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Thermal Equilibrium: Two objects are in thermal equilibrium when they are at the same
temperature and no net heat transfer occurs between them. At thermal equilibrium, the
objects have reached a state of balance, and their temperatures are equal.
Heat: Heat is the transfer of energy between objects or systems due to a temperature
difference. It flows from a region of higher temperature to a region of lower temperature
until thermal equilibrium is reached. Heat transfer occurs through three mechanisms:
Laws of Thermodynamics: The laws of thermodynamics describe the behavior of energy and
its transformation in thermal systems.
First Law of Thermodynamics (Law of Energy Conservation): The total energy of an isolated
system remains constant. It can change its form or be transferred between objects, but the
total energy is conserved.
Second Law of Thermodynamics: The second law introduces the concept of entropy, which is
a measure of the disorder or randomness in a system. It states that the entropy of an
isolated system tends to increase over time.
Third Law of Thermodynamics: The third law states that as the temperature approaches
absolute zero (0 Kelvin), the entropy of a pure crystalline substance approaches zero.
Kinetic Theory of Gases: The kinetic theory of gases provides an explanation for the
macroscopic properties of gases based on the behavior of individual gas particles.
Ideal Gas Law: The ideal gas law relates the pressure (P), volume (V), and temperature (T) of
an ideal gas using the equation PV = nRT, where n is the number of moles of the gas and R is
the ideal gas constant.
Kinetic Energy and Temperature: The average kinetic energy of gas particles is directly
proportional to the temperature. It is given by the equation KE = (3/2) kT, where k is the
Boltzmann constant.
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