SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr.

C-120 __Jee-Mains_WTM-10_KEY & Sol’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur – Hyderabad
Sec: Jr. C-120 Jee Main Date: 26-08-23
Time: 09.30Am to 12.30Noon WTM-10 Max. Marks: 300

KEY SHEET
PHYSICS
1) 2 2) 4 3) 2 4) 3 5) 3
6) 1 7) 2 8) 3 9) 2 10) 1
11) 4 12) 3 13) 2 14) 3 15) 1
16) 4 17) 1 18) 3 19) 3 20) 3
21) 1440 22) 2 23) 5 24) 30 25) 10
26) 3 27) 1 28) 3 29) 375 30) 50

CHEMISTRY
31) 4 32) 2 33) 4 34) 2 35) 1
36) 3 37) 2 38) 4 39) 2 40) 1
41) 1 42) 3 43) 2 44) 1 45) 3
46) 1 47) 2 48) 1 49) 3 50) 3
51) 4 52) 180 53) 5 54) 7 55) 4
56) 1 57) 4 58) 4 59) 1 60) 5

MATHEMATICS
61) 1 62) 1 63) 1 64) 2 65) 4
66) 4 67) 4 68) 2 69) 2 70) 1
71) 2 72) 3 73) 1 74) 3 75) 3
76) 2 77) 2 78) 2 79) 1 80) 1
81) 2 82) 3 83) 4 84) 2 85) 3
86) 0 87) 2 88) 5 89) 5 90) 1

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S

SOLUTIONS
PHYSICS
 g 2mgd
1. w  T .S where T-tension T  m  g  a  w  T .d  m  g   d 
 3 3

2. Area under F-S graph gives work done.

Force (N)

10

4 8 12

Displacement (m)

1 1 1
Area =80 J w  mv 2  mu 2 80   0.1 v 2  0 v  40ms 1
2 2 2

 h
3. wnet  K .E uv0 wg  wR  0 mg  h  s   R.S  0 R  mg 1  
 s

dx dx x1/ 2 k 2t 2
4. vk x k x  kdt x 1/ 2 dx  kdt   x 1/2 dx  k  dt   kt  2 x  kt , x 
dt x 1/ 2 4

2
k 2t 2 kt k 2t 1 1 1  k 2t  mk 4t 2
But v  k x  v  k vk  w  mv 2  mu 2  w  m    w 
4 2 2 2 2 2  2  8

l
5. Initial potential energy of all blocks U1  n  mg Final potential energy of all blocks
2

nl l l l l
U 2  nmg  n 2 mg Work done w  u2  u1  n 2 mg  n  mg w  mg n  n  1
2 2 2 2 2
2 2 2
2k p  k  p 100k  p 
6. k p  1   1       
k2  p2  125k  p2  225 k  p2 
k
100

10  p  2 p 3p  p  p1 
    p2   2  100  50%
15  p2  3 p2 2  p1 

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S

U1 1  cos 1 U1 1  cos 300

7. U  mgh 1  cos   U  1  cos   
U 2 1  cos  2
 
U 2 1  cos 600
 U1 : U 2  2  3 :1  
4h 4h 4
8. T .E  mgh P.E at a height is U  mg  mgh K .E  T .E  P.E
5 5 5

4mgh mgh mgh 4mgh

K  mgh   K :U  : K : U  1: 4
5 5 5 5

dm
9. P  v2  52  12  25 12 P  300 w
dt

1
10. P  mg sin  v P  6000  10   5 P  1500w  15kw
20

mv 2 2  v2
11. T  mg  140.6  2  9.8  v 2  121 v  11ms 1
r 2

12. P.E  K .E at lowest point

1 2 1 5R 5D
mgh 
2
m  5 gR  gh  5 gR
2
h
2
h
4

m1 x1  m2 x2  m3 x3  m4 x4 m1 y1  m2 y2  m3 y3  m4 y4
13. xcm  , ycm 
m1  m2  m3  m4 m1  m2  m3  m4

m  0   m  a   m  a  b cos    m  b cos   m  0   m  0   m  b sin    m  b sin  

xcm  , ycm 
4m 4m

 a  b cos   b sin 
xcm    , ycm 
 2  2

1
1 0   2 1  3  
m1 x1  m2 x2  m3 x3 2 m1 y1  m2 y2  m3 y3
14. xcm  xcm  ycm 
m1  m2  m3 1 2  3 m1  m2  m3

 3
1 0   2  0   3  
 2 

1 2  3
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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S

3
ycm  cm
4

1 3
m3  3kg  , 
2 2 

m1  kg  0,0  m2  2kg 1,0

15. They meet at C.O.m 4 x  6  20  x  x  12m from 4kg.

20m
x
4kg  20  x  6kg

m m d m  r  l 0.003  0.005   0.006  d

16. d  2   2     2    100  4%
v r l d m  r  l 0.3  0.5   0.6  d
 
1  A.B 1  AB cos  1  cos  2sin  / 2 
2
17.     2
 tan 2  / 2 
1  A.B 1  AB cos  1  cos  2 cos  / 2 

1 2 1 1 2 3 3 1 2
18. 0.1  gt1 t1  sec 0.9  gt2 t2  sec t2  t1    sec
2 7 2 7 7 7 7

u0

10cm t
1

t2

80cm

    u
19. u  u cos  iˆ  u sin  ˆj v  u cos  iˆ   u sin   gt  ˆj u , v  0 , t 
g sin 

v2
20. tan     450
rg

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S

h l  l h  mg  vg
21. U1  mg U 2  mg w  U 2  U1  mg     l  h   l  h   1440kJ
2 2 2 2 2 2

1 2 1 1
22. k mv  Vv 2   1.2  103  1 4  2.4kJ
2 2 2

1 1 2
n mv2 360   m   600 
23. P 2  5400  2 m  5 gm
t 60

4 4 4
 x2 
24. w   Fdx w   5 xdx  5 xdx  5    30 J
2 2  2 2

25. 10ms 1 v  gr v  10ms 1

26. m p v p   m p  mb  vb vb  2ms 1

a b c
27. F Aa v b D c  MLT 2    L2   LT 1   ML3  on solving a  1, b  2, c  1

 
28. c 2  a 2  b 2  2ab cos    1200 a  b  a 2  b 2  2ab cos   3

2h 2  45
29. time taken by stone to reach water is t1    3sec
g 10

d 45
t  t1  t 2  3.12  3  t2  t2  0.12sec vsound    375ms 1
t2 0.12

30. mg  2nmu

CHEMISTRY
31. In iso electronic species atomic number increases atomic (or) ionic radii decreases.

Ionic radii order N 3  O 2  F 

10  5 5
32. O2  16  1  15 B.O    2.5
2 2

10  16 4
O2  16 B.O    2.0
2 2

10  7 3
O2  16  1  17 B.O    1.5
2 2

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S
10  8 2
O22  16  2  18 B.O    1.0
2 2

Bond order  Bond strength  Bond dissociation energy.

33. NH 3 , NH 2  NH 2 , NH 2OH hydroxyl amine do not contains ‘C’ so it can not give lassign’s test.

34.
1 2 3 4
CH 2  CH  CH  CH 3

CH 3
3-Methyl but 1-ene

Br
Br H 3C  CH  CH 2 CH 3  C  CH3
H 3  CH 2  CH
35. C3 H 6 Br2 Br Br Br Br

CH 2  CH 2  CH 2

Br Br

36. Energy order conformational isomerism in butane. Energy order : fully eclipsed
>eclipsed>Gauche>Anti.

37.

Cl Cl Cl
1 1 1
2 Cl 2 6 2
6 6

3 3
5 3 5 Cl 5
4 4 4
Cl
1,2 dicloro benzene 1,3 dicloro benzene 1,4 dicloro benzene

38.

NH 2

1. H 3C  CH 2  CH 2  CH 3  NH 2 2. H 3C  CH  CHCH 2  CH 3

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S

CH 3

3. H 3C  CH  CH 2  NH 2 4. H 3C  C  NH 2

CH 3 CH 3 5. CH 3  CH 2  CH 2  NHCH3

7. CH 3  CH 2  NH  CH3 CH 3
8. CH 3  CH 2  N
6. CH 3  CH 2  NH  CH 2  CH 3 CH 3 CH 3

1 and 2 positions 1 and 5,8 functional 5,6,7 metamers.

39.
OH

H OH

H H

In gauche configuration forms hydrogen bonding so it is more stable.

40.

CH 3
2 1
3
CH 3  N  C  CH 2  CH3

CH 3 CH 2  CH 3
4 5 3-methyl, N,N-methyl 3-pentamine

1 1 1 1 1 1 1 1
41. rSO2 : rO2 : rCH 4  : :    : :
M SO2 M O2 M CH 4 64 : 32 :16 4 : 2 :1 2 2 1

2 2 2
 : :  1: 2 : 2
2 2 1

V2 T2 V T 310  300
42.  , V2  1 2   310cm3  volume expelled =310-300
V1 T1 T1 300

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S

 10cm 3

Cav  CH 4  TCH 4 .M O2 TCH 4  34 300  16

43.  1  1  TCH 4   150 K
Cav  O2  TO2 .M CH 4 300 16 32

4 2
44. No. of moles of O2   0.125 No. of moles of H 2   1 Total no. of moles =
32 2
nRT 1.125  0.0821 273
1  0.125  1.125 P   25.215atm
v 1

45. Higher the P.P, lower is the solubility.

46. Pressure exerted by oxygen will be proportional to mole fraction of O2 .

w
32 1
 M.F. of O2  
w w 3

16 32

 KE  He THe
47. K .E T and    K .E  He   KE  H (same as that of H 2 molecules)
 KE  H2
TH 2 2

48. CH 4  OD  NF3  0.2 D  NH 3  1.47 D  H 2O  1.85 D

h h h 1 h
49. x.P  If x  P  P 2  P   But P  m.v
4 4 4 2 

1 h 1 h
 mv  v 
2  2m 

50. Due to lanthanide contraction.

51.

CH 2  CH 3 CH 3 CH 3 CH 3
CH 3

CH 3

CH 3

52.

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S

CH 3

H H

H H

CH 3

Anti conformation
dehydral angle is 1800

53.

CH 2 NH 2 NHCH 3 NH 2 NH 2 NH 2

CH 3

CH 3

CH 3

54.

2) H3C  CHCH 2  OH

CH 3
1) H 3C  CH 2  CH 2  CH 2  OH

CH 3
3) H C  C  OH OH
3

CH 3 4) H 3C  CH 2  CH  CH 3
5) H 3C  CH 2  CH 2  O  CH 3

6) H 3C  CH  O  CH 3

CH 3 7) H 3C  CH 2  O  CH 2  CH 3

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S

CH 3

CH 3  C  NH 2 10 
H 3C  CH  CH 2  NH 2 10 

CH 3 CH 3
55. H 3C  CH 2  CH 2  CH 2  NH 2 10 

CH 3  CH  CH 2  CH 3 10 

NH 2

p1 1 p1 v2 v2 1
56. If  , p1v1  p2 v2 (Acc to boyl’s law)   
p2 2 p2 v1 v1 2

v2 1 2
 v2   1lit
2lit 2 2

R
57. K  R  K  N A  6.023 10 23 1.380  10 23 j.mol 1k 1
NA

There are ‘4’ significant figures in each term. Hence significant figure on ‘R’ value should
be ‘4’.

rH 2 M HC 3 3 M AC 2 M HC
58.
rHC

M H2 1

2
Squaring on both sides 3 3  
2

2
 
M HC  3 3  2  9  3  2  54  Cn H 2 n  2 12  n   2n  2   54

56
14n  2  54 14n  56 n 4
14
2
59.  Fe x  H 2O 0 NO 1  SO42  x  0  1  2 x  1
 5 

M .wt 140
60. M.Wt= 2  v.d  70  2  140 x    5   C  0  12  16  28 
wt. of 'CO ' 28

MATHEMATICS
3  9  8 3  17
61. 3a 2  a 2  2  0 Or a 2  3a  2  0 Or a  
2 2
Therefore, there are two values of a.

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 SRI CHAITANYA IIT ACADEMY, INDIA 26-08-2023_ Jr. C-120 __Jee-Mains_WTM-10_KEY & Sol’S

62.  
Acute angle between the lines x 2  4 xy  y 2  0 is tan 1  2 4  1  / 1  1  tan 1  / 3 . The angle
x 2  y 2 xy
bisectors of x 2  4 xy  y 2  0 are given by 
11 2
Or x2  y 2  0 or x   y As x  y  0 is perpendicular to x  y  4 , then given triangle is
isosceles with vertical angle equal to  / 3 . Hence, it is an equilateral triangle.
63. 9 x 2  24 xy  16 y 2  12 x  16 y  12  0 Or  3x  4 y  2  3x  4 y  6   0
6   2  8
Hence, the distance between the lines is 
5 5
64. Let y  mx be a line common to the given pairs of lines. Then,
m2 m 1
am2  2m  1  0 and m 2  2 m  a  0 Or  2 
2 1  a  a  1 2 1  a 
a 1
Or m 2  1 and m  Or  a  1 2  4 Or a  1 or 3
2
But for a a  1 , the two pairs have both the lines common. So a  3 and the slope m of the
line common to both the pairs is 1.
Now,
x 2  2 xy  ay 2  x 2  2 xy  3 y 2   x  y  x  3 y 
and ax 2  2 xy  y 2  3x 2  2 xy  y 2    x  y  3x  y 
So, the equation of the required lines is
 x  3 y  3x  y   0
Or 3x 2  10 xy  3 y 2  0
65. The combined equation of the bisectors of angles between the lines of the first pair is
x 2  y 2 xy
 as the equations are the same, the two pairs are equality inclined to each other.
2 1 9
66. Here, my  y  mx   x  y  mx   0
i.e.,  y  mx    my  x   0
1
So, the lines are y  mx and y   x . Therefore, m  1 or 1 .
m
67. Each point  x, y  has an image in line y  0 as  x,  y  . So, replacing y by  y in the givne
equation, we get the image as ax 2  2hxy  by 2  0
68. The given pair of lines is
135 x 2  136 xy  33 y 2  0
The equation of bisector of angles between the pair of lines is
x 2  y 2 xy x2  y 2 xy
 or 
a b h 135  33 68
Or 2 x 2  3xy  2 y 2  0
Or  x  2  2 x  y   0
One of the bisectors is x  2 y  0 which is parallel to the line x  2 y  7 .
Hence, the line x  2 y  7 is equally inclined to the given lines.
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69. Let m and m 2 be the slopes of the lines represented by ax 2  2hxy  by 2  0 . Then,
2h
m  m2  
b
a a
And mm 2  or m3 
b b
2
3  2h 
  m  m2     
 b 
8h 3

 m3  m6  3mm 2 m  m 2   b3
a 8h3 6ah
  a  b    2
b2 b3 b
2
a  b 8h
  6
h ab
70. ax 2  2hxy  ay 2  0 is symmetrical about y  x

71. Put 2h    a  b  in ax 2  2hxy  by 2  0 . Then,

ax 2   a  b  xy  by 2  0
Or  x  y  ax  by   0
Therefore, one of the lines bisects the angle between the coordinates axes in the positive
quadrant. Also, putting
c  2h  a in ax  by , we have
ax  by  ax   2h  a  y  ax   2h  a  y
Hence, ax   2h  a  is a factor of ax 2  2hxy  by 2 . However, statement 2 is not the correct
explanation of statement 1.
72. The lines by which triangle is formed are x  0, y  0 , and x  y  1 . Clearly, it is a right
triangle . We know that in a right-angled triangle, the orthocenter coincides with the vertex
at which right angle is formed. Therefore, the orthocenter is  0, 0 
73. x 2  y 2  2 y  1 or x    y  1
The bisectors of the above lines are x  0 and y  1 .
So, the area between x  0, y  1 , and x  y  3 is 2 sq. units.

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74. The sides of parallelogram are x  2, x  3, y  1, y  5

The equation of diagonal AC is
y 1 x  2

5 1 3  2
Or y  4 x  7
D  2,5 C  3,5

A  2,1 B  3,1

and the equation of diagonal BD is

x2 y5

3 2 1 5
Or 4 x  y  13
75.   1  x  0   x   1
0  y 1   y  0
1 z  2  z 1
Hence, the given determinant is
0 0 1
1 1 1  1   z 
1 0 2
76. Put a  0, b  1, c  2
k 2
77. We have,
 A  2I  A  4 I   O
 A2  2 A  4 A  8 I  O
 A2  6 A  8I  O
 A1  A2  6 A  8 I   A1O
 A  8 A1  6 I
1 4
 A  A1  1
6 3
78. We have
x y z
Let   k
cos   2   2 
cos     cos    
 3   3 
x  y  z  k 0  0

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79. A   2 sin 900
2 2
1 1 
B  2  sin 440  cos 440 
2 2 
 2 sin  450  440 
 2 sin890  2 sin 900  2
A B
80. We have tan 60 tan 420 tan 66 0 tan 780  tan 6 0 tan  600  180  tan  600  60  tan  600  180 
 tan  600  180  tan  600  180  
 tan 6 tan  60  6  tan18
0 0 0 0

 tan180 
tan 60 tan  600  60  tan  3 180 

tan180
tan 60 tan  600  6  tan  60 0  6 

tan180
tan180
 1
tan180
2
81.  x  7 y   4 2  x  7 y   42  0
Or  x  7 y 2  7 2  x  y   3 2  x  y   42  0
Or  x  y   x  7 y  7 2   3 2  x  7 y  7 2   0
Or  x  7 y  7 2  x  7 y  3 2   0
Or x  7 y  7 2  0 and x  7 y  3 2  0
7 2  3 2 10 2
Or d   2
1  49 50
82. We have
y 2  9 xy  18 x2  0
Or y 2  6 xy  3xy  18 x 2  0
Or y  y  6 x   3x  y  6 x   0
Or  y  3x   0 and y  6 x  0
The third lines is y  6 . Therefore, the area of the triangle formed by these lines
0 0 1
1
 1 6 1
2
2 6 1
1
 6  12
2
= 3units2

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83. The equation 4 x 2  8xy  ky 2  9  0 represents a pair of straight lines if  4  k   a    a  4 2  0

or k  4
84. m1  m2  4m1m2
2h 4a
Or  
b b
Or 2c  4 or c  2
85. Let m1 and m2 be the slopes of the lines x 2  hxy  2 y 2  0 . Then,
h 1
m1  m2   , m1m2 
2 2
But m1  2m2 (given). Therefore,
h 1
3m2   and 2 m22 
2 2
1
i.e., m22 
4
h
Also, m2  
6
2
h 1
  or h 2  9 or h  3
36 4
86. The equation of the bisectors of the angles between the lines x 2  2 pxy  y 2  0 is
x2  y 2 xy

1   1  p
x 2  y 2  xy
Or 
2 p
Or px  2 xy  py 2  0
2

This is the same as x 2  2qxy  y 2  0 . Therefore,

p 2 p
 
1 2 q 1
Or pq  1  0
87. We must have
abc  2 fgh  af 2  bg 2  ch 2  0

The equation of the y-axis is x  0 ,

we get by 2  2 fy  c  0
Which must have equal roots. Therefore,
f 2  bc
fgh  bg 2
Putting f 2  bc, fgh  bg 2 in we get
bg 2  ch 2
 2 fgh  bg 2  ch 2
88. Given vertices of triangle are O  0,0  , B  6,8  , and C  4,3

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8
Slope of OB 
6
3
Slope of OC  
4

 BOC 
2
OBC is right – angled at O.
11 
Circumcenter=midpoint of hypotenuse BC  1, 
 2
Orthocenter =Vertex O  0, 0 
121 5 5
Required distance = 1    units.
 4  2
89. PQRS will represent a parallelogram if and only if the midpoint of PR is the same as that
midpoint of QS. Hence,
1 5 4  a 27 6b
 and 
2 2 2 2
Or a  2 and b  3
90. Lines  k  1 x  8 y  4k and kx   k  3 y  3k  1 are coincident. Then we can compare the ratio
of coefficients as
k 1 8 4k
 
k k  3 3k  1
Or k  4k  3  8k and 24k  8  4k 2  12k
2

Or  k  3 k  1  0 and  k  2  k  1  0
 k 1

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