Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_NUCLEUS & STERLING BT CTA-09/CTA-01_(QAT-01) Date: 24-09-2023
Time: 02:00PM to 05:00PM JEE-ADVANCE-2022_P1 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 10 2 7 3 7 4 2.10 5 1 6 4

7 1 8 19 9 ABC 10 ABD 11 ABC 12 ABCD

13 D 14 ABCD 15 C 16 B 17 A 18 B

PHYSICS
19 1 20 8 21 9 22 5 23 1.67 24 1.73

25 4 26 7 27 AC 28 AB 29 AC 30 BD

31 AD 32 ABCD 33 A 34 B 35 C 36 D

CHEMISTRY
78.3
37 462 38 292 39 5.6 40 to 41 8 42 662.4
78.5
43 13 44 432 45 ABC 46 ABCD 47 ABD 48 AC

49 ABD 50 BD 51 A 52 B 53 D 54 B
 Sri Chaitanya IIT Academy 24-09-2023_Jr.SU60_NUCLEUS & STERLING BT_Jee-Adv(2022-P1)_CTA-09 & CTA-01_(QAT-01)_Key & Sol’s

SOLUTIONS
MATHEMATICS
1. Put x  cos  , see that two cosine rules for two triangles. Max value  109  sum  10
n 1
 k  n
2. Put n  14 in  sin    n1
k 1  n 2
c.a  6 
3. Let c lies on line  
c.b  10 

 distance 
c ab    10a  6b  l  10 l  m  2 4

ab ab m  6
 No. of divisors = 5
1 2 1 T 1 T
4. 2
1 3   5. A  A1
4
   
21 1 1 2 T T 8 1 2

4
 2
. A  
1 3 
 A1   
21 1 3 
8  1 1
 A1  
21  2 3
 21  1   3 1
 A  
 8   5   2 1 
21  3 1
A 
40  2 1 
21 21
Trace of    3  1 
40 10
a b c a b c
5. b c a  3abc a  b  c  3 3 3
 c a b  a 3  b3  c 3  3abc
c a b b c a
a  b  c  3abc  0   a  b  c  a  b 2  c 2  ab  bc  ca  0
3 3 3
 2

 a  b  c  0 or a  b  c
 sin 1 x  sin 1 2 x  sin 1 3 x  0 or sin 1 x  sin 1 2 x  sin 1 3x
  sin 1 x,   sin 1 2 x,   sin 1 3 x  x  0
       cos  cos   sin  sin   cos 
 1  x 2 1  4 x 2  2 x 2  1  9 x 2  onlysolution
 3
4 3  1 0 
6. We have AB  1 2    I
  2 2   0 1 
1 2   
 AB  C1  C1 ,  AB  C2  C2 and so on.
1 2

tr  Cr   r.3r   r  1 .3r   2r  1 .3r

50

 tr   AB    AB  C   tr  AB  C   .....  tr  AB  
r 1 2 50
Cr  tr 1 2 C50  S  Let 
r 1

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 Sri Chaitanya IIT Academy 24-09-2023_Jr.SU60_NUCLEUS & STERLING BT_Jee-Adv(2022-P1)_CTA-09 & CTA-01_(QAT-01)_Key & Sol’s

S  tr  C1   tr  C2   .....  tr  C50 
S  1.31  3.32  5.33  .....  99.350
3S  1.32  3.33  .....  97.350  99.351
2S  1.3  2.32  3.33  .....  2.350  99.351
 3  2.3  2.32  ......  2.350  99.351
3.  350  1
 3  2.  99.351
3 1
 3  3  3  99.351  6  98.351  S  3  49.351
51

 a  b  100
1
7. Solutions are, 3  , 2  3,  2  3  Product  1
3
 
x  11y  2 y
8. (i)  k1 ,
11
 x  2 y is divisible by 11
x  13 y  2 y
(ii)  k2
13
 x  2 y is divisible by 13
6 x  12 y 6x  y 6 x  12 y 6 x  y  13 y 6x  y
1  1  1  1  1
11 11 13 13 13
 6 x  y  143k
6 x  6 y  143k  5 y  138k  5 y  5k
 k  y is divisible by 6
6 x  6 y  138k  5  6   x  y  28
Minimum = 28  K 2  789  sum  19
1
9. Simplify : 2cos 4 x  1  0  cos 4 x  and now proceed
2
10. BC 1  B  C 
 BC 1B  B 1CC
 BC 1B  B
 BC 1B  CC 1B
  B  C  C 1 B
1
 A  B 1C  B  C  . B  C  C 1B
=I
A I
11.  AB  2  2 AB  0  AB  AB  2 I   0
Since AB  O2  AB  2 I  0  AB  2I is singular also
AB  2 I  0  A B  2 A1  0  B  2 A1  0 if A  0

12. A line through A  5, 4  with slope tan 

 x  5  y y
r
cos  sin 
Any point on this line is  5  r cos  , 4  r sin  
If this lies on x  3 y  2  0  5  r cos   3  4  r sin    2  0

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 Sri Chaitanya IIT Academy 24-09-2023_Jr.SU60_NUCLEUS & STERLING BT_Jee-Adv(2022-P1)_CTA-09 & CTA-01_(QAT-01)_Key & Sol’s
15
r  AB
cos   3sin 
Similarly other options can be proved.
13.

  3 6  
 E  ,  lies on 6 x  10 y  59  0
 2 8 
Solve for  we get   10
 C  10,5 
Also reflection of A about CF lies on BC. Find A’ and find equation of BC.
  
14. Since they are unit vectors, we have A  B  1  C . It is also given that the angle 
   
between
 
A and C equals that between B and C , i.e.,
 
A.C   B.C  
   A.C  cos     B.C
AC B C
  
Since A.B  0, we get from the given value of C ,
        

A.C   A. A   A.B   A A  B   
 
i.e.,   cos , and similarly, B.C  cos    . This is,     cos , so that answer (a) is
correct.
Next, we have
   2 2 2  
1  C.C  2 2   2 A  B  2 2   2  A B  A.B   2 2   2
 
 
  2  1  2 2  1  2 cos 2    cos 2
1   2 1  cos 2
 2   2  
2 2
15. P   a b c   2
2
 2 a  b 3b  c c  a   6  a b c   6  4  24
Q   a b c   5
6  a  b b c c  a   12  a b c   60
1
R a  b  20
2
1
2
 2a  3b    a  b 
1
2  a  b   3  a  b 
2
5
 40  100
2
S  a  b  30

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 Sri Chaitanya IIT Academy 24-09-2023_Jr.SU60_NUCLEUS & STERLING BT_Jee-Adv(2022-P1)_CTA-09 & CTA-01_(QAT-01)_Key & Sol’s

  a  b   a  b  a  30
 s  a 2   s  a   1  s  b  2  2  s  b   1  s  c  2  3  s  c   1
16. A)    
 
s  a  
s  b  
s  c
 1  1  1 
 s  a   s  a  1  s  b   s  b  2  s  c   s  c  3
i  i  1 2i  1
B) ai  12  22  ......i 2 
6
10
S   ai  
 
10 i i  1 2i  1

i 1 i 1 6
n2
C) Tn 
500  3n3
1 500
Let U n   2  3n
Tn n
dTn

 
500  3n3 2n  m 2 9n 2 n 1000  3n3
 0
 
dn 
500  3n3
2
500  3n3   
1/3
 1000 
 n 
 3 
1/3
1000 
Now, 6    7
 3 
2

D) Tr  2 
 r  1  r 2
2r  1

1

1
2 2
r  r  1 r 2  r  1 r  r  1 2
2

n n
S n   Tr   Vr  Vr 1 
r 1 r 1

1
 V1  Vn1  1  2
 n  1
n 2  r  1  

17. A) S n   cos4    
r 1  n 
1 n   4  r  1   
   1  cos  2   
4 r 1   n 
1 n   4  r  1     4  r  1  
   1  cos2  2     cos  2  
4 r 1  n n
   
1 n  1  8  r  1    
   1  1  cos  4    
4 r 1  2   n 
1 3 3
  n n
4 2 8
A B   A B  2 mC
B) cos mA  cos mB  cos mC  2 cos m   cos m    1  2sin
 2   2  2
mC   A B  mC 
 1  2sin  cos m    sin  for m   4n  1
2   2  2 

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 Sri Chaitanya IIT Academy 24-09-2023_Jr.SU60_NUCLEUS & STERLING BT_Jee-Adv(2022-P1)_CTA-09 & CTA-01_(QAT-01)_Key & Sol’s

mC   AB   A  B 
 1  2sin  cos m    cos m  
2   2   2 
mA mB mC
 1  4sin sin sin
2 2 2
n n
C) cos x  1  sin x, for n even x  m ,
3
For n odd x  2m or x   2 p  
 2 
 as cos n
x  sin n x  sin 2 x  cos2 x  1if n  2 
6 4
D) sin x  2
or , but for exactly three roots sin x  1
5m  m 5m  m 2
6
  1  m  2,3, 1, 6
5m  m 2
18.  
0  x  1  f  x   15  x   x 2  x 7  x8  0
 8 7
 
x  1  f  x   x  x  x  x  15  0 2

X  1 is not root. Also there can not be negative root
C) No. of real roots = 0
3 1 3 3
D) x 2   or   x  4    4  4 4  3
2 2 4 4
PHYSICS
19.

When the ball is just released, the net force on ball is Weff    mg – buoyant force 
The terminal velocity ' v f ' of the ball is attained when net force on the ball is zero.
 Viscous force 6 rv f  Weff
2
When the ball acquires rd of its maximum velocity v f
3
2
the viscous force is = Weff .
3
2 1
Hence net force is Weff  Weff  Weff
3 3
a
 required acceleration is =
3
20. Let the tension at highest point be Fo and at lowest point be F
 g
Then FoCos  F and Fo sin  
2
 g
Therefore F  cot  and if F is tension at losewt point and R is radius of curvature
2
then Fd   Rd g . Calculating we get R = 8 m.

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 Sri Chaitanya IIT Academy 24-09-2023_Jr.SU60_NUCLEUS & STERLING BT_Jee-Adv(2022-P1)_CTA-09 & CTA-01_(QAT-01)_Key & Sol’s

m l2 l m l
21. i) Li  L f ;   MV   V 
12 2 6M
mV l
ii) Pi  Pf ; 0  MV  mV1  V  1   V1
M 6
V  (V1 )  l ml  l l  m 
iii) e  1   V  V1  ;   ;   1  3
l 2 6 M 6 2 M 
 0
2
m m
  2  M   9 kg .
M 2
M
0 V

m 
V1

4S
22. The excess pressure  , where R = 2 cm.
R
23. Let the tangential acceleration of m1 be a.
 m2 g  m1 g sin    m1  m2  a
40  25 15
a  m / s2
9 9
the normal acceleration of m1 is zero.
 speed of m1 is zero.
15
 The magnitude of acceleration of m1  m / s2.
9
24.

Let the magnitude of velocity of top of the rod be VR towards left and the
speed of block B be V .
d 1 d  2
l1  l2  constant    0  u  VR cos 60  0 ......... 1
dt dt
d d
l3  l4  constant  3  4  0  VR cos 30  V  0 .........  2 
dt dt
Solving (1) & (2)
V  3u m/ s
25. Let velocities of block 2 and block 3 be v2 and v3 towards right.
2 v 3 2 v 3 v
2 3

before first collision after first collision

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 Sri Chaitanya IIT Academy 24-09-2023_Jr.SU60_NUCLEUS & STERLING BT_Jee-Adv(2022-P1)_CTA-09 & CTA-01_(QAT-01)_Key & Sol’s

 from conservation of momentum

mv  mv2  2mv3 ........ 1
and from equation of restitution
v3  v2  v ........  2 
from (1) and (2)
2v
v3 
3
Since collision between 3 and 4 is inelastic.
2v
2m
 final velocities of 3 and 4 are v4  3  4v
m  2m 9
26. When the block is slightly rotated clockwise, centre of buoyancy should be to the right
a   
of centre of mass. From this condition we can find  6 1  
b  o  o 
27.
y clockwise

+4
3
x
+4
3
Anti-clockwise
28. Frictional force on mass A  0
Static limiting frictional force on mass B   ' B  mA  mB  g  0.5   5  15 10  100 N
29. Using energy conservation between initial moment and equilibrium moment when
T  mg
1 mg 2 1
 L  mv 2  mg  2L
2 L 2
V  3gL
If ball falls a maximum distance of L  x.
1 mg 2
mg  L  x   x
2 L

x L 3 
 PEmax  mgL 2  3  
t
5t 2
30. for A : y A  10t; x A   0.5 10t dt 
0
2
t
for B : y B  20t; x B   0.5  20t dt  5t 2
0

xB  x A  250
Difference of height of tower  y B  y A

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 Sri Chaitanya IIT Academy 24-09-2023_Jr.SU60_NUCLEUS & STERLING BT_Jee-Adv(2022-P1)_CTA-09 & CTA-01_(QAT-01)_Key & Sol’s

31. Let L1 and L2 , m1 and m2 ,V1 and V2  be the length of the arms of the balance, the mass
and volume of the balls, respectively.
The equilibrium condition on such scales: m1 L1  m2 L2
Since the buoyant force is proportional to the volume of a given body, when immersed
in water, the balance of the balance will not be disturbed if V1L1  V2 L2
Divide term by term the first equality by the second:
m1 m2
 or 1  2 .
V1 V2
This suggests that the average densities of the balls are equal. From this it is clear that in
a denser (silver) ball there is a cavity, as a result of which the equilibrium is maintained.
32. Since net force on block is zero. Hence net reaction exerted on block by
incline plane is vertically upwards and has magnitude equal to mg.
33. A) Initial velocity of centre of mass of given system is zero and net external force is in
vertical direction. Since there is shift of mass downward, the centre of mass has only
downward shift.
B) Obviously there is shift of centre of mass of given system downwards. Also the
pulley exerts a force on string which has a horizontal component towards right. Hence
centre of mass of system has a rightward shift.
C) Both block and monkey moves up, hence centre of mass of given system shifts
vertically upwards.
D) Net external force on given system is zero. Hence centre of mass of given system
remains at rest
34. Use equation of continuity and concept “pressure is greater at lower and broader
section”.
35. Point J  No equilibrium
K  Unstable equilibrium
L  Stable equilibrium
M  Neutral equilibrium
36. Equation of path is given as y  ax  bx 2
Comparing it with standard equation of projectile;
g x2
y  x tan  
2u 2 cos2 
g
tan   a, 2 b
2u cos 2 
g
Horizontal component of velocity  u cos 
2b
 g 
2 a
2u sin  2(u cos  ) tan   2b  2a 2
Time of flight T =   
g g g bg
2
 g 
 .a
u 2 sin 2  [u cos  .tan  ]2  2 b  a2
Maximum height H =   
2g 2g 2g 4b

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 g  g 
2  . a  
u 2 sin 2 2(u sin  ) (u cos  )  2b   2b  a
Horizontal range R    
g g g b
CHEMISTRY
37. 100 gm of impure Si contain 84g of Si 200 gm contain
200  84
 168 g.
100
168
Number of moles of Si  6
28
One mole of silicon can give one mole of  CH 3 2 SiCl2
 6 moles of Si gives 6 moles of  CH 3  2 SiCl2
Condensation of 6 moles  CH 3 2 SiCl2 after hydrolysis may give a straight chain silicone
or a cyclic silicone
CH3 CH3 CH3 CH3 CH3 CH3

HO - Si - O - Si - O - Si - O - Si - O - Si - O - Si - OH

CH3 CH3 CH3 CH3 CH3 CH3

432 gm
38. Li3 N  4 H 2O  3LiOH  NH 4OH
To neutralize one mole of Li3 N , 4 moles of HCl is required. To neutralize 2 moles of
Li3 N in 1 litre 8 moles are required. So the wt of HCl required is 8  36.5  292 gm
2 NaBH 4  I 2  B2 H 6  2 NaI  H 2
39.
76 254 28 300 2
If 300gm of NaI is formed, the diborane produced is 28 gms, then if 60g of NaI is
60  28
formed the diborane produced is  5.6
300
40. Since molarity is defined as moles of solute per litre of solution, it is always
recommended to consider 1.0 L of solution to determine molarity when the density is
given.
Therefore, mass of one litre of the above solution
 volume  density
 1000 mL 1.2 g / mL  1200 g
 Mass of FeSO4  NH 4 2 SO4 present in 1.0 L of above solution
30 11.833
= Mass of 1.0 L solution   1200   142 g
100 100
 Mass of FeSO4  NH 4 2 SO4 present in 1.0 L solution
142
 0.5
284
 Molarity (M )  0.5 M
 Moles of anhydrous salt in 400 mL solution
 0.5  0.40
 0.2

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Moles of hydrated salt dissolved = Moles of the anhydrous salt in solution

Moles of hydrated salt dissolved for 400 mL of solution = 0.2
 Mass of hydrated salt dissolved  0.2  392  78.4 g
0.6 1000
41. mmol of urea in 0.6 g sample   10
60
mmol of ammonia produced from 0.6 g urea  2 10  20
mmol of H 2 SO4 present in 50 mL solution = 12
 mmol of H 2 SO4 left unreacted in solution  12  10  2
 mmol of KOH required KOH
4
 Volume of KOH required for back titration   8 mL.
0.5
42. meq of H 2 SO4 needed for phenolphthalein end point  25  0.12  3.0  meq of Na3 PO4
Additional meq of H 2 SO4 required continuing the titration till methyl orange end point
 35  0.12  4.2
Out of 4.2 meq,3.0 meq of acid would be consumed for Na2 HPO4 produced from Na3 PO4
in the previous step of titration.
 4.2  3  1.2 meq of H  would be required for neutralizing Na2 HPO4 present in original
sample to NaH 2 PO4 .
 mass of Na3 PO4  3 10 3  64  0.492 g
 492 mg
 mass of Na3 HPO4  1.2  103  142  0.1704 g
 170.4 mg
43.

1,6,6-trimethylcyclohex-1-ene
44. x  18, y  24
45. Due to hybridization the size of orbitals change Electron distribution in s-orbitals is
much more diffuse than in sp n hybrids or p-orbitals alone. The hybridization of 3s and
3p orbitals on sulphur or phosphorous would produce more favorable bond angles with
regard to repulsion, but the overlap between those orbitals and the hydrogen 1s orbitals
is less effective. The hydrogen orbitals can overlap better with a smaller unhybridized
p-orbital on sulphur or phosphorous . The result is that the orbitals used by the central
atom have a very slight degree of hybridization but closely resemble pure p-orbitals
46. All the given statements are correct.
47. With increasing temperature maxima moves towards higher velocity. And with
increasing mass maxima moves towards lower velocity side.
48. At 300 K , G 0  H 0  T S 0  28.44 kJ/mole proceeds in forward direction
At 1200 K , G 0  2.59 kJ/mole proceeds in reverse direction
49. At 300 K , G 0  H 0  T S 0  28 kJ/mole and at 1200 K , G 0  3 kJ/mole

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50. When helium is added to system at constant pressure, in order to maintain constant
pressure volume of the system has to be increased, so reaction moves in the forward
direction.
51.
53. Conceptual
54. Lower be the ka value of acid, higher be the degree of hydrolysis of its salt of strong
base.
Stronger acids release maximum heat when titrated with strong base.
Equal values of ka & kb for acid and base respectively will evolve same amount of heat
and titration.

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