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4239-LZ-VD-AC304046420xx
PORT HARCOURT REFINING COMPANY LIMITED SHEET DOC. CLASS: REV.
(PHRC)
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filename: 4239-LZ-VD-AC304046420xx-IS00
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1 INTRODUCTION ........................................................................................................ 4
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1 INTRODUCTION
This document presents the design review report of the existing impressed current cathodic
protection systems for Refurbishment of Port Harcourt Refinery Company (PHRC) Jetty. This
document is the design basis for the refurbishment of the existing impressed current cathodic
protection systems for all piles in the Jetty area shown in Figure 1 below.
The design review is carried out to ascertain that the refurbishment for the existing ICCPS of
the Jetty piles are in accordance with the findings and recommendations of 4239 LZ-VD-
CD30404642015, Report on Integrity Assessment and Installation of the Cathodic Protection
Systems, ISO 15589-2 and Mineral Oils Safety Regulations.
The design basis for the cathodic protection system for all other isolated structures (such as
berthing, mooring dolphins and protective barriers) shall be presented in another report. All
isolated structures shall be cathodically protected using galvanic anodes.
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2.1 Definitions
The following definitions shall be applied to the standard terms used throughout this
document.
COMPANY Port Harcourt Refinery Company.
CONTRACTOR: Tecnimont.
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2.2 Abbreviations
AC Alternating Current
Ag/AgCl Silver/Silver Chloride Reference Electrode
API American Petroleum Institute
ASME American Society of Mechanical Engineers
ASTM American Society for Testing and Materials
BS British Standard
CA Corrosion Allowance
CASHES Community Affairs, Safety, Health, Environment and Security
CFRP Carbon Fiber Reinforced Plastic
CPS Cathodic Protection System
Cu/CuSO4 Copper/Copper Sulphate
DC Direct Current
DED Detailed Engineering Design
GB Groundbed
HDPE High Density Polyethylene
HSCI High Silicon Cast Iron Anodes
ICCPS Impressed Current Cathodic Protection System
ID Inside Diameter
ISO International Organization for Standardization
MMO Mixed Metal Oxide
NACE National Association of Corrosion Engineers
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ND Nominal Diameter
NNPC Nigerian National Petroleum Company Limited
OD Outer Diameter
PHRC Port Harcourt Refinery Company
SCE Saturated Calomel Electrode
SWA Steel Wire Armoured Cable
TP Test Post
TR Transformer Rectifier
WT Wall Thickness
3 REFERENCE DOCUMENTS
Mineral Oil (Safety) Regulations These regulations, in so far as they apply to pipelines, require
1997, as amended. compliance with the IP, API and ASME codes and standards.
Oil Pipelines Act, 1956. CAP. Provides for licenses to be granted for the establishment and
145 (Amended 1965, CAP. 338, maintenance of pipelines incidental and supplementary to
LFN 1990) oilfields and oil mining, and for purposes ancillary to such
pipelines.
Document Title
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All the piles of Port Harcourt Refinery Jetty were cathodically protected using impressed
current cathodic protection systems (ICCPS) designed originally for 10 years performance life
as shown in Table 4-1 below:
51 CP 1 100 A / 20V -
Linkway to Jetty A 102
51 CP 2 100 A / 20V -
49 CP 3 100 A / 20V -
Jetty A 98
49 CP 4 100 A / 20V -
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The piles have outlived the 10 years design life of the original impressed current cathodic
protection systems and some of the CP components such cables are either vandalized or not
found. Hence, the existing ICCPS require refurbishment in order to effectively protect the piles.
5.1 General
For the design review, all piles in the jetty shall be cathodically protected using impressed
current cathodic protection systems. The minimum requirement for the upgraded cathodic
protection system shall be in accordance with ISO 15589-2 and with consideration of the
following:
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The potentials are referenced to an SCE reference electrode, which are equivalent to a
silver/silver chloride reference electrode (Ag/AgCl/seawater) in 30 Ω⋅cm seawater.
However, from the original cathodic protection design, the protection potential criteria were
based on the present pH value of 7.2 at 20" C (referring to sampling), the potential to be
reached in order that the steel would be the site of only metal reduction reaction [ Fe++ (ion) +
2 electrons - Fe (metal)] is -780 mV in relation to the silver chloride half-cell comparison
electrode.
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• Coal tar epoxy (CTEP) on the upper part of the piles up to the lower level of the water
bottom
• Zinc silicate primer (ZNSIL) on the buried part of the piles.
For refurbishment of Port Harcourt Refinery Jetty, all the piles shall be jacketed with a 3mm
CFRP in accordance with this project requirement. The annulus between the CFRP jacket and
the deteriorated pile shall be filled with concrete.
The current density used for the original cathodic protection design for the piles were:
Considering that CFRP coating has a better performance compared to the original coatings on
the piles, the above current density for the respective zones shall be conservatively adopted and
used for this design review.
The design life of the ICCPS for the piles was 10 years based on original CP design, however
for refurbishment of the existing ICCPS, a design life of 20 years shall be used.
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The anode for the impressed cathodic protection system shall be of alloy with satisfactory
performance under similar field conditions. The anode shall be sized such that sufficient
current is delivered to the piles to maintain the required protection potentials throughout the
design life.
Iron Silicon anode of 38.2 kg were used as groundbed anodes in the original design of the
impressed cathodic protection system of the piles. The Iron Silicon anodes with 4.5 %
chromium had 0.2 kg / A-year consumption rate, 30 A/m2 current density and of 10 years basic
life time.
For this design review, the cathodic protection system is expected to optimally operate for 20
years design life. In view of this, Ruthenium oxide (RuO2) MMO anode which performs better
in chlorinated environment like sea water shall be used as the ICCPS groundbed anodes.
MMO anodes have imperceptibly low wear rates and are often referred to as Dimensionally
Stable Anodes as they do not change geometry over time like the graphite and high silicon cast
iron. MMO anode with a current density in the range of 50 to 100 A / m2, has a consumption
rate that is negligible when compared to Iron Silicon anodes and other anodes. MMO anode
has an exceptional long life, light weight and low cost when compared to other anodes.
In view of the above, the selected anode for ICCPS groundbed shall be Ruthenium oxide
(RuO2) MMO Anode tubes with center connection for cables with the following
characteristics:
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The anodes shall be arranged as Anode Sled suitable for sea bottom use. The anode sled shall
be protected using heavy duty, machined fiberglass housing and shall have 120 m length of 1C
x 50 mm2 PDVF (Kynar) / HMWPE anode cable. The MMO anode sled shall be sized to
operate with the existing transformer rectifiers with output rating as shown in Table 4-1 above.
Each of the anode sled shall be built with reinforced concrete end weights to allow for
permanent stay put at the sea bottom for stability and also to minimize the possibility of the
anodes becoming covered with mud or silt as required of section 12.5 of ISO 15589-2:2012.
All the existing transformer rectifiers were subjected to integrity test as provide in 4239 LZ-VD-
CD30404642015, Report on Integrity Assessment and Installation of the Cathodic Protection
Systems.
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The CP junction boxes comprise of positive junction boxes, negative junction boxes and bond
boxes and are being refurbished to be re-installed for used.
The negative junction boxes and bond boxes may be provided with variable resistor for
balancing of the piles potential as required in accordance with design protection criteria.
6.4 CP Cables
Based on original design, the CP cables were as follows:
• Positive cables
The positive cable connects the positive terminal of the transformer rectifier to ground bed
via positive junction box. The cable is DC single core multiple stranded copper cable. Based
on the original CP design, the specification of positive cable was 1 x 50 mm2 PE/PVC
0.3/0.5 kV grade of red colour in accordance with IEC 277.
For refurbishment of the existing ICCPS, the positive cable shall be 1 x 50 mm2 XLPE/PVC
0.6/1.0 kV grade of red colour conforming to ASTM Specification B-8 and ASTM D-1248.
The assumed total length of the positive cable for CP sizing shall be 170 m. This consist of
the cable length from anode sled to positive junction box and the from positive junction box
to transformer rectifier.
The positive cable length from the anode sled to positive junction box shall be installed in an
anti-theft conduit with in fill concrete mix of ratio 1:2:4 as to be detailed in “cathodic
protection installation details-ICCPS.”
• Negative cables
The negative cable connects the negative terminal of the transformer rectifier to negative
junction box. The cable is DC single core multiple stranded copper cable. Based on the
original CP design, the specification of negative cable was 1 x 50 mm2 PE/PVC 0.3/0.5 kV
grade of black colour in accordance with IEC 277.
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For refurbishment of the existing ICCPS, the negative cable shall be 1 x 50 mm2
XLPE/PVC 0.6/1.0 kV grade of black colour conforming to ASTM Specification B-8 and
ASTM D-1248. The assumed total length of the negative cable for CP sizing shall be 100 m.
• Bond cables
The bond cable connects the negative cable of the negative junction box to piles. The cable
is DC single core multiple stranded copper cable. Based on the original CP design, the
specification of bond cable was 1 x 35 mm2 PE/PVC 0.3/0.5 kV grade of green colour in
accordance with IEC 277.
For refurbishment of the existing ICCPS, the bond cable shall be 1 x 35 mm2 XLPE/PVC
0.6/1.0 kV grade of green colour conforming to ASTM Specification B-8 and ASTM D-
1248. The assumed total length of the bond cable for CP sizing shall be 50 m.
• Test cables
The test cable connects piles to test points. The cable is DC single core multiple stranded
copper cable. Based on the original CP design, the specification of test cable was 1 x 16 mm2
PE/PVC 0.3/0.5 kV grade of red colour in accordance with IEC 277.
For refurbishment of the existing ICCPS, the test cable shall be 1 x 16 mm2 XLPE/PVC
0.6/1.0 kV grade of red colour conforming to ASTM Specification B-8 and ASTM D-1248.
The test cable shall be 10 m length maximum.
• Earth cables
The earth cable connects CP equipment to earth. The cable is DC single core multiple
stranded copper cable. Based on the original CP design, the specification of earth cable was
1 x 16 mm2 PE/PVC 0.3/0.5 kV grade of yellow/green colour in accordance with IEC 277.
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For refurbishment of the existing ICCPS, the earth cable shall be 1 x 16 mm2 XLPE/PVC
0.6/1.0 kV grade of yellow/green colour conforming to ASTM Specification B-8 and ASTM
D-1248. The earth cable shall be 10 m length maximum.
• AC cables
The AC cables connects transformer rectifier to AC power source. The cable is AC four
core multiple stranded copper cable. Based on the original CP design, the specification of
AC cable was 4 x 4 mm2 XLPE/SWA/PVC 1.0 kV grade of black colour in accordance
with IEC 502.
− The deteriorated piles are to be jacketed with CFRP in accordance with this project
requirement.
− The piles sea water environment is zoned into tidal, submerged and buried and current
density of 120 mA/m2, 800 mA/m2 and 50 mA/m2 are adopted in line with original CP
design.
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− Mixed Metal Oxide anode with utilization factor of 0.9 is selected in accordance with
Section 8.4 of ISO 15589-2: 2012 for a design life of twenty (20) years. The MMO anodes
shall be arranged as anode sled suitable for sea water use in line with section 7.1 above.
− The piles are steel with specific resistivity assumed to be 18 x 10-6 Ohm.m as applicable in
the industry. The pile steel outer diameter are taken to be 711 mm and 720 mm in line with
section 5.2 above .
−
− Design factor of 1.25 to take care of risk factors such as possible coating gaps during
coating, coating damage during construction, non-uniform current distribution on piles,
based on section 6.1.5 of DNVGL-RP-F103: 2016.
− Based on section 7.2 of ISO 15589-2: 2012, the maximum protection potential for the
piles shall be 1100 mV wrt Ag/AgCl Reference Electrode.
− The adjoining cables for the cathodic protection systems are assumed to have the
parameters and characteristic provided in section 6.4 above.
Breakdown factors shall be applied to calculate the bare metal surface areas of the CFRP
jacketed piles for mean conditions and at the end of the design life respectively.
Mean and final coating breakdown factors shall be calculated in accordance with Equation (1)
and Equation (2) of ISO 15589-2: 2012 as follows:
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where,
𝑆𝐴 = 𝜋 × 𝐷𝑜 × 𝐿 (3)
where,
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where,
ic = is the current density, selected for mean and final conditions (A/m2)
k = Design factor (1.25), based on section 6.1.5 of DNVGL-RP-F103: 2016
𝑡𝑑𝑙
𝑀𝐴 = 𝐼𝑐𝑓 × 𝑄 × (6)
𝑈𝑓
From the total anode mass above, the number of anode required based anode weight is
calculated using:
where,
Also, the required number of anode based on current requirement is calculated using equation 8
below:
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where,
𝑅𝑇 = 𝑅𝑎 + 𝑅𝑐 + 𝑅𝑝 (10)
𝐸𝐷
𝑅𝑒𝑝 = 𝑎𝑏𝑠𝑜𝑙𝑢𝑡𝑒 ( ) (11)
𝐼𝑐𝑚
This is not considering the pile armoring resistance and
newly applied pile jacketing specific resistance.
where,
The resistance of each of the cables is calculated by multiplying the per unit resistance of the
cable with the cable length.
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The single anode groundbed resistance in sea water is calculated in accordance with equation
A.9 of ISO 15589-2: 2012 as shown in equation 12 below:
𝜌 𝐿
𝑅𝑎 = [𝐿𝑛 (4 𝑎⁄𝑟𝑎 ) − 1] (12)
2𝜋𝐿𝑎
𝑉𝑠 = (𝐼𝑐𝑓 × 𝑅𝑇 ) + 𝑉𝑏 (13)
a. Based on the design calculations as shown in Appendix 1, anode sled with one (1)
MMO anode will serve, however considering the piles status, the saliferous
environment and contingency for optimal performance of the system, anode sled with
five (5) MMO anodes connected in parallel is selected for all the groundbeds of the
impressed current cathodic protection system for the Jetty Piles.
b. The existing transformer rectifiers with output rating of 200 A / 10 V dc, 200 A/ 10 V
dc and 100 A / 10 V dc of the respective cathodic protection system meet the
requirement for the DC supply based on the design calculations of Appendix 1. Hence,
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the existing transformer rectifier of each of the ICCPS shall be used as the DC source
for respective system.
c. The MMO anode sled shall have output rating of up to 200 A or 100 A current capacity
as provided in Appendix 1 with performance service life of a minimum of 20 years.
e. The current drain cable shall be connected or attached to the lead and end pile of each
CP section by Pin Brazing with drain cables completely embedded in pile CFRP jacket.
f. The positive cable from the anode sled to positive junction box shall be installed in an
anti-theft conduit with in fill concrete mix of ratio 1:2:4 as shall be detailed in “cathodic
protection installation details-ICCPS”
g. The cathodic protection equipment and materials required for the installation of the
Jetty Piles ICCPS shall be as indicated in “Cathodic Protection MTO – ICCPS”
h. The CP design for the refurbishment of the existing ICCPS are of comparative
advantage to the origin CP design in terms of :
• Cost
The cost for the purchase, installation and handling of CP materials such as
groundbed anodes has been reduced by using five(5) numbers of MMO anodes
(0.35kg) as one unit of anode sled as against the use of up to twenty two (22)
numbers of Iron Silicon anodes(38.2kg) of the original CP design.
• Performance
With this design, five (5) numbers of MMO anodes (0.35kg) per anode sled as
groundbed a design life of 20 years is achieved at very low consumption rate as
against the twenty-two (22) numbers of Iron Silicon anodes(38.2kg) used as
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General comments:
Considerations of mooring piles CP is missing.
Comments on Appendix 1:
Each proposed anode sled is composed by 5 anodes so, the total current capacity of a sled is 5 x 8A = 40A. This is in
contrast with note 3 of appendix 1 that states a sled current capacity of 200A.
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