 =
15

K  1000 5  107  120  1000

MC = HA  = × 104
0.0015
= 40

MC 1
= =
M 15

M = 600 = Z × 102 sm7

Z = 6 Ans.
Paragraph :
Using the information which is available in three columns of table given below, give answer of
questions Q.31., Q.32 and Q.33.
Wave function n,l,m1 is a mathematical function, which value depends on spherical polar coordinates
(r, , ) and titrated from quantum numbers n, l and m1. Here, r is distance from nucleus, is
Colatitude and  is azimuth. In mathematical functions which are given below table, Z is atomic
number and a0 is Bohr Radius.
Column 1 Column 2 Column 3

3
Zr
 Z 2 –
(i) n,l,m1    e a0
(I) 1s Orbital  a0 
(P)

(II) 2s Orbital (ii) a radial node (Q) nucleus per probability density
1

a30

5  zr 
 Z  2 – 2a 
(III) 2pz Orbital (iii) n,l,m1    re  0  cos  (R) nucleus per probability density
y
 a0 
is maximum

(IV) 3dz2 Orbital (iv) xy- plane is node (S) energy requires to excited a electron

27
from level n = 2 to n = 4, is times
32
to energy requires to excited a electron
from level n = 2 to n = 6

uhpsnhxbZVscy dsr hu dkW

y eksaesami y C/k l w
puk dk mi ; q
Dr <+
a
x l sl q
esy dj i z'uksaQ.31., Q.32 vkS
j Q.33 dsmRr j
nhft , &
rja
x Qy u] n,l,m , d xf.kr h; Qy u gSft l dk eku by sDVªkW
1
u dsxksy h; /kzq
oh; funZs'kka
d (r, , ) i j fuHkZ
j dj r k gSvkS
j
Doka
Ve l a
[ ; k n, l vkS
j m1 l svfHky f{kr gksrk gS
A ; gk¡ r uwfDy vl l snw j h]  dksfV' kj (Colatitude) gS ] vkS
j  fnUx' k
(azimuth) gS A Vscy esafn, x; sxf.kr h; Qy uksaesaZ i j ek.kqØeka
d gSvkS j a0 cksj f=kT; k (Bohr Radius) gS A
dkW
ye 1 dkWye 2 dkW ye 3

3
Zr
 Z 2 –
(i) n,l,m1    e a0
(I) 1s vkW
fcZ
Vy  a0 
(P)

(II) 2s vkW
fcZ
Vy (ii) , d f=kT; kRed (radial) uksM (Q) U; w
fDy vl i j i zkf; dr k ?kuRo
1
(Probability density)  a3
0
 5  zr 
 Z  2 – 2a 
(III) 2pz vkW
fcZ
Vy (iii) n,l,m1    re  0  cos  (R) U; w
fDy vl i j i zkf; dr k ?kuRo
 a0 

(Probability density) vf/kdr e gS

A

(IV) 3dz2 vkW

fcZ
Vy (iv) xy- l er y , d uksMh; gS (S) by sDVªkW
u dksn = 2 voLFkk l sn = 4 voLFkk
r d mRr sft r dj usdhÅt kZ
] by sDVªkW
u dksn = 2
voLFkk l sn = 6 voLFkk r d mRr sft r dj usds
27
fy ; svko' ; d Åt kZl s xq
uk gS
A
32

31. For He+ ion, which of the followig option is incorrect ?

(A) (I) (i) (S) (B) (II) (ii) (Q) (C) (I) (iii) (R) (D) (I) (i) (R)
31. He vk; u dsfy ; sfuEufy f[ kr fodYi ks
+
aesal sdsoy xy r (Incorrect) la
; kst u gS%
&\
(A) (I) (i) (S) (B) (II) (ii) (Q) (C) (I) (iii) (R) (D) (I) (i) (R)
Sol. C

32. For orbital which are given in column 1, which of the following options has correct combination
for any hydrogen like species :
(A) (II) (ii) (P) (B) (I) (ii) (S) (C) (IV) (iv) (R) (D) (III) (iii) (P)
32. dkW
y e 1 esafn, x; svkWfcZVy (Orbital) dsfy ; sfuEufy f[ kr fodYi ksaesal sfdl hHkhgkbMªkst u&l eku Li h'kht (Species)
dsfy ; sdsoy l ghl a
; kst u gS%
&
(A) (II) (ii) (P) (B) (III) (ii) (S) (C) (IV) (iv) (R) (D) (III) (iii) (P)
Sol. A

27 1 1  1 1 
× 13.6 × 22  4  36  = 13.6 ×  4  16 
3    

27 8 3
× =
32 36 16

33. Which of the following options has correct combination for hydrogen atom ?
(A) (I) (i) (P) (B) (I) (iv) (R) (C) (II) (i) (Q) (D) (I) (i) (S)
33. gkbMªkst u i j ek.kqdsfy ; sfuEufy f[ kr fodYi ksaesl sdsoy l ghl a
; kst u gS
%
&
(A) (I) (i) (P) (B) (I) (iv) (R) (C) (II) (i) (Q) (D) (I) (i) (S)
Sol. D

34. The only CORRECT combination in which the reaction proceeds through radical mechanism is
(A) (IV) (I) (Q) (B) (III) (II) (P) (C) (II) (iii) (R) (D) (I) (ii) (R)
34. fuEufy f[ kr fodYi ksaesal sdsoy l ghl a
; kst u ft l esavfHkfØ; k ew
y d (radical) i zfØ; k } kj k c<+
r hgS
] gS
a
(A) (IV) (I) (Q) (B) (III) (II) (P) (C) (II) (iii) (R) (D) (I) (ii) (R)
Sol. D
35. For the synthesis of benzoic acid, the only CORRECT combination is
(A) (II) (i) (S) (B) (I) (iv) (Q) (C) (IV) (ii) (P) (D) (III) (iv) (R)
35. csUt ksbZ
d vEy dsl a
' y s"k.k (Synthesis) dsfy ; sfuEufy f[ kr fodYi ksaesal sdsoy l ghl a
; kst u gS%
&
(A) (II) (i) (S) (B) (I) (iv) (Q) (C) (IV) (ii) (P) (D) (III) (iv) (R)
Sol. A

36. The only CORRECT combination that gives two different carboxylic acid is
(A) (IV) (iii) (Q) (B) (II) (iv) (R) (C) (I) (i) (S) (D) (III) (iii) (P)
36. fuEufy f[ kr fodYi ksaesal sdsoy l ghl a
; kst u t ksfd nksfHkUu dkckZ
sfDl fy d vEy nsrk gS
(A) (IV) (iii) (Q) (B) (II) (iv) (R) (C) (I) (i) (S) (D) (III) (iii) (P)
Sol. D
 MATHS

1 1 2
37. Let X and Y be two events such that P(X) = , P(X|Y) = and P(Y|X) = . Then
3 2 5
4 1 2 1
(A) P(Y) = (B) P(X'|Y) = (C) P  X  Y  = (D) P  X  Y  =
15 2 5 5
1 1 2
37. ekuk fd X vkS
j Y bl i zd kj dhnks?kVuk; sa(events) gSfd P(X) = , P(X|Y) = vkS
j P(Y|X) = gS
Ar c
3 2 5
4 1 2 1
(A) P(Y) = (B) P(X'|Y) = (C) P  X  Y  = (D) P  X  Y  =
15 2 5 5

Sol. A, B
1 1 2
(A) P(x) = P X | Y   P  Y | X 
3 2 5

P(x  y) 1 P(x  y) 2
 & 
P(y) 2 P(x) 5

2 1 2
 P(x  y)   
5 3 15

2
4
 15  1  P(y) 
P(y) 2 15

2
 x '  P(x ' y) 15 1
(B) P    
y  P(y) 4 2
15

P(x) P(y)

1 2 2 4 2
 
3 15 15 15 15
3 2
 
15 15
8
15

(D) P(x  y)  P(x)  P(y)  P(x  y)

1 4 2 542 7
=    
3 15 15 15 15
38. Let f : R  (0,1) be a continuous function. Then, which of the following functions (s) has(have)
the value zero at some point in the interval (0,1) ?

x
2
x
(A) e   f  t  sin t dt (B) f  x    f  t  sin t dt
0 0


x
2
(C) x   f  t  cos t
0
dt (D) x9 – f(x)

38. ekuk fd f : R  (0,1) , d l r r Qy u (continuous function) gS

A r c fuEu Qy uksaesal sdkS
u l sQy u¼
uksa
½dk ¼
ds½
eku vUr j ky (interval) (0,1) dsfdl hfcUnqi j ' kw
U; gksxk?

x
2
x
(A) e   f  t  sin t dt (B) f  x    f  t  sin t dt
0 0


x
2
(C) x   f  t  cos t
0
dt (D) x9 – f(x)

Sol. C, D
f : R (0, 1)
(A) range of ex in (0, 1) is (1, e)
x
 f(x) sin t dt will be less than 1
0

(B) always +ve


x
2
(C) x  0
f(t) cos t dt


x
2
at x = 0 x  0
f(t) cos t dt 0


1
2
at x = 1 1  0
f(t) cos t dt

+ve
 will be zero in (0, 1)
(D) x – f(x) will be zero at x  (0, 1)
9

39. Let a, b, x and y be real numbers such that a – b = 1 and y  0. If the complex number z = x +
 az  b 
iy satisfies Im   = y, then which of the following is(are) possible value(s) fo x ?
 z 1 

(A) 1  1  y2 (B) 1  1  y2 (C) 1  1  y2 (D) 1  1  y2

39. ekuk fd a, b, x vkS
j y bl i zd kj dhokLr fod l ¡[ ; k; sa(real numbers) gSfd a – b = 1 vkS
j y  0 gS
A ; fn l fEeJ
 az  b 
l ¡[ ; k (complex number) z = x + iy, Im  z  1  = y dksl a
rq
"V dj r hgS
] r c fuEu esal sdkS
u l k¼
l s½x dk ¼
ds½
 
l EHkkfor eku gS
¼gS
½\
(A) 1  1  y2 (B) 1  1  y2 (C) 1  1  y2 (D) 1  1  y2
Sol. B,D

 ax  b  aiy 
a – b = 1, Im   y
 x  1  iy 

 (ax  b  aiy)(x  1  iy) 

 Im  y
 (x  1)2  y2 

ay(x  1)  (ax  b)y

 y
(x  1)2  y2
 axy + ay – axy – by = y((x + 1)2 + y2)
 (a – b)y = y((x + 1)2 + y2)

 1  (x  1)2  y2

x+1=± 1  y2
x  1  1  y2

x  1  1  y2
x=–1± 1  y2

x2 y2
40. If 2x – y + 1 = 0 is a tangent to the hyperbola  = 1, then which of the following CANNOT
T
a2 16
be sides of a right angled triangle ?
(A) a, 4, 1 (B) 2a, 4, 1 (C) a, 4, 2 (D) 2a, 8, 1
2 2
x y
40. ; fn 2x – y + 1 = 0 vfr i j oy ; (hyperbola)  = 1 dh Li ' kZ
j s[kk (tangent) gSr ksfuEu esal sdkS
ulh
a2 16
l edks.kh; f=kHkq
t (right angle triangle) dhHkq
t k; saughagksl dr hgS
¼
gS½\
(A) a, 4, 1 (B) 2a, 4, 1 (C) a, 4, 2 (D) 2a, 8, 1
Sol. A,C,D

x2 y2
2x – y + 1 = 0  1
a2 16
m=2 tangent is

 4a2  16  1 y  mx  a2m2  b2

4a2 = 17 y  2x  4a2  16

17 17
a2  a 2x  y   4a2  16
4 2
Now check option.

41. Let [x] be the greatest integer less than or equals to x. Then, at which of the following points (s)
the function f(x) = cos((x + [x])) is discontinuous ?
(A) x = – 1 (B) x = 1 (C) x = 0 (D) x = 2
41. ekuk fd x l sNksVk ; k x dsl eku l cl scM+
ki w
. kkZ
a
d (integer) [x] gS
A r c f(x) = cos((x + [x])). fuEu esal sfdu
fcUnq
¼
vksa
½i j vl r r ~(discontinuous) gS?
(A) x = – 1 (B) x = 1 (C) x = 0 (D) x = 2
Sol. A,B,D
f(x) = xcos ((x + [x]))
x = n, f(x) = n cos(2n) = n
f(n+) = n cos  (2n + n) = n
f(n–) = n cos ((2n – 1)) = – n
For n = 0  limit
n = – 1, 1, 2  discontinuous

42. Which of the following is(are) NOT the square of a 3 × 3 matrix with real entries ?

1 0 0  1 0 0   1 0 0  1 0 0
       
0 1 0 0 1 0  0 1 0  0 1 0
(A)  (B)  (C)  (D) 
0 0 1 0 0 1  0 0 1 0 0 1

42. fuEu esal sdkS

u l k¼
l s½okLr fod l ¡[ ; kvksads3 × 3 vkO
;w
g (matrix) dk oxZughagS¼
gS
½\
1 0 0  1 0 0   1 0 0  1 0 0
0 1 0  0 1 0   
(A)   (B)   (C) 0 1 0 (D) 0 1 0
   
0 0 1 0 0 1  0 0 1 0 0 1
Sol. A,C
From options square of the determinant value of matrices in option (A) and (C) is –1 which is not
real so options (A) & (C)

43. If a chord, which is not a tangent, of the parabola y2 = 16x has the equation 2x + y = p, and
midpoint (h,k), then which of the following is (are) possible value (s) of p,h and k ?
(A) p = – 1, h = 1, k = –3 (B) p = 2, h = 3, k = – 4
(C) p = – 2, h = 2, k = –4 (D) p = 5, h = 4, k = – 3
43. ; fn i j oy ; (parabola) y = 16x dh , d t hok (Chord), t ks Li ' kZ
2
j s[kk (tangent) ughagS
] dk l ehdj .k
2x + y = p r Fkk e/; fcU
nq(midpoint)(h,k) gS
, r ksfuEu es
al sp,h , oe~k dsl EHkkfor eku gS
¼
gS½?
(A) p = – 1, h = 1, k = –3 (B) p = 2, h = 3, k = – 4
(C) p = – 2, h = 2, k = –4 (D) p = 5, h = 4, k = – 3
Sol. B
Eq of chord AB (with given middle point)
T = S1
yk – 8(x + h)= k2 – 16h
AB : yk – 8x = k2 – 8h ...(1)
Given eqn AB : y + 2x = p ...(2)

k 8 k2  8h
(1) = (2)   
1 2 p

A
k 2  8h  4p (h,k)
k  4 16  8h  4p
4  2h  p
B
 2h  p  4

Chek option.

44. For a real number , if the system

1  2   x   1
    
 1   y  1
=   of linear equations, has infinitely many solutions, then 1 +  + 2 =
 2  1  z   1

44. okLr fod l a
[ ; k (real number) dsfy ; s] ; fn j S
f[ kd l ehdj .k fudk; (system of linear equations)
1  2   x   1
   
 1   y  1
=   dsvuUr gy (infinitely many solutions) gS
] r c 1 +  + 2 =
 2  
 1  z   
  1
Sol. 1

1  2 
 
 1 
D=  =0
 2 
  1

1(1 – 2) – ( – 3) + 2(2 – 2) = 0

1 – 2 – 2 + 4 = 0
1 + 4 = 22
4 – 22 + 1 = 0
(2 – 1)2 = 0
2 = 1  = ±1

If  1   1
x+y+z=1 x–y+z=1
x+y+z=1 x–y+z=1
x + y + z = –1 –x + y – z = –1
No solution x–y+z=1
Infinite
Hence 1 +  + 2 = 1
Ans.  = –1

45. The sides of a right angled triangle are in arithmetic progression. If the triangle has area 24, then
what is the length of its smallest side ?
45. , d l edks.kh; f=kHkq
t (right angled triangle) dhHkq
t k; sal ekUr j Js<+
h (arithmetic progression) esagS
A ; fn bl dk
{ks=kQy 24 gSr c bl dh l cl sNksVhHkq
t k dhy EckbZD; k gS\
Sol. 6

a+d
a–d
(a – d)2 + a2 = a2 + d2

a
1
a. (a – b) = 24 a2 + d2 – 2ad + a2 = (a + d)2
2
a(a – d) = 48 ........(1) a2 = 2ad
 a
a a –  = 48 a  4d
 4 
 39
a× = 48
4
48  4
a2 =
3
a2 = 64
a=8 d=2
Smallest side = 6


46. Let f : R  R be a differentiable function such that f(0) = 0, f   = 3 and f'(0) = 1. if
2

2  
g  x   f '  t  cos ec t  cot t cos ec t f  t   dt for x   0,  , then lim g x =
x
 2 x0

  
46. ekukfd f : R  R bl i zd kj dkvody uh; Qy u (differentiable function) gSfd f(0) = 0, f  2  = 3 , oe~f'(0)
 

  2
=1 gS
A ; fn x   0,  ] r c lim
dsfy ; sg  x   f '  t  cos ec t  cot t cos ec t f t   dt gS g x =
 2 x
x0

Sol. 2

f(0) = 0, f  2  = 3, f'(0) = 1.
 

2
 
g(x) =  f '(t) cos ect– cot t.cos ect.f(t) dt
x
II I
using by parts

  
2 2 2
=  f(t).cos ect  dt +  cot t cos ectf(t)dt   cot t.cos ectf(t)dt
x x x


=  f(t) cos ect  2
x


g(x) = f  2  .1 – f(x) cosec x
 

g(x) = 3 – f(x) cosec x  xlim

0
g(x)

 xlim
0
3 – f(x).cosec x

f(x)  0 
3 – xlim Apply L-Hospital rule
0 sin x  0 

f '(x) 1
3 – xlim
0 cos x
=3– =3–1=2
cos 0
47. For how many values of p, the circle x2 + y2 + 2x + 4y – p = 0 and the coordinate axes have
exactly three common points ?
47. p dsfdr usekuks adsfy ; soÙ̀k(circle) x2 + y2 + 2x + 4y – p = 0 , oe~funsZ
' kka
d v{kksa(coordinate axes) esadsoy
r hu fcUnqmHk; fu"B (common) gS?
Sol. 2
Centre(–1, –2) r= 5P = 2

x 1
–2 r = 2 P=0
–1
–1

12  22  P = 2 circle passes 3 points

 P = –1
 f2 – c > 0
4–1>0=3
5P = 1
P = –4
 g2 – c > 0
1–4>0×

48. Words of length 10 are formed using the letters A,B,C,D,E,F,G,H,I,J. Let x be the number of such
words where no letter is repeated ; and let y be the number of such words where exactly one
y
letter is repeated twice and no other letter is repeated. Then, =
9x
48. v{kj ksaA,B,C,D,E,F,G,H,I,J l s10 y EckbZds' kCn cuk; st kr sgS Aekukfd x bl r j g dsmu ' kCnksadhl ¡[ ; kgSft uesafdl h
Hkhv{kj dhi q uj kof̀Ùk ughagksrhgS
] r Fkk y bl r j g dsmu ' kCnksadhl ¡[ ; k gSft u esadsoy , d v{kj dhi quj kof̀Ùk nksckj
y
gksrhgSo fdl hvU; v{kj dh i q
uj kof̀Ùk ughagksrhgS
Ar c =
9x
Sol. 5
A,B,C,D,E,F,G,H,I,J  10 letter
x = 10!
y = when exactly 1 letter is repacted twice.
10C × 8 ×2
9

x x

10C 10C
10
1
× 2
×1× 8 = = 50 9
2

y 50 9
 = 10 = 5
9x
 Answer 49, 50, and 51 by appropriately matching the information given in the three
columns of thee following table
Column 1,2 and 3 contain conics, equation of tangent to the conics and point of contact, respectively
Column 1 Column 2 Column 3
 a 2a 
(I) x2 + y2 = a2 (i) my = m2x + a (P)  2 , m 
m 

 –ma a 
(II) x2 + a2y2 = a2 (ii) y = mx + a m2  1 (Q)  , 
2 2 
 m 1 m 1 

 –a2m 1 
(III) y2 = 4ax (iii) y = mx + 2 2 (R)  2 2 , 
a m –1
 a m 1 a2m2  1 

 –a2m –1 
(IV) x2 – a2y2 = a2 (iv) y = mx + 2 2 (S)  2 2 , 
a m 1
 a m –1 a m  1 
2 2

49. For a = 2 , if a tangent is drawn to a suitable conic (Column 1) at the point of contact (–1, 1),
then which of the following options is the only CORRECT combination for obtaining its equation ?
(A) (I) (ii) (Q) (B) (I) (i) (P) (C) (III) (i) (P) (D) (II) (ii) (Q)

1
50. The tangent to a suitable conic (Column 1) at ( 3 , ) if found to be 3 x + 2y = 4, then which
2
of the following options is the only CORRECT combination ?
(A) (IV) (iv) (S) (B) (II) (iv) (R) (C) (IV) (iii) (S) (D) (II) (iii) (R)

51. If a tangent to a suitable conic (Column 1) is found to be y = x + 8 and its point of contact is
(8, 16), then which of the following options is the only CORRECT combination ?
(A) (III) (i) (P) (B) (I) (Ii) (Q) (C) (II) (iv) (R) (D) (III) (ii) (Q)

uhpsnhx; hVscy dsr hu dkW y kesaesami y C/k l w

puk dk mi ; q
Dr <a x l sl q
esy dj i z'uksa49,50 , oa51 dsmÙkj nhft ; sA
dkW
y e 1,2 r Fkk 3 esaØe' k%dkWfud (conic), dkW fud i j Li ' kZ
j s[kk (tangent) dk l ehdj .k r Fkk Li ' kZ
fcunq(point) of
contact) fn; sx; sgSA
dkW
ye 1 dkWye 2 dkWye 3
 a 2a 
(I) x2 + y2 = a2 (i) my = m2x + a (P)  2 , m 
m 

 –ma a 
(II) x2 + a2y2 = a2 (ii) y = mx + a m2  1 (Q)  , 
2 2 
 m 1 m 1 

 –a2m 1 
(III) y2 = 4ax (iii) y = mx + 2 2 (R)  2 2 , 
a m –1
 a m 1 a2m2  1 

 –a2m –1 
(IV) x2 – a2y2 = a2 (iv) y = mx + 2 2 (S)  2 2 , 
a m 1
 a m –1 a2m2  1 
49. a= 2 dsfy ; smi ; q
Dr dkW
fud ¼dkWy e 1½i j , d Li ' kZ
j s[kk [ kha
pht kr hgSft l dk Li ' kZ
fcUnq(–1, 1) r c fuEu esal sdkS
u
l k fodYi bl Li ' kZ
j s[kk dk l ehdj .k i zkIr dj usdk dsoy l ghl a ; kst u gS
(A) (I) (ii) (Q) (B) (I) (i) (P) (C) (III) (i) (P) (D) (II) (ii) (Q)

1
50. ; fn mi ; qDr dkWfud (dkW
y e 1) dsfcUnq( 3 , ) i j Li ' kZ
j s[kk 3 x + 2y = 4 gS
] r c fuEu esal sdkS
u l kfodYi dsoy
2
l ghl a; kst u gS]
(A) (IV) (iv) (S) (B) (II) (iv) (R) (C) (IV) (iii) (S) (D) (II) (iii) (R)

51. ; fn mi ; q
Dr dkW
fud (dkW
y e 1) dsLi ' kZ
fcUnq(8,16) i j Li ' kZ
j s[kk y = x + 8 gS
] r c fuEu esal sdkS
u l kfodYi dsoy l gh
la; kst u gS]
(A) (III) (i) (P) (B) (I) (Ii) (Q) (C) (II) (iv) (R) (D) (III) (ii) (Q)
Sol. I, (ii), Q
II, (iv), R
III, (i), P
IV, (III), S
49. A

a 2
(I) x2 + y2 = 2
P : (–1, 1)
T:y–x=2
(II) x2 + 2y2 = 2
P (–1, 1) No tangent

(III) y2 = 4 2x No tangent
(IV) x – 2y = 2
2 2
No tangent
50. B
T: POC

 1
3x + 2y = 4  3, 2 
 

3
y x 2
2

3
m
2

3
a  2 , m2 
2
51. A
y=x+8 (8, 16)

m1
a=8

Answer 49, 50, and 51 by appropriately matching the information given in the three
columns of thee following table
Let f(x) = x + logex – xlogx, x  0,  
* Column 1 contains information about zeros of f(x), f'(x) and f"(x)
* Column 2 contains information about the limiting behavior of f(x), f'(x) and f"(x) at infinity.
* Column 3 contains information about increasing / decreasing nature of f(x) and f'(x)

Column 1 Column 2 Column 3

(I) f(x) = 0 for some x  (1, e2 ) (i) xlim

f(x) = 0 (P) f is increasing in (0, 1)

(II) f'(x) = 0 for some x  (1, e) (ii) xlim


f(x) = – (Q) f is decreasing in (e, e2)

(III) f'(x) = 0 for some x  (0, 1) (iii) xlim


f'(x) = – (R) f' is increasing in (0, 1)

(IV) f"(x) = 0 for some x  (1, e) (iv) xlim


f"(x) = 0 (S) f' is decreasing in (e, e2)

52. Which of the following options is the only INCORRECT combination ?

(A) (I) (iii) (P) (B) (II) (iv) (Q) (C) (II) (iii) (P) (D) (III) (i) (R)

53. Which of the following options is the only CORRECT combination ?

(A) (I) (ii) (R) (B) (III) (iv) (P) (C) (II) (iii) (S) (D) (IV) (i) (S)

54. Which of the following options is the only CORRECT combination ?

(A) (III) (iii) (R) (B) (IV) (iv) (S) (C) (II) (ii) (Q) (D) (I) (i) (P)

uhpsnhx; hVscy dsr hu dkW

y eksaesami y C/k l w
puk dk mi ; q
Dr <a
x l sl q
esy dj i z'uksa52,53 , oa54 dsmÙkj nhft ; sA
ekuk fd f(x) = x + logex – xlogx, x  0,   gS A
* dkW
y e 1 esaf(x), f'(x) , oe~f"(x) ds' kw
U; ksadhl w
puk nhxbZgS A
* dkW
y e 2 esaf(x), f'(x) , oe~f"(x) dsvuUr dhr j Q l hek i j O
; ogkj (limiting behaviour at infinity) dhl w
puk
nhxbZgS A
* dkW
y e 3 esaf(x) , oe~f'(x) dso/kZeku @gkzkl eku (increasing/ decreasing) gksusdhi zÑfr (nature) dhl w puk
nhxbZgS A
dkW
ye 1 dkW
ye 2 dkW
ye 3
(I) f(x) = 0 fdl h x  (1, e2) dsfy ; s (i) xlim

f(x) = 0 (P) f esa(0, 1) o/kZ
eku gS

(II) f'(x) = 0 fdl hx  (1, e) dsfy ; s (ii) xlim


f(x) = – (Q) f esa(e, e2) gkzkl eku gS

(III) f'(x) = 0 fdl h x  (0, 1) dsfy ; s (iii) xlim


f'(x) = – (R) f' esa(0, 1) o/kZ
eku gS

(IV) f"(x) = 0 fdl hx  (1, e) dsfy ; s (iv) xlim


f"(x) = 0 (S) f' esa(e, e2) gkzkl eku gS
A
52. fuEu esal sdkS
u l k fodYi dsoy xy r l a
; kst u (only INCORRECT combination) gS\
(A) (I) (iii) (P) (B) (II) (iv) (Q) (C) (II) (iii) (P) (D) (III) (i) (R)

53. fuEu esal sdkS

u l k fodYi l ghl a
; kst u gS\
(A) (I) (ii) (R) (B) (III) (iv) (P) (C) (II) (iii) (S) (D) (IV) (i) (S)

54. fuEu esal sdkS

u l k fodYi dsoy l ghl a
; kst u gS?
(A) (III) (iii) (R) (B) (IV) (iv) (S) (C) (II) (ii) (Q) (D) (I) (i) (P)
Sol.
Column 1 Column 2 Column 3
(I) Correct (i) Incorrect (P) Correct
(II) Correct (ii) Correct (Q) Correct
(III) Incorrect (iii) Correct (R) Incorrect
(IV) Incorrect (iv) Correct (S) Correct

52. D 53. C 54. C

For f = x + lnx – xlnx

(i) lim f(x)   (iii) f  (0, ) 1<<e

x 

(ii) f(1).f(e2) < 0 f  ()

1
For f '   ln x
x lnx
(i) f'(1).f'(e) < 0 1/x
(ii) f'(0).f'(1) > 0 1 e

(iii) f '(x)  


1 1
For f ''  2

x x
f'' < 0  f' 

im f ''  0
x 