Volumetric Calculations 161

(c) bromothymol blue (6 to 75) (d) phenolphthalein (8 to 96)

NB Figures in the brackets show the pH range of the indicator. (IIT 1985)
30. In a compound AxBy ,
(a) moles of A = moles of B = moles of AxBy
(b) eq. of A = eq. of B = eq. of AxBy
(c) y  moles of A = y  moles of B = (x + y)  moles of AxBy
(d) y  moles of A = y  moles of B

31. The volume strength of 15 N H2O2 solution is

(a) 48 (b) 84 (c) 30 (d) 80
32. The number of moles of KMnO4 that will be needed to react completely with one
mole of ferrous oxalate in acidic solution is
(a) 3/5 (b) 2/5 (c) 4/5 (d) 1 (IIT 1997)
33. The number of moles of KMnO4 that will be needed to react with one mole of
sulphite ions in acidic solution is
(a) 2/5 (b) 3/5 (c) 4/5 (d) 1 (IIT 1997)
34. Which of the following reactions is not a disproportionation reaction?
(a) 2NO2  H2O  HNO3  HNO2
(b) Cl2  H2O  HCl  HClO
(c) 3K2MnO4  2H2O  2KMnO4  MnO2  4KOH
(d) 2FeSO4  2H2O  Fe2OH2SO4  H2SO4

35. Dissolving 120 g urea (mol. wt. = 60) in 1000 g of water gives a solution of density
1.15 g/mL. The molarity of the solution is
(a) 1.78 M (b) 2.00 M (c) 2.05 M (d) 2.22 M (IIT 2011)
[Hint : Volume of solution = mass of solution  density]

36. The molarity of a solution obtained by mixing 750 mL of 0.5 M HCl with 250 mL
of 2 M HCl will be
(a) 0.875 M (b) 1.00 M
(c) 1.75 M (d) 0.0975 M (IIT 2013 Main)
37. 3 g of activated charcoal was added to 50 mL of acetic acid solution (0.06 N) in a
flask. After an hour it was filtered and the strength of the filtrate was found to
be 0.042 N. The amount of acetic acid adsorbed (per gram of charcoal) is
(a) 18 mg (b) 36 mg
(c) 42 mg (d) 54 mg (IIT 2015 Main)
[Hint: m.e. of CH3COOH adsorbed = 50(0.06 – 0.042)]

Answers
1-a, 2-a, 3-c, 4-b, 5-b, 6-c, 7-b, 8-d, 9-b, 10-b, 11-b, 12-c, 13-a, 14-d, 15-b, 16-c, 17-c,
18-d, 19-b, 20-c, 21-b, 22-d, 23-a, 24-b, 25-a, 26-d, 27-b, 28-d, 29-d, 30-b, 31-b, 32-a,
33-a, 34-d, 35-c, 36-a, 37-a.