University of Bahrain, College of Science, Department of Chemistry

General Chemistry (CHEMY 101) Test 2

First Semester 2022-23

Time: 75 minutes December 22, 2022

Examiners: Prof. Salim Akhter, Prof. Ayman Kamel, Drs. Wael Amer, Gul Khan, Tariq Mahmood, Ahmed
Hefnawy, Suad Rashdan, Kheireddine Elboubou, Javed Iqbal, Abdulla Almutawa, Ali Hussain, & Mrs.
Reema Balachandra

Marks for part A (Fill in the blanks): __, Marks for Part B(MCQs): __ , Marks for Part C(Practical): ___
08 12 6

Two A4 pages are provided for calculations (rough work), Only the circled answers on this exam copy will
be graded.

STUDENT NAME: _______________ Section#: ____ I.D.#: ______________

(Note: R= 0.0821 L.atm/mol. K, 1 atm= 760 mmHg, Kelvin = t(oC) + 273.15)

Part A : Fill in the Blanks ( 08 Points)

1. The oxidation number of iodine in KIO3 is -----+5-----------------

2. The Van’t Hoff factor “i” for NaNO3 is ----------2--------------
3. According to Boyle’s law, at constant ‘n’ and ‘T’, the volume of a gas is -----------------------proportional
to the pressure. (Inversely/directly)
4. The density of a gas is -------------------proportional to its molar mass at constant T and P.
(Inversely/directly)
5. 0.05 ppm is equal to –0.05x10-4--------mass %
6. In carbonated drinks, the solubility of gas in gas-liquid systems --------------------- as temperature
increases. (decreases, increases)
7. Boiling point of a solution is always -----------than the boiling point of a solvent. (less, greater)
8. 10 g C6H12O6 dissolved in 140 g water. The mass percent of C6H12O6 is---6.67--------

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Part B : Multi[ple Choice Questions ( 12 Points)

Q.1 : Consider the following balanced redox reaction:

3Ag + NO3- + 4H+ 3Ag+ + NO + 2H2O
Which of the following statements is true?
a Ag is reducing agent and is reduced
b Ag is reducing agent and is oxidized
c Ag is oxidizing agent and is reduced
d Ag is oxidizing agent and is oxidized
e Ag does not change its oxidation number in this reaction

Q.2: When the following redox reaction is balanced (in acidic medium) with smallest whole number
coefficients, the coefficient for the Fe+2 ion will be
Fe2+ + MnO4-1 Fe3+ + Mn2+
(aq) (aq) (aq) (aq)
(a) 4 (b) 5 (c) 6 (d) 8 (e) 14

Q.3: A solution is prepared by dissolving 50.0 g of C3H7OH in 90.0 g of water. The mole fraction of
C3H7OH is

(a) 0.172 (b) 0.143 ( c) 0.250 (d) 0.346 ( e) 0.077

Q.4: What volume of 12.6 M HCl must be added to enough water to prepare 5.00 L of 3.00 M HCl

(a) 1.19 L ( b) 21.0 L (c) 0.794 L (d) 7.56 L (e) 0.595 L

Q.5: A 15.00 % by mass aqueous solution of lactose (C12H22O11, MM= 342 g/mol) has a density of
1.0602 g/ml at 20 oC. What is the molarity of this solution?

(a) 0.933 M (b) 0.413 M ( c) 0.466 M (d) 1.55 M (e) 3.10 M

Q.6: If the solubility of a gas in water is 0.400 M at 0.620 atm, at what pressure will the solubility increase
to 1.00 M?

(a) 1.80 atm (b) 1.86 atm (c) 1.55 atm (d) 2.56 atm (e) 1.24 atm

Q.7: Calculate the freezing point of a solution made from 21.0 g NaCl in 100 g of H2O (Kf of water is 1.86
o
C/m) ( MM of NaCl = 58.44 g/mol)

(a) -4.46 oC (b) -6.68 oC (c) -3.59 oC (d) -13.4 oC (e) -2.67 oC

Q.8: 0.102 g of a nonelectrolyte compound is dissolved in water to make a 100 mL solution. The solution has
an osmotic pressure of 28.1 mmHg at 20.0 oC. Calculate the molar mass of the compound.

(a) 110 g/mol (b) 664 g/mol (c) 133 g/mol (d) 221 g/mol (e) 727 g/mol
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Q.9: Which of the following has highest boiling point?

(a) Pure water (b) 2 m KCl (c) 1m MgCl2 (d) 1.5 m Li3PO4 (e) 1 m C6H12O6

Q.10: A sample of nitrogen gas has a volume of 328 mL at 15 oC and 748 mm Hg. Calculate the temperature
when this gas occupies a volume of 0.800 L and at a pressure of 642 mm Hg. Assume the amount of nitrogen
gas does not change.

(a)102 oC (b) 404 oC (c) 256 oC ( d) 330 oC (e) 41.9 oC

Q.11: The density of a gas is 2.60 g/L at 30 oC and 0.500 atm. What is the density of the gas at 50oC and 850
mm Hg?

(a) 4.55 g/L ( b) 2.73 g/L (c) 3.21 g/L (d) 5.46 g/L (e) 1.94 g/L

Q.12: In a solution of 0.2 M Cr2(SO4)3, the concentration of sulfate anions is ………

(a) 0.1 (b) 0.2 (c) 0.4 (d) 0.6 (e) 0.8

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Part C : Experimental ( 06 Points)

Q.1. Write true or false. (3 points)

1 In a chemical reaction, the actual yield is always less than the theoretical yield. True False

2 Paper chromatography is used for separation of mixtures. True False

3 If density of air at 21 oC and 1 atm is 0.00122 g/cm3 and volume of air is 107 cm3. True False
The mass of air will be 0.130 g.

4 According to beer’s law, the absorbance is inversely proportional to the True False
concentration of salicylic acid solution.

5 Retention factor (Rf) is measured in mol/L. True False

6 A brown gas (NO2) is evolved when copper metal reacts with concentrated HNO3 True False
solution.

Q.2. Choose the correct option (3 points)

1. In acid base titration, 22.0 ml of 0.2 M NaOH solution was needed to neutralize 25.0 ml of HCl

solution. The concentration of HCl and the moles of NaOH are ………. and …………, respectively.

(a) 0.176, 5 (b) 0.176, 0.0044 (c) 0.227, 0.005 (d) 0.227, 4.4 (e) 0.176, 0.005

2. The active ingredient present in the aspirin tablet is --------------------

(a) phenol (b) FeCl3 (c) acetyl salicylic acid (d) acetic acid

3. The name of the developer which is used to get the colour of the Fe2+ is -------------------------

(a) acetone (b) ammonia (c) dimethylglyoxime (d) developer not required

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