MAHATMA GANDHI UNTVERSITY KOTTAYAM

VI Semester Core Practical Examination March/April 2020

CH6CRP05 Physical Chemistry Experiments
Time: 3 hours Total Marks: 40

Attempt the question marked X and copy it down into your answer book

P1. Study the variation of miscibility temperature of phenol water system

on addition of KCI. Use the data to determine the concentration of the 3
given solution of KCI

P2. Find the molecular mass of the given solute by Rast's method. You are
provided with a solvent of known mass and K=
P3. Determine conductometrically the concentration of the given acid. You at
are provided with standard NaOH. Find the equivalent point manually
or by using spread sheet programme

P4. Determine by potentiometric titration the concentration of given Fe*

You are provided with standard KMnO4. Determine the concentration
manually or by using spread sheet programme
PS. Determine viscometrically the composition of the given sucrose
solution

P6. Determine the heat of solution of the given solute in water.

P7. Determine the heat of neutralization of a strong acid by a strong base
P8. Determine the mass of the given salt hydrate from transition
temperature. You are provided a salt hydrate with Kf = and
molar mass of solute =

P9. Determine the first order kinetics of acid hydrolysis of methyl acetate
P10. Determine the surface tension of a liquid by drop weight or drop
number method
 Total = 40 marks
CH6CRPO5: Physical Chemistry Experiments
1. Select experiments such that an experiment is not given to more than 3 students
2. Direct the students to write the procedure/theory of the experiment given to him/her in
the first 5 minutes in a separate sheet of paper and to submit to the examiners.
3. Instruct the student how to do the experiment
Expt. Experiment Procedure Tabular Graph Calculation Accuracy
No column
& Data
Pl CST-Unknown Comp. 5 5 10 20

P2 Rasts Method 10 15

P3 Conductometry(manual 10 15

spread sheet)
P4 Potentiometry (manual 10 15

spread sheet)
P5 Viscosity 5 10 20

P6 Heat of Solution 10 15
P7 Heat of Neutralization 5 10 15

P8 Mass of salt hydrate by 15

Tran. Temp.
P9 Ester Hydrolysis 5 10 10 10
P10 Surface Tension 10 10 10

(Up to 5% error - give full marks; 5-6 % - deduct Imark for every 0.2%; above 6% - deduct
Imark for every 0.1%)
Note:
P1. Give 0.2M solution of KCl and phenol. Unknown solution given may be 0.08 to 0.I M
P2. (a). Solvent:Naphthalene(M.P= 80.1'C,Kf= 6.95) and Solute: Acetanilide(Mol wt = 135)
(b). Solvent: Biphenyl (M.P. =69.2°C, K¹= 8.00) and Solute: Acetanilide (Mol.wt = 135.
Molecular weight of solute M= 1000.K, W/AT. Wi

2
P3. Give 8-12 ml of IN HCland N/10 NaOH
P4, Give 20-24 ml N/2 Mohr's salt and N/10 KMnO4
P5. Prepare 15% sucrose solution. Unknown: between 5-10%.
P6. Give crystals of potassium nitrate or ammonium chloride
P7. 0.5N HCl and 0.5 N NaOH solutions may be given.
P8. About 8-10g crystals of salt hydrate (eg: sodium thiosulphate: TT=48.2°C, K, = 4.26;
sodium acetate: TT-58° C, KF3.5) and 0.3-0.4g of accurately weighed solute (eg: urea:
Mol.Mass =60, glucose: Mol. Mass 180, sucrose: Mol.Mass= 342) may be given.
M =1000.K.w/AT.VW
P9. Methyl acetate, 0.5N HCI, 0.IN NaOH and phenolphthalein.
P10. Give 10 M acetic acid solution

CH6CRPO6: Gravimetric Analysis Total = 40 marks

Procedure: 5 marks; Calculation: 5 marks; Accuracy: 30 marks

Give 20, 22, 24 mlsolution for estimation.
S.No Expt.Code Estimation To precipitate as Wt in 500 ml
1 GI Sulphate BaSO4 19 g KTSO4
2 G2 Barium BaSO4 28 g BaCk

(Up to 1% eror, give full marks; 1-2%, deduct Imark for every 0.1%; 2-3%, deduct 1.5 marks
for every 0.1%; above 3%, give 5 marks as grace mark.)
CH6PRPO1: Project, Viva Voce &I.V Report Total Marks = 80

Content andStructure of the Project Report: = 20 marks

(antroduction: 2, Objectives: 2, Experimental: 2, Results and Discussion: 10, Conclusion: 2,
References: 2)
Project Presentation = 10 marks

L.V Report 10 marks

Project Viva Voce 10marks
Comprehensive Viva = 30 marks