A Premier Institute for Engineering & Medical A TEST ID 24140

24140 Chemical Euilibirum with Solution

1. (c) Any change in coefficient is change in power of K

1 1 1
2. (d) K2     5 x 1016
K1 4 x 10 –34 2 x 10–17
3. (c) Reaction must shift in backward direction.

4. (c) k p  k c (RT)n

n  1 – 3 –1
2 2

x2
5. (a) As, n  0, k p  k c 
(1 – x)2
6. (d) Increase in pressure shifts equlibrium towards lesser no.of moles

N2  3H2  2NH3
7. (d)

1 3 O

As, 1 – x = 0.6 x = 0.4

n = 4– 2 x = 3.2
n 1
8. (d) Active mass = 
v 4
2 2
9. (a) k  Ca2   F–   4 Ca2   F– 
       new

2 1 2 1
F–   F –  
 new 4  old 2

10. (a) 

H2  I2  2HI

4.5 4.5 O

4.5–x 4.5–x 2x

ATQ, 2 x = 3 so, x = 1.5

32
k 1
3 x3
11. (b) 
NH4 HS(s)  NH3(g)  H2 S(g)
p p
2 p = 30

p = 15

kp = (15) = 225

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12 (d) Conceptual

13. (b) As, ratio of NO & Br2 is 2 : 1

p 2P p P
No  Br2 
9 9

 2P P  2P
p P—  
NOBr  9 9 3

2
kp 
 2 P   P  4P2 x P x 9
9 9
 
P
2 2 2 81
2 P 3 9 x9 x 4P

kp 1

P 81

A  B C D
14. (d) [D]  2 [A]
t=O a a o o x= 2 a– 2x
2a
t= q a–x a–x x x x
3

2a x 2a
K 3 3 4
a x a
3 3

CO2 
15. (d) 5
CO
CO2  = 5 x 2.5 x 10 –2
= 0.125 m

16. (a) Ratio of volume will be ratio of moles for gases


N2  3H2  Vf 0.64 4
 2NH3  
Vi 0.8 5
0.2 0.6 0
0.2 – x 0.6– 3x 2x
n  0.8 — 2x  0.64

(0.331)2
17. (a) K  2.5
(0.662)2 (0.101
K is

2
SO3 
2.5 
SO2 2 O2 
1
O2    0.4 atm
2.5

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18. (a) K = [A] [B]

[A] = 2 [A]

[A] [B] = [2A] [B’]

1
B'  B
2
19. (b) Pressure & volume have no effect if n = O

kf 2 x 10–4
20. (c) Kq    40
kb 5 x 10–6

21. (c)
1 1
K2  
k1 10

22. (c) When n = O, there is no effect of temperture & pressure

23. (c) 
NH4 Br(s)  NH3(g)  HBr(g)

p p
2 2
p p 1 2
kp  p .p  x  p
NH3 HBr 2 2 4
24. (c) Kq only depend upon temperature

[ ]
25. (d) 0.64 
[A] [B]2

1 10
[B]    1.25
0.64 8

kp 14
kp  1  10  108 atm –1
26. (a) kp
2 106
27. (a) 
CH 3 COOH  C2H5 OH  CH3 COOC2H5  H2 O
t=O 1.2 1.2 O O
t=q 1.2 – x 1.2 – x x x
[Ester] = [H2O] = x = 0.4

0.4 x 0.4 1
K 
0.8 x 0.8 4
28. (d) kp = kc (RT)n
If Dn > O

kp > kc
29. (d) Conceptual

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30. (a) 


AB A B

1–x x x
x = 0.5
0.5 x 0.5 P
kp  x
0.5 1.5
P = 3 x kp
31. (c) 

A  2B  2C

1–x 1–2x
[A] > [B]
D–d
32. (a) 
(2 – 1)d
‘d’ decreases with increase in '  ' .
33. (c) Conceptual
34. (c) 

PCl5  PCl3  Cl2
[PCl3] = [Cl2]
PCl  PPCl  0.25 x 2  0.5
2 3
35. (d) Conceptual

36. (a) Conceptual

37. (a) 

2 NO  N2  O2

x x
4–x 2 2
ATQ, x = 0.4
0.2 x 0.2 1
K 
(3.6)2 (18)2

(0.7)2
38. (c) k  49
(0.1 (0.1)
39. (d) No effect
D
40. (c)  —1
d
If x is zero, D = d
41. (d) 42. (d) 43. (d) 44. (c) 45. (a)

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