●● Practice questions

Practice questions
1 C (1)
2 D (1)
3 C (1)
4 q = mc∆T = 200 × 4.18 × 51.6 = 43137.6 J (1)
1.0 =0.01163 mol
moles of C6H14 = (1)
86.0
43 6 = 3 709 165.95 J mol−1 (1)
energy change per mole =
0.01163
energy change in kJ per mole = 3 709 165.95
1000
= −3710 kJ mol to 3 significant figures
−1 (1)
5 a) i) the enthalpy change when 1 mole of a substance is burned
completely in excess oxygen with all substances in standard
states under standard conditions. (1)
ii) CH3CH2CH2CH2OH(l) + 6O2(g) → 4CO2(g) + 5H2O(l) (1)
b) moles of butan-1-ol = 0.600 = 0.00811 mol (1)
74.0
q = mcT = 250 × 4.18 × 19.40 = 20273 J (1)
20 273 = 2 499 753.391 J mol−1 (1)
energy change per mole =
0.00811
energy change in kJ per mole = 2 499 753.391
1000
= −2499.75 kJ mol−1 (1)
6 moles of benzene = 0.750 = 0.009615 mol (1)
78.0
q = mc∆T = 200 × 4.18 × 43.7 = 36533.2 J (1)
energy change per mole = 36533.2 = 3 799 604.784 J mol−1 (1)
0.009615
energy change in kJ per mole = 3799604.784 = 3799.6 kJ mol−1 (1)
1000
7 a) i) Ba(s) + C(s) + O2(g) → BaCO3(s) (1)
ii) Ba(s) + O2(g) → BaO(s) (1)
iii) C(s) + O2(g) → CO2(g) (1)
b) +1216 (1) + (−554) + (−394) (1) = +268 kJ mol−1
8 a) 4(+178) (1) + 2(−824) + 8(−297) (1) = −3312 kJ mol−1 (1)
b) it is an element (1)
9 2(−398) − 2(−468) (2) = +218 (1) kJ mol−1 1
10 Bonds broken = 6635 (1)
Bonds made = 8522 (1)
Energy change = +6635 − 8522 = −1887 kJ mol−1 (1)