24-09-2023 - JR - Super60 - NUCLEUS & STERLING BT - Jee-Adv (2022-P2) - WTA-20&WTA-15 - Q. Paper

Sri Chaitanya IIT Academy., India.
 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office, Madhapur – Hyderabad
Sec: Jr.Super60_NUCLEUS & STERLING BT 2022_P2 Date: 24-09-2023
Time: 09.00Am to 12.00Pm WTA-20/WTA-15 Max. Marks:180
MATHEMATICS : Vector and Cartesian form of a line equation, Vector and Cartesian
form of a plane, Angle between the planes and Angle between line
and plane, Skew lines and shortest distances between the lines,
Intersection of two lines & intersection of two planes
PHYSICS : Surface Tension : Surface Phenomena In Liquids, Molecular Theory
Of Surface Tension, Quantitative Definition, Determination Of
Surface Tension, Surface Energy, Excess Pressure Inside A Liquid
Bubble, Excess Pressure Inside A Air Bubble In A Liquid, Angle of
contact in the context of surface tension, Capillarity, rising of liquid in
a capillary tube, Experiment: Surface tension of water by capillary
rise
CHEMISTRY : Estimation of carbon, hydrogen, nitrogen, halogens, sulphur,
phosphorus: IUPAC NOMENCLATURE: Nomenclature of
Hydrocarbons,, Nomenclature of mono and bi-functional organic
compounds including common names
Name of the Student: ___________________ H.T. NO:

Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20&WTA-15_Q.P
JEE-ADVANCE-2022-P2-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 8) Questions with Integer Answer Type +3 -1 8 24
Questions with Multiple Correct Choice
Sec – II(Q.N : 9 – 14) +4 -2 6 24
with partial mark
Sec – III(Q.N : 15 – 18) Questions with Single Correct Choice +3 -1 4 12
Total 18 60
PHYSICS:
Sec – I(Q.N : 19 – 26) Questions with Integer Answer Type +3 -1 8 24
Sec – II(Q.N : 27 – 32) +4 -2 6 24
with partial mark
Total 18 60
CHEMISTRY:
Sec – I(Q.N : 37 – 44 Questions with Integer Answer Type +3 -1 8 24
Sec – II(Q.N : 45 – 50) +4 -2 6 24
with partial mark
Total 18 60
Sec: Jr.Super60_NUCLEUS & STERLING BT Space for rough work Page 2

MATHEMATICS Max Marks: 60
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains EIGHT (08) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
1 1 1
1. Find the distance of the point P (3, 8, 2) from the line (x  1)  (y  3)  (z  2) measured
2 4 3
parallel to the plane 3x  2y  2z  15  0 .
x 1 y  1 z x 1 y  3 z  1
2. If  is the acute angle between the lines   and   where
l m n m n l
l  m  n, and l , m, n are the roots of the cubic equation x 3  x 2  4x  4 then 9cos =


3. Line L1 is parallel to vector   3iˆ  2ˆj  4kˆ and passes through a point A (7, 6, 2) and line

L 2 is parallel to a vector   2iˆ  ˆj  3kˆ and passes through a point B(5, 3, 4). Now a line

L 3 parallel to a vector r  2iˆ  2ˆj  kˆ intersects the lines L1 and L 2 at points C and D

respectively, Then find | CD |
4. The plane denoted by 1 : 4x  7y  4z  81  0 is rotated through a right angle about its line
of intersection with the plane 2 : 5x  3y  10z  25 . If the plane in its new position be
denoted by  , and the distance of this plane from the origin is k where k  N , then find
sum of digits of k.
5. Consider the plane
 1 1  1 
  
E : r   1     2    0 
 1   0  1 
Let F be the plane containing the point A(-4, 2, 2) and parallel to E. Suppose the point B
is on the plane E such that B has a minimum distance from the point A if C(-3, 0, 4) lies
in the plane F. If A is area of the angle ABC then find [A] (where [ ] denotes GIF).

6. A variable plane lx  my  nz  p (where l , m, n are direction cosines) intersects with co-
ordinate axes at points A, B and C respectively the coordinates of circumcentre of
 p  l 2p p  m2p p  n 2p 
triangle ABC is  , ,  . Find k1  k 2  k3 =.
 k1l k2m k 3n 
7. Through a point P(h, k, l ) a plane is drawn at right angles to OP to meet the co-ordinate
pn
axes in A, B, and C. If OP = p, such that the area of ABC is , where O is the
2hkl
origin. Find n
8. Lengths of two opposite edges of a tetrahedron are a and b . Shortest distance between
m
these edges is d and the angle between them is  . Such that its volume is abd sin .
n
m
Find m + n (Where is a rational number in simplest form)
n
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.
9. If three planes P1  2x + y + z – 1 = 0, P2  x  y  z  0 and P3  x  y  3z  5  0 intersects
each other at point P on XOY plane and at point Q on YOZ plane, where O is the origin
then identify the correct statement(s)?
(A) The value of  is 4
x 1 y  1 z
(B) Straight line perpendicular to plane P3 and passing through P is   .
4 1 3

(C) The length of projection of PQ on x-axis is 1.
1 1 1
(D) Centroid of the triangle OPQ is  , , 
3 2 2

  
10. A parallelepiped is formed using three non-collinear vectors, a,b and c with fixed
magnitudes. Angles between any of the vector with normal of the plane determined by
the other two is  and volume of the parallelepiped is T and its surface area is Y. If
Y 1 1 1
 4        then:
T  a |b| c 
 
3 21
(A) cos 2   cos   (B) sin 2   sin 4  
4 16
32 3 5
(C) cos 2   cos   (D) sin 2   sin 4  
4 16
x  6 y  10 z  14
11. The line   is the hypotenuse of an isosceles right angled triangle whose
5 3 8
opposite vertex is (7, 2, 4). Find the equation of the remaining sides.
x7 y2 z4 x7 y2 z4
(A)   (B)  
3 6 3 3 6 2
x7 y2 z4 x7 y2 z4
(C)   (D)  
2 3 6 3 6 2
x y z
12. Consider the equation of line AB is   . Through a point P(1, 2, 5)line PN is
2 3 6
drawn perpendicular to AB and line PQ is drawn parallel to the plane 3x  4y  5z  0 to
meet AB is Q. Then,
52 78 156 
(A) coordinate of N are  , , 
 49 49 49 
9
(B) the coordinates of Q are  3,  ,9 
 2 
x 1 y  2 z  5
(C) the equation of PN is  
3 176 89
156 52 78 
(D) coordinates of N are  , , 
 49 49 49 

13.  
Let P1 denote the equation of a plane to which the vector ˆi  ˆj is normal and which

contains the line whose equation is r  ˆi  ˆj  kˆ  (iˆ  ˆj  k)
ˆ and P denotes the equation
2
of the plane containing the line L and a point with position vector ĵ . Which of the
following holds good?
(A) The equation of P1 is x + y = 2


(B) The equation of P2 is r.(iˆ  2jˆ  k)
ˆ =2
(C) The acute angle between P1 and P2 is cot 1( 3) .
(D) The angle between the plane P2 and the line L is tan 1 3 .
14. In R 3 , let L be a straight line passing through the origin. Suppose that all the points on L
are at a constant distance from the two planes P1 : x  2y  z  1  0 and
P2 : 2x  y  z  1  0 . Let M be the locus of the feet of the perpendiculars drawn from the
points on L to the plane P1 . Which of the following points lie (s) on M?
 5 2  1  1 1  5 1  1 2
(A)  0,  ,   (B)   ,  ,  (C)   , 0,  (D)   , 0, 
 6 3 6 3 6   6 6  3 3
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
15. From a point P (  ,  ,  ) perpendiculars PQ and PR are drawn respectively on the lines
y  x,z  1and y  x,z  1. If P is such that QPR is a right angle then the possible
value of  is
(A) 1 (B) -1 (C) 3 (D) -3

16. If the points (2  x, 2, 2) , (2, 2  y, 2) (2, 2, 2  z) and (1,1,1) are coplanar, then
1 1 1
(A)   1 (B) x + y + z = 1
x y z
1 1 1
(C)   1 (D) None of these
x 1 y 1 z 1
17. The length of the perpendicular from the origin to the plane passing through the point a
and containing the line r = b + λc is
[a b c] [a b c]
(A) (B)
| a ×b + b ×c + c× a | | a ×b + b × c |
[a b c] [a b c]
(C) (D)
| b ×c + c× a | | a ×b + c× a |
18. A straight line ‘L’ cuts the lines AB, AC and AD of a parallelogram ABCD at points
1
B1 ,C1 and D1 , respectively. If AB1,  1AB, AD1   2AD and AC1  3AC , then is
3
equal to
1 1 1 1
(A)  (B)  (C) 1   2 (D) 1   2
1  2 1  2

PHYSICS Max Marks: 60
SECTION-I
19. The surface tension of water is 75 dyne/cm. The circumference of the ring is 20 cm and
its weight is 0.1 N. The minimum vertical force required to pull a thin wire ring up (refer
5x
figure) if it is initially resting on a horizontal water surface is, F   0.1  
 N. Find x.
1000  
20. If the surface tension of a certain solution is 1N/m. Which is forming a square film on a
wire of side 5 cm. Find out the surface energy stored in mJ
21. The pressure inside the two soap bubbles be 1.05 atm and 1.10 atm respectively. Then if
the volume of second bubble is V and that of other will be x times V. Find x.
22. A liquid rises in a capillary tube whose 8 cm length extends out of liquid to a height of
4cm. Find the rise (in cm) of liquid in capillary if the whole experimental set up is kept in
a lift which is in free fall.
23. One end of a uniform glass capillary tube of inner radius 1.0mm is held vertically such that
one end is just dipped in pure water (surface tension = 0.07 N/m) and a length of 1cm is
2x
outside water. The radius of meniscus of free surface is mm. Find x.
10

24. The limbs of a manometer consist of uniform capillary tubes of radii 1.44 × 10-3 m and
7.2 × 10-4 m. If correct pressure difference in SI units if the level of the liquid (density
103 kgm-3, surface tension 72  103 Nm1 ) in the narrower tube stands 0.2 m above that in
the broader tube is given by 310 times k. Find k.
25. In a zero gravity region, a drop of a liquid of surface tension  assumes a cylindrical
shape of diameter D between two parallel glass plates that are a distance d apart. If
curved surface of the drop is at right angles to the plates as shown in the figure. The force
D
exerted by the drop on a plate is given find k.
k
26. Two soap bubbles of radii 2 mm and 4 mm are brought in contact. If the surface tension
of liquid is 7  10 –2 Nm –1 . Then calculate the radius (mm) of the common surface
SECTION – II
27. When large number of similar drops are merged together. Then:
(A) Surface energy decreases (B) Energy is evolved
(C) Energy is absorbed (D) Surface energy increases

28. Consider two hollow glass spheres; one of them containing water in approximately 10%
of its volume, and the other containing a similar volume of mercury. If the spheres are
brought in a zero gravity environment of a space-shuttle, what will you observe?
(A) Water and mercury both float in their spheres as spherical drops.
(B) Water forms a layer on inner surface of the sphere while mercury floats as a spherical
drop.
(C) Mercury forms a layer on inner surface of the sphere while water floats as a spherical
drop.
(D) In each case, some amounts of the liquids form layers on inner surfaces of the
spheres and remaining amounts floats as spherical drops.
29. When two soap bubbles of different radii coalesce, some portions of their surface make a
common surface, the three surfaces meet at angles ,  and  . Find incorrect relation(s)
(A)    (B)      (C)      (D)     

30. A hemispherical bowl of radius R is completely filled with water. The density of water is
 , the surface tension of water is T and the atmospheric pressure is p0 . Consider a
vertical section ABC of water through a diameter of top of bowl. The force in magnitude
on water on one side of the section by water on other side of the section is not given by

p0 R 2 R 3g p0 R 2 2R 3g
(A)   2TR (B)   2TR  TR
2 4 2 3
2 3 p0 R 2 2gR 3
(C) 2p0 R  gR  2TR (D)   2TR
2 3
31. Identify Correct statements

A) Surface tension of a liquid increases with increase in temperature
B) Surface tension of a liquid increases with decrease in temperature
C) Surface tension of lubricating oils is kept high so that they spread over large area
(D) Antiseptics have low values of surface tension

32. A capillary tube is immersed in a liquid. There will be :
(A) Ascent for angle of contact   900
(B) Ascent for angle of contact   900
(C) Descent for angle of contact   900
(D) Force of adhesion > Force of cohesion for   900
SECTION – III

33. The addition of soap solution to water changes surface tension from 1 to 2 , then 1 and
2 are related as
(A) 1  2 (B) 2  1
(C) 1  2 (D) can’t be predicted
34. A container contains two immiscible liquids of density 1 & 2 ( 2  1 ). A capillary of

radius r is inserted in the liquid so that its bottom reaches upto denser liquid. Denser
liquid rises in capillary & attain height equal to h which is also equal to column length of
lighter liquid. Assuming zero contact angle find surface tension of heaver liquid
r 2 gh r
(A) (B) 2r2gh (C)  2  1  gh (D) 2r(2  1 )gh
2 2
35. Drops of liquid of density  are floating half immersed in an immissible liquid of density
 . The surface tension of liquid is T then the radius of the drops are
3T 3T 3T 3T
(A) (B) (C) (D)
g(2  ) g(2  ) g(  2) 2g(   )
36. A vertical glass capillary tube of radius r open at both ends contains some water (surface
tension T and density  ). If L be the length of the water column, then :
4T 2T T T
(A) L  (B) L  (C) L  (D) L 
rg rg 4rg 2rg

CHEMISTRY Max Marks: 60
SECTION-I
37. Number of functional groups present in the given compound is
38. What is the sum of position number assigned to Bromine atoms while numbering the
parent chain in given structures. Report the answer by dividing the sum by 3
39. How many total number of substituent’s are in parent chain of given structure

40. According to IUPAC numbering, position of (-OH) & (-Br) in M and N
Find the sum of [M+N]

41. During estimation of nitrogen in an organic compound by Kjeldahl’s method, ammonia
evolved from 0.5 g of the compound is neutralized by 10 mL of 1M. H 2SO4 . The
percentage of N in compound is X? report the value of (x/molar mass of N)
42. Consider the following compound
x = Number of sp 2 hybridized C in the molecule
y = Number of 3o (tertiary) C in the molecule

z =Number of 4o (Quaternary) C in the molecule
Report the value of ( x – y – z)
43. How many of the following functional groups are given priority over – OH group in
IUPAC naming.
CHO,  NH 2 , COOH, CONH 2
CH  CH2 , C  C  H,  F,  O CH3 ,
SH,  COOCH 3 , C  N ,
44. Number of organic molecules whose name is correctly written according to IUPAC
system.
A.
4- Formyl-5-oxo cyclopentane-1, 3-dicarboxylic acid.
B.
3- Bromo-4-(hepta-2,4,5-trienyl) cyclopenta-2, 4-dien-1-ol
C.
3-Ethyl-5,5- diisopropyl – 7 – methylnonane
NH
||
D. C| H 2  C C| H  CH 2  CONH 2
CONH 2 CONH 2
3- Imino-4-carbamoylhexane-1, 6- diamide
E.
5-Ethylidene-2-methylcyclopentan-1-one
CH 2COOH
|
F. C| H 2  CH 2  C H  CH 2  CH 2  COOH
COOH
3-carboxymethylheptane-1,7-dioic acid
SECTION – II
45. Which of the following Structures have correct indicated IUPAC

nomenclature/Common Name
A)
Iso-propyl-3-( 2 -bromo- 3 -hydroxypropylidene) cyclopentane carboxylate
B)
3-chlorocarbonylMethyl-6-(N,N-diethylamino) hex-4-en-1-oic acid
C) Isoctane
D) CH  C  CH  CH 2
But-3-en-1-yne
46. Which name is correct for the following compound
CH3  C H  C  N
|
CH3
(A) 2-methyl propanenitrile (B) Isobutyl cyanide
(C) Isobutyronitrile (D) Isopropyl cyanide
47. Consider the given statements
(i) Acetone and acetaldehyde are homologues.
(ii) is secondary amine while is a tertiary amine.
(iii) is a secondary alcohol while is a tertiary alcohol.
(iv) and both have different functional groups

Which is incorrect?
(A) i (B) ii (C) iii (D) iv
48. Which of the following name will NOT be correct?
(A) =3,6-Dimethyl cyclohexene
(B) =1,2-Dimethyl cyclohexene
(C) =6,6-Dimethyl cyclohexene
(D) =1,5-Dimethyl cyclohexene

49. How many of the following compounds have locant ‘2’ in their IUPAC name?
(A) (B)
(C) (D)
50. How many of the following are correctly matched? (Consider both IUPAC & common)
(A) 2-ethyl-1,
1- dimethylcyclopropane
(B) n-Propylcyclohexane
(C) Cyclopropyl propionate
(D) penta-2, 4-dienal
SECTION – III

51. What is the structure for 2,5-dimethyl-1,3-cyclopentadiene?
(A) (B) (C) (D)

52. The IUPAC name of the given compound is
CHO CONH 2
| |
CH 3  C H  C H  C H  CH  COOH
| |
Br COCl
(A) 2-Bromo-4-carbamoyl-5-chloroformyl-3-formylhexanoic acid

(B) 5-Bromo-3-carbamoyl-3-chloroformyl-4-formylhexanoic acid
(C) 4-Formyl-2-chloroformyl-3-carbamoyl-5-bromohexaoic acid
(D) 2-Chloroformyl-3-carbamoyl-4-formyl-5-bromohexanoic acid
53. IUPAC name of isopentyl alcohol is
(A) 1-Hydroxy-2-methyl pentane (B) 3-Methyl butan-1-ol
(C) 2-Methyl propanol (D) 2-methyl-2-butanol
54. IUPAC name of the following compound is
(A) 2-(1-carboxyethyl)-4-methyl pentanoic acid

(B) 3, 5-Dicarbixy-3-methyl hexanoic acid
(C) 2, 4, 5-Hexane tricarboxylic acid
(D) 2,3,5-Hexane tricarboxylic acid


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Sri Chaitanya IIT Academy., India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

Name of the Student: ___________________ H.T. NO:

Sec: Jr.Super60_NUCLEUS & STERLING BT Space for rough work Page 2

l  m  n, and l , m, n are the roots of the cubic equation x 3  x 2  4x  4 then 9cos =

Sec: Jr.Super60_NUCLEUS & STERLING BT Space for rough work Page 3

Sec: Jr.Super60_NUCLEUS & STERLING BT Space for rough work Page 4

Sec: Jr.Super60_NUCLEUS & STERLING BT Space for rough work Page 5

(A) The equation of P1 is x + y = 2

(C) The acute angle between P1 and P2 is cot 1( 3) .

Sec: Jr.Super60_NUCLEUS & STERLING BT Space for rough work Page 6

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(A)    (B)      (C)      (D)     

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31. Identify Correct statements

(D) Antiseptics have low values of surface tension

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34. A container contains two immiscible liquids of density 1 & 2 ( 2  1 ). A capillary of

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Find the sum of [M+N]

x = Number of sp 2 hybridized C in the molecule

y = Number of 3o (tertiary) C in the molecule

CH  CH2 , C  C  H,  F,  O CH3 ,

45. Which of the following Structures have correct indicated IUPAC

(ii) is secondary amine while is a tertiary amine.

(iii) is a secondary alcohol while is a tertiary alcohol.

(iv) and both have different functional groups

(A) =3,6-Dimethyl cyclohexene

(B) =1,2-Dimethyl cyclohexene

(C) =6,6-Dimethyl cyclohexene

(D) =1,5-Dimethyl cyclohexene

(C) Cyclopropyl propionate

(D) penta-2, 4-dienal

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(A) (B) (C) (D)

(A) 2-Bromo-4-carbamoyl-5-chloroformyl-3-formylhexanoic acid

(A) 2-(1-carboxyethyl)-4-methyl pentanoic acid

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