Hand written note by DP SIR

For quick revision.

For
IIT JEE
NEET
CLASS 11TH
The properties which show gradual change when we move from left
to
night in period and top to bottom in group called periodic
proper ties
a a are

Atomic size : It is defined as distance between centre of nucleus of an

atom to it's out most shell

of electrons It is expressed in terms of
following
em .

three radius :

Covalent radius
a Mettalie radius Vanden Waal 's radius
b c

It depends on
following factors :

a Number of shells : Atomic radius increases with increase in number

of shells .

b.Effective nuclear charge : Atomic radius decreases with increase in

effective nuclear change .

Multiplicity of bond : Atomic radius decreases with increase

multiplicity
C in
of bonds .

Example :

I radius of
77 Pm 67 Pm 60 pm

Variation of atomic radii :

i On down the atomic radius increases due to increase

moving group the
in number of shell .

atomic radius decreases due to

moving left to right in period
ii On
increase
in effective
nuclear charge .
,

Important points :

✓ Increase of atomic radii is more in the beginning of a group

in
magnitude
difference in
,

since,
✓ Decrease
energy between energy shells is more .

in
magnitude of atomic radii is more among representative elements
among transition elements since e-s are added to penultimate shells
than ,
.

✓ Small increase in atomic radii in end

of a period is due to the fact
that, VandenWaal radius is measured for the noble gases
's .

Van der Waal 's radius > Covalent radius

Ionisation enthalpy It is the amount of energy

:
required to
remove most bound electron from
loosely isolated an
gaseous atom .

Acg, t I. E - >
Atcg , t e-

Successive Ionisation Enthalpies :

Acg , Acg , AFG AT81

It a @Chem infusion
Units of I. E .
: Ie v1atom = 23.06 KCallmob =
93.6 KJI mob
Factors affecting I. E .

I
a- Atomic size : I EdAfricaine
.

1
a
screening effect : I. E. A
Tueeeningeffeet
Effective I E A Nucleate
3 nuclear
change : . .

Charge
4 Electronic Configuration : fully filled > half filled > normal
5 Penetration effect : I penetration effect configuration
.
E. a
→ The order
of penetration effect is s > p > d >f
Variation of I. E .

In I E increases due to
1
decrease
left
a to
night
period
in atomic
,
as we move . .

size .

2 In
group .
as we move down ,
I E .
. decreases due to increase in
atomic size .

Points to
grab attention : .

I In second period :

I. E. his Be > Be Cs N > OC FL Ne

I. Ez Li > Bec B > CINCO > FL Ne

2 In third period :

I. E Nac Mg > Alcs : Cp > sects Are

,

I. Ez Na >
Mgc Al > sic PCs > Us Are
3. Element with Lowest I E. .
= Cs
Element with
highest I. E. = He

where
4
Leff =L G -

Zeff effective nuclear

=
change
Actual nuclear
2 =
change
Slaters coast const
• on
screening
=
.

www.thecheminfusion.com
 Flew

t.to/:::f:e:.#
Electrons -

in th
subshells nth shell Ch 1) -
Cn -
2) ( n -
3) . . . . .
..

¥351.001.0
Electron Gain electron affinity
Enthalpy ore : .

Amount
of when electron is added to an
enthalpy
isolated change
gaseous atom
Meg , + e- Mig
.

I
→
, ; egH
Factors
affecting election affinity : .

1 Atomic size : E. A X-1

Atomic size
2
Effective nuclear
change : E AA Left
.

3.
Stability of electronic
configuration : Elements
having
fully filled on half filled configuration have very low on aereo
value of E A and
Aeg H = tire-
- .

Variation of E. A .
: -

1 Variation in
as atomic
period :
size decreases
Along the period
.
the E. A increases

2 Variation in Down the E. A decreases as the

atomic size
group
increases
:

.
group .

Points to grab attention

:{
Among
Among high
all elements U
all metals ,
'
has
Au has
main E. A Value
E. A . .
.
.

3 I E .

of
= X E. A
of xt
4 U IF 7 Br > I
5 S >O > P > N

Electronegativity
attract It is the
tendency
shared pain of e- towards itself
of
: atom to
-

s .
an

Facebook Chem infusion :

Factors affecting
z
E. N :

a- Atomic size
E.NL#omicSiIe :

2 Nuclear
change E. No nuclear change :

#
3
Screening effect E. Na screening effect :

4 % of S Character : E. N a %
-

of S -
Character

Various E. N scales : -

scale C Bond
1
Pauling energy scale ) :

Na NB- = O 1017 VE ( if
. I in KJImol)

=
0.208 VE ( if I in KCallmot )
And
D= Ea -
B
-

{ ( EA at EB B ) - -

Note :

Fore reference ,
take Na =2.1
masem E. N f- 4)
On this scale F is found to have
TEA
2 Mul liken scale :
Na =

na
I er = kcallmol =
¥f¥A KJImot
Relationship between Mulliner and
N multiKen
Pauling scale : -

N
pauling -2.8
3. Allred Roc how scale
-
: E. N .
=
+0.744
Covalent radius defective nuclear
7- .
Legg =
change
Variation of E. N : -

the period E. N increases

1
Along
2. Down the E. N decreases
.
.

group ,
.

Summary of Variation of periodic properties :

jcproperydownmgoyeft-wugu.im
{1l"
4 I
Atomic size

www.#ingusin.C0M
 :f:÷÷¥##
Io##kT
Elect
Electronegativity I t

Valency constant First '

#
Reducing ability
#
T t

Jyoti : T increases
:

* i. decreases
 channel for
Follow
my instagram daily Q !A session

@ Chem
II G infusion