Industrial Water Treatment

Advanced Water Solutions

IWT&P General presentation
Italmatch at a glance

A global specialty chemicals company founded in Italy, and active throughout the world

Advanced Flame Lubricant Personal Care, Oil & Gas

Performance Products Retardants Performance
& Specialties Water Solutions Fabric Softeners Solutions
Additives & Plastic Additives

>1,100 19
manufacturing
~€800M
employees sales
plants revenues

20% 6 100 100

Of our products have R&D centers Patents granted with Strong R&D and
been developed in the 30 patent families technical support
last 5 years team
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Italmatch global coverage

19
manufacturing
Sites around
the world

16
Warehouse &
Logistics
Hubs
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Italmatch Advanced Water Solutions

Sudamfos do
Dequest and P-chlorides Brazil and Magpie BWA Water Additives,
from ThermPhos Eco Inhibitors and
Solvay Water Investment in KSA:
2013 Additives & 2017 WST Water Science JV with Biolab,
Desalination Technologies JV with SADIG – Saudiphos
businesses
2019 2020
2015

2016 2020

2018
Compass and Solvay RecoPhos
mining and corrosion Project
2014 Jiayou Chemical from
inhibitors businesses
Ecolab
GRS Chemical Bain Capital acquires 90%
Technologies
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Italmatch Key Capabilities

• Worldwide Footprint:
❖ Production plant in Europe, USA, China, Middle East
❖ Solid Supply Chain
❖ Global Coverage Logistic and Warehouses

• Broad Portfolio:
❖ Leader Manufacturer of Phosphonates and Polymers

• Technical Support:
❖ Multiple R&D Center of Excellence
❖ Technical Consultanting
❖ Tailor Made Products & Solutions

• Top Quality Standards:

❖ European and American Production Standards
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Innovation
Solutions beyond products
We specialize in providing bespoke solutions to
specific problems

We bring new ideas to market

We are a back integrated specialty chemicals
manufacturer with the product knowledge to bring
genuine innovation to our customers

Technical expertise
If you have an unsolved problem, talk to our team of
technical experts
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Sustainability

We have a sustainable business model.

• Water is precious. Our technology helps the

world to manage this finite resource

• A global vision with a local presence which

brings shared values and wellness to our
stakeholders

• Respect for people, the environment and the

local communities of which we are a part

• We are continuously adapting and researching,

delivering a constant flow of new ideas
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Advanced Water Solutions Markets

Fabric &
Home Care

Thermal
Desalination
Geothermal

Reverse
Osmosis

Industrial
Water Industrial &
Treatment & Institutional
Process

Mining
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Industrial Water Treatment & Process

IWT&P

• 40% of AWS Annual Revenues

• 15% = Target Vitality Index
• >160 = Products Portfolio
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Industrial Water Treatment & Process
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Industrial Water Treatment - Portfolio
CORROSION FLOCCULATION &
SCALE CONTROL MICROBIAL CONTROL
INHIBITION COAGULATION
LOW MOLECULAR NON-OXIDISING HIGH MOLECULAR
PHOSPHONATES ORGANIC & P FREE OXIDISING BIOCIDES
WEIGHT POLYMERS BIOCIDES WEIGHT POLYMERS

Dequest®
Mayoquest® Belcor®
Briquest® BromiCide® *
OPEN EVAPORATIVE Belclene®
SYSTEMS Dequest® P
LiquiBrom® **
Bellacide®
Bricorr®

CLOSED COOLING
Belcor®
SYSTEMS

Belsperse®
BOILER FEED WATER
Belclene®
SYSTEMS
Dequest® P

RAW WATER
CLARIFICATION & Qualipol
WASTE WATER Qualifloc
PROCESSES

* Available for Global Market

** Not Available for EU Market
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Cooling system

We offer a range of specific products chemistries

applied as:
• Scale and deposition control agents
• Corrosion inhibitors
• Biocides

Challenges met
o Scale and deposition tendency while increasing cycle of
concentration
o Corrosion on steel and yellow metals
o Microbiological growth

Our portfolio include

✓ LMW Polymers
✓ Phosphonates
✓ Non-oxidizing and oxidizing Biocides
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Cooling System - Portfolio
Product Chemistry Value Proposition

Belclene® 200
Maleic Homopolymer (HPMA) -
Superior CaCO3inhibitor for high stress conditions
Solvent process
Dequest® P9000

Maleic Homopolymer (HPMA) -

Dequest® P9000W Excellent CaCO3inhibitor for low stress conditions
Water process
SCALE Effective CaCO3inhibitor & Zinc stabilizer for low to moderate stress
Belclene® 283 Maleic Terpolymer - Solvent Process
CONTROL conditions

Low Molecular Sulfonated Phosphino Carboxylic Acid Superior iron oxides dispersant agent and effective Ca3(PO4)2 , zinc
Weight Belclene® 400
Polymer (SPCA) stabilizer
Polymers
Superior silica, Ca3(PO4)2 , iron oxides dispersant agent and zinc
Belclene® 497 Sulfonated Carboxylic Terpolymer
stabilizer

Belclene® 499 Sulfonated Phosphono Carboxylic Polymer Excellent zinc stabilizer, Ca3(PO4)2 inhibitor and effective CaCO3 inhibitor

Sulfonated Acrylic Acid Copolymers

Dequest® P9300/P9310 Effective Ca3(PO4)2 inhibitor and zinc stabilizer
(AA/AMPS)

Belclene® 110 Phosphino Carboxylic Acid Polymer (PCA) Effective CaCO3, CaSO4 and scale inhibitor
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Cooling System – Product Selection Guide
Low Molecular Weight Polymers
CaCO3 CaSO4 Ca3(PO4)2 Clay/Silt Iron Oxide
Chemistry Polymer Zinc Stabilization Silica Dispersion
Inhibition Inhibition Inhibition Dispersion Dispersion
Belclene® 200
Dequest® P9000

Maleic Polymers Dequest® P9000W

Belclene® 283

Belclene® 400

Belclene® 497

Acrylic Sulfonate
Belclene® 499
Polymers

Dequest® P9300

Dequest® P9310

Phoshino Acrylic
Belclene® 110
Polymer

Highly recommended Not Recommended

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Cooling System – Product Selection Guide
Scale and Microbial Control

Product Chemistry Value Proposition

Dequest® 2000/2006 * ATMP

SCALE CONTROL Competitive CaCO3 inhibitors
Dequest 2010/2016 * HEDP
Phosphonates
Dequest® 7000 * PBTC High Tolerance CaCO3inhibitor, stable in oxidizing conditions

BromiCide® ** BCDMH Highly effective solid oxidizing biocide, for medium, effective in high pH conditions
MICROBIAL CONTROL

Oxidizing Biocides LiquiBrom® *** NaBr Hypochlorite precursor

Powerful bactericide and fungicide with enhanced additive stability.

Bellacide® 337 *** -
Synergistic with halogens
MICROBIAL CONTROL Bellacide® 355 *** TTPC High performance bactericide and fungicide

Non-oxidizing Biocides
Bellacide® 325 *** TBZ Highly effective algaecide. Synergistic with halogens

Mayosperse 7700 *** WSCP Effective multipurpose biocide

* Most Used - Full range of Phosphonates available

** Available for UE Market
*** Available for US Maket
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Cooling System – Product Selection Guide
Biocides

Compatibility with Compatibility with Performance at

Chemistry Product Algae Bacteria Legionella Biofilm
chemical additives ammonia alkaline pH

BCDMH Bromicide

- Bellacide 337 (NEW)

TTPC Bellacide 355

TBZ Bellacide 325

WSCP Mayosperse 7700

Highly recommended Not Recommended

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Cooling System – Product Selection Guide
Corrosion Control

Product Chemistry Value Proposition

Multifunctional corrosion inhibitor for mild steel and CaCO3 inhibitor, stable under oxidizing
Bricorr® 288 POCA
environment

CORROSION CONTROL
All organic products Belcorr® 575 HPAA Superior all organic corrosion inhibitor for mild steel for open and closed cooling system

Belcor® 593 Subsituted Triazine Highly effective phosphorous free all organic corrosion inhibitor for closed cooling system
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Cooling System – Product Selection Guide
All Organic Corrosion Inhibitors

Corrosion Corrosion
inhibition in high inhibition in non- Phosphorus Open cooling Closed cooling
Chemistry Product CaCO3 inhibition Halogen stability
Oxidising Oxidising content systems systems
conditions conditions

Phosphono
Bricorr 288
carboxylic

Hydroxy-
Belcor 575
phosphonacetic acid

Substituted triazine Belcor 593

Highly recommended Not Recommended

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Boiler system

We offer a range of low molecular weight

polymers applied as dispersants and scale
control agents for internal boiler water
applications
Challenges met

✓ High heat transfer rate and high evaporation rate

✓ Higher cycles of concentration to reduce water
consumption
✓ Sludge dispersant and deposition control to avoid
overheating failures and boiler shut down
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Boiler system - portfolio
Low molecular weight polymers

Product Chemistry Value Proposition

Phosphino Carboxylic Acid Polymer Effective dispersant agents with superior properties respect to polyacrylate,
Belsperse® 161 / 164
(PCA) FDA approved
Low Molecular
Weight
Polymers Belclene® 497 Sulfonated Carboxylic Terpolymer Superior Iron oxides, silica, calcium phosphate, dispersant agent

Sulfonated Acrylic Acid Copolymers

Dequest® P9300 Effective Iron oxides, calcium phosphate dispersant agent
(AA/AMPS)
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Boiler system – Product Selection Guide
Low molecular weight polymers

CaCO3
Chemistry Product Iron Dispersion Silica Control Thermal Stability Sludge Dispersion Phosphate control
Inhibition

Phosphino Carboxylic Acid Belsperse 161/164

Sulfonated Carboxylic
Belclene 497
Terpolymer

Sulfonated Acrylic Acid

Dequest P9300
Copolymer

Highly recommended Not Recommended

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Influent Water systems
Our solutions for Influent Water Systems include
high and medium molecular weight Coagulants.

Our organic coagulants compete against the

traditional inorganic coagulants having:
- higher performance
- lower sludge formation
- broader operating pH range
- no impact on final stream pH

Our products include:

Qualipol EPH medium molecular weight
Coagulants
Qualipol PD, EPH high molecular weight
Coagulants
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Waste Water Systems
Our solutions for Wastewater Systems include high
and medium-weight molecular weight anionic,
cationic and polyacrylamide flocculants

Challenges met:
- Ensuring high performance with affordable costs
- Meeting the broad requirement for cationic,
anionic and neutral species
- Fulfilling the demand for polyacrylamide
flocculants

Our products include

✓Qualifloc AE, anionic flocculants
✓Qualifloc CE, CLC, BC cationic flocculants
✓Qualifloc AF, Polyacrylamide (PAM) free
flocculants
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Coagulant and Flocculants

Qualipol
• Organic Coagulants

Qualifloc AE/CE/BC/CLC<
• Emulsion Flocculants (PAM) – Solvent Based

Qualifloc BD
• Brine Dispersion (PAM) – Water Based

Qualifloc AF
• Emulsion Flocculant Acrylamide free – Solvent Based
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Coagulants products – Qualipol
All Organic Corrosion Inhibitors

Qualifloc AF 100A liquid cationic poly-dadmac product range

• 100 % cationic charge

Qualifloc AF 100 liquid cationic polyamines product range

• 100 % cationic charge
• molecular weight, medium to high
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Flocculant products – Qualifloc
Anionic & Cationic High Molecular Weight Polymers

Qualifloc AE Qualifloc CE
3020 2002 Qualifloc BD
3030
Qualifloc BD
Qualifloc AE Qualifloc AE Qualifloc CE Qualifloc
3090 3030 2080 CE2010 CATIONIC Water
based PAM at
Qualifloc AE Qualifloc CE different charge
ANIONIC CATIONIC density
Emulsion PAM at Emulsion PAM at Qualifloc BD
different charge different charge
density density
01

Qualifloc AE Qualifloc AE Qualifloc CE Qualifloc

3070 3040 2060 CE2030 Qualifloc
BD02

Qualifloc AE Qualifloc CE
3050 2040
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Flocculant products – Qualifloc
Cationic High Molecular Weight – Branched & Cross Linked Structure

Qualifloc BC
Qualifloc 9020
CLC 7020

Qualifloc BC
Qualifloc 9040
CLC 7040 Qualifloc BC
Qualifloc CLC
Cationic
Cationic Branched
Cross linked Emulsion PAM at
Emulsion PAM different charge
at different density
charge density Qualifloc BC
Qualifloc 9060
CLC 7060

Qualifloc BC
Qualifloc 9080
CLC 7080
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Flocculant products – Qualifloc
Acrylamide Free (*) Emulsion Flocculants

Qualifloc AF 100A Anionic Charged – Linear Structure

Qualifloc AF 100 Cationic Charged – Linear Structure

Qualifloc AF 100 BC Cationic Charged – Branched Structure

Qualifloc AF 100 CLC Cationic Charged – Cross Linked Structure

(*) Acrylamide is a toxic substance, classified carcinogenic of category 1B, is an accumulation neurotoxic
substance being a risk for exposed personnel
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Waste Water System – Product Selection Guide

DEWATERING PAPER SLUDGE

AE 3010 – AE 3020 – CE 2010
CE 2020 – CLC 7020 - CLC 7040

DEWATERING DIGESTED SLUDGE GENERAL INDUSTRIAL

CE 2010 – CE 2020 – CE 2040 EFFLUENT
CLC 7020 – CLC 7040 – CLC 7060 AE 3020 – AE 3030 – AE 3040 – AE 3050

DEWATERING MIXED SLUDGE COAL WASHING

CE 2060 – CE 2040 AE 3010 – AE 3030
CLC 7060 – CLC 7040 AE 3040 – AE 3050

DEWATERING SUGAR PROCESSES

BIOLOGICAL SLUDGE AE 3010 – AE 3030
CE 2080 – CE 2060 AE 3040 – AE 3050
CLC 7080 – CLC 7080

CATIONIC NON IONIC ANIONIC

+100% QUALIFLOC POSITIONING -100%
Thank you