I N TE RN ATI ON

S TAN
AL D ARD

I N TE RN ATI ON AL OR G AN I ZATI ON FOR S TAN D ARD I ZATI ON M %K~ YH . u O~ H AI I OP r AH H 3 AU M R n0 CTAH ~ AP TM 3 AU M M ~ ORG AN I S ATI ON I N TE RN ATI ON ALE D E N ORM ALI S ATI ON

Gl as s h yd romet ers - Con ven t i o n al val u e for th e t h ermal

cu bi c expan s i on coeffi ci en t ( for u se i n th e preparat i on of

m e as u re me n t t abl es for l i q u i d s)

Arbo m Bt res e n verre - Val eu r cq n ven ti on n el l e po u r l a d i l atabi l i te vo l u mi q u e t h ermi q u e ( ci u ti l i ser l ors d e

I ’ e ’ tabl i ssemen t
d e s tabl es d e m e s u rag ed e s l i q u i d es)

Fi rst ed i ti on - 1 975- 09 - 0 1

UDC 542. 3 : 531 . 754. 3 : 53. 081 . 7 Ref. No. I S0 1 768- 1 9 75 ( E)

Descri ptors : l aboratory g l assware, h yd romet ers, t h e rmal expan si on .

Pri ce bas ed on 2 pag e s

F O R E WO R D

I S0 (the I n t e rn at i o n al Org an i z at i o n f or St an d ard i z at i o n ) i s a wo r l d wi d e f e d e rat i o n

of n at i o n al s t an d ar d s i n s t i t u t es ( I S0 Member Bo d i e s ) . Th e wo r k of d e ve l o p i n g

I n t e rn at i o n al S t an d ar d s is carri e d ou t t h rou g h I S0 Te ch n i cal Co m m i t t e e s . E ve r y

Member Bod y i n t e re s t e d in a s u bj e ct fo r wh i c h a Te ch n i cal Co mmi t t ee h as been set

up h as th e ri g h t to be re p r e s e n t e d on t h at Co m m i t t e e . I n t e rn at i o n al o rg an i z at i o n s ,

g o ve r n m e n t al an d n o n - g o ve r n m e n t al , in l i ai s o n wi t h I SO, al s o t ake part in th e wo rk.

Draf t I n t ern at i o n al S t an d ar d s ad o p t e d by th e Te ch n i cal Co m m i t t e e s ar e ci rcu l at e d

to th e Member Bod i es fo r ap p ro val b e f o re t h ei r ac ce p t an c e as I n t e rn at i o n al

St an d ar d s by th e I S0 Co u n ci l .

Pri o r to 1 972, th e res u l t s of th e wo r k of th e Te ch n i cal Co m m i t t e e s we r e pu bl i s h ed

as I S0 Re c o m m e n d at i o n s ; th ese d o cu m en t s are now in th e proces s of bei n g

t ran s f o r m e d i nto I n t ern at i o n al S t an d ar d s . As part of th i s pr o ce s s , Te ch n i cal

Co m m i t t e e l S O/TC 48 h as re vi e we d I S0 R e c o m m e n d at i o n R 1 768 an d fou n d it

t e ch n i cal l y s u i t abl e for t ran s f o rm at i o n . I n t ern at i o n al S t an d ar d I S0 1 768 t h e re f o re

re p l ace s I S0 Re co m m e n d at i o n R 1 768- 1 970 to wh i ch it i s t ech n i cal l y i d en t i cal .

I S0 Re co m m e n d at i o n R 1 768 wa s ap p r o ve d by th e Member Bod i es of th e

fo l l o wi n g co u n t ri e s :

Au s t ri a I ndi a Sou th Afri ca, Re p . of

Bel g i u m I ran S p ai n

Can ad a I re l an d Th ai l an d

Co l o m b i a I s rael Tu r ke y

Cz e ch o s l o vaki a I t al y U n i ted Ki n g d o m

E g yp t , Ar ab Re p. of N e t h e r l an d s U . S. A.

Fr an ce ’ New Ze al an d Yu g o s l avi a

G e rm an y Peru

Greece P o l an d

No Member Bo d y expres s ed d i s ap pro val of th e Re c o m m e n d at i o n .

No Member Bod y d i s ap p ro ve d th e t ran s f o rmat i o n of I S O/R 1 768 i n to an

I n t ern at i o n al S t an d ar d .

0 I n t e rn at i o n al Org an i z at i o n for St an d ard i z at i o n , 1 975 l

Pri n t e d in Swi t z e rl an d
I N TERN ATI ON AL STAN D ARD I S0 1 768- 1 975 ( E)

Gl as s h yd rometers - Con ven ti on al val u e for th e th ermal

cu bi c expan si on coeffi ci en t (for u se in th e preparati on of

measu remen t tabl es for l i qu i ds)

1 SCOP E AN D FI ELD OF APPLI CATI ON coeffi ci en t of th e h vd rometers u s ed di ffers from

0, 000 025/“C

Th i s I n tern ati on al Stan d ard speci fi es, for u se in th e

preparati on of measu remen t tabl es for l i qu i ds, a

con ven t i on al val u e for th e th ermal cu bi c expan si on

5 U SE OF TH E TABLES IN ASSOCI ATI ON WI TH
coeffi ci en t of g l ass h yd rometers. It st ates h ow th e
H YD ROM E TE RS H AVI N G A TH E RM AL CU BI C
i n d i cati on s of h yd romet ers h avi n g . a. ‘ th ermal cu bi c
EXP AN SI ON COEFFI CI EN T DI FFEREN T FROM
expan si on coeffi ci en t d i fferi n g from th e reco mmen d ed
0, 000 02 5/k
con ven t i on al val u e may be corrected for u se in con n ecti on

wi t h measu remen t tabl es- i n th e con st ru cti on of wh i ch th e

5. 1 Gen eral
con ven t i on al val u e h as been u sed .

Th e rel ati on sh i p bet ween

a) th e i n di cati on ( R) at 0 “C of a h yd romet er of wh i ch

2 APPLI CABI LI TY OF COEFFI CI EN T th e stan d ard temperatu re is t “C an d the th ermal expan -

si on i s eq u al to th e con ven ti on al val u e 0, 000 0 2 5PC, an d

Measu remen t tabl es for l i qu i ds provi d e mean s for d eri vi n g ,

from th e i n d i cati on s of d en si ty an d /or rel ati ve d en si ty b) th e i n d i cati on ( I ?‘ ) at 6 “C of a h yd rometer h avi n g

h yd romet ers at vari ou s temperat u res, th e correspon d i n g th e th ermal expan si on y/OC, bu t oth erwi se si mi l ar,

val u e of th e d en si ty an d /or rel ati ve d en si t y wi th respect to

i s g i ven by
wat er of the l i qu i d at a referen ce temperatu re. In pri n ci pl e

su ch meas u remen t tabl es mu st t ake acco u n t of the th ermal

R= R ’ [1 +( 0, 000025- $( 8- t) ]

expan si on of th e h yd romet ers . Si n ce h yd romet ers are mad e

Con seq u en t l y, before u si n g measu remen t tabl es in th e

of vari ou s g l asses, th ei r expan si on coeffi ci en ts di ffer.

con stru cti on of wh i ch the coeffi ci en t 0 , 000 0 2 5pC h as

Con seq u en t l y, it is d esi rabl e to u se a si n g l e, con ven t i on al

been u sed , the h yd romet er i n d i cati on R’ at 0 “C sh al l be

th ermal cu bi c expan si on coeffi ci en t in th e con st ru cti on of

mod i fi ed to
meas u remen t tabl es an d to associ ate wi t h th e tabl es

i n formati on on h ow to ad j u st appropri atel y to the tabl es

R’ [ 1 + ( 0, 000 0 25 - y) (0 - t) ]
th e i n di cati on of a h yd rometer h avi n g an y oth er th ermal

cu bi c expan si on coeffi ci en t. It is apparen t th at R’ may be mod i fi ed ei th er by

mu l ti pl yi n g it by

1 + ( 0, 000 0 25 - 7) (0 - t)

3 CON VE N TI ON AL VALU E OF COEFFI CI EN T

or by ad d i n g to it

It is reco mmen d ed th at wh en prepari n g meas u remen t tabl es

R’ ( 0, 000 02 5 - y) (0 - t)

for l i qu i d s th e th ermal cu bi c expan si on coeffi ci en t of g l ass

h yd romet ers sh ou l d be taken to be 0, 000 025/“C.

5. 2 Appl i cabi l i ty to d en si ty h yd romet ers

As su mi n g th at t ‘C is 20 ° C, th e preferred stan d ard

t emperatu re of d en si ty h yd romet ers compl yi n g wi th

4 I N DI CATI ON OF COEFFI CI EN T U SED

I SO/R 649, Den si t y h yd romet ers for g en eral pu rposes , R’

may be mod i fi ed ei th er by mu l ti pl yi n g it by
4. 1 Th e th ermal cu bi c expan s i on coeffi ci en t of the

h yd rometers, n amel y 0, 000 025/“C, u s ed in the

1 + ( 0, 000 025 - 7) (6 - 20)

con st ru cti on of measu remen t tabl es for l i qu i ds sh al l be

stat ed in th e tabl es. or by ad d i n g to it

R’ ( 0, 000 0 25 - y) (0 - 20)

4. 2 It sh al l be i n d i cated in th e meas u remen t tabl es th at

h yd rometer read i n g s may h ave to be mod i fi ed preparatory If t “C is 1 5 “C or 27 ‘ C, the oth er reco mmen d ed stan d ard

to u si n g th e tabl es if th e th ermal cu bi c expan si on t emperatu res, t h ese val u es sh al l be su bsti tu ted for 20 “C.

1
I SO1 768- 1 975 ( E)

TABLE 1 It fol l ows th at R’ may be mod i fi ed ei th er by mu l ti pl yi n g it

by
Val u es of R’ ( 0, 000 025 -7) (0 - t) wh en (0 - rl = 1

Un i t : 0, 001 g /ml

1 + ( 0, 000 025- y) : (8 - 60)

Val u e of (0, 000 025 -7)

R’ or by ad d i n g to it

0, 000 01 0 0, 000 01 5 0, 000 020

R' ( 0, 000 025- y) $9 - 60)

‘ 3. 6 0, 006 0, 009 0, 01 2

0. 7 0, 007 0, 01 05 0, 01 4

TABLE 2
0. 6 0, 008 0, 01 2 0, 01 6

0. 9 0, 009 0, 01 35 0, 01 8 Val u es of R’ (0, 000 025 - y) 5 (0 - 60) wh e n

1 .0 0, 01 0 0, 01 5 0, 020
(8 - 60) = 1 an d 0 is expressed in deg rees Fah ren h ei t

1 .1 0, 01 1 0, 01 65 0, 022
Un i t : 0, 001 rel ati ve d en si ty

1 .2 0, 01 2 0, 01 8 0, 024

Val u e of ( 0, 000 025 - 7)

R’

5. 3 Appl i cabi l i ty to rel ati ve d en si ty 60/60 “F h yd romet ers 0, 000 01 0 0, 000 01 5 0, 000 020

Wh e n rel ati ve d en si ty 60/6O”F h yd romet ers are u sed , it is

0. 6 0. 0033 0. 0050 0, 0067

u su al to express the temperat u re of th e l i qu i d in d eg rees

0. 7 0, 0039 0. 0058 0. 0078

Fah ren h ei t. Th e mod i fi cati on formu l a q u oted in 5. 1 th en

‘ 33 0. 0044 0. 0067 0, 0089

beco mes

03 0. 0050 0. 0075 0, 01 00

R' [l + ( 0, 000 025- y) ; (0 - 601 1 1 .0 0, 0056 0. 0083 0, Ol l l

1 .1 0. 0061 0, 0092 0. 01 22

wh ere ti OF is th e temperatu re of th e l i qu i d an d y sti l l

1 .2 0, 0067 0. 01 00 0. 01 33

represen ts th e expan s i o n per d eg ree Cel si u s.