Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_STERLING BT WTA-13 Date: 10-09-2023
Time: 02:00PM to 05:00PM JEE-ADV_(2020-P2) Max. Marks: 198

KEY SHEET
PHYSICS
1 7 2 2 3 0 4 7 5 6 6 4

7 AB 8 D 9 BC 10 ABC 11 CD 12 ABC

13 30 14 0.5 15 25 16 2.75 17 70 18 1.4

CHEMISTRY
19 8 20 3 21 0 22 4 23 6 24 0

25 AC 26 ACD 27 BCD 28 ABCD 29 D 30 AD

2.8 to
31 26 32 10 33 800 34 35 79 36 34 to 35
3.8

MATHEMATICS
37 3 38 6 39 3 40 5 41 6 42 8

43 ABC 44 AB 45 ABC 46 AD 47 BC 48 AC

49 5 50 0 51 -5 52 36 53 4 54 3
 Sri Chaitanya IIT Academy 10-09-2023_Jr.Super60_STERLING BT_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
SOLUTIONS

PHYSICS
1. Weight of sphere + chain   m   h  g
 m h   h 
Buoyant force   l g  l g    3m  g
  s  c   7 
For equilibrium,
Weight = Buoyant force
h
Or, m   h  3m 
7
7m
Or, h 
3

y z

h dz
p 
2.
z  y sec  dz  dy sec
p    gy 
dA   b  dz   b  dy sec
dF  pdA    gb sec  ydy
1
 F  0h dF   bh 2 g sec
2
3. Writing equation of motion for the block
T  mg sin 300  ma ............. i 
For the sphere
Weight – Buoyant force T  ma ............ ii 
mg
Or mg   T  ma
2
Solving, we get a0
4. Let water level falls by x meter due to kerosene oil. Equating pressure on both sides of
the tube,

0.1 x
x
x

0.29

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 Sri Chaitanya IIT Academy 10-09-2023_Jr.Super60_STERLING BT_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
800  g  0.1  1000  g  2 x
8 1
 x m  m  0.04m
200 25
Hence, h2  0.29  0.04  0.33m
And h1  0.29  0.04  0.1  0.35m
h 35
So, 1 
h2 33
2 2
1 H H
5.    H  g   P0   gH     Fv
3  2  2
H2 H3  H 3 g
Fv  P0  g 
4 4 12
 H 2  gH 3  P  gH 
 P0  H2 0  
4 6  4 6 
6. The force exerted by liquid on the gate
A hR

R 3R
 O

FH  Pav  vertical projected area of the gate

 P  PB 
 A    2 R 
 2 
 R  g  3R  g 
   2 R
 2 
 4  gR 2
7. a) Volume of water inside the tank remains constant
 3  y0 
  5  4  5  2  4 or y0  1 m
 5 
3 1
 tan 0   0.4
5
0

3m a0 2m
y0

5m
a
Since, tan 0  0 , therefore a0  0.4 g  4 m / s 2
g

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 Sri Chaitanya IIT Academy 10-09-2023_Jr.Super60_STERLING BT_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
b) When acceleration is increased by 20%
a  1.2a0  0.48 g
a
tan    0.48
g
x
AIR
y

3m
Water

5m
Now, y  3  5tan   3  5  0.48   0.6m
Fraction of water spilt over
4 25
 3  0.6   5  4
 2  0.1
25 4
Percentage of water spilt over = 10%
8. Pascals Law states: “Pressure exerted anywhere on a confined liquid is transmitted
unchanged in every direction, to every portion of the liquid, and to all the walls of the
containing vessel.
9.
T
U
C P
l l
4 M 4
O W1  240 N

W2  120 N

T  U  W1  W2  360 N ……… (i)

V
U   w g  V / 2  103 10 
2
 
Or U  0.5  104V …….. (ii)
  Moments  about M  0
l  3l  l
 120    T    240  
4 4 4
240  120
Or T  40 N  4 g
3
Now from Eqs. (i) and (ii)
V  6.4  102 m3

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 Sri Chaitanya IIT Academy 10-09-2023_Jr.Super60_STERLING BT_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s

 2r 2
10. The equation of the free surface is y   y0
2g

When the free surface touches the brim of the cylinder, the lowest point of the
paraboloid is at a height H/3 above the base, as shown in figure. When the lowest point
of the free surface touches the base of the cylinder, the height of water in the tank must
be H/2. It means that water must spill out.
11. The pressure intensity at the bottom of the container is
P  h  g  0.20  1000  10  2  103 N / m3
Force at the bottom of container
 P  base area  Pa  base area

  
 2  103  20  104  1.  105  20  10 4 
 204 N
b) Weight of the water in the container
 Volume  density of water  g
 0.5  103  1000  10  5N
From the diagram, the force exerted by the container is in upward direction (because
 P2  P1  . Let force exerted by sides of container is F, then
 4  F  5N
 F  1N
P2  P1
p1 p1

p2 p2
5N

4N
Force exerted by Force exerted by
water on the container container on water
From the diagram, the force exerted by the container in upward direction (because
 P2  P1  . Let force exerted by sides of container is F, then
 4  F  5N
 F 1 N
12. Liquid A exerts all round horizontal force on the cylinder and so net on it is zero.
If A is the area of cross – section of the cylinder, then for the floating cylinder

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 Sri Chaitanya IIT Academy 10-09-2023_Jr.Super60_STERLING BT_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
Weight of the cylinder = buoyant force by the liquids
 hA  hB  h  A  0.8 g   hA A   A g   hB A   B g
1.2  0.8  h  A  0.8 g  1.2 A  0.7 g   0.8 A   1.2 g
 h  0.25 cm
The extra buoyant force
Fh   A h   B g
F
Acceleration a  h
m
Ah  B g

m
Here m   hA  hB  h  A  0.8
 1.2  0.8  0.25  A  0.8
 1.8A
A  0.25  1.2 g
 a
1.8 A
g
 m / s2 .
6
13.

FB stick (2.5 kg)

E
B
A 1m

 mg
O C D

OE  l
1
l ........... i 
sin 
OD  2cos ............ ii 
l cos
OC  cos  .......... iii 
2 2sin 
FB   w Al g
Torque about O
mg  OD    w Alg  OC 
On solving
1
sin 2  
4
  300
14. According to question,

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 Sri Chaitanya IIT Academy 10-09-2023_Jr.Super60_STERLING BT_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
 r  r sin    g   r  r cos   g   r sin   r cos  g

R





 cos  sin      cos  sin  
cos       sin      
 
 tan  
 
4
15. T1  T2 , Mg  2T1   r 3  w g , T1  250 2 N
3
4 3
 r w g
3

450 450

T2
T1
Mg
16. a) Free body diagram of the block is shown.
F  upthrust force
 V   g  a 
 mass of block 
    g  a 
 denisty of block 
F
a

W T
 1 
  1000 10  1  13.75 N
 800 
W  mg  10 N
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 Sri Chaitanya IIT Academy 10-09-2023_Jr.Super60_STERLING BT_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
Equation of motion of the block is,
F  T  W  ma
 13.75  T  10  1  1
 T  2.75 N
b) When the string is cut T  0
F W
 a
m
13.75  10
  3.75 m / s 2
1
17. Buoyancy force,
2
Fb  V  g  3
 103  10  2 N
10  10
FBD of block is an shown
T

Fb
2g
 T  Fb  20  T  18 N
The reading of S1 is equal to tension in string,
The effect of putting the mass inside the water is equivalent of adding an amount of
water equal to volume of block.
So total force on S1 is 5 g  2  52 N
18. A piece touches glass at small number of points, water would be there on bottom of
piece also and hence buoyancy force acts on it. From equilibrium condition,
mg  FB  N
m 0.16
FB  V  water g    water  g   10  0.2 N
 metal g
160
So N  mg  FB   10  0.2  1.4 N
1000
CHEMISTRY
19. x  22
y 8
x y
z2 7
z
20. 1, 3, 6 are correct.
21. All the above are not effected by cold water.

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 Sri Chaitanya IIT Academy 10-09-2023_Jr.Super60_STERLING BT_Jee-Adv(2020-P2)_WTA-13_Key & Sol’s
f f f
B B B 4
(i) f  1.33
f f f f f 3
22.
O O O
(ii) O S O 4
O S O O S O  1.33
3
O O O
(iii) N O 4
N O N O  1.33
O O O 3

O O O O
5
(iv) O P O O P O O P O O P O  1.25
4
O O O O
O O O O
6
(v) O S O O S O O S O O S O 4
 1.5

O O O
O
Average bond order in graphite is 1.33

COOH

HOOC COOH

HOOC COOH

23. COOH

THE NO OF Sp 2 carbon atoms 12

x  12
x 12
 6
2 2
2 2 2
24. GeF62 , Sn  OH 6 ,  SnCl6  , RbCl6  - octahedral geometry

 BH 4  - Tetrahedral geometry
25. I  reduces Pb  iv  to Pb  2 
SnCl2  H 2O  Sn  OH  Cl  HCl
 aq   s  aq 
Sn 2 acts as reducing agent.
26. Stability of +2 oxidation state down the group increases.
Ability to form p  p to form multiple bonds decreases down the group.
The tendency for catenation decreases down the group. All form oxides with the
formula MO2 .
27. CONCEPTUAL
28. Lapis Lazuli is a precious stone blue in colour
CuSO4 Al2  SO4 3 24 H 2O belongs to pseudo alam

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Alums are prepared by using K 2 SO4 . Al2  SO4 3 .4 Al  OH 3
Aqueous solutions of alums are acidic in nature.
29. CONCEPTUAL
30. C  OH 4 easily lose two H 2O molecules and convert into stable CO2 molecule which
contain strong p  p bonds but silicon cannot form such bonds due to bigger size.
31. In fullerene there are 30 bonds. Hence c  30
 3a  2b  c  312   2  20   30  26
32. B2O3 , CO2 , SiO2     Acidic
A 2O3 , SnO2 , RbO2 , SnO, RbO     Amphoteric
Basic – T O, In2O3
Co - neutral
35 2
 10
1
33. 1 carat = 200 grams
1+ carats = 200  4  800 grams
34. C – C bond length in graphite  141.5
Small C – C bond length = 138.5 in fullerere
 y  x  3.2 pm
35. IT IS A FACT

36. C  1 / 2 O2 
 CO
12 gr ' C ' 
 28 gr
?  19.2gr
19.2  12
 8.22857
28
8.22857
 100  34.2857
24
MATHEMATICS
  
37. 6  2a.b  2b .c  2c .a  9
      3   2
  
a.b  b .c  c .a 
2
 a b c 0
  

 3  2 a.b  b .c  c .a  0
      3
 a.b  b .c  c .a 
2
      3
Since a.b  b .c  c .a 
2
     
 a b c 0 a b c 0
  
 2a  5   a   3a  3
1 1
38. p  OB  AC  10a  2b    b  a 
2 2
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p
 6 a  b  q  OA  OC  a  b , 6
q
39.  a .c  a   a .a  c  3b  0
 2 3cso a  3c  3b  0
 2cos a  3c  3b  0
2 2
 2cos a  3c 
  3b 
 12cos 2   9  24cos 2   0
3
 cos2  
4
2 2 2
40. a b  b  c  c  a  200
2
2  a  b  c   200
2 2

 
a  b  c  100  10
 
41.    
2V  V  iˆ  2 ˆj  2iˆ  kˆ .............  i 

or     
2V . iˆ  2 ˆj  0  2iˆ  kˆ iˆ  2 ˆj
  2
or 2V . iˆ  2 ˆj   2 or V . i 2 ˆj   1
2 2
 V iˆ  2 ˆj cos2   1

( is the angle between V and iˆ  2 ˆj )
2

Or V 5 1  sin 2   1 
2 2
Or V 5sin 2   5 V  1....... ii   m6
 
42. Volume of the parallelepiped   abc 
 
 (area of the base parallelogram) h  abc
    4
 a  b h  abc   38h  4  h 
38
 38h 2  4  4  19h 2  8
  
43. Since a , b and c are unit vectors inclined at an angle  , we have
   
a  b  1 and cos  a.c  b .c
    
Now, c   a   b   a  b   (i)
     
   
 a.c    a.a    a.b   a. a  b 

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2    
 cos   a    
 a.b  0, a a  b  0

Similarly, by taking dot product on both sides of (i) by b , we get   cos
  
    
Again, c   a   b   a  b  
2    
 c  a  b   a  b  
2 2  2
2 a  2 b  a b
   
   
2 a.b  2 a. ab 
  
  
2  b . a  b
 2
 12   2  2 a b
 2 2 
 2 2   2  a b sin 2 
 2
2 2 1  2
2
 2   or  
2
But     cos .
1  2 2   2   2  1  2cos 2    cos 2
1   2 1  cos 2
2
   
 2
  2 
44. Let EB  p, AB and CE  q CD .
D B

E
A C
Then 0  p and q  1
   
Since EB  BC  CE  0

     
pm 2iˆ  6 ˆj  2kˆ  iˆ  2 ˆj  qn 6iˆ  15 ˆj  3kˆ  0

Or  2 pm  1  6qn  iˆ   6 pm  2  15qn  ˆj   2 pm  6qn  kˆ  0
  
 2 pm  6qn  1  0, 6 pm  2  15qn  0,2 pm  96qn  0
Solving these, we get
   
45. We know that a  b  c  0 , then
     
a  b  b  c  c  a 
 
Given a  2b  3c  0
     
Or 2 a  b  6b  c  3c  a
     
Or 2 a  b 6b  c  3c  a
   
Hence a  b  b  c  c  a
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     
   
 2 a  b or 6 b  c or 3  c  a 
   
46. a  b  a  2b
2
  b
 a.b 
2
2
  1 b 2 1
Also, a.b      1
2 2 2
b 2 b 2
 2 1 (using A.M .  G.M )
   1
47.  
a  b c  b
2
    1
 
or  a.c  b  a.b c  b
2
 1 
 a.c  and a.b  0
2
1  
 1.1cos   and a  b
2
  
   and a  b
3
    
48.    
a  b  c  a.b b
 
 
  4  2 x  sin y  b  x 2  1 c
     
   
Or  a.c  b  a.b c  a.b c
  
Now,  c .c  a  c . Therefore,
   
 c.c  a.c    c.c  or a.c  1
 
  
1  a.b  4  2 x  sin y, x 2  1   a.b

Or 1  4  2 x  sin y  x 2  1
2
Or sin y  x 2  2 x  2   x  1  1
But sin y  1  x  1,sin y  1

 y   4n  1 , n  I
2
  
49. c a b
2 2  2 
 c  a  b  2c .b
2  2 2    
 c  a  b  2 a . b cos a , b  
2 2 2  
 c  a  b  2 c b cos3
50. AC  AB  BC
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u v  u v  u v 
BC    AB.BC     .  
u v  u v  u v 
2 2
u v
  0
2 2
u v

B  hence  cos 2 A  1  0
2
51. Here we are given that
 
a  3iˆ  ˆj , b  iˆ  2 ˆj  kˆ
    

As a  b  c  b  c 
     
  
 a.c b  a.b c  b  c
 
 a.c  1, a.b  
  
3iˆ  ˆj . iˆ  2 ˆj  kˆ   
   5
1  
52. 3   a b c 
6
 
Or  a b c   18
Volume of the required parallelepiped
       
  a  b b  c c  a   2  a b c   36
 
53. Let angle between a and b be  .
  
a  b  1  1  2cos  2 cos  a  b  1
2
  
Similarly, a  b  2 sin
2
      
So, 3 a  b  a  b  2  3 cos  sin 
 2 2
 Maximum value of  a cos  b sin    a 2  b 2
2 2
 Maximum value  2  3  1  4 .
54. p.a  q .b  r .c  1 and p.b  q .c  r .a  0

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