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8) The conductivity of 103 M Na2 SO4
conductivity of pure water is 5.7 10 m ,
solution is 2.6 104 S cm1 and increases to
determine K w (ionic product) of water.
7.0 104 S cm1 when the solution is
saturated with CaSO4. Given m Na and
(density of H2O = 1 g/mL) 0
3) At 298 K, 0eq of propanoic acid is
1
0m Ca 2 are 50 and 120 S cm2 mol 1 .
386.6 S cm eq . If its ionization constant
2
Calculate
(Ka) is 1.4 105 . Calculate eq of 0.05 N a) of only CaSO4 in the solution
propanoic acid at 298K. b) Solubility of CaSO4.
4) The conductivity of H2O in a big irregular- c) Ksp of CaSO4.
shaped vessel contained water whos 9) 0m Ag and 0m CrO42 are 61.9
conductivity is 2.0 105 S cm1 . 585 g of 104 S m2 mol 1 and 120
NaCl was then added to the water and the
conductivity after the addition of NaCl is 104 S m2 mol 1 , respectively.
3.0 105 S cm1 . Find the capacity of the Assuming that m differs very slightly
vessel if its fulfilled with water. Given
from 0m . Calculate the solubility of
NaCl 150 .0 S cm mol .
0 2 1
5) 0
AgNO 3 , HCl and HNO3
0 0
are a, b
Ag 2CrO4 = 4.32 104 S m1mol 1 and
m m m
2 -1
and c S-cm -mol , respectively. If the
conductivity of saturated AgCl solution is pure water 0.86 104 S m1 mol 1 at
z S cm 1 . Calcualte the Ksp of AgCl. 300 K.
6) The conductivity of 0.1 M KOH solution is 10) Molar conductivity of aqueous solution of
1
0.022 S cm . When an equal volume of HA is 200 cm2 mol-1, pH of this solution is
0.1M HCl is added , the conductivity 4. Calculate the value of pKa (HA) at
decreases to 0.005 S cm . A further
1 250C. Given m NaA =100 S cm2 mol 1 ,
addition of HCl solution, the volume of which m HCl =425 S cm2 mol 1 , m NaCl
is equal to that of the first portion added, the
=125 S cm2 mol 1 .
conductivity increases to 0.017 S cm 1 .
Calculate
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