24-09-2023 - Jr.C-120 - Jee-Adv (2022-P2) - WTA-14 - Q Paper

Sri Chaitanya IIT Academy 24-09-2023_Jr.C-120_Incoming_Jee-Adv(2022-P2)_WTA-14_Q.
Paper
Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Jr.C-120 2022_P2 Date: 24-09-2023
Time: 09.30 AM to 12.30 PM WTA-14 Max. Marks:180
24-09-2023_Jr.C-120_Incoming_Jee-ADV(2022-P2)_WTA-14
Weekend Test Syllabus
PHYSICS : Rotatory Dynamics up to Concpet of rolling and problems on uniform

rolling motion, Problems on above concepects
CHEMISTRY : Thermodynamics & Thermochemistry upto Enthalpy of solution,

Hydration, GOC upto Reactive intermediates (Carbocations,
Carbanions, Free radicals, Carbenes, nitrenes)
MATHEMATICS : Limits up to Existence of limits (L.H.L and R.H.L), L'Hospital rule,

Series Expansions
Sec:Jr.C -120 Page 1

Sri Chaitanya IIT Academy 24-09-2023_Jr.C-120_Incoming_Jee-Adv(2022-P2)_WTA-14_Q.Paper
JEE-ADVANCE-2022-P2-Model
Time: 3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N : 9 – 14) +4 -2 6 24
with partial mark
Sec – III(Q.N : 15 – 18) Questions with Single Correct Choice +3 -1 4 12
Total 18 60
PHYSICS:
Sec – II(Q.N : 9 – 14) +4 -2 6 24
with partial mark
Total 18 60
CHEMISTRY:
Sec – II(Q.N : 9 – 14) +4 -2 6 24
with partial mark
Total 18 60

MATHEMATICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
 
1. If f  n  1  1  f  n    9   n  N and f (n) >0 for all n  N, then the value of lim f (n)
2  f (n)
  n 
is
sin t 
2. The value of lim  min(x 2  2 x  5) is equal to
t 0
 t 
  5 x   4sin x  
3. The value of lim   sin x    x   where [.] represents the greatest integral
x 0
   
functions is ……..
x2 x4
4. If 8   f ( x)  8  for all x  0 then lim f ( x) 
15 6 x 0
log10 ( x  5)  [ x ]  5
5. lim
x  [ x  5]
  x 3  x  3 
6. lim      is ______ where [ ] is G.I.F
x 3  3  3  

 a x  x a  
7. If lim  x a   = -1 then the value of ‘a
 x  a  
x a
 x
1  cos 1  cos 
 2
8. If lim m n
is equal to the derivative of ex at x  0 the then
x0 2 x
the value of n 2  m

SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are
chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
 2x
1  , 0  x  1
9. Let f ( x)   a lim f (x) exists then a  ________
x1
 ax, 1  x  2
A) 1 B) -1 C) 2 D)-2
 1  n2 
10. If lim  an    b where ‘b’ is finite number, then
n 
 1 n 
A) a=1 B) a =0 C) b=1 D) b= -1
2
3x  ax  a  1
11. If f (x)  , Then which of the following can be correct?
x2  x  2
A) lim
x1
f (x) exists  a  2 B) x
lim f (x) exists  a  13
2
4 1
C)If a=-2 then lim f ( x)  D)If a=13 then xlim f ( x) 
x 1 3 2 3
x2
a  a 2  x2 
12 Let L  lim 4 , a  0 If L is finite then
x 0 x4
A) a  2 B) a  1 C) L  1 D) L  1
64 32
n
sin x
13. If m, n  N Then lim m
is
x0
 sin x 
A) 1 if m  n B) 0 if n > m C)  If n < m D) n If n < m
m
1
14. lim(4 n  5 )
n
n n
is equal to = ____
A)  B) 0 C) 5 D) 7

SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
10 10 10
15.
 x  1   x  2   ........   x  100 
is equal to
Lt
x  x10  1010
A) 0 B) 1 C) 10 D) 100
1
 f  x  x
f  x
16. If lim 1  x    e3 , then lim 
x0
 x  x0 x2
A) e3 B) e3  1 C) 1 D) 2
17 is equal to
A) 1 B)  1 C) 3 D) 5
2 2 4 6
n
  n x 1
18. If f ( x)  lim  
n   n  1
  sin  where x  Q then f (1) 
  n 
1
A) 0 B) -1 C) 1 D)
2

PHYSICS Max Marks: 60
SECTION-I
19. A shell of mass ‘m’ is projected with a velocity ‘v’ at an angle 60o to horizontal.
When it reaches the maximum height its angular momentum with respect to point of
3mvn
projection is where n = _____
16 g
20 A sphere is performing pure rolling as shown in figure. Velocity of point ‘A’ (where
R xv
OA= ) is m/ s then x= _______
2 2
O V
21. A circular disc is rotating about its natural axis with angular velocity  . A second
disc of same mass is joined to it coaxially. If the radius of the second disc is half of
the radius of the first disc, then they together rotate with an angular velocity of 4
n
rad/s. The value of n is

22. A small particle of mass m moving horizontally collides with a vertical hinged rod
inelastically (e=0) as shown. The kinetic energy of rod and particle system is
m 2 vo 2
. The value of xy is
 M
xm  
 y 

23. When a solid sphere is rolling without slipping on rough horizontal surface then the
500
percentage of its total kinetic energy which is translational is %. Find m.
m
24. A wheel of diameter ‘d’ is rolling without slipping with speed v on a horizontal
road. When it is at point ‘A’ on the road a small lump of mud separates from the
wheel at its highest point ‘B’ and drops at point ‘C’ on the road. The distance ‘AC’
xd
will be v then x  ______
g
25. A uniform bar of length ‘L’ and mass ‘M’ lies on a smooth horizontal table a point
mass ‘m’ moving on same horizontal plane with speed ‘v’ strikes the bar as shown
nv
and sticks to the bar. Immediately after collision angular velocity of the system is
7L
then n=
M=3 kg
M L
m= 1 kg
m V
o
26. For a rolling body on a moving platform Vcm=R  . For no slipping u = _______
R
o Vcm
w
p
u

SECTION – II
chosen;
27. A particle of mass ‘m’ is projected with a velocity ‘v’ making an angle of 450 with
the horizontal .The magnitude of the angular momentum of the projectile about the
point of projection when the particle is at its maximum height ‘h’ is
mv3 mv3
A) Zero B) C) D) m 2 gh3
4 2g 2g

28. A force F  Ai  Bj acts at a point whose radius vector with respect to origin is
r  ai bj. where a, b , A & B are constant and then
aB  bA
A) Torque about ‘O’ is ( aB  bA)
k B) Arm of force about origin
2 2
A B
C) Torque about ‘O’ is zero D) Torque about ‘O’ is aB  bA

k
29. A ring type fly wheel of mass 100kg and diameter 2m is rotating at the rate of
300 /   revolutions per minute .Then
A) The moment of inertia of the flywheel is 100kgm 2

B) The kinetic energy of rotation of the flywheel is 5kJ
C) The fly wheel, if subjected to a rotating torque of 200Nm will come to rest in
5s.
D) The moment of inertia of the fly wheel is 143kg m 2

30. A uniform circular disc of mass M and radius R rolls with out slipping an a
horizontal surface if the velocity of its center is vo then the total angular momentum
of the disc about fixed point ‘p’ at a height 3R/2 above the center C
p
3R
2
Vo
c
A) increases continuously as the disc moves away

B) decreases continuously as the disc moves away
C) is always equal to 2MRVo
D) is always equal to MRVo
31. A particle of mass m collides with the end of a spinning rod of mass 2m and length
‘l’, at the end of the rod. If the coefficient of restitution of collision is e= 2 , then
3
vo
A) speed of particle after collision is
6
5vo
B) speed of center of rod after collision is
12
3vo
C) angular speed of rod just after collision w 
2l
D) change in kinetic energy of the particle is  K  0

2m
vo
wo 
l
m
vo
32. A thin ring of mass 1kg and radius 1m is pure rolling at speed of 1m/s then
A) Its total kinetic energy 1 J
B) Translational kinetic energy 1 J

2
1
C) Rotational kinetic energy J
2
D) Total kinetic energy 1 J

2
SECTION – III
33. A hoop of radius r and mass m rotating with an angular velocity ‘ 0 ’ is placed on
rough horizontal surface the initial velocity of centre of mass of the hoop is zero
.what will be the velocity of the center of hoop when it ceases to slip
o r 1
A) o r B) C) 2o r D) 0 r
2 3

34. A thin rod of length L is vertically straight on horizontal floor. This rod falls freely to
one side without slipping of its bottom. The linear velocity of centre of rod when its
top end touches floor is
3gl 3gl
A) 2gl B) C) 3gl D)
2 4
35. A particle performs uniform circular motion with an angular momentum ‘L’ . If
angular frequency f of the particle is doubled and kinetic energy is halved, its
angular momentum becomes
L L
A) 4L B) 2L C) D)
2 4
36. A particle of mass ‘m’ is moving along a circle of radius ‘r’ with time period T. Its
angular momentum is
2 m r 4 m r 2 mr 2 4 mr 2
A) B) C) D)
T T T T

CHEMISTRY Max Marks: 60
SECTION-I
37. An ideal gas is taken through the cycle A  B  C  A as shown in the figure. If net heat
supplied to the gas in the cycle is 5J, the magnitude of work done in the process
C  A is --------
C B
2
V
in m3
1 A
10
P in N/m2
38. Standard molar enthalpy of combustion of glucose is -2880 KJ . If only 25% of energy is
available for muscular work and 1.0 Km walk consumes 90KJ of energy , What
maximum distance ( in km) a person can walk after eating 90 gm of glucose.
39. Find the change in internal energy, when 0.5 mole of Ar having a specific heat at
constant pressure of 20.814 J gm 1 deg 1 is heated from 270 C to 310 C at Constant volume
.( atomic mass of Ar=40)(give your ans in KJ).

40. Calculate H for the isothermal reversible expansion of one mole of an ideal gas from
an initial pressure of 1 bar to a final pressure of 0.1 bar at a constant temperature of
273K.
41. How many of the following show hyper conjugation effect?
     C6H5 CH2 ,
CH 3  C H 2 , (CH 3 )2 C H , (CH )3 C , C6 H 5 C H 2 , C H3 ,

CH 2
42. How many of the following act as ambident nucleophiles?


BH  4 , NH 3 , CN  , NO2  , R  CH  CH  O , OH  , H 3O  , AlCl3
43. The number of hybrid orbitals in methyl carbocation is x and that in methyl carbanion
is y, then the value of x+y is
44. The number of lone pair of electrons present in singlet and triplet forms of the carbene
(CH2) are x and y, then x-y value is
SECTION – II
chosen;
45. E must be zero for
A) Isothermal expansion of an ideal gas.
B) Isothermal Expansion of a real gas
C) Free Expansion of an ideal gas
D) Cyclic Process

46. Which of the following is /are correct?
A) H  U  (PV) when P&V both changes
B) H   U  P  V when P Is constant
C)  H   U  V  P when V is constant
D) H  U  P V  V P when P&V both changes
47. In adiabatic process, the work involved during expansion (or) compression of an ideal
gas is given by
nR  T2 P1  T1P2  V2
A) nCv T B) (T2  T1 ) C) –nRPext   D) 2.303RT log
 1  P1P2  V1
48. Which of the following are ortho & para directing groups in EAS reaction?
A) -NH2 B) -OH C) -NO2 D) -CN
49. Which of the following are electrophiles?
A) BF3 B) AlCl3 C) Water D) R-O-R
50. The more stable carbanions than the benzyl carbanion is/are
CH2 CH2
CH2 CH2
NO2 CH 3
A) B) C) CN D) CHO

SECTION – III
51. Using the data provided, calculate the multiple bond energy (kJ/mol) of a C  C bond
in C2 H 2 Given that the heat of formation of C2 H 2 =225kJ/mol

(take the bond energy of a C-H bond as 350 kJ/mol)
2C( S )  2C( g ) H  1410 KJ / mo l , H 2(g)  2 H (g) H  330 KJ / mol
A) 1165 B) 83 C) 865 D) 815

52. In the cyclic process shown in P-V diagram, the magnitude of the work done is
V
V2
V1
P1 P2 P
2 2
p p  v v 
A)   2 1  B)  2 1
 2   2 
 2
C)  p2  p1  v2  v1  D)   v2  v1 
4
53. The decreasing order of –I effect of the orbitals in I. SP II. SP 2 III. SP3 is
A) I >II >III B) III > II > I C) I > III >II D) II > III > I
54. The most stable alkene is
A) CH 2  CH 2 B) CH 3  CH  CH 2
C) CH 3  CH  CH  CH 3 D) CH 3  CH 2  CH  CH 2


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Sri Chaitanya IIT Academy 24-09-2023_Jr.C-120_Incoming_Jee-Adv(2022-P2)_WTA-14_Q.

Sri Chaitanya IIT Academy.,India.

PHYSICS : Rotatory Dynamics up to Concpet of rolling and problems on uniform

CHEMISTRY : Thermodynamics & Thermochemistry upto Enthalpy of solution,

MATHEMATICS : Limits up to Existence of limits (L.H.L and R.H.L), L'Hospital rule,

Sec:Jr.C -120 Page 1

Sec:Jr.C -120 Page 2

Sec:Jr.C -120 Page 3

Sec:Jr.C -120 Page 4

Sec:Jr.C -120 Page 5

rad/s. The value of n is

Sec:Jr.C -120 Page 6

Sec:Jr.C -120 Page 7

r  ai bj. where a, b , A & B are constant and then

C) Torque about ‘O’ is zero D) Torque about ‘O’ is aB  bA

A) The moment of inertia of the flywheel is 100kgm 2

D) The moment of inertia of the fly wheel is 143kg m 2

Sec:Jr.C -120 Page 8

A) increases continuously as the disc moves away

D) change in kinetic energy of the particle is  K  0

Sec:Jr.C -120 Page 9

B) Translational kinetic energy 1 J

D) Total kinetic energy 1 J

Sec:Jr.C -120 Page 10

top end touches floor is

angular momentum becomes

Sec:Jr.C -120 Page 11

maximum distance ( in km) a person can walk after eating 90 gm of glucose.

.( atomic mass of Ar=40)(give your ans in KJ).

Sec:Jr.C -120 Page 12

an initial pressure of 1 bar to a final pressure of 0.1 bar at a constant temperature of

41. How many of the following show hyper conjugation effect?

42. How many of the following act as ambident nucleophiles?

Sec:Jr.C -120 Page 13

A) H  U  (PV) when P&V both changes

D) H  U  P V  V P when P&V both changes

A) -NH2 B) -OH C) -NO2 D) -CN

49. Which of the following are electrophiles?

A) BF3 B) AlCl3 C) Water D) R-O-R

Sec:Jr.C -120 Page 14

in C2 H 2 Given that the heat of formation of C2 H 2 =225kJ/mol

A) 1165 B) 83 C) 865 D) 815

Sec:Jr.C -120 Page 15

Sec:Jr.C -120 Page 16

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