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CET-2.

O
Some Basic Concept of
Chemistry
1. 0.24g of a volatile gas, upon vaporisation, gives 45 6. The molar mass of diacidic organic Lewis base (B), if
mL vapour at NTP. What will be the vapour density of 12 g of chloroplatinate salt (BH PtCl ) on ignition
2 6

the substance? produced 5 gm residue of Pt,will be -


(Density of H2 = 0.089) 1. 52
1. 95.93 2. 58
2. 59.93 3. 88
3. 95.39 4. None of these
4. 5.993
7. What volume of 75% alcohol by weight (d=0.80g/
2. The number of moles of BaCO3 which contains 1.5 cm ) must be used to prepare 150 cm of 30% alcohol
3 3

moles of oxygen atoms is: by weight (d=0.90 g/cm )? 3

1. 0.5 1. 67.5 mL
2. 1 2. 56.25 mL
3. 3 3. 44.44 mL
4. None of these
4. 6.02 ×1023
8. The percentage of oxygen present in the compound
3. 25.3 g of Sodium carbonate Na2CO3 is dissolved in
CaCO . 3 Ca3 (PO ) is-
3 4
enough water to make 250 mL of 1. 23.3%
2

solution. If sodium carbonate dissociates completely, 2. 45.36%


molar concentration of sodium ion, 3. 41.94%
Na+ and carbonate ion CO are respectively (Molar
2−

3 4. 17.08%
mass of Na2CO3 = 106 g mol-1)
1. 0.955 M and 1.910 M 9. In the given diagram, the paired open spheres
2. 1.910 M and 0.955 M represent H molecules and the paired solid spheres
2

3. 1.90 M and 1.910 M represent N molecules. When the molecules in the box
2

4. 0.477 M and 0.477 M react to form the maximum possible amount of ammonia
(N H ) molecules, what is the limiting reactant and how
3

4. Concentrated aqueous sulphuric acid is 98% H SO many molecules of N H can be formed?


3
2 4

by mass and has a density of 1.80 g mL-1. Volume of


acid required to make one litre of 0.1 M H2S04 solution
is :
(1) 11.10 mL
(2) 16.65 mL
(3) 22.20 mL
(4) 5.55 mL

5. Phosphoric acid (H PO ) prepared in a two step


3 4

process.
(1) P + 5O → P O
N is a limiting reactant, 5 molecules of NH3 can be
4 2 4 10

(2) P O + 6H O → 4H PO
4 10 2 3 4 1. 2
We allow 62g of phosphorus to react with react with formed
excess oxygen which form P O in 85% yield. In the N is a limiting reactant, 10 molecules of NH3 can
4 10
2. 2
step (2) reaction 90% yield of H PO is obtained. 3 4 be formed
Produced mass of H PO is:
3 4
H is a limiting reactant, 8 molecules of NH3 can
1. 37.485 g 3. 2
be formed
2. 149.949 g
3. 125.47 g H is a limiting reactant, 12 molecules of NH3 can
4. 2
4. 564.48 g be formed

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10. How many atoms of hydrogen are there in 3.0 kg of 17. A compound contains 4.07% hydrogen, 24.27%
ethane? carbon and 71.65% chlorine. Its molar mass is 98.96 g.
[relative atomic mass: H=1, C=12; Avagadro constant= Its empirical and molecular formulas are respectively -
6. 0 × 10
23
per mol] 1. CH2Cl and C2H4Cl2
1. 3. 6 × 10 26
2. CH3Cl and C2H6Cl2
2. 3. 9 × 10 26
3. C2HCl and C4H2Cl2
3. 6. 0 × 10 25

4. C2HCl and C2H4Cl2


4. 3. 6 × 10 23

18. A solution is prepared by adding 2 g of substance A


11. Two solutions of a substance (non electrolyte) are
to 18 g of water. The mass percent of the solute is-
mixed in the following manner.
1. 20%
480 ml of 1.5 M first solution + 520 mL of 1.2 M second
2. 10%
solution. What is the molarity of the final mixture?
3. 15%
1. 1.20 M
4. 18%
2. 1.50 M
3. 1.344 M
19. The mass of ammonia in grams produced when
4. 2.70 M
2.8 kg of dinitrogen quantitatively reacts
with 1 kg of dihydrogen is- .
12. Maximum number of oxygen atoms are present in:
1. 3600 g
1. 24 gm O 3
2. 3000 g
2. 11 gm CO 2
3. 3400 g
3. 32 gm SO 2
4. 4000 g
4. 8 gm O 2

20. 6.023 × 1022 molecules are present in 10 g of


13. Which has the maximum number of molecules
among the following? substance ‘x’. The molarity of a solution containing 5 g
1. 64 g SO2 of substance ‘x’ in 2L solution is-
1. 0.00025
2. 44 g CO2
2. 2.5
3. 48 g O3 3. 0.025
4. 8 g H2 4. 25

14. The number of significant figures in 1.0001 are 21. The ratio of masses of oxygen and nitrogen in a
1. 1 particular gaseous mixture is 1:4. The ratio of a number
2. 2 of their molecule is:
3. 4 1. 7:32
4. 5 2. 1:8
3. 3:16
15. Which will have the largest number of atoms among 4. 1:4
the following?
1. 1 g Au (s) 22. 0.1 mole of carbohydrate with empirical formula
2. 1 g Na (s) CH2O contains 1 g of hydrogen. What is its molecular
3. 1 g Li (s) formula?
4. 1 g of Cl2(g) 1. C5H10O5
2. C6H12O6
16. The molecular mass of the glucose (C6H12O6) is- 3. C4H8O4
1. 178.156 u 4. C3H6O3
2. 182.162 u
3. 181.142 u
4. 180.162 u

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23. The number of atoms in 560 g of Fe (atomic mass 27. In the following reaction:
56 g mol-1 ) is: 4H Cl + M nO2 → 2H2 O + M nCl2 + Cl2

1. Twice that of 70 g N Amount(in g) of manganese dioxide that reacts with 7.3


g of HCl is:
2. Half that of 20 g H
(Atomic weight of Mn is 55)
3. Both 1 and 2 1. 0.23
4. None of the above 2. 5.85
3. 4.35
4. 5.18
24. Given below are two statements:
Atoms can neither be created nor 28. Mass of H2O formed on reaction of 11.2 L H2 and
Assertion (A):
destroyed. excess O2 at STP will be:
Under similar conditions of temperature 1. 18 g
and pressure, an equal volume of 2. 9 g
Reason (R):
gases do not contain an equal number of 3. 36 g
molecules. 4. 4.5 g

Both (A) and (R) are true and (R) is the correct 29. In an experiment it showed that 10 mL of 0.05 M
1.
explanation of (A). solution of chloride required 10 mL of 0.1 M solution of
Both (A) and (R) are true but (R) is not the correctAgNO3, which of the following will be the formula of
2.
explanation of (A). the chloride (X stands for the symbol of the element
3. (A) is true but (R) is false. other than chlorine):
4. Both (A) and (R) are false. 1. X2Cl2
2. XCl2
3. XCl4
25. The moles of methane required to produce 81 g of 4. X2Cl
water after complete combustion is A× 10-2 mol. The
value of A is: 30. Consider the following reaction:
[nearest integer] CS2 + 3O2 → CO2 + 2SO2
1. 240 2. 225 How much carbon disulfide must be used to produce 64
3. 204 4. 198 grams of SO2?
1. 38 g
2. 57 g
26. The minimum mass of sulphur dioxide needed to 3. 76 g
make 500 mL of a solution of concentration 3.0 mol / L 4. 114 g
is:
[Atomic mass values: O = 16; S = 32]
1. 32 g
2. 96 g
3. 192 g
4. 384 g

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