Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Jr.C-120 Jee Main Date: 23-09-2023
Time: 09.30Am to 12.30Noon WTM-14 Max. Marks: 300

23-09-2023_Jr.C-120 Jee-Mains WTM-14_Syllabus

PHYSICS : Rotatory Dynamics up to Concpet of rolling and problems on uniform

rolling motion, Problems on above concepects +30% Cumulative

CHEMISTRY : Thermodynamics & Thermochemistry upto Enthalpy of solution,

hydration + 30% Cummulative, GOC upto Reactive intermediates
(Carbocations, Carbanions, Free radicals, Carbenes, nitrenes) + 30%
Cummulative

MATHEMATICS : Limits up to Existence of limits (L.H.L and R.H.L), L'Hospital rule, Series
Expansions + 30 % Cumulative
Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. The angular position of a particle on the rim of a rotating wheel is given by   4t  3t 2  t 3 ,
where  is in radian and t is in seconds
(a) What is the angular velocity at t  2s ?
(b) What is average angular acceleration for the time interval that begins at t  2s and ends
at t  4s ?
1) 4 rad / s, 12 rad / s 2 2) 6 rad / s, 14 rad / s 2
3) 8 rad / s, 6 rad / s 2 4) 10 rad / s, 12 rad / s 2
2. Three particles, each of mass M are situated at the vertices of an equilateral triangle ABC
of side L. Find moment of inertia of system about an axis passing through the centroid
and perpendicular to plane of the triangle ABC.
A
M

M M
B L C
1) ML2 2) 2ML2 3) 4ML2 4) 3ML2
3. A ring of mass M  10kg and radius R  2m is taken as shown in the figure. Calculate the
MOI of ring about the diametric axis.
B

A o A1

B1
1) 25 kg m 2 2) 30 kg m2 3) 40 kg m 2 4) 20 kg m 2
4. The moment of inertia of a uniform thin rod of length L and mass M about an axis passing
through a point at a distance of L / 3 from one of it’s ends and perpendicular to the rod is
7 ML2 2 ML2 ML2
1) 2) ML 3) 4)
48 9 3

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
5. A thin wire of length L and uniform mass density  is bent into a circular loop with
centre at O as shown. The moment of inertia of the loop about an axis XY is
X Y

 L3  L3 5 L3 3 L3
1) 2) 3) 4)
8 2 16 2 8 2 8 2
6. A cubical block of side 30 cm is moving with velocity 2ms 1 on a smooth horizontal
surface. The surface has a bump at a point O as shown in figure. The angular velocity (in
rad/s) of the block immediately after it hits the bump is
a

o
1) 13.3 2) 5.0 3) 9.4 4) 6.7
7. A hot solid sphere is rotating about a diameter at an angular velocity  . If it cools so that
1
its radius reduces toof its original value, its angular velocity becomes
n

1)  2)  n 3) 2 4)  n 2
n
8. The moment of inertia of a body about a given axis is 1.2kgm 2 .Initially the body is at rest.
In order to produce a rotational kinetic energy of 1500 joule, an angular acceleration of
25 rad / s 2 must be applied about that axis for a duration of
1) 4s 2) 2s 3) 8s 4) 10s
9. A uniform rod of length l is free to rotate about a fixed horizontal axis through O. The
rod begins rotating from rest from its unstable equilibrium position. When it is turned
through an angle  , its angular velocity  is given as
o


6g 6g  6g  6g
1) sin  2) sin 3) cos 4) cos 
l l 2 l 2 l

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
2
10. A wheel having moment of inertia 2 kg m is rotating about its geometrical axis at the rate
of 60 rpm about its axis. The average torque which can stop the wheel’s rotation in one
minute would be
 2  
1) Nm 2) Nm 3) Nm 4) Nm
18 15 12 15
11. A block of mass 1kg slides with velocity 6 m/s on a frictionless horizontal surface and
collides with a uniform vertical rod and sticks to it as shown in fig. The rod is pivoted
about O and swings as a result of the collision making angle  before momentarily
coming to rest. If the rod has mass M  2kg and a length l  1m , the value of  is
approximately  g  10ms 2 

o
M ,l

m 
m
V m

1) 630 2) 550 3) 690 4) 490

12. A false balance is such that the beam remains horizontal when the pans are empty .An
object weighs W1 when placed in one pan and W2 when placed in the other pans. The true
weight of the object is
W1  W2 2 2 W12  W22
1) 2) W1W2 3) W1  W2 4)
2 2
13. A uniform ladder of length 5 m is placed against the wall as shown in the figure. If
coefficient of friction is the same for both the walls, what is the minimum value of
for it not to slip

1 1 1 1
1)   2)   3)   4)  
2 4 3 5
Sec: Jr.C-120 Page 4
Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P

14. If the velocity of a rotating body of mass 50 kg is given by v  3i  4j  5
k and radius

vector r  2i  3j  4
k , then its angular momentum is .
1) 50i  50j  50k 2) 50i  100j  50
k
3) 50i  50j  100k 4) 50i  100j  50k
15. A carpet of mass m made of an extensible material, rolled along its length in the form of a
cylinder of radius R and kept on a rough floor. If the carpet is unrolled without sliding to a
radius R / 4 , the decrease in potential energy is
7 63 15 mgR
1) mgR 2) mgR 3) mgR 4)
8 64 16 2
16. As shown in the fig, a bob of mass m is tied by a massless string whose other end portion
is wound on a fly wheel (disc) of radius r and mass m. The fly wheel can rotate about its
axis. When released from rest the bob starts falling vertically. When it has covered a
distance of h, the angular speed of the wheel will be

1 2 gh 3 1 4 gh 3
1) 2) r 3) 4) r
r 3 4 gh r 3 2 gh
17. Two identical balls A and B are released from the top positions of fixed length inclined
plane as shown in fig. They collide elastically on a horizontal portion MN. The ratio of
heights attained by A and B after collision will be (neglect friction)

1) 1 : 4 2) 2 : 1 3) 4 : 13 4) 2 : 5

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
kx 2
18. The centre of mass of a non-uniform rod of length L whose mass per unit length   ,
L
where k is a constant and x is the distance from one end is
3L L L 2L
1) 2) 3) 4)
4 3 4 3
19. A ball of mass m moving with a speed ‘2V’ strikes a heavy wall elastically, which is
moving with a velocity ‘V’ in the same direction. The work done by the heavy wall on
the ball is
1
1) mv 2 2) mv 2 3) 2mv 2 4) none
2
20. A uniform rod AB is suspended from a point X, at a variable distance x from A, as shown.
To make the rod horizontal, a mass m is suspended from its end A. A set of  m, x  values
are recorded. The appropriate set of variables that give a straight line is (when plotted)

1 1
1) m, 2) m, 3) m, x 4) m, x 2
x x2
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example
i,e. If answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. The minimum speed of bucket full of water whirled in a vertical circle of radius 10m at
the highest point so that the water may not fall is  g  10ms 2  ________  ms 1 

22. The coefficient of friction between 4kg and 5kg blocks is 0.2 and between 5kg block and
ground is 0.1 respectively. The minimum force required for slipping between 4kg and 5kg
block is n  3 N. The value of n is

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
23. A block of mass 5kg is at rest on a smooth horizontal surface water coming out of a pipe
horizontally at rate of 2kgs 1 , hits the block with a velocity of 6ms 1 . The initial
n
acceleration of the block is ms 2 . The value of n is
10

3
24. The speed of a projectile at its maximum height is times its initial speed. If the range
2

of the projectile is p times the maximum height attained by it, then p  n 3 value of n is
_____

25. A freely falling body starting from rest travels _____% of total distance in 5th second
(which is last second)  g  10ms 2 

26. A thin rod of mass 6m and length 6L is bent into a regular hexagon. The moment of
inertia of the hexagon about a normal axis to its plane and through centre of system is
_____ mL2

27. A shell of mass ‘m’ is projected with a velocity ‘v’ at angle 600 to horizontal. When it
reaches the maximum height, its angular momentum with respect to point of projection is
3mv 3
. The value of x is ___
xg

28. A shaft rotating at 3000 rpm is transmitting a power of 3.14kW. The magnitude of torque
is _____________Nm (take  =3.14 )

29. Two racing cars of masses m and 4m are moving in circles of radii r and 2r respectively.
If their speeds are such that each makes a complete circle in the same time, then the ratio
of the angular speeds of the first car to the second car is x : 1 . The value of x is

30. Three identical rods, each of length L, are joined to form a rigid equilateral triangle. Its
radius of gyration about an axis passing through a corner and perpendicular to the triangle
L
is . The value of n is
n
Sec: Jr.C-120 Page 7
Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
31. The heat of formation of NH 3  g  is 46KJmol 1 . The H  inKJmol 1  of the reaction,
2 NH 3  g   N 2  g   3H 2  g  is
1) 46 2) -46 3) 92 4) -92
32. For the reaction : FeCO3  s   FeO  s   CO2  g  ; H  82.8KJ at 250 C , what is  E or U  at
250 C ?
1) 82.8kj 2) 80.32kj 3) -2394.77kj 4) 85.28kj
33. In which of the following sets, all the properties belong to same category (all extensive or
all intensive)
1) Mass, volume, specific heat 2) Temperature, pressure, volume
3) Heat capacity, density, entropy 4) enthalpy, internal energy, volume
34. In the Isothermal expansion of an ideal gas
(i) T  0 (ii) E  0 (iii) w   q
1) (i) and (ii) only 2) (ii) and (iii) only 3) (i) and (iii) only 4) (i), (ii), and
(iii)
35. In a process a system does 140J of work on the surroundings and only 40J of heat is
added to the system, hence change in internal energy is
1) 180J 2) -180J 3) -23.92cal 4) -120J
dp
36. For a reversible adiabatic expansion of a perfect gas , is
p
dV dV dV dV
1) 2)  . 3)  . 4)  2 .
V V V V
37. 16g oxygen at 00 C and 10 atm is subjected to reversible adiabatic expansion to a pressure
cp
of 1 atm. Calculate the work done in litre atmosphere  1.4
cv
1)-13.5 2) -23.5 3)-33.5 4)-54
38. 1L of NH 3 at 27 c is expanded adiabatically to x L and final temperature is 1230 c , what
0

is the value of x ? (γ=1.33)

1) 6 2) 8 3) 10 4) 16
39. The bond dissociation energies of gaseous H 2 , Cl2 , HCl are 104, 58 and 103 k cal / mole
respectively. If magnitude of heat of formation of HCl  5.5 x, x  ?
1) 4 2) 10 3) 14 4) 6

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
40. Enthalpies of solution of BaCl2(s) and BaCl2⋅2H2O(s) are −20.6 kJ/mol and
8.8 kJ/mol, respectively. ΔH Hydration of BaCl2(s) to BaCl2⋅2H2O(s) is
1) −29.4 kJ 2) −11.8 kJ 3) 29.6 kJ 4) 11.8 kJ
41. Heat of combustion of C2 H 4 is -337 kcal. If 11.2lit O2 is used at STP, in the combustion,
calculate heat liberated in K cal
1) 28 2) 38 3) 56 4) 66
42. Which of the following options is the correct order of relative stabilities of cations, I, II,
and III as written below

CH 2 CH 3
 
H 3C  C  CH 2
 CH 3
(I) (II) H 2C  CH  CH 2  CH  CH 3 (III)

1) I  II  III 2) II  III  I 3) III  I  II 4) I  III  II

43. What is the decreasing order of stability (most stable  least stable) of the following
carbocations?

   

  
1 2 3 4 5
1) 3  2  1  4  5 2) 3  2  5  4  1 3) 1  4  2  5  3 4) 3  1  4  2  5

44. Which of the following phenols has the largest pka value
Cl O2 N OH
OH
1) 2)

H 3C OH N C OH
3) 4)

45. Carbon – Carbon double bond length will be maximum in which of the following
compounds?
1) CH 3  CH  CH 2 2) CH 3  CH  CH  CH 3
CH 3  C  C  CH3

CH 3 CH 3
3) 4) CH 2  CH 2

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
46. Total number of   hydrogen in given compound is :

1) 4 2) 5 3) 6 4) 7
47. The most stable alkene among the following is

1) 2) 3) 4)
48. Which of the following carbanion is more stable
  
Cl  CH Cl  C  Cl

1) CH 3  2) Cl  CH 2   3) Cl 4) Cl

49. Which of the following species is paramagnetic

1) A carbonium ion 2) A free radical 3) A carbanion 4) benzyne
50. Which of the following is an ambident nucleophile?
HSO NO2
I) 3
II) CN III)
1) I and II only 2) II and III only 3) I and III only 4) I, II, and III
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
51. 10g of argon gas is compressed isothermally and reversibly at a temperature of 27 c C from
20lt to 10lt. calculate work done  R  2.0cal k 1mol 1 , Ar  40 

52. One mole of an ideal gas is heated at constant pressure from o0c to 1000 c . Calculate work
done  R  2.0 calk 1mol 1  in  x cal. What is ' x '?

53. The standard heats of formation for CCl4  g  , H 2O  g  , CO2  g  and

HCl are  25.5,  57.8,  94.1 and 22.1kcal respectively. Calculate H  298 for the reaction, in

 xkcal what is ' x '? CCl4  g   2 H 2O  g   CO2  g   4 HCl  g 

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
54. Two moles of an ideal gas is expanded spontaneously into a vacuum. Calculate the work
done in J
55. Which of the following unit conversions are correct
1. 1lt  atm  101J 2. 1lt atm  110 J
3. 1KJ  103 J 4.1cal  4.18 J
7
5. 1erg 10 J 6. 1J  0.24cal
7.1ev / atom  96.47 KJ / mole 8. 1KJ / mole  96.47ev / atom

56. How many of following functional groups show -M effect

 
(I)  NH 3 (II) COOH (III) PH 3 (IV) CH  CH 3 2 (V) CN (VI)
 SO3 H

57. Number of hyper conjugate structures possible for

58. Find the number of correct statement(S)

 
(a) CH 3O CH 2 is more stable than CH 3 CH 2
 
(b) Me2 CH is more stable than CH 3CH 2 CH 2
 
(c) CH 2  CH  CH 2 is more stable than CH 3CH 2 CH 2
 
(d) CH 2  CH is more stable than CH 3 CH 2

59. Total number of groups which can have higher -I effect than -F
 NR3 ,  SR2  ,  NO2 ,  SO2 R , CN , OR , OH , Cl , COOH

60. How many of the following groups/atoms are considered as  I group (s)
 
CH 3 ,  O ,  COO  ,  Cl , OH

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1
ex
1  x  x  e 
61. lim 2  ______
x0 sin 2 x
11e 11e 11e
1) 2) 3) 4) 0
24 24 12
 x3 
2 x x
cos x  cos x  e cos x  e   
62. The integral value of n for which lim  2  is finite and non –
n
x  x
zero is
1) 2 2) 4 3) 5 4) 6
63. Let  a and  a be the roots of the equation
 3

1  a  1 x2    
1  a 1 x  6

1  a  1  0 where a  1 , then lim   a  and lim   a  are ____
a0 a 0
5 1 7 1 9
1)  and 1 2)  and  1 3)  and 4)  and 3
2 2 2 2 2

 k2 k2  1
64. What is the value(s) of k for the existence of lim sec   
x 1
 log x x  1 

1)  2,   2)  ,  2    2,   3)  ,  3    3,   4)  3,  
2
65. The number of integral values of a for which lim
x a
 x    x 2  exists( where  x is greatest
integer less than or equal to x )
1) 1 2) 0 3) 2 4) Infinite
66. If f is a periodic function with period T and  .  denotes the greatest integer function then

 f  x  T  f  x T     22 f  x  2T  f  x  2T    32 f  x  3T  f  x 3T         n 2 f  x  nT  f  x  nT  
lim     
3
    ____
n  n
f  x f  x f  x f  x
f  x f  x f  x f  x
1) 2) 3) 2 4)
6 4 3 3

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
67. Let
f  x    x , x  z
 x  1, x  z
 where . denotes the greatest int eger function 
g  x   sin x  cos x, x  0
 1 , x0
lim f  g  x    ____
x0

1) 0 2) 1 3) -1 4) does not exist

sin 1 1   x  cos 1 1   x 
68. Let f  x   where x denote the fractional part of x then
2  x 1   x


1) lim f  x   0

2) lim f  x  

x 0 x 0 2 2

3) lim f  x  

4) lim f  x   0

x 0 2 2 x 0

a sin x  bx  cx 2  x3
69. If lim exists and is finite then a  b  c  ____
x 0 2 x 2 log e 1  x   2 x3  x 4

1) 6 2) 12 3) 24 4) 36
ln sin xcos x  1
70. For a function f  x   where  .  denotes fractional part function, then
sin xcos x
   
1) f  0    f   2) f  0    f   3) lim f  x  1 4) lim f  x   1
 2   2  x 0 x
2

x2
a  a2  x2 
71. Let L  lim 4 , a  0 If L is finite, then L 
x 0 x4
1 1 1
1) 2) 3) 1 4)
64 34 16

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Sri Chaitanya IIT Academy 23--09-2023_Jr. C-120_Jee-Mains_ WTM-14_Q.P
1  cos x.cos 2 x.cos 3 x
72. lim 
x 0 sin 2 2 x
3 5 7 9
1) 2) 3) 4)
2 2 4 2

y y  xx
73. lim 
yx yx

1) x y x 1 2) y x y 1 3) xy 4) x x 1  log x 

sin x 4  x 4 cos x 4  x 20
74. lim 
x 0
 4
x 4 e2 x  1  2 x 4 
1 1 1 1
1) 2) 3) 4)
3 4 6 2

  1  cosm x  
75. If lim sin   exists where is n  N , then the sum of all possible values of n, is
x 0  xn 
 

1) 3 2) 2 3) 1 4) 4
5
x 5   sin x 
76. lim 
x 0 x7
1 5 7
1) 2) 3) 4) 0
6 6 6

2  cos x  sin x
77. lim 2

x

4
 4x   
1 1 1 1
1) 2) 3) 4)
16 2 32 2 16 8

78. If the mapping f  x   ax  b, a  0 maps  1, 1 onto  0, 2 then cot  cot 1 7  cot 1 8  cot 1 18  

1) f  1 2) f  0  3) f 1  1 4) f 1  1

 3  3  3
79. cot 1  12    cot 1  2 2    cot 1  32       is
 4  4  4

1) 2) tan 1 2 3) tan 1 3 4) tan 1 4
4

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80. The value of sin  cos 2   cos  sin 2   tan  cot 4   cot 1  tan 4   sec1  cos ec6   cos ec 1  sec 6 
1 1 1

1) 0 2) 3 3) 8  3 4) 5  16

(NUMERICAL VALUE TYPE)

Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If
answer is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
2 2 4
81. If f  x    cos 1 x    sin 1 x  the sum of all the possible integral values of f  x  is
2


82. Number of solutions of the equation sin 1 1  x   4sin 1 x  , is equal to
2

 n  2r  1 
83. If tan   tan 1     961 then the value of n is equal to
 r 1   r 2  r  1 r 2  r  1  2r 3  
  

 x a
84. If the value of lim  3 x 3  4 x 2  x 2   is where a and b are co-prime then the value of
x 
 3 b

a  b is equal to
1

85. If lim
 4 x  1 3  a  bx exist and is equal to 1 , then ab=
x 0 x 3
86. Let f  x   2 p  2 x  5  q 3x  7  ,If lim f  x  exists, then 2 p  q  (where  .  denote greatest
x 1

integer function)
sin  ax   sin x  x
87. If lim exists and finite then a 
x0 x3

8 x2 x2 x2 x2  1
88. If L  lim 1  cos  cos  cos , cos  then
x 0 x 8 2 4 2 4 L


x3
89. If lim  1, a  0 then a  b 
x0 a  x  bx  sin x 

 20 k 
  x   20
90. lim  k 1  
x 1 x 1

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