PEA Association Pvt. Ltd.

Thapathali, Kathmandu, Tel: 5345730,

45730, 5357187
2080-3-16 Hints & Solution
Section - I 9
or, ∆F = ∆C
2Tcosθ 5
1.(c) h= 9
rρg
or, ∆F = × 25
If θ = 90°, then h = 0 5
1 or, ∆F = 45°F
2.(b) Energy density = × stress × strain 13.(b) V ∝ R3 ∝ A (‡ R ∝ A1/3)
2
1 VH 1
= × Y × (strain)2 ∴ =
2 VAl 27
1 14.(a) Liquid is heated from top to bottom by conduction.
= Y (‡ strain = 1)
2 15.(b)
3.(c) a = ω2r 1
16.(b) I ∝ A2 ∝
or, a = ω × ωr r2
or, a = ωv 1
⇒ A∝
r
ω
Now, a' = × 2v = ωv = a A' r
2 ∴ =
A 2r
4.(a)
1 2 A
5.(b) h = ut – gt or, A' =
2 2

or, 0 = ut –
1 2
2
gt 17.(a) (II )
β = 10 log10
0
–9
24 10
= 10 log (
or, t=
g 1010 ) –12

2 × 10 = 10 log10 (103)
or, t =
10 = 10 × 3
or, t = 2 sec = 30 dB
6.(c) I+2=5+5 18.(c) Order of electronegativity: O > N > Br > S
or, I = 8A z2
19.(b) E = –13.6 2 ev/atom
7.(b) θi = 2θn – θc n
= 2 × 320 – 10 On increasing value of n, E increases but energy
= 630°C difference between successive energy levels decreases.
1 20.(d) a. K+CN-
8.(d) P ∝ for parallel
R b. NH4+Cl–
P20 10 c. PCl6– PCl4+
∴ =
P10 20 d. H–O–O–H
1 21.(c) In condensation, freezing ing and crystallization, entropy
or, P20 = P10
2 decreases while vaporization is endothermic and
P entropy is increases hence it is entropy driven.
or, P20 =
2 22.(c) (c)) is not redox reaction CaCO3 → CaO + CO2
9.(b) The slope of Q – V graph represents the capacitance. 23.(c) Neo-hexyl
hexyl chloride is the primary halide. Because in it
q e Cl atom is attached to a primary carbon atom. It is can

10.(a)
()m electron me
=
be seen in its structure.
q e
() m proton mp
mp
=
me
1836 me
= (‡ mp = 1836 me)
me
= 1836 : 1
11.(a) PN diode is reverse biased.
24.(d) Electron donating group decreases the strength of acid,
C F – 32
12.(c) = and electron withdrawing group increases the acidity.
5 9
25.(b)
1 1
∴ ∆C = ∆F 26.(c) Thermite is a mixture of one metal oxide and another
5 9
metal powder. Usually aluminium is used as metal that
reduces the metal oxide e.g. iron thermite (Fe2O3 +Al)

1
 PEA Association Pvt. Ltd. Thapathali, Kathmandu, Tel: 5345730, 5357187
2080-3-16 Hints & Solution
π π
27.(a) Hydrofluoric acid, HF(aq), cannot be stored in glass
45.(a) Required area = I sinxdx = [–cosx]
bottles because compounds called silicates in the glass 0 0
are attacked by the HF(aq) (itching of glass). = –cosπ – (–cos0) = 1 + 1 = 2
28.(b) White phosphorus is the highly reactive allotrope of π π π
sin–1sin = sin–1sinπ –  = sin–1sin =
3π
46.(c)
phosphorus. 4  4 4 4
29.(d) A⊆B, B⊆C implies A⊆C. 2 2 dy x
47.(c) Curve is x + y = 36, = – . For tangent
dx y
Then C'⊆A'. So that A'∩C' = C'
1 dx
perpendicular to x-axis, we have =0
30.(a) Here sin7x cosx is odd. So I sin7x cosxdx = 0 dy
–1
i.e. y = 0 So, we get x = ±6.
3π Required point = (±6, 0)
lim lim lim 3sin
secx cos3x –3sin3x 2
31.(d) π = π = π = 48.(d) Distance of point (3, 4, 5) from y-axis = 32 + 52
x → sec3x x → cosx x → –sinx π
2 2 2 sin = 9 + 25 = 34 units
2
3–1 49.(c) 50.(b) 51.(b) 52.(d) 53.(c) 54.(d)
= = –3 55.(b) 56.(b) 57.(a) 58.(c) 59.(a) 60.(d)
1
32.(c) log xx = 2log x x = 2 Section – II
∆L
So its derivative is zero. 61.(a) τ=
∆t
–1 + 3i 4L0 – L0
33.(d) –1 + –3 = × 2 = 2ω =
2 4
So (–1 – –3)18 = (2ω)6 = 26 = 64 3
= L0
4
34.(c) Here coeff. of x2 = constant term. So roots are reciprocal
62.(b) ∆U = U2 – U1
1
to each other. Other root is . GMm GMm
α =– +
(R + h) R
35.(d) We have A2 + A + I = 0
GMm GMm
So A–1A2 + A–1A + A–1I = 0 i.e. A–1 = –A – I =– + (‡ h = R)
2R R
Given (a, b) = λ(5, 1) implies a = 5λ, b = λ So a = 5b GMm
36.(a)
37.(d) Given equation is 9x2 + 36y2 = 324
=
R (1 – 21)
gR2m 1
x2 y2 = × (‡ GM = gR2)
i.e. + =1 R 2
36 9
mgR
x2 y2 =
2
Comparing with + = 1, we get a2 = 36, b2 = 9
a2 b2
63.(d) dQ = +400 J
So, PS + PS' = 2a = 2.6 = 12 dW = –100 J
6–y 3 6–y dU = dQ – dW
38.(d) Slope = or, – = or, –3 = 6 – y ∴ y = 9
4–2 2 2 = 400 – (–100)
39.(b) As the circle passes through the point (3, 4), so 32 + 42 = a2 = 500 J
i.e. a2 = 25 64.(b) F = (M + m)a; a = common acceleration ...(i)
∴ Required area = πa2 = π.25 = 25π sq. units For block A (not to slip)
Ff = ma
1
40.(b) We have, a = 2RsinA or, 2 = 2R. ∴ R=2 or, µR = ma
2
or, µ mg = ma
41.(d) Max. and min. value = ± 12 + 12 = ± 2 i.e. 2 and – 2
or, a = µg
42.(a) Total no. of people = 4 + 4 = 8, so number of Then from (i),
arrangements = 8! = 40320
F = (M + m) µg
2 1 1 1
43.(c) The expansion is valid if |3x| < 2 i.e. |x| <
3 65.(c)
λ
=R ( –
n 12 n 22)
44.(b) Two lines are perpendicular to each other if K – 3 = 0 For longest wavelength in Lyman seris: n1 = 1 and n2 = 2
i.e. K=3 1 1 1
∴
λL (
=R 2– 2
1 2 )
2
 PEA Association Pvt. Ltd. Thapathali, Kathmandu, Tel: 5345730, 5357187
2080-3-16 Hints & Solution
1 3 λ
or, =R× ×D
λL 4 µ
=
4 d
or, λL = 2
3R
For shortest wavelength: n1 = 1 and n2 = ∞ λD 2
= ×
d µ
= R 2 – 2 
1 1 1
∴
λs 1 ∞  2
=β×
1 4
or, λs = 3
R
4 3
λL 3R 4 = β
2
∴ = =
λs 1 3
R 1 T
72.(a) f= = 450 Hz
ld πρ
m 1 t/T
66.(c)
m0
= () 2
1/2

Now, f ' =
1
l'd'
T'
πρ
(12)
t/T
1/2
or, m = m0 × 1
T
1 4
1 10/2.5 or, f'=
or, m=1×( ) l πρ
2 × 2d
2
1
or, m= g 1 1 T
16 or, f'= ×
ld 2 πρ
67.(a) K.E. = hf – φ;
1
hf = photon energy or, f'= f
2
φ = work function 1
or, f'= × 450 = 225 Hz
KE1 (hf)1 – φ 2
∴ =
KE2 (hf)2 – φ 73.(c)
1.5 – 1 q1 q2
=
3–1 i r i
0.5 1 q 1q 2
= F= 2 ... (i)
2 4πε0 r
1 When half space is filled with dielectric
=
4 q2
q1 εr = 4 ε0
68.(d) P = Irms Vrms cosφ r r
I0 V 0 π 2 2
= × × cos 1 q 1q 2
2 2 2
F' = 2
4πε0 r r
=0
dI
(
εr × +
2 2 )
69.(c) ε=L (in magnitude) 1 q 1q 2
dt = 2
4πε0 r r
= 5 × 10–3 × (10.1– 0) (
4× +
2 2 )
=  4 4F
q 1q 2
= 5 × 10–2 V 4πε0r2 × 9 = 9
µ0nI 74.(a) miLf = mwSw∆θw
70.(b) B=
2 80 × 1 × (30 – 0)
or, mi =
4π × 10–7 × 800 × 1.6 80
=
2 or, mi = 30g
= 8 × 10–4 T 75.(d) As more OH− is removed, more Fe(OH)3 dissolves. The
λD solubility of Fe(OH)3 would be maximum in 0.1M
71.(b) β= H2SO4 ( as it ionizes to give 2H+ ions while HCl gives
d
only one H+ ions).
λ'D
Now, β' = 76.(c) 2KClO3 →2KCl+3O2
d'

3
 PEA Association Pvt. Ltd. Thapathali, Kathmandu, Tel: 5345730, 5357187
2080-3-16 Hints & Solution
Molar mass of KClO3 = 122.5 g 87.(c) Put y = sinx ∴ dy = cosx dx
Mass of KCl = 74.5 g dy y–1/2 2
Then I = I = Iy–3/2 dy = +c=– +c
122.5 – 74.5 y y 1 y
So, percentage loss = × 100 = 39.18% 2
122.5
77.(b) Fe2 O3 (s) + 3C(s) →2Fe(s) + 3CO(g) 2
=– +c
1 mol of Fe2 O3 requires 3 mol of C sinx
So 6 mol of Fe2 O3 will require 18 mol of C 88.(b) For extrema, h'(x) = 0 or, f ' (x) – f '(–x) = 0
But only 9 mol of C is present. i.e. f '(x) = f '(–x) So f '(x) is an even.
So the limiting reagent is carbon 6 6 6 6
89.(b) |a | = | i + j – 3k | = 12 + 12 + (–3)2 = 11,
3 mol of C gives 2 mole of Fe 6 6 6 6
|b | = |– i – 2 j – 3k | = (–1)2 + (–2)2 + (–3)2 = 14
So 9 mol of C will give 6 mol of Fe
66
∴ Theoretical yield of Fe = 6 mol and a .b = 1.(–1) + 1.(–2) – 3.–3 = –1 – 2 + 9 = 6
78.(c) Nitric acid is as oxidizing agent, when H2S is passed 66
6 6 a .b 6
over nitric acid, is oxidises S2− to Colloidal Sulphur S. ∴ Projection of a on b = 6 =
|b | 14
H2S + 2HNO3 → S + 2NO2 + H2O
79.(d) According to faraday's law: W = ZQ = (E/96500) × Q. 90.(c) Centroid = (2, 3, 4) So, a = 3.2 = 6, b = 3.3 = 9, c = 3.4
= 12.
Here, we are flowing same charge through cathode and
anode, so at cathode and anode same mass reacts. At x y z x y z
Eqn is + + = 1 i.e. + + =1
cathode if 2.5 gm is reducing then at anode 2.5gm of Cu a b c 6 9 12
will be oxidized into solution so there is a decrease of 1
2.5 g of mass takes place. 91.(b) Eqn of tangent at t1 is y = x + at1, Eqn of tangent at t2
t1
80.(c) Fe= 1s2 , 2s2 2p6 ,3s2 3p6 ,4s2 3d6 1
is y = x + at2
t2
Number of orbitals which contain one or more electrons
= 1+ 1+ 3+ 1+ 3+ 1+ 5= 15 1 1
As the tangents are perpendicular to each other so .
t1 t2
81.(d) Copper has less affinity for oxygen than Sulphur at high
= –1 i.e. t1t2 = –1
temperature.
92.(c) log tan1° + log tan2° + .... + log tan88° + log tan89°
2Cu2S + 3O2 → 2Cu2O + 2SO2
= log tan1° tan2° .... tan88°.tan89° = log tan1° tan2° ...
2Cu2O + Cu2S → 6Cu + SO2 cot1° cot2° = log1 = 0
82.(c) As x2 + 1 ≠ 0 for all real x. 93.(a) We have (1 + x)n = c0 + c1x + c2x2 + ... + cnxn.
x2 Differentiating we get
So domain = R. Also x ≥ 0 and2
< 1.
1 + x2 n(1 + x)n–1 = c1 + 2c2x + .... + ncnxn–1.
So range = [0, 1) Putting x = 1, n 2n–1 = c1 + 2c2 + .... + ncn
b 4
y3 4
Required area = I x dy = I y2 dx = [
94.(d) Total no. of triangles = c(12, 3) but 8 are collinear
83.(c)
a 0
]
3 0 points, so no of triangles = c(12, 3) – c(8, 3) = 164
43 64
(x3) + (y4) = (cost + sint) + (cost – sint)
2 2
= – 0 = sq. units 2 2
3 3 95.(a)
π x2 y2
84.(b) sin–1x + sin–1y = or, sin–1x = cos–1y i.e. + = 1, which is an ellipse
2 18 32
or, cos–1 1 – x2 = cos–1y or, 1 – x2 = y a+c
96.(a) a, b, c are in AP. So b = . b, c, d are in HP.
i.e. x2 + y2 = 1 2
dy d 2y 2bd
85.(d) = mAemx – Bme–mx, = m2Aemx + m2Be–mx So c =
dx dx2 b+d
= m2(Aemx + Be–mx) = m2y (a + c)d
The c = or, bc + cd = ad + cd ∴ bc = ad
α+β b+d
86.(c) Let α, β be the roots. Then A = i.e. α + β = 2A 97.(a) 98.(d) 99.(d) 100.(c)
2
and G = αβ i.e. αβ = G . So the required equation is
2

x2 – (α + β)x + αβ = 0 i.e., x2 – 2Ax + G2 = 0

…The End…