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16 x
IstBohr's orbit r0= 0.529 A of hydrogen
1. (b) 9 n2
Change in kinetic energy is (i) n 2, Be3 r r0 r0
Z 4 Z
x 8x
x 2 2 4r
9 9 (ii) n 2, Li 2 r r0 0
Z 3 3 3
For Bohr model of atom 2
The kinetic energy in a state is equal to half 2
(iii) n 2, He2 r r0 2r0
of the potential energy in magnitude. Z 2 2
Potential energy 3 2
(iv) n 3, Li 2 r r0 3r0
= 2 Kinetic energy Z 3 3
8 x 16 x
2
9 9
7. (a)
2 a0
nh h
2. (c) n2= 9 to n1= 6
First line in balmer series means transition 2
from n = 3 to n = 2. Now, 9thorbit of Li2+ has n=2
same energy as third orbit of 'H' atom & 6th n2 22
r a0 a0 2a0
orbit of Li2+ has same energy as second orbit z 2
of 'H' atom. So n = 9 to n = 6 transition in 2 2 r
Li2+ would have same wavelength as first r 2a0
line in balmer series of
H-spectrum.
v
3. (d)486.4 nm 8. (b) 4
1 1 h h
1
RH Z 2 2 2 x.m.v or .m.v
4 4
n1 n2 h h
1 1 1 or m.v
RH 12 2 2 mv 4
2 4 v
or v
1 1
3 4
912 16
0
4864 A 9. (b) 1.6 x 1016
4860.4nm nhc
E
4. (b) -82kJmol-1 1240
5 103 J / s n 1.6 1019 J
Z
2 632.8
We know that En= Elx n 1.6 1016
n
E
Given E2 21 328kJ mol 1 10. (a)5 :9
2 We know that
E2 328
E4 2 kJ mol 1 82kJ mol 1 1 1 1 R
2 4 R
min 4 4
5. (a) 0.55eV
4
1 1 1 5R 5
13.6 13.6 13.6 R min R
En 2
eV ; E2 2 ; E4 2 eV / atom min 4 9 36 max
36 9
n 2 4
5R
E E4 E2 2.55eV
Absorbed energy = work function of metal +
KE 11. (b) 6 x
2.55 = 2 + K.E. for Hydrogen atom, rn n2
K.E. - 0.55 eV r1=x
r3=9x
6. (a) n = 2, Be3+ Now, 2 r3 n
x 1 x 8 x 12 e
h h
n 14 n 8 So for: 2 2
2 11 16 4 a0
[(x -1) (x -8x +12)] should be equal to zero
2
Z 2
P.E 2 13.6 2 eV
n [(x -1) (x2-8x +12)] = 0, solve the equation
2 (x-1)(x2-8x+12)
Z
Potential energy = -2 x 13.6 x X = 1, 2, 6
n i.e.i = 0.5a ,a ,3a ; 0 0 0
2
3 2r
Potential energy = -2 x 13.6 x x
8 a0
forLi ,Z = 3
2+
So minimum 0.5a0
maximum 3a0
13. (d)
16. (c) at the angle of 45° from the x-and y-axis
The maximum probability of finding
electron in the dxy orbital lies at the angle of
45° from the x-and y-axis.
h / mv
6.626 1034 J s
1103 kg
= 6.626 x 10-31m
h2
18. (b)
32 2 ma02
1
K.E.= mv2...(i)
2
nh This is correct graph for Is.
mvr=
2
nh
v …(ii)
2 mr
Putting (ii) and (i)
1 n2 h2 n2 h2
K.E.= m 2 2 2 2 2
2 4 m r 8 r m
Now r = 4a0 (since n = 2 ) and a0= Bohr's
radius
n2 h2 n2 h2 23. (d) A - Li2+, B - He+, C – H
8 16a0 m 128 a0 m
2 2 2 2 Radial nodes for 2s orbital is at distance
Now n = 2 2a0
Z
4h 2
h 2
K .E.
128 ma0 32 ma0
2 2 2 2 2a
For (a) 0 is least Z = 3 for Li2+
Z
2a
6h 4 For (b) 0 is intermediate Z = 2 for He+
Z
19. (a) 2
2a
321 : n= 1,1 = 2,m= 1 For (c) 0 is maximum Z = 1 for H.
Z
h 6h
Angular momentum = 11 1 A - Li ,B - He+, C - H.
2+
2 2
Spherical nodes = 3 -2 - 1 = 0; Angular node
=2
n2
6h 6h 4 rn 0.529A
Sum of all the above = 2 Z
2 2 24. (a)
3 3
r3 for Li 2 0.529
20. (b)2,0 3
Number of radial nodes = (n -1 -l) 1.587A o
For 3s, n = 3,1 = 0 (Number of radial node =
3-0-1 = 2) 25. (c)According to Heisenberg’s uncertainty principle
For2p,
h
n = 2,1 = 1 Number of radial node =2-1-1 = x p
0 4
4 mur
nh
v
nh
1 h 2 2 mr
2 31. (c)
2
2m 4 distance 2 r 4 2mr 2
Time
1 h velocity nh / 2 mr nh
v
2m 2 32. (d) JEE Main 2019
As we know that,
26. (b)Series limit is the last line of the series, i.e. n2
̅ ( ) (where, )
1 1 1 1
v R 2 2 R 2 After putting the values, we get
n1 n 2 n1
R 109677 ̅ ( )
v 2 6854.8
n1 n12
̅
109677
n12 16 Comparing to , we get
6854.8
Thus, n1 4 means Brackett series. and (slope)
A 3 107 m
28. (c)
( )
B 3 104 m
C 3 109 m 34. (c) JEE Main 2019
D 3 109 m
1
E
Thus, increasing order of energy
CDAB
38. (a) JEE Main 2019 46. (c) : d x2 y 2 and d z2 orbitals have electron density
Atomic numbers of N, O, F and Na are 7, 8, 9 along the axes while d xy , d yz and d xz orbitals have
and 11 respectively. Therefore, total number of electron density inbetween the axes.
electrons in each of and are 10
and hence they are isoelectronic. 47. (b): For the two electrons occupying the same
orbital values of n, l and ml are same but ms is
39. (a) JEE Main 2019
H.N. 481 Sector 4 Keshavepura kota Rajasthan : 9099002757 / 9694418782
different, i.e., 1 and‐ 1 .
2 2