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Applied Energy
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h i g h l i g h t s
We develop a plant layout for Adiabatic Compressed Air Energy Storage (A-CAES) aiming at lower thermal storage temperatures.
We show that roundtrip efficiency of A-CAES is independent of the temperature level of the stored heat of compression.
The proposed plant concept delivers fast cycling capabilities allowing for a plant start-up <5 min.
Compared to high temperature A-CAES the proposed plant concept shows better profitability due to fast cycling capabilities.
a r t i c l e i n f o a b s t r a c t
Article history: Most of the recent approaches on Adiabatic Compressed Air Energy Storage (A-CAES) aim at Thermal
Received 17 September 2013 Energy Storage (TES) at high temperatures. High TES temperatures together with high pressures intrinsic
Received in revised form 3 February 2014 to CAES are not easy to handle. In order to avoid this technical challenge, we introduce a low-temperature
Accepted 8 March 2014
Adiabatic Compressed Air Energy Storage (LTA-CAES) plant. We select and design multistage radial com-
Available online 16 April 2014
pressors and expanders with single stages rotating with different speeds allowing for intermediate cool-
ing and reheating of the air flow. The proposed LTA-CAES design shows roundtrip efficiencies in the range
Keywords:
of 52–60%, slightly lower compared to those envisioned for high temperature A-CAES. However, it can be
Compressed Air Energy Storage
Adiabatic
shown in an economic analysis that its fast start-up characteristics and wide-ranging part load ability
Thermal Energy Storage overcompensates the lower cycle efficiencies with regard to plant profitability.
Two-tank system Ó 2014 Elsevier Ltd. All rights reserved.
GOMES
LTA-CAES
http://dx.doi.org/10.1016/j.apenergy.2014.03.013
0306-2619/Ó 2014 Elsevier Ltd. All rights reserved.
D. Wolf, M. Budt / Applied Energy 125 (2014) 158–164 159
Fig. 1. Simplified block diagram of the first compressed air energy storage plant located in Huntorf, Germany.
2. Current A-CAES design approaches of the A-CAES designs mentioned above, including a significant fas-
ter start-up behavior and will be described in detail in the following.
Up to now A-CAES plants have only been realized on laboratory
scale [15]. Recently, several design approaches for A-CAES plants 3. Idea behind low-temperature A-CAES
on larger scale have been proposed [16,17]. These approaches are
characterized by applying TES at comparably high temperatures Conventional thermal power plants applying Rankine and Joule
of around 600 °C. At such elevated temperatures the TES comprises cycles can be considered pure heat engines. Here, heat as the only
a pressurized packed bed being operated in thermocline mode input energy stream is transferred into useful work. The intrinsic
[18]. The concrete jacket of the pressurized TES container has to nature of heat engines dictates that an increase in maximum
be cooled actively in order to guarantee a safe operation. Main process temperature directly translates into an increase in thermal
advantage of such a design approach is the usage of relatively inex- efficiency. This especially holds true for gas turbines, where the
pensive solid TES material. Furthermore, there is no need for addi- temperature of the hot combustion gases mostly determines the
tional heat exchanging devices, since the TES material is in direct thermal efficiency to be achieved. While 30–40 years ago hot gas
contact with the compressed air [19]. Howsoever, this high-tem- temperatures below 900 °C were still common, current gas
perature TES also leads to some technical challenges such as: turbines are designed for hot gas temperatures of more than
1400 °C [27].
– Currently available turbo compressors are limited to outlet tem- The direct relation of maximum process temperature and
peratures far below 600 °C. Consequently, new compressors theoretically attainable thermal efficiency of any heat engine can
have to be designed and developed with high interstage and be expressed by the Carnot efficiency gCarnot.
discharge temperatures [16]. T min
– Due to the coexistence of high temperatures (600 °C) and gCarnot ¼ 1 ð1Þ
T max
pressures (70 bar) in the TES, a high constructional and main-
Herein, the ratio of minimum process temperature Tmin and
tenance effort has to be accepted [17].
maximum process temperature Tmax gives an upper efficiency
– Thermal and mechanical stress may lead to attrition of TES
limit, which can be approached but never be achieved by real
material releasing small particles into the air, which could cause
processes. The Carnot relation governs all heat engines, in which
damage to the inlet blading as well as the expander wheels
heat as only energy source is transformed into useful work. This
[19,20].
includes Rankine cycles (steam power plants) and Joule cycles
– High temperatures require a rather slow start-up from cold
(gas turbines).
start limiting the A-CAES plant to applications with a start-up
Diabatic CAES being derived from an open cycle gas turbine in
time of 15 min and above [18].
part can be considered a heat engine. Here, an increase in turbine
inlet temperature still results in a higher thermal efficiency. How-
Summarizing current high-temperature TES approaches, A-
ever, for pure electric storage devices such as A-CAES plants the
CAES can be considered promising but they also involve high
magnitude of interest is not the thermal efficiency but the cycle
development and testing efforts along with considerable technical
or round trip efficiency. Identical to any other pure electrical stor-
challenges.
age device the cycle efficiency g cycle of an A-CAES is calculated by
One possible way to overcome these challenges is to lower the
the ratio of electrical energy delivered while discharging Edch,el to
TES temperature. Therefore, different A-CAES concepts on a mid-
energy consumed for charging the storage Ech,el.
temperature level around 400 °C were presented during the last
years [21,22]. In these concepts the challenges concerning the Edch;el
TES and compressor technology are avoided, while the rather slow
gcycle ¼ ð2Þ
Ech;el
start-up behavior remains.
The latest development on this road to lower temperatures fo- Having only electrical input and output energy streams A-CAES
cuses on TES temperatures in the range of 80–200 °C [23–26]. plants cannot be classified as heat engines. Therefore, the overall
The low-temperature Adiabatic Compressed Air Energy Storage A-CAES cycle efficiency is not governed by the Carnot efficiency
(LTA-CAES2) presented in this paper aims to avoid all the challenges [28]. The next question to ask would be if cycle efficiency of
A-CAES is dependent on the maximum process temperature at
all. This question can be answered simply by using the ideal gas
Ò
2
LTA-CAES is a registered trademark of Fraunhofer UMSICHT. law,
160 D. Wolf, M. Budt / Applied Energy 125 (2014) 158–164
pv ¼ RT ð3Þ
stored without thermal stratification in a two-tank system – one designed for this application. However, they do not require signif-
tank for the cold, one for the hot TES liquid. As can be seen in icant testing efforts or new materials to be applied. The LTA-CAES
Fig. 3 the compression and expansion processes are desired to con- system as depicted in Fig. 3 requires four of these pure counter-
sist of several individual stages each comprising aftercooling or flow heat exchangers. Because of the need to reach TES tempera-
preheating, respectively. tures as close as possible to the air temperature at the compressor
The process scheme of Fig. 3 essentially shows two different outlet, the main heat exchangers need a transfer surface up to five
types of heat exchangers being applied in the compression process. times larger than usually. Of course, the required transfer surface
The intercooler (IC) type rejects a small part of the absorbed heat to depends on the desired terminal temperature difference, which is
the ambience. The other type discharges the extracted heat of com- directly linked to the resulting TES temperature and therefore to
pression to the hot TES tank, where the heat exchanging liquid is the achievable cycle efficiency of the storage. Hence, the heat ex-
stored as is. The same heat exchangers are applied to preheat the changer dimensioning is carefully optimized in the present project.
air during expansion process. This optimization is of special importance, since the main heat ex-
The intended fast plant start-up limits the compressor dis- changer components represent a significant part of the capital cost
charge temperature to a maximum of 200 °C. Therefore the maxi- not as high but in the same range as the cost of the turbomachinery
mal TES temperature lies, depending on the heat exchangers itself. Therefore, a well balanced solution taking into account cap-
terminal temperature difference, slightly below this point. The ital cost against possible plant revenues has to be found. Depend-
lower boundary of the hot TES temperature range is set to 95 °C. ing on the chosen thermal solution roundtrip efficiencies from 0.52
This corresponds to the highest temperature water at ambient to 0.60 can be achieved [30].
pressure can be dealt with safely at liquid state. In any case the
TES medium has to be pumpable, because of the determination 4.2. Turbomachinery
to conventional heat exchanger technologies. Furthermore, the
TES medium has to deliver defined inlet temperatures to the heat The aim of low TES temperatures requires recooling of the air at
exchangers during the charging and discharging process and hence various points throughout the whole compression process. For this
has to be stored in at least two separated tanks. The number of purpose large single-shaft trains with axial blading or radial inline
applicable media under these boundary conditions and in this tem- compressors are not appropriate. Axial turbo compressors de-
perature range is rather small. Only water and thermal oil can be signed for high pressure ratios consist of many stator and rotor
used, whereby thermal oil is much more expensive and has a lower disks, arranged one after the other. Such types of compressors do
heat capacity at the same time. Therefore, water is the first choice. not allow intermediate recooling of the air, which is a prerequisite
It provides a high heat capacity, is generally available, cheap and for maintaining low TES temperatures. Radial type inline compres-
not endangering the environment. The main difficulty is that water sors can be intercooled between the stages, but the number of
needs to be pressurized for temperatures above 95 °C to prevent stages is limited to five and very special intercoolers are integrated
evaporation. parts of the compressor with low accessibility. Therefore, the most
Depending on the system temperature the LTA-CAES plant con- appropriate compressor types for LTA-CAES-plants are integrally
cept applies up to four heat exchangers (IC) to recool the com- geared radial turbocompressors allowing for up to ten intercooled
pressed air (compare Fig. 3). These auxiliary heat exchangers use stages. This kind of turbocompressor has a clear advantage when
normal cooling water rejecting the heat to the ambience. The heat realizing low storage temperatures and is chosen as basic turboma-
rejected here comprises only a small portion of the overall heat of chinery concept for the LTA-CAES plant. With this turbomachinery
compression. The auxiliary heat exchangers are designed as a concept it is possible to recool the air after each stage. Fig. 4 shows
cross-counter-flow shell-tube configuration and are of well proven a 3D rendering of the designed LTA-CAES plant in the configuration
design. of 50 MWComp/30 MWTurb and 150 bar. The shown plant works at a
In contrast, the main heat exchangers required to charge and TES temperature of 150 °C. Therefore the compressor is recooled
discharge the TES of the LTA-CAES are components especially after each stage and both machines are connected to the same heat
162 D. Wolf, M. Budt / Applied Energy 125 (2014) 158–164
Table 1 1,800
Fig. 6. Specific break-even capital costs calculated for the time period from 2008 to
2011.
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