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Molybdenum and Stainless Steel -

about Mines and Markets


Dr. Hans Imgrund

Prospects for the development of the Russian


stainless steel market

Chelyabinsk, 22nd March, 2007


International Molybdenum Association
Rue Père Eudore Devroye 245 · 1150 Brussels · Belgium
Tel: +32 2 770 8878 · Fax: +32 2 770 8898
E-mail: info@imoa.info · www.imoa.info
Molybdenum

• Properties and uses


• Sources
• Market observations

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Molybdenum

• Properties and uses

3
First Use of Molybdenum
6%
Stainless Steel
14% 25% Constructional Steel
Tool & High Speed Steel
Cast Iron
Superalloys
5%
Chemicals
Mo metal
6%

9%

35%

Total 2006: approx. 425 million lb – 190,000 t


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Source: IMOA Estimates
Molybdenum Metal & Alloys
Properties

High melting point – 2610°C

Courtesy of Plansee
• High hot strength
• High wear resistance
• Good corrosion resistance

High temperature vacuum furnace


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Molybdenum Metal & Alloys
Uses

• Glass melting electrodes


• High temperature furnaces

Courtesy of Plansee
• Halogen lamps – sealing and
supporting wire
• Electronic industry – high power
semi conductor parts
• Mo spray wire and sputtering
targets for coating applications
• Metal and plastic forming TZM piercing plug for
6 rolling stainless steel tubes
Molybdenum in Alloy Steels

Molybdenum is almost always used in combination


with other metals including

• Chromium
• Nickel
• Vanadium
• Tungsten
• Niobium

moly grade steels are usually required for high


end applications
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Effects of Molybdenum
In tool steels (average Mo 0.8%)
and in high speed steels
(average Mo content 5%):

• moly enhances hardenability


• contributes to secondary
hardening

Courtesy of Boehler Uddeholm


• is an important constituent
of the primary M6C-carbide
(hardness > 2000 HV),
which confers wear resistance
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Effects of Molybdenum
in constructional steels &
high strength low alloy steels-HSLA
(Mo content 0.1- 1.2%)
moly enhances

• hardenability
• strength and toughness
• weldability
• elevated temperature strength
• resistance to sulfide stress cracking
9 Orbis photo
Oil rigg with drill pipe
Uses of moly grade constructional steels/HSLA
Applications cover the whole energy chain from raw meterial
production through end use:

•Quenched & tempered (Q&t) CrMo seamless oil contry tubular


goods.

•HSLA pipelines for Oil and Gas

•High temperature CrMo and CrMoV grades for petrochemical


processing and energy generation.

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•Q & t CrMo engineering steels in automotive, shipbuilding,
aerospace
Uses of moly grade constructional steels

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Energy generation Oil & Gas transportation
Uses of moly grade constructional steels

Courtesy of Plansee
Gears made of CrMo carburising for everything that moves
steel…

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Effects of Molybdenum

in stainless steels
(average Mo content approx.
2.2%)

• moly improves corrosion


resistance

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Use of moly grade stainless steels
• About 10 % of world stainless steel production is
molybdenum grade with average 2.2% Mo

• Moly grade stainless steels are invaluable in


• industrial processing such as

• chemical, petrochemical,
• pulp and paper
• oil and gas,
• power generation

Corbis photo
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Petrochemical Processing
Use of moly grade
stainless steels

© Ulrich Otte (Stadt Düsseldorf), Germany


Stainless steel has
become the material of
choice for many
architectural uses
around the world

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Zollhof, Düsseldorf
Use of stainless steel - grade selection
is critical.

Nobody likes
stainless steel which
is rusting.

Moly-grade stainless
steels are resistant to
de-icing salt or
coastal air attack.

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Use of moly grade stainless steel

AISI 316 stainless steel


with 2,2 % Mo has
replaced aluminum at
Brussels Atomium.

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Molybdenum

• Sources

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Global Production - Geographically
7%
19% Southamerica
Northamerica
China
CIS & Mongolia

38%

36%

Total 2006: 425 million lb – 192,000 t


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Source: IMOA; Adams Metals


Global Production – Mine Types
By-product West
24%
Primary West
China & CIS

60%
16%

Total 2006: 425 million lb – 190,000 t


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Source: IMOA ; Adams Metals


Molybdenum from Primary Mining

Calculation example:

• Ore grade 0.2% Mo yielding 1.8 kg/t Mo in concentrate


• Producing 1 t of Mo ctd requires 550 t of ore

• Annual production of 10,000 t Mo contd. in MoS2 concentrate


requires mining and milling
5.5 million t of ore (approx. 20,000 t per day)

The initial investment for a primary mine usually requires


several hundred million US Dollars.
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Molybdenum from Primary Mining

Courtesy of Climax Molybdenum


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Henderson operational schematic
Molybdenum By-product from Copper Mining

Courtesy of Kennecott Utah Mine Corp.


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Molybdenum By-product from Copper Mining
• Copper mines producing molybdenum as byproduct usually have
ore grades falling between 0.5% and 1.5% Cu (5 to 15 kg/t) and
between 0.01% and 0,05% Mo (0.1 to 0.5 kg/t).

• Major operations mine more than 50 million tons of ore per year,
producing in excess of 200,000 t of copper and between 5,000
and 15,000 t Mo contained in MoS2 concentrate as by-product.

• The revenues from molybdenum are usually less than 10% of


total sales.

• Consequently the moly output of these mines follows the copper


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market rather than the demand for molybdenum.
Molybdenum supply structure

450
CIS-Mongolia By-product and Chinese
400 China production increases
350 Western By-Product
MM lbs. Molybdenum

significantly
Western Primary
300
250
200
150
Climax mine
100
started: 1918
50

25
0
1920 1930 1940 1950 1960 1970 1980 1990 2000 2005
Source: Climax Molybdenum, presented at Ryans’s Notes Conference 2005
Molybdenum

• Market Observations

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Global Molybdenum Use
450

400

350
MM lbs Molybdenum

300

250 AGR 2000 – 2005:


200 6.0 %
AGR 1990 – 2005
150 3.5%
100

50

0
1990 1992 1994 1996 1998 2000 2002 2004 2006
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Source: IMOA; Adams Metals


Molybdenum Price Driven by Energy-
and by China Demand
$35

$30

$25

$20

$15
$/lb Mo
$10

$5

$0
1970 1975 1980 1985 1990 1995 2000 2005
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Source: Metals Week Dealer Oxide Price
Molybdenum Price and Price of Crude Oil
1970 through 2005
$40

$/Barrel Crude Oil


$30

$/lb Mo
$20

$10

$0
1970 1975 1980 1985 1990 1995 2000 2005
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Source: Metals Week Dealer Oxide Price; Oilenergy.com
By-product and China-Production Increased
Significantly Since 1990
350
China
310
Production (Million lb Mo)

300 By-product
252
250

200

150

100

50

0
1990 1992 1994 1996 1998 2000 2002 2004
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Source: IMOA
Moly Price Was Below $ 4.00/lb in 10 of
the Last 15 Years
$20

$16 $/lb Mo
US $/lb Mo

$12

$8

$4

$0
1990 1992 1994 1996 1998 2000 2002 2004
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Source: Metals Week Dealer Oxide Price
Molybdenum Price and Western
Primary Production
$20 100
90
$16 80
70
US $/lb Mo

Production
Million lb Mo
$12 60
50
$8 40
30
$4 20
10
$0 0
1990 1992 1994 1996 1998 2000 2002 2004 2006

6 mines 2 mines 4 mines


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Source: IMOA; Metals Week Dealer Oxide Price


Molybdenum Market: Demand and Price

$20 450
399

Consumption (Million lb)


375 400
$16
340 350
310 310 310
$12 294 297
US $/lb

276 280 285 300


252 260
240 234 250
$8 228

200
$4
150

$0 100
1990 1992 1994 1996 1998 2000 2002 2004
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Source: IMOA; Metals Week Dealer Oxide Price
Molybdenum Market: Demand Change and Price

$20
55

$16 45

Demand Change
Million lb Mo
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US $/lb Mo

$12
25

$8 15

5
$4
-5

$0 -15
1990 1992 1994 1996 1998 2000 2002 2004 2006
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Source: IMOA; Metals Week Dealer Oxide Price
New Primary Molybdenum Mine Projects

Mine Expected Annual Status Production Start


Capacity Indicated
(Million lb Mo)
Roca Mines - Max Moly Canada 2.5 Under construction ???
Bluepearl Davidson Canada 5 to 10 Feasibility study end 2007
PD Climax mine USA 20 to 30 Conditionally approved 2009
Mt. Hope Nevada USA 35 Currently being permitted 2009
Adanac - Ruby Creek Canada 10 Feasibility study 2009

A comprehensive list of new molybdenum projects, including a number of


by-product expansions, can be found under www.infomine.com
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Source: Company Reports
Estimated Western Roaster Utilization Rates
Western Roasters: Utilization of Available Time
120

100
100
94
% Utilization

80
77
60

40

20

0
2003 2004 2005
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Source: Climax Molybdenum, presented at Ryans’s Notes Conference 2005
Projection of Western Roasting Capacities

450 Europe
400 Northamerica
350
Southamerica
Million lb Mo/Year

300
250
200
150
100
50
0
2006 2007 2008 2009 2010
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Source: IMOA, Company Reports
Global Molybdenum Reserve Base
8%
Southamerica
Northamerica
China
16%
CIS & Mongolia
43%

33%

Total 19 million metric tons Mo ctd. – worth 100 years of present use
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Source: US Geological Survey 2006
World Stainless Production & Molybdenum
Use
450 30.000

400
25.000
350

M tons Stainless Steel


MM lbs Molybdenum

300 20.000

250
15.000
200

150 10.000

100
5.000
50

0 0
39 1990 1995 2000 2005
Source: IMOA; Adams Metals
Everything that glitters is stainless –
and moly is happy to be part of it.

Courtesy of Outokumpu
Thank you

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