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Article history: Concrete and plastic are a major source of environmental contamination and unsustainability. This study
Received 11 July 2021 has been employed to come up with the eco-friendly concrete by using the plastic waste to promote the
Revised 26 July 2021 sustainability. Gamma radiations were used to enhance the micro-structure of plastic waste to increase
Accepted 11 August 2021
the mechanical properties of resulting concrete. The crystallinity and chemical properties of regular and
Available online 02 September 2021
irradiated plastic were studied using x-ray diffraction (Xrd) and x-ray fluorescence (Xrf), respectively.
Enhancement in the crystallinity and chemical properties were observed in the irradiated plastic.
Keywords:
Different compositions by weight were opted for replacement of cement and fine aggregate for both reg-
Regular plastic waste
Irradiated plastic waste
ular and irradiated plastic waste with silica fume and superplasticizers. A set of experiments were per-
High density polyethylene formed on concrete and the effect of plastic waste on the compressive strength and split tensile
Split tensile strength strength of concrete was examined. Untreated replacement of plastic waste has shown to decrease the
compressive strength and anomalous behavior was observed in case of split tensile strength. Both the
mechanical properties were enhanced by replacing the cement and fine aggregates with irradiated plastic
waste including silica fume and superplasticizers. This study contributes towards sustainable develop-
ment of green concrete by lowering the carbon emissions and overcoming the fine aggregate scarcity
problem. Moreover, as plastic is ductile and inclusion of plastic in concrete lowers the overall weight
of the structure; impact of an earthquake is reduced.
Ó 2021 THE AUTHORS. Published by Elsevier BV on behalf of Faculty of Engineering, Ain Shams Uni-
versity. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/
by-nc-nd/4.0/).
1. Introduction
https://doi.org/10.1016/j.asej.2021.08.006
2090-4479/Ó 2021 THE AUTHORS. Published by Elsevier BV on behalf of Faculty of Engineering, Ain Shams University.
This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
T. Liu, A. Nafees, S. khan et al. Ain Shams Engineering Journal 13 (2022) 101563
of disorientating change, but like any good thing in excess it can in compressive strength with water-cement ratio of 0.42, for 5%
create more problems than it solves. replacement of polyethylene terephthalate (PET) waste with fine
The construction activities in almost all the developing coun- aggregate. Nibudey et al. [10] employed plastic fibers from mineral
tries increased exponentially. In this century after water concrete water bottles by 1% of volume without any processing and noticed
is the widely used material on planet. Beside undoubted benefits an improvement in compressive strength and tensile strength by
of concrete it has harmful effects on human health too. About 8% 7.35 percent while substituting more than 3% of plastic waste
of the total carbon dioxide emission is due to the manufacturing resulted in a drop in characteristics. Schaefer et al. [11] attempted
of structural concrete and it is one of the leading causes of global to replace the ordinary Portland cement with gamma radiated
warming [1]. 900 kg of carbon dioxide is released to the environ- plastic waste. They examined 3 different samples: one without
ment for manufacturing of every ton of cement [2]. Half of con- radiation and the other two with low dose of 10KGy and high dose
crete’s CO2 emissions is during the manufacture of clinker of 100KGy of gamma radiation. They concluded that by replacing
(produced by heating limestone and clay minerals in a kiln), the 1.25% of cement by weight with IPW at a dose of 100 kGy can
most-energy intensive part of the cement making process. While increase the compressive strength by 1%. Khan et al. [12] studied
manufacturing cement, it must be heated to very high tempera- the effect of IPW as a replacement of ordinary Portland cement
tures to form Clinkers, it is then heated with gypsum at a temper- in the presence of silica fume. It was observed that 10% replace-
ature of 1500◦C to form alite which contributes to the binding ment of irradiated PET with cement reduces the compressive
properties of cement. Some research suggests that alite can be strength by only 3%. Tensile strength was observed to be same as
replaced by some other naturally available minerals with the roast- conventional concrete.
ing temperature less than that of Alite without compromising Recent studies conducted on inclusion of plastic waste with or
other properties of Alite, this will help in the reduction of carbon without processing in the concrete produces an eco-friendly con-
dioxide released hence it promotes sustainability [3]. crete but with the trade of mechanical properties. This study is
Similarly, World produces 381 million tonnes of plastic waste employed to regain the strength loss due to the addition of inert
yearly and this is expected to be double in next 10 years. Only man-made material as a replacement of natural aggregates. Irradi-
9% of this waste has ever been recycled [4]. Most of the plastic ends ation treatment is opted to treat the plastic waste with gamma
up in landfilling, oceans endangering wildlife. Plastic is widely rays of CO-60 to improves its crystalline structure so that it makes
used material due to its durability and inexpensive nature, but a better bonding with aggregates. Silica fume is added to imparts
the excess use of plastic is an alarming situation for the sustain- pozzolanic properties and to contribute towards strength loss.
ability. New techniques of recycling the plastic wastes are adopted Optimum percentage of super plasticizer i.e. 1000 ml/100 kg [13]
nowadays. Recycling one ton of plastic can save 7.4 cubic yards of is also added to keep the resulting concrete workable by keeping
landfill [5]. Recycling is increasing due to improved environmental the water-cement ratio constant. Addition of super plasticizer in
awareness and economic benefits. With rapid industrial growth the concrete will also affect its mechanical properties in a signifi-
and urbanization there has been an uncontrollable increase in cant way.
amount of waste plastics produced every year. This plastic waste
has very adverse impact on environment. To circumvent the pollu-
3. Objectives of research
tion crisis the recycling of plastic waste is carried out nowadays,
but a very small fraction as compared to production can be recy-
After a detailed literature review it was observed that the inclu-
cled rest is landfilled [6]. It takes 1000 of years of decompose, also
sion of virgin/regular plastic waste in the concrete as a replace-
release toxic gases like Sulphur dioxide and carbon dioxide if we
ment of cement or fine aggregate effects its mechanical
attempt to get rid of it by burning [7]. All types of plastic used
properties as a loss in strength, but plastic used in the form of
by humans in daily life eventually becomes waste. Several tons
fibers enhance concrete properties at lower percentages. In this
of these plastic wastes require large areas of land for storage and
study, plastic waste was first treated with the gamma radiation
cannot be fully recycled at once. Only a very small portion is recy-
to improve its structural properties. This study aimed to evaluate
cled. Using plastic waste in the construction industry is an environ-
and compare the mechanical properties of concrete with regular
mental solution to minimize the proportion of landfills used in
plastic waste (RPW) and IPW as a replacement of fine aggregate
waste incineration. Presently, coming up with an approach to uti-
and ordinary Portland cement. One of the major significances of
lize plastic in construction industry will be of great advantage. The
this research is to achieve environmentally friendly concrete. Nat-
major input of construction industry is concrete. The scarcity of
ural aggregate scarcity and the problem of plastic waste landfilling
raw materials used in the manufacturing of concrete is observed
may both be resolved. Plastic is a promising material for use in
over last few years due to the high demand. Hence the use of plas-
some areas of construction that might help us address problems
tic waste in the concrete as a raw material can solve both problems
such as the inability to recycle plastic, satisfying sand demand,
to an extent. Plastic can be grinded to use as a replacement of fine
and lowering CO2 emissions.
aggregate or ordinary Portland cement in concrete to promote sus-
tainable development.
4. Materials used
2. Literature review High density polyethylene (HDPE) plastic waste was sorted out
from a scrap collected from local scrap market. HDPE is commonly
Various studies have been conducted to promote the use of used in the manufacturing of shampoo bottles, mobile oil contain-
plastic waste in the concrete as a replacement of either cement ers and water storage containers. The properties of HDPE are men-
or fine aggregate. Their mechanical properties were evaluated tioned in Table 1. The Waste plastic was treated with gamma-
and found that replacement of plastic waste with different ratios radiations. Prior to treatment it was crushed into flakes of 2 mm-
exhibits different properties. Nenoi et al. [8] reported that the 4 mm. It was grinded using mechanical pulverizer to obtain the
use of irradiated plastic waste (IPW) up to 5% as a replacement particle size distribution suitable for replacement with fine aggre-
of fine aggregate resulted in 23% increase in compressive strength. gate and cement. Sieve analysis was then carried out on powdered
Similarly, Rahmani et al. [9] reported 8.86% increase in compres- waste plastic. The plastic passing through mesh no 200 was
sive strength with water-cement ratio of 0.52 and 11.97% increase replaced with cement having average particle size of 75–100 mm.
2
T. Liu, A. Nafees, S. khan et al. Ain Shams Engineering Journal 13 (2022) 101563
Table 1 Fig. 1 shows the Crystallinity of RPW, while Fig. 2 represents the
Properties of high-density polyethylene. crystallinity of HDPE after treatment. It is clearly observed from
Property Value Units Reference the graphs that the gamma radiation enhanced the microstructure
Compressive yield strength 2900 psi [14] of waste plastic and make it more crystalline resulting in better
Tensile strength 4050 psi [15] mechanical properties. The chemical composition from XRF analy-
impact Strength 247.2 kJ/m2 [15] sis is shown in Table 2.
% Elongation 213.1 % [15]
Elastic modulus (short-term:1 min) 1.0 103 MPa [16]
Service life >50 years – 7. mix proportioning
Thermal conductivity 0.29 kcal/m.hr°C [16]
Materials used in the research were locally available and their
properties are mentioned in above section. Mix design calculations
Retained one was used for replacement with fine aggregate. Type-1 were carried out for concrete with compressive strength of 3000
(Ordinary Portland cement) was as used a binding material under psi by keeping the water-cement ratio of 0.50–0.55 for assuring
specification of ASTM C150/150 M. Fine aggregate occupies 70– the slump value of 3 in.. The concrete mix quantities are in
80% of concrete in both fresh and hardened state. Lawrencepur kg/m3 and their designation are shown in Table 3 and Table 4.
Sand is used in this research having fineness modulus 2.47 deter- Concrete mix proportion of 1:1.86:2.45 by mass was used in the
mined by sieve analysis following ASTM C136, and specific gravity research. Two different types of mix were prepared. In first mix,
of 2.60 evaluated by pycnometer apparatus under ASTM C128. cement was replaced by RPW and IPW with different proportion
Coarse aggregate of fineness modulus of 7.52 and maximum size including 1%, 2%, 3%, 5 %and 7% by weight of cement. In second
aggregate of 19 mm is used in this study following ASTM C33. Sil- mix, fine aggregate was replaced by RPW and IPW following the
ica fume used in the research was purchased from a chemical store same proportions. Concrete cylinders of 6 12in were casted
at Rawalpindi following the standard specification of ASTM C 1240. and tested for 3, 7 and 28 days of curing.
The SiO2 content is 87% and having the specific are of 15 m2/g men-
tioned on the manual. 8. Results and discussion
Gamma radiation treatment of plastic polymers causes chemi- Conventional concrete cylinders with no plastic waste and silica
cal and physical changes in its micro-structure. This technique is fume were casted and tested for 3,7 and 28 days. Their results were
becoming common for the medical products sterilization and foods used as a reference for further study. Table 5 represents the com-
irradiation for the purpose of preservation. Cobolt-60 (Radioactive pressive strength and split tensile strength values for the concrete
isotope) is the most used source of gamma radiation worldwide cylinders without the replacement of plastic waste and silica fume.
[16]. Rays are supplied in the form of electron beam having the Compressive strength of 20.54 MPa and split tensile strength of
energies in the range of 1.173 and 1.332 MeV(Mega Electron Volts) 3.42 MPa were used as standard value for 28 days of curing period.
[17]. The half-life of Co-60 is about 5.27 years [18]. Gamma radia-
tion from a source of radio nuclei of Co-60 was used for the treat- 8.2. Formulation of compressive strength
ment of HDPE. The plastic polymer was treated at a dose rate of
50Gray/min for a total cumulative dose of 100 kGy. The sample 8.2.1. Compressive strength of RPW as replacement of cement
of 60 kg was divided into 4 Bags of 20 kg and wrapped in plastic RPW without any processing was replaced with cement with
bag by machine to make it airtight. The radiations cause the different proportions of 1%, 2%, 3%, 5% and 7%. Mix design quanti-
crosslinking among the chain structure of polymer and enhance ties for replacement of plastic waste with cement in kg/m3 are tab-
the crystallinity of polymer. The effect of radiation was studied ulated in Table 3. Fig. 3 shows the compressive strength value for 3,
by x-ray diffraction. This process of cross linking increase the crys- 7 and 28 days of curing at different percent composition of RPW. At
tallinity of the polymer chain resulting in improved HDPE proper- first, slight decrease in compressive strength was observed but
ties [19]. The resulting HDPE after cross linking has 20 times the after 3% replacement the decreasing trend became sharp. For 1%
environmental stress crack resistance to normal HDPE, and 10 replacement the decrease in strength was observed to be 2.72 %,
times more molecular weight. The impact and tensile strength of for 3% replacement decrease in strength was 2.96% and for 7%
treated HDPE is also increased by 5 times [20] replacement the strength decrease was witnessed to be 9.98%.
Plastic being an inert man-made material does not possess any
6. X-ray diffraction of regular and irradiated plastic waste pozzolanic properties therefore the decreasing trend was detected.
However, some of the strength can be regained by using the opti-
Mechanical behavior of material under different loading condi- mal quantities of super plasticizer and silica fume RPW is preferred
tions can be predicted from its structural information, which can for non-structural use or for the structure with minimum compres-
be explored using X-ray diffraction (XRD) technique. In this study, sive loads. Table 6 shows the experimental values of compressive
XRD analysis was performed on RPW and IPW to observe the strength for different composition at different curing ages.
impact of gamma radiations. Size of the Sample placed in the x
ray diffractometer operating at voltage of 20-40Kev(Kilo Electron 8.2.2. Compressive strength of IPW as replacement of cement
Volt) was 2 mm-4 mm in the form of flakes. Sample placed in Gamma radiated plastic waste was used as a replacement of
the apparatus was exposed to rays having wavelength of 1.5418Å cement to regain the strength loss observed in the replacement
(Angstrom), sample rotated with synchronization such that each with RPW, which was mainly due to reduction in the content of
particle of the material should be subjected to rays. Graph was binding material. The improved crystalline structure due to gamma
plotted between the intensities and rotation angle to check the radiation helps in making bond with aggregates to have better
crystallinity of sample. The degree of crystallinity is directly pro- mechanical properties. Fig. 4 shows the values of compressive
portional to the peak area. Exact value of degree of crystallinity strength evaluated by testing the concrete cylinders with different
can be determined by integrating the areas of all the curves [21]. percentages of IPW at different curing ages using compression test-
3
T. Liu, A. Nafees, S. khan et al. Ain Shams Engineering Journal 13 (2022) 101563
Table 2
Chemical composition of OPC, SF, IPW, RPW.
Chemical Composition (mass % of oxide) CaO SiO2 Al2O3 MgO SO3 TiO2 K2O Fe2O3 Na2O Zn H2O
Binder Type
OPC 65.2% 19.2% 5.2% 3.4% 1.5% – 0.62% 2.4% 0.3% – –
Silica fume 0.25 96% 0.25% 0.56% 0.12% 0.56% 0.5% 0.25% 0.02% 0.6%
Regular Plastic 4.87% 64.3% <0.01% <0.01% 14.76% 5.0% 1.89% 4.12% <0.01% 1.7% –
Irradiated Plastic 5.24% 68.6 % <0.01% <0.01% 13.47% 5.91% 2.02% 3.26% <0.01% 0.71% –
OPC = Ordinary Portland cement, SF = Silica Fume, RPW = Regular plastic waste, IPW = irradiated plastic waste.
Table 3
Mix design quantities in kg/m3 for Replacement of cement with Regular Plastic Waste.
Quantities in kg/m3
Mix ID Replacement Super Plasticizer W/C Ratio Fine Aggregate Coarse Aggregate Water Content Cement content Plastic Waste Silica fume
(ml/kg)
CCP0SF0 0 0 0.50 816 928 202 404 0 0
RPW1SF2 1% 10 0.50 816 928 202 391.88 4.04 8.08
RPW2SF4 2% 10 0.50 816 928 202 379.76 8.08 16.16
RPW3SF6 3% 12 0.50 816 928 202 367.64 12.12 24.24
RPW5SF10 5% 14 0.50 816 928 202 343.3 20.20 40.40
RPW7SF14 7% 15 0.50 816 928 202 319.16 28.28 56.56
4
T. Liu, A. Nafees, S. khan et al. Ain Shams Engineering Journal 13 (2022) 101563
Table 4
Mix design quantities in kg/m3 for Replacement of Fine Aggregate with Regular Plastic Waste.
Quantities in kg/m3
Mix ID Replacement Super Plasticizer (ml/kg) W/C Ratio Fine Aggregate Coarse Aggregate Water Content Cement content Waste Silica fume
RPW0SF0 0% 0 0.55 852.73 928 202 367.27 0 0
RPW1SF2 1% 10 0.55 844.21 928 202 359.93 8.52 7.34
RPW3SF6 3% 12 0.55 827.15 928 202 345.24 25.58 22.03
RPW5SF10 5% 12 0.55 810.10 928 202 330.55 42.63 36.72
RPW7SF14 7% 14 0.55 796.04 928 202 312.86 59.69 51.41
RPW10SF17 10% 14 0.55 767.46 928 202 304.84 85.27 62.43
RPW15SF20 15% 14 0.55 724.83 928 202 293.82 127.90 73.45
Table 5
Compressive strength and split tensile strength of conventional concrete.
Table 6
Compressive strength and split tensile strength for Replacement of cement with Regular Plastic Waste.
Mix ID Slump Value in mm. Compressive strength in N/mm2 Split Tensile strength in N/mm2
3 Days 7 Days 28 Days 3 Days 7 Days 28 days
CCP0SF0 86.36 7.60 13.35 20.54 1.54 2.38 3.42
RPW1SF2 81.53 7.57 13.06 19.98 1.55 2.42 3.46
RPW2SF4 80.26 7.55 13.02 19.95 1.59 2.47 3.52
RPW3SF6 78.49 6.87 12.37 19.93 1.57 2.46 3.46
RPW5SF10 75.69 6.29 11.88 18.93 1.52 2.38 3.41
RPW7SF14 76.32 5.75 11.61 18.49 1.48 2.32 3.29
5
T. Liu, A. Nafees, S. khan et al. Ain Shams Engineering Journal 13 (2022) 101563
Fig. 4. Compressive strength for IPW cement. Fig. 5. Compressive strength for RPW_FA.
Table 7
Compressive strength and split tensile strength for Replacement of cement with Irradiated Plastic Waste.
Mix ID Slump Value in mm. Compressive strength in N/mm2 Split Tensile strength in N/mm2
3 Days 7 Days 28 Days 3 Days 7 Days 28 days
CCP0SF0 86.36 7.60 13.35 20.54 1.54 2.38 3.42
IPW1SF2 76.20 8.24 14.21 21.54 1.73 2.55 3.55
IPW2SF4 76.30 8.55 15.12 21.66 1.84 2.63 3.71
IPW3SF6 78.49 9.04 15.25 22.51 1.99 2.70 3.78
IPW5SF10 72.39 7.94 13.48 20.76 2.15 2.76 3.89
IPW7SF14 68.58 6.87 12.97 19.80 1.55 2.37 3.43
6
T. Liu, A. Nafees, S. khan et al. Ain Shams Engineering Journal 13 (2022) 101563
Table 8
Compressive strength and split tensile strength for Replacement of Fine aggregate with Regular Plastic Waste.
Mix ID Slump Value in mm. Compressive strength in N/mm2 Split Tensile strength in N/mm2
3 Days 7 Days 28 Days 3 Days 7 Days 28 days
CCP0SF0 86.36 7.60 13.35 20.54 1.54 2.38 3.42
RPW1SF2 78.74 8.62 14.63 21.43 1.80 2.66 3.66
RPW3SF6 75.69 8.12 13.88 20.68 1.67 2.45 3.57
RPW5SF10 77.42 7.57 13.71 20.60 1.48 2.47 3.51
RPW7SF14 79.21 6.78 12.58 19.06 1.49 2.25 3.13
RPW10SF17 80.68 6.16 11.81 18.07 1.36 2.17 3.20
RPW15SF20 80.12 4.90 10.71 16.79 1.20 2.05 2.93
7
T. Liu, A. Nafees, S. khan et al. Ain Shams Engineering Journal 13 (2022) 101563
Table 9
Compressive strength and split tensile strength for Replacement of Fine aggregate with Irradiated Plastic Waste.
Mix ID Slump Value in mm. Compressive strength in N/mm2 Split Tensile strength in N/mm2
3 Days 7 Days 28 Days 3 Days 7 Days 28 days
CCP0SF0 86.36 7.60 13.35 20.54 1.54 2.38 3.42
IPW1SF2 78.74 8.02 13.68 21.51 1.82 2.69 3.68
IPW3SF6 75.69 8.28 14.53 21.80 1.88 2.84 3.88
IPW5SF10 77.42 8.89 14.97 22.17 2.00 3.13 4.06
IPW7SF14 79.21 9.11 15.60 23.24 2.15 3.25 4.21
IPW10SF17 80.68 7.76 13.60 19.79 2.24 3.31 4.44
IPW15SF20 80.12 6.76 12.93 19.05 1.68 2.41 3.52
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