You are on page 1of 22

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_STERLING BT JEE-MAIN Date: 10-09-2023
Time: 09:00AM to 12:00PM CTM-01 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball
Point Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space)
on the Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and
Mathematics having 30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

(II) Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if
more than 5 questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and if answer is from
10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use
of pencil is strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone
any electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in
the Hall. However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________
Admission Number:

Candidate’s Signature: __________________ Invigilator’s Signature: ____________________


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Test Syllabus

PHYSICS : Fluid Staics, Work Power Energy, Circular Motion


CHEMISTRY : THERMODYNAMICS - I & II, THERMOCHEMISTRY
MATHEMATICS : Tigonometry upto transformations, Trigonometic
Equations,Functions, Inverse Trigonometric Functions

Sec: Jr.Super60_STERLING BT Page 2


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A vertical U-tube of uniform inner cross-section contains mercury in both sides of its
arms. A glycerin (density = 1.3 g/cm3) column of length 10 cm is introduced into one of
its arms. Oil of density 0.8 gm/cm3 is poured into the other arm until the upper surfaces
of the oil and glycerin are in the same horizontal level. Find the length of the oil column.
Density of mercury = 13.6 g/cm3

1) 10.4 cm 2) 8.2 cm 3) 7.2 cm 4) 9.6 cm


2. Some liquid is filled in a cylindrical vessel of radius R . Let F1 be the force applied by the
liquid on the bottom of the cylinder. Now the same liquid is poured into the vessel of
uniform square cross section of side R . Let F2 be the force applied by the liquid on the
bottom of this new vessel. (Neglect atmosphere pressure) Then
F2
1) F1   F2 2) F1  3) F1   F2 4) F1  F2

3. Assertion (A): Centripetal acceleration causes change of direction of velocity.
Reason(R): Tangential acceleration cause change in the magnitude of velocity.
1) Both Assertion and Reason are correct and Reason is correct explanation for Assertion
2) Both Assertion and Reason are correct and Reason is not correct explanation for
Assertion
3) Assertion is correct and Reason is incorrect
4) Assertion is incorrect and Reason is correct

Sec: Jr.Super60_STERLING BT Page 3


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
4. Assertion (A): A body submerged in a liquid experiences an upward thrust known as

buoyant force.

Reason(R): The pressure at the bottom of the submerged body is more than the pressure

at the top of the body.

1) Both Assertion and Reason are correct and Reason is correct explanation for Assertion
2) Both Assertion and Reason are correct and Reason is not correct explanation for
Assertion
3) Assertion is correct and Reason is incorrect
4) Assertion is incorrect and Reason is correct
5. A concrete sphere of radius R has a cavity of radius r which is packed with sawdust.

The specific gravities of concrete and sawdust are respectively 2.4 and 0.3 for this sphere

to float with its entire volume submerged under water. Ratio of mass of concrete to mass

of sawdust will be

1) 8 2) 4 3) 3 4) zero

6. A block of mass m slides down a rough inclined plane of inclination  starting from rest,
from a height h. Length of inclined plane is L. Coefficient of friction  
Column-1 Column-2
A Work done by gravitational force P Zero
B Work done by Normal reaction force Q    mg cos  L
C Work done by kinetic friction force R    mg sin   L
D Change in the potential energy S mgh
T  mgh
1) A-P, B-Q, C-R, D-S 2) A-Q, B-P, C-Q, D-R
3) A-T, B-R, C-P, D-Q 4) A-T, B-P, C-Q, D-S

Sec: Jr.Super60_STERLING BT Page 4


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
7. A body having volume V and density  is attached to the bottom of a container as
shown. Density of the liquid is  d    . Container has a constant upward acceleration a
.Tension in the string is

1) V dg    g  a   2) V  g  a  d    

3) V  d    g 4) none
8. If the K.E. of a body is increased by 300%, its momentum will increase by
1) 100% 2) 150% 3) 300% 4) 175%
9. A body of mass 0.5 kg travels in a straight line with velocity v  5 x 3 2 m/s. The work done
by the net force during the displacement from x  0 to x  2m
1) 25 J 2) 50 J 3) 75 J 4) 100 J
10. Assertion (A): In a Torricelli Barometer, mercury is used.
Reason(R): If water was used, the height of tube required would be 10.3 meters.
1) Both Assertion and Reason are correct and Reason is correct explanation for Assertion
2) Both Assertion and Reason are correct and Reason is not correct explanation for
Assertion
3) Assertion is correct and Reason is incorrect
4) Assertion is incorrect and Reason is correct
11. Two masses m1 and m2  m1  m2  are positioned as shown in figure, m1 being on the
ground and m2 at a height above the ground. When m2 is released, the speed at which it
hits the ground will be

Sec: Jr.Super60_STERLING BT Page 5


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.

2ghm1 2gh  m1  m2  2gh  m1  m2  2gh  m2  m1 


1) 2) 3) 4)
m2  m1  m2   m1  m2   m1  m2 
12. A simple pendulum is given the minimum velocity at the lowest point so that it can just
complete the vertical circle.
Column-1 Column-2
A Velocity at the lowest point P gl
B Velocity at highest point Q 2gl
C Velocity when string becomes horizontal R 3gl
D Velocity when the string makes 60 angle with vertical S 4gl
T 5gl
1) A-P, B-Q, C-R, D-S 2) A-Q, B-P, C-Q, D-R
3) A-T, B-R, C-P, D-Q 4) A-T, B-P, C-R, D-S
13. Which of the following statements are true about circular motion?
(A) If a particle is moving with constant speed on a circle then its total acceleration is
zero.
(B) If a particle moves along a circle with increasing speed then the angle between total
acceleration vector and velocity vector is acute angle.
(C) If a particle moves along a circle with constant speed then tangential acceleration and
angular accelerations are zero but centripetal acceleration is not zero
(D) If a particle moves along a circle with speed which is directly proportional to time t,
then tangential acceleration is constant but centripetal acceleration is not constant.
1) B, C, and D 2) A and B 3) B and C 4) All are correct

Sec: Jr.Super60_STERLING BT Page 6


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
14. A string of length 1m is fixed at one end with a bob of mass 100 g and the string makes
2 1
  rev s around a vertical axis through a fixed point. The angle of inclination of the
 
string with vertical is
1) tan 1   2) tan 1   3) cos 1   4) cos 1  
5 3 3 5
8 5 5 8
15. Which of the following statements are true about Fluids statics (Assume non-viscous
fluid)?
(A) If a container filled with water is accelerated with constant acceleration 10 3 m/s 2
then the free surface makes angle 30 with the horizontal.
(B) If a container filled with water is rotated with constant angular velocity about a
vertical axis passing through its center, then the free surface will form an elliptical shape.
(C) If a body is fully or partially submerged in a liquid, then it experiences an upward
thrust force equal to the weight of displaced liquid.
(D) Force exerted by a fluid at rest on submerged bodies is perpendicular to the surface of
the body at all points.
1) A, C, and D 2) A and B 3) C and D 4) All are correct
16. Assertion (A): Pressures at two points on a horizontal line in a horizontally accelerated
fluid are not equal.
Reason(R): Pressures at two points on a horizontal line are equal if the container is at
rest.
1) Both Assertion and Reason are correct and Reason is correct explanation for Assertion
2) Both Assertion and Reason are correct and Reason is not correct explanation for
Assertion
3) Assertion is correct and Reason is incorrect
4) Assertion is incorrect and Reason is correct
17. A rough horizontal plate rotates with angular velocity  about a fixed vertical axis. A
5a
particle of mass m lies on the plate at a distance from this axis. The coefficient of
4
1
friction between the plate and the particle is . The largest value of  2 for which the
3
particle will continue to be at rest on the revolving plate is
g 4g 4g 4g
1) 2) 3) 4)
3a 5a 9a 15a

Sec: Jr.Super60_STERLING BT Page 7


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
18. A ball attached to one end of a string swings in a vertical plane such that its acceleration
at point A (extreme position) is equal to its acceleration at point B (mean position). The
angle  is

1) cos 1   2) cos 1   3) cos 1  


2 4 3
4) None of these
5 5 5
19. A particle of mass m describes a circle of radius r. The centripetal acceleration of the
4
particle is . What will be the momentum of the particle?
r2
m m m
1) 2 2) 2 3) 4 4) None of these
r r r
20. Assertion (A): Work done by conservative force in a closed path is zero.
Reason(R): Work done by conservative force depends on the path.
1) Both Assertion and Reason are correct and Reason is correct explanation for Assertion
2) Both Assertion and Reason are correct and Reason is not correct explanation for
Assertion
3) Assertion is correct and Reason is incorrect
4) Assertion is incorrect and Reason is correct
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

21. A U-tube with uniform cross section filled with a liquid is being rotated about an axis
with angular speed   40 rad/s as shown in the figure. The difference in heights of liquid
in two arms is 10n centimeter. Find n.

Sec: Jr.Super60_STERLING BT Page 8


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
22. A container filled with water is accelerated horizontally such that its free surface makes
1
angle tan 1   with respect to horizontal. The pressure difference between two points
2
located 10 cm apart along horizontal line inside the fluid is 100 n Pascal. Find n.
23. An ornament weighing 50 g in air weighs only 46 g in water. Assuming that some copper
is mixed with gold to prepare the ornament, the mass of copper added in the ornament is
10n grams. Find n. (Specific gravity of gold is 20 and that of copper is 10).
24. A rod of length 2.0 m and mass 0.6 kg fixed at one end is initially hanging vertical. The

other end is now raised until it makes an angle 60˚ with the vertical. How much work is

required in Joules? (Take g  10 m/s 2 )


25. A sphere of mass m and radius R  20 cm held at a height 2R between a wedge of same
mass and a rigid wall, is released from rest. Angle of incline   60 . Assuming all
surfaces are frictionless, find the speed of the wedge (in meter per second) when the
sphere hits the ground. (Take g  10 m/s2 )

26. Two blocks are connected to an ideal spring of stiffness 200 N/m. At a certain moment,
the two blocks are moving in opposite directions with speeds 4 ms1 and 6 ms1 , and the
instantaneous elongation of the spring is 10 cm. The rate at which the spring energy
 kx 2 
  is increasing (in Joules per second) is 100n. Find n.
 2 

Sec: Jr.Super60_STERLING BT Page 9


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
27. A simple pendulum having mass m and string of length l is rotating in a vertical circle.
When the velocity given at the lowest point is 6gl then the difference of tensions at

highest and lowest points is 6mg. If the velocity given at lowest point is now 9gl then
the difference of tensions at highest and lowest points will be n times mg. Find n.
28. A 70 kg man stands in contact against the inner wall of a hollow cylindrical drum of
radius 4 m rotating about its vertical axis. The coefficient of friction between the wall and
his clothing is 0.4. The minimum rotational speed of cylinder (in rad/s) to enable the man
10
to remain stuck to the wall (without falling) when the floor is suddenly removed is .
n
Find n. (Take g  10m / s 2 )
29. A boy whirls a stone of small mass in a horizontal circle of radius 2.5 m and at height
20m above level ground. The string breaks and the stone flies off horizontally and strikes
the ground after travelling a horizontal distance of 10 m. The magnitude of the centripetal
acceleration in m / s 2 of the stone while in circular motion is 2n. Find n. (Take g  10m / s 2 )

30. A small block slides with velocity 0.5 gr on the horizontal frictionless surface as shown
n
in the figure. The block leaves the surface at point C. The value of cos  Find n.
n 1

Sec: Jr.Super60_STERLING BT Page 10


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. The heat capacity of bomb calorimeter is 500J / C. A 2C rise in temperature has been
observed on the combustion of 0.1 g of methane. What is the value of E per mole of
methane?
1) 1 kJ 2) 160 kJ 3) -160kJ 4) -1 kJ
32. Statement-1: Spontaneous process is an irreversible process and may be reversed by some
external agency.
Statement-2: Decrease in enthalpy is a contributory factor for spontaneity.
1) Both the statements are TRUE and Statement-2 is the correct explanation of
Statement-1
2) Both the statements are TRUE and Statement-2 is NOT the correct explanation of
Statement-1
3) Statement-1 is TRUE and Statement-2 is FALSE
4) Statement-1 is FALSE and Statement-2 is TRUE
33. Study the following thermochemical equations
A  B; H  100 kcal
B  C ; H  80 kcal
The correct order of enthalpies of formation of A, B and C is
1) A  B  C 2) A  C  B 3) C  A  B 4) B  C  A
34. Statement-1: Air quickly leaks out of balloon and becomes cooler.
Statement-2: The leaking air undergoes adiabatic expansion.
1) Both the statements are TRUE and Statement-2 is the correct explanation of
Statement-1
2) Both the statements are TRUE and Statement-2 is NOT the correct explanation of
Statement-1
3) Statement-1 is TRUE and Statement-2 is FALSE
4) Statement-1 is FALSE and Statement-2 is TRUE

Sec: Jr.Super60_STERLING BT Page 11


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
35. Enthalpies of combustion of CH 4 , C2 H 4 and C2 H 6 are 890, 1411 and 1560 kJ/mole,

respectively. Which has the highest fuel value (heat produced per gram of the fuel)?

1) CH 4 2) C2 H6 3) C2 H 4 4) All are same

36. Benzene burns in oxygen according to the following reactions.

15
C6 H 6 (l )  O ( g )  3H 2O(l )  6CO2 ( g )
2 2

If the standard enthalpies of formation of C6 H 6 (l ), H 2O(l ) and CO2 are 11.7, 68.1 and

94 kcal/mole, respectively, the amount of heat that will liberate by burning 780 g of

benzene is

1) 7800 kcal 2) 780 kcal 3) 78 kcal 4) 608.4 kcal

37. Enthalpy of neutralization of oxalic acid is 25.4 kcal/mol using strong base NaOH .
Enthalpy change for the process H 2C2O4 (aq )  2 H  (aq )  C2O42 (aq) is about
1) 2.0 kcal 2) 11.7 kcal 3) 1.0 kcal 4) 4.0 kcal
38. Statement-1: The heat absorbed during the isothermal expansion of an ideal gas against
vacuum is zero.
Statement-2: The volume occupied by the molecules of an ideal gas is zero.
1) Both the statements are TRUE and Statement-2 is the correct explanation of
Statement-1
2) Both the statements are TRUE and Statement-2 is NOT the correct explanation of
Statement-1
3) Statement-1is TRUE and Statement-2 is FALSE
4) Statement-1 is FALSE and Statement-2 is TRUE

Sec: Jr.Super60_STERLING BT Page 12


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
39. With what minimum pressure (in kPa), a given volume of an ideal gas (C p ,m  7 / 2 R ),

originally at 400 K and 100 kPa pressure can be compressed irreversibly adiabatically in
order to raise its temperature to 600 K:
1) 362.5 kPa 2) 275 kPa 3) 437.5 kPa 4) 550 kPa
40. Based on the following thermochemical equations,
H 2O( g )  C ( s)  CO( g )  H 2 ( g ) : H  131 kJ

CO ( g )  1 O2 ( g )  CO2 ( g ) : H  282 kJ
2

H 2 ( g )  1 O2 ( g )  H 2O ( g ) : H  242 kJ
2

C ( s)  O2 ( g )  CO2 ( g ) : H  X kJ
1)  393 kJ 2)  655 kJ 3) +393 kJ 4) +655 kJ
41. Enthalpies of solution of BaCl2 ( s) and BaCl2  2 H 2O(s) are 20.6 kJ/mol and
8.8 kJ/mol, respectively. H Hydration of BaCl2 ( s) to BaCl2  2 H 2O( s) is
1) 29.4 kJ 2) 11.8 kJ 3) 29.6 kJ 4) 11.8 kJ
42. For the following reaction, C6 H12O6 ( s)  6O2 ( g )  6CO2 ( g )  6 H 2O(l ) which of the

following expression is correct?

1) H reaction  6 f H (CO2 , g )  6 f H ( H 2O, l )  6 f H (C6 H12O6 , s )

2) Greaction  6 f G(CO2 , g )  6 f G ( H 2O, l )  6 f G(C6 H12O6 , s )

3) S reaction  6S (CO2 , g )  6S ( H 2O, l )  6S (C6 H12O6 , s)

4) S reaction  6S (CO2 , g )  6S ( H 2O, l )  S (C6 H12O6 , s)  6S (O2 , g )

43. Heat absorbed in the reaction H 2 ( g )  Cl2 ( g )  2 HCl ( g ) is 182 kJ. Bond energies of
H  H  430 kJ/mole and Cl  Cl  242 kJ/mole . The H  Cl bond energy is
1) 763 kJ/mole 2) 245 kJ/mole 3) 336 kJ/mole 4) 154 kJ/mole

Sec: Jr.Super60_STERLING BT Page 13


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
44. The enthalpy of atomization of PH 3 ( g ) is 954 kJ/mol and that of P2 H 4 is
1.488 kJ/mole . The bond energy of the P-P bond is
1) 318 kJ/mol 2) 372 kJ/mol 3) 216 kJ/mol 4) 534 kJ/mol
45. Statement-1: There is a natural asymmetry between converting work to heat and
converting heat to work
Statement-2: No process is possible in which the sole result is absorption of heat from a
reservoir and its complete conversion in to work
1) Both the statements are TRUE and Statement-2 is the correct explanation of
Statement-1
2) Both the statements are TRUE and Statement-2 is NOT the correct explanation of
Statement-1
3) Statement-1 is TRUE and Statement-2 is FALSE
4) Statement-1 is FALSE and Statement-2 is TRUE
46. Statement-1: ∆S, ∆H and ∆G are zero for cyclic process
Statement-2: Free energy, entropy and internal energy are state functions
1) Both the statements are TRUE and Statement-2 is the correct explanation of
Statement-1
2) Both the statements are TRUE and Statement-2 is NOT the correct explanation of
Statement-1
3) Statement-1 is TRUE and Statement-2 is FALSE
4) Statement-1 is FALSE and Statement-2 is TRUE
47. Out of molar entropy (I), specific volume (II), heat capacity (III), volume (IV), extensive
properties are:
1) I, II 2) I, II, IV 3) II, III 4) III, IV
48. A system undergoes a process in which E  300 J while absorbing 400 J of heat
energy and undergoing an expansion against 0.5 bar. What is the change of the volume
(in L)?
1) 4 2) 5 3) 2 4) 3

Sec: Jr.Super60_STERLING BT Page 14


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
49. If w1 , w2 , w3 and w4 for an ideal gas are magnitude of work done in isothermal, adiabatic,
isobaric and isochoric reversible expansion processes, the correct order will be:
1) w1  w2  w3  w4 2) w3  w2  w1  w4
3) w3  w2  w4  w1 4) w3  w1  w2  w4
50. 2 mole of an ideal gas at 27C expands isothermally and reversibly from a volume of 4
litre to 40 litre. The work done (in kJ) by the gas is
1) w  28.72 kJ 2) w  11.488 kJ
3) w  5.736 kJ 4) w  4.988 kJ
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
51. 6 kJ heat is provided to a system as well as work equivalent to 2 kJ is done on the

system. The total change in internal energy during these operations in kJ is _____

52. If G and S for the reaction:


A( g )  B( g )  P( g ) at 300 K are  600 cal and  10 cal/K. The E for the reaction in

kcal is  y, the value of y is _____ ( R  2 cal K 1mol1 )


53. A perfect gas undergoes a reversible adiabatic expansion from (300 K, 200 atm) to (90 K,
10 atm), the atomicity of gas is _____
54. A reaction becomes spontaneous only at 500 K. If H at 500 K is 3.0 kJ, the change in

entropy at 500 K in JK 1mol1 is:


55. A certain amount of gas  P  5 atm, V  2l , T  500 K  in state A is compressed to state

B  P  2 atm, T  100 K,V  ?  . The final volume of state in litre is _____


56. In an adiabatic expansion of air the volume increases by 5%. The change in % of pressure
is

Sec: Jr.Super60_STERLING BT Page 15


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
57. The heat required in calories to change 10 g ice at 0C to steam at 100C ? Latent heat of
fusion and vaporization for H 2O are 80 cal / g and 540 cal / g respectively. Specific heat
of water is 1 cal / g.
58. 10 moles of an ideal gas confined to a volume of 10 L is released into atmosphere at 300
K where the pressure is 1 bar. The work done by the gas in L bar is:
( R  0.083 L bar K 1mol1 )

59. Determine the standard entropy change in JK 1mol1 for the reaction given below:
2 H 2 ( g )  O2 ( g )  2 H 2O(l ) at 300 K. If standard entropies of

H 2 ( g ), O2 ( g ) and H 2O (l ) are 126,201 and 68.0 JK 1mol 1 respectively


1
60. For the reaction, CO( g )  O2 ( g )  CO2 ( g ) at 300 K. Calculate the standard Gibbs free
2
energy change is  X , when the standard Gibbs energies of formation for
CO2 and CO are  394 and  137 kJ mol 1 , respectively, the value of X is____

Sec: Jr.Super60_STERLING BT Page 16


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

 1 
61. Statement-1: If sin x  cos x   y   , x  [0,  ], then x  , y  1
 y 4

Statement-2: AM  GM

1) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for


Statement-1
2) Statement-1 is True, Statement-2 is True; Statement-2 is not a correct explanation for
Statement-1
3) Statement-1 is True, Statement-2 is False
4) Statement-1 is False, Statement-2 is True
  x
62. If x   ,   then 4cos 2     4sin 4 x  sin 2 2 x 
2   4 2
1) 2 2) 2  4 cos x 3) 2  4 cos x 4) 2  4sin x
63. If  ,  ,  ,  are the smallest positive angles in ascending order of magnitude which have
their sines equal to the positive quantity K the value of
       
4sin    3sin    2sin    sin   
2 2 2 2

1) 2 1  K 2) 2 1  K 3) 2 K 4) K 1
sin x sin 3x sin 32 x sin 3n1 x  
64. If f n  x    2
 3
 ......  n
then f 2    f 3   
cos3x cos3 x cos3 x cos 3 x 4 4
1) 0 2) 1 3) -1 4) 2
65. The period of the function on f  x    6 x  7  cos  x  6 x where . denotes the greatest
integer function is
1) 3 2) 2 3) 2 4) 

Sec: Jr.Super60_STERLING BT Page 17


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
66. Statement I: Let f :[0,3]  [1,13] is defined by f ( x)  x 2  x  1, then inverse is
1  4 x  3
f 1 ( x) 
2
Statement II: Many one function is not invertible.

1) Both Statement I and Statement II are correct and Statement II is the correct
explanation of Statement I
2) Both Statement I and Statement II are correct and Statement II is not the correct
explanation of Statement I
3) Statement I is correct but Statement II is incorrect
4) Statement II is correct but Statement I is incorrect
x
ex  e
67. Let f be a real valued function defined by f ( x )  x x
, then range of f is
e e

 1  1
1)  0, 2  2) [0, 1] 3) [0, 1) 4) 0, 
   2
 x    x  
68. The fundamental period of the function f ( x)  4cos 4    2cos   is equal to
 4  2
2 2
 
1)  3 2) 4 2 3) 3 2 4) 2 3

 2 tan x  1  cos 2 x   sec x  2 tan x 


2
1
69. If f   then f   
 1  tan x 
2
2  3
1 4 2
1) 2) 3) 4) 1
3 3 3
cos x
70. f ( x)  where x is not integral multiple of  and . denotes G.I.F, is
x 1
    2
1) An odd function 2) an even function
3) Neither odd nor even 4) can’t be determined

Sec: Jr.Super60_STERLING BT Page 18


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
71. The range of the function f ( x)  | sin x |  | cos x | where . denotes G.I.F, is
1) {1} 2) {2,3} 3)  4) {4,5}

72. If the equation x3  bx 2  cx  1  0  b  c  has only one root  then the value of

2 tan 1  cos ec   tan 1  2sin  sec 2   is

 
1)  2) 3) 4) 
2 2
1
 1  x  3 x  1 
2  7
If f ( x)   {x} tan  2   3  x  where . denotes G.I.F and {.} denotes
7
73.
 x  3 x  5
   
fractional part function, then the value of f 1  50   f  50   f  f 100   , is

1) 0 2) 25 3) 50 4) 100
n
 1
74. The value of lim  cot 1  2r 1  r  is equal to
n
r 1  2 

1) tan 1 2 2) cot 1 2 3) sec 1 2 4) cos 1 2

1 1

1  x 3  3x 2  
75. Statement 1: If  x  1, then cos x  sin    is equal to 
2  2 2  6

   1 1 
Statement 2: sin 1 2 x 1  x 2  2sin 1 x, if x    ,
 2 2

1) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for


Statement-1
2) Statement-1 is True, Statement-2 is True; Statement-2 is not a correct explanation for
Statement-1
3) Statement-1 is True, Statement-2 is False
4) Statement-1 is False, Statement-2 is True

Sec: Jr.Super60_STERLING BT Page 19


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
The function f : R  R defined by f ( x)  2x  2 is
x
76.
1) one-one and onto 2) many-one and onto
3) one-one and into 4) many-one and into
77. If 32tan8   2cos2   3cos and 3cos2  1, then the most general values of  are
 2  
1) n  2) 2n  3) n  4) n 
3 3 3 3

78.  
If cos sin   sin 2   sin 2   k , then the value of k is

1) 1  cos 2  2) 1  sin 2  3) 2  sin 2  4) 2  cos 2 


79. Total number of solutions of sin x tan 4 x  cos x in x   0,  is/are
1) 7 2) 6 3) 5 4) 4
80. The number of ordered triplets (A, B, C) satisfying the equation

 2sin 2
A  2 cos
2
B
e C
 e2C  eC  1 where A, B   0,2  and C  R, is

1) 2 2) 3 3) 4 4) 6
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
tan 3 x  tan 2 x
81. Number of values of x   0,4  which satisfy the equation  1, is
1  tan 3x tan 2 x
82. If the value of
 
27sin 3 9  9sin 3 27  3sin 3 81  sin 3 243   sin  , and   R ,    0,  , then the
 2
value of    6  (where [.] denotes G.I.F)

 x  2
83. The domain of f ( x )  is ( , a )  b, c    4,   , a  b  c then the value of
 x  3
a  b  c is  x  denotes G.I.F 

Sec: Jr.Super60_STERLING BT Page 20


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.
2010 x  165 2010
84. If f ( x )  , x  0 and x  then the least value of f  f  x    f  f  4 x  
165 x  2010 165
is _____

85. If a    1, b    2 and af ( x)   f 1  x   bx   x , x  0, then the value of the


expression
 x  is _____
f ( x)  f 1
x 1
x
86. Let m be the number of solutions of sin 2 x  cos 2 x  cos x  1  0 in
    7  1  7 
x   0,  and n  sin  tan 1  tan   cos  cos   , then find the value of m  n
 2   6   3 
87. Find the number of ordered pairs (a, b) where a, b  R and satisfying

 1   1 
a 2  3a  3  2
b2  2b  1  b3
 2a    2  b 
2
1
sgn(cot 1 a) sgn 1  b 

 Note: k  denotes greatest integer less than or equal to k and 


Note:  
sgn(k ) denotes signum function of k . 
 x2  b
88. If the range of the function f ( x )  cot 1  2  is  a, b , then find the value of
 x 1 a
89. If the largest possible value of x such that 0  x   satisfying the equation
2sin 2 x  1 a
 2 is . Find a  b (Where a , b are co-prime )
cos x  sin x b
 cos 61  cos 62   cos119 
90. The value of 1  1        1  
 cos1  cos 2   cos59 

Sec: Jr.Super60_STERLING BT Page 21


Sri ChaitanyaIIT Academy, India 10-09-2023_Jr.Super60_STERLING BT_Jee-Main_CTM-01_Q.P.

Sec: Jr.Super60_STERLING BT Page 22

You might also like