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Consumer Chemistry
Quarter 1 - Module 4
Alcohols, Ethers and Aldehydes
Consumer Chemistry – Grade 9
Alternative Delivery Mode
Quarter 1 - Module 4: Alcohols, Ethers and Aldehydes
First Edition, 2020
Management Team
Gregorio C. Quinto, Jr., EdD
Chief, Curriculum Implementation Division
Rainelda M. Blanco, PhD
Education Program Supervisor - LRMDS
Agnes R. Bernardo, PhD
EPS-Division ADM Coordinator
Glenda S. Constantino
Project Development Officer II
Marinella P. Garcia Sy, PhD
EPS – Science
Joannarie C. Gracia
This module was collaboratively designed, developed and reviewed by educators from
public institutions to assist you, the teacher or facilitator, in helping the learners meet the
standards set by the K to 12 Curriculum while overcoming their personal, social, and
economic constraints in schooling.
This learning resource hopes to engage the learners into guided and independent learning
activities at their own pace and time. Furthermore, this also aims to help learners acquire
the needed 21st century skills while taking into consideration their needs and
circumstances.
In addition to the material in the main text, you will also see this box in the body of the
module:
As a facilitator, you are expected to orient the learners on how to use this module. You also
need to keep track of the learners’ progress while allowing them to manage their own
learning. Furthermore, you are expected to encourage and assist the learners as they do
the tasks included in the module.
1
This is a brief drill or review to help you link the
What’s In
current lesson with the previous one.
2
What I Need to Know
What I Know
Read the following questions and answer each by writing the CAPITAL letter that
corresponds to your BEST response. Write your answers on a separate sheet of
paper.
3
4. What is the IUPAC name of the organic compound below?
A. Ethane
B. Ethanone
C. Ethanal
D. Acetic acid
5. Alcohol is less volatile than ether having the same molecular formula. This is due
to the fact that
A. alcohols have resonance structures.
B. ethers have dipolar character.
C. alcohols have inter-molecular hydrogen bonding.
D. ethers have inter-molecular hydrogen bonding.
A. C.
B. D.
4
12. Which of these would you expect to have the lowest boiling point?
A. CH3-CH2-CH2-OH C. CH3-O-CH3
B. CH3-CH2-O-CH2-CH3 D. CH3-CH2-CH2-CH2-OH
13. What functional group can never be found at the end of a carbon chain?
A. alcohol C. aldehyde
B. ether D. no correct response
What’s In
Below are some aromatic compounds (arenes) that you have learned in the
previous module. Name and draw the structure of each. Write your answers on a
separate sheet of paper.
a. b. c.
Cl CH2CH3 CH(CH3)2
5
2. Draw the structure of each of the following organic compounds.
a. benzaldehyde
b. benzoic acid
c. phenol
c. 1,3-dimethylbenzene
d. 3-ethylphenol
Now that you know how to name and write the structures of aromatic
hydrocarbons, let’s proceed with another interesting organic compounds.
Are you ready?
What’s New
Observe the pictures below. What do you notice? Can you identify each of the
substances being used? Describe and name each of them. Write your answers on a
separate sheet of paper.
A. B.
C.
Let us uncover more about the given pictures above to deepen your
understanding regarding them.
6
Alcohols, Ethers and Aldehydes
What is It
Alcohols
Alcohols are functional groups characterized by the presence of an -OH
group. They are organic compounds in which the hydroxyl functional group (-OH) is
bound to a carbon atom. In addition, they are an important class of molecules with
many scientific, medical, and industrial uses.
Structure and Properties of Alcohols
The same with water, the structure of an alcohol has a
bent shape. The presence of the -OH groups allows for
hydrogen bonding with other -OH groups, hydrogen atoms
and other molecules (polar). Since alcohols are able to
hydrogen bond, their boiling points are higher than those of
their parent molecules. Furthermore, their solubility in water
decreases with increase in molecular mass. Methanol,
ethanol, and propanol are miscible in water.
Before we reveal more about alcohols, let’s explore first the two ways
on how they are given names by doing the next activity.
What’s More
INDEPENDENT ACTIVITY 1
Objectives:
● Draw the structural formula of the given alcohols.
● Write the two acceptable names for alcohols.
Materials:
paper and pen
7
Procedures:
Analyze and complete the table by following the step by step instructions
below. Write your answers on a separate sheet of paper.
CH3-CH2- C2H5OH
OH
CH3-CH-OH C3H7OH
-CH3
(CH3)3COH C4H9OH
CH3-CH2- C5H11OH
CH2- CH2-
CH2-OH
Step 3. In the common name column, write the name of simple alcohol as
alkyl alcohol; for example, CH3OH is methyl alcohol (combine the name of the
alkyl group with the word alcohol).
8
Step 4. In the final column, using the IUPAC system, add the suffix “-ol” to
the parent chain of the alkane name. The position of the −OH functional group is
indicated in the name. Numbering starts with the parent chain on the end closest
to where the −OH is located. For example, the IUPAC name of the compound
CH3OH is methanol.
Guide Questions:
Q2. What are the two names of the compound shown below?
Explain your answer.
In addition, compounds with more than one -OH are named as diols
(2 -OH), triols (3 -OH), etc., as shown below.
In your previous activity you have learned that alcohols fall into different
classes depending on how the -OH group is positioned on the chain of carbon
atoms. Shown below are their structures with common and IUPAC names.
9
For your further understanding in naming alcohols, below are other examples:
Uses of Alcohols
Alcohols are important compounds. They are used as sweeteners and in
making perfumes. They are also valuable intermediates in the synthesis of other
compounds. Other uses of alcohols are as follows:
Ethanol (also called alcohol, ethyl alcohol and grain alcohol) is a clear,
colorless liquid and the principle ingredient in alcoholic beverages like beer,
wine or brandy. It is also an ingredient in a range of products, from personal
care and beauty products to paints and varnishes to fuels.
Methanol (also known as methyl alcohol) is a highly versatile chemical
and is widely used for industrial purposes. It is also used as a solvent and as a
raw material for the manufacture of formaldehyde.
INDEPENDENT ASSESSMENT 1
Analyze the structures of the following alcohols and give the IUPAC name of each.
Write your answers on a separate sheet of paper.
1. 2.
3.
10
4. 5.
Now that you understand how to draw and name alcohols, let us now
proceed with another organic compounds that may be considered a derivative
of water in which both hydrogen atoms are replaced by alkyl or aryl groups,
the ethers.
Ethers
The types of organic compounds that contain oxygen between two alkyl or
aryl groups are the ethers. They have the general formula R-O-R', with R's being
the alkyl groups. Aside from being considered as a derivative of water, they may
also be considered as a derivative of alcohol (ROH) in which the hydrogen atom of
the -OH group is replaced by a second alkyl or aryl group:
11
Ether molecules do have an oxygen atom, however, and engage in hydrogen
bonding with water molecules. Accordingly, an ether has about the same solubility
in water as the alcohol that is isomeric with it. For example, dimethyl ether and
ethanol (both having the molecular formula C2H6O) are completely soluble in water,
whereas diethyl ether and 1-butanol (both C4H10O) are barely soluble in water
(8 g/100 mL of water) and are tasteless.
So far, you have learned the structure and properties of ethers. Before
proceeding with the uses of ethers, you will first experience how to name
ethers in two (2) acceptable ways.
INDEPENDENT ACTIVITY 2
12
Step 1. In the structural formula column, draw the 2-dimensional structure of
each of the given ethers base on their condensed or molecular formulas.
Step 2. In the classification column, classify ethers into two categories based
on their attached substituent groups. The compound is said to be symmetrical if
two identical groups are attached to either side of an oxygen atom and
asymmetrical if two different groups are attached to either side of an
oxygen atom.
Step 3. In the common name column, use the alkyl alkyl ether system or
simply write the names of the groups attached to the oxygen atom (arrange them
alphabetically), followed by the generic name ether. For example, the common
name of the compound CH3–O–CH2CH2CH3 is methyl propyl ether. Moreover, if
both groups are the same, the group name should be preceded by the prefix
di-, as in dimethyl ether (CH3–O–CH3).
Step 4. In the final column, using the IUPAC system, (ether functional group
does not have a characteristic IUPAC nomenclature suffix, so it is
necessary to designate it as a substituent) find the shorter alkyl group (becomes
the alkoxy substituent) and the longer alkyl group side (becomes alkane
base name). Each alkyl group on each side of the oxygen is numbered
separately. The numbering priority is given to the carbon closest to the oxygen.
The alkoxy side (shorter side) has an "-oxy" ending with its corresponding
alkyl group. For example, the IUPAC name of the compound CH3-O-CH3 is
Methoxymethane.
Guide Questions:
Q4. What are the two names of the compound (CH 3)2CH-O-CH
(CH3)2?
13
Moreover, in cyclic ethers, the stem of the compound
is known as a oxacycloalkane. The “oxa” is an indicator of
the replacement of the carbon by an oxygen in the ring. An
example is oxacyclopentane (Tetrahydrofuran (THF),
Tetrahydrofuran
a five-membered ring in which there are four carbon atoms (THF) is a common
and one oxygen atom. organic solvent that is
miscible with water.
Uses of Ethers
Ethers are desirable solvents for fats, oils, waxes, perfumes, resins, dyes,
gums, and hydrocarbons. In addition, vapors of certain ethers are used as
insecticides and fumigants for top soil. Other uses of ethers are as follows:
Dimethyl ether (Methoxymethane) or otherwise known as codeine is an
effective pain-relieving drug, and is the primary ingredient in morphine.
Diethyl ether (Ethoxyethane) or often referred to as just “ ether,” is used as
a reaction or extraction solvent in the chemical, fragrance, and pharmaceutical
industries. It was one of the first anesthetics used for surgical procedures
during the 1800s.
Methyl t-butyl ether (MTBE) is a gasoline stabilizer which increases octane
concentration and reduce pollutants.
INDEPENDENT ASSESSMENT 2
Analyze the structures of the following ethers and give the IUPAC name of each.
Write your answers on a separate sheet of paper.
1. CH3-CH2-O-CH2-CH2-CH3 2. CH3-CH2-CH2-O-CH2-CH2-CH3
3. 4.
5. CH3-CH2-CH2-CH2-CH2-O-CH2-CH2-CH2-CH3
14
Aldehydes
The most important functional groups (often called the formyl or methanoyl
group) are the aldehydes. They are classes of organic compounds that
contain a carbonyl group (functional group which has a carbon double bonded to an
oxygen atom: C=O).
Now that you are familiar with the structure and properties of
aldehydes, you will now learn how they are given names in the next
activity.
INDEPENDENT ACTIVITY 3
Objectives:
● Draw the structural formula of the given aldehydes.
● Write the two acceptable names for aldehydes.
Materials:
paper and pen
Procedures:
Analyze and complete the given table by following the step by step
instructions. Write your answers on a separate sheet of paper.
15
Structural Condensed Molecular Common IUPAC
Formula Formula Formula Name Name
Example:
HCHO CH2O Formaldehyde Methanal
CH3-CHO C2H4O
CH3-CH2-
C3H6O
CHO
CH3-CH2-CH2-
C4H8O
CHO
CH3-CH2-CH2-
C5H10O
CH2-CHO
Guide Questions:
Q5. Draw the structure and write the two acceptable names for the
compound with molecular formula C10H20O.
Q6. Briefly explain how aldehydes are named?
16
Please do note that when you are writing formulas, the aldehyde group (the
carbonyl group with the hydrogen atom attached) is always written as -CHO and
never as COH. That could easily be confused with an alcohol. Ethanal, for example,
is written as CH3CHO; methanal as HCHO.
Example 1:
Name the organic compound below according to the IUPAC rules and
the common name system.
Solution:
The parent chain contains 3 carbon atoms, and it has a carbonyl group on the
end of the chain. Therefore, the IUPAC name is propanal and the common name is
propionaldehyde.
Example 2: Name the compound with structure
Solution:
The longest carbon chain contains five carbon atoms, and so the parent name
is pentane; the suffix -al is added to indicate the presence of the aldehyde group,
and the chain is numbered beginning at the carbonyl group. The methyl group is
given the number 4, because it is bonded to the fourth carbon of the chain.
Therefore, the organic compound IUPAC name is 4-methylpentanal and the
common name is 4-methylvaleraldehyde.
Uses of Aldehydes
Formaldehyde is a gas. It forms Formalin (with 40% solution in water)
which is used in preserving biological specimens. It is also used in
embalming, tanning, preparing glues and polymeric products, as
germicides, insecticides, and fungicides for plants.
In the food industry, Acetaldehyde is used in the manufacture of
preservatives and flavorings and occurs naturally in fruit and fruit juices. It is
also used in the manufacture of various types of building materials, fire
protection paints, synthetic lubricants and explosives.
Benzaldehyde is used in perfumes, cosmetic products, and dyes. It is
added to provide almond flavor to food products and also used as a bee
repellent.
17
INDEPENDENT ASSESSMENT 3
Read the following statements. If the statement is correct, write AGREE, but if it is
incorrect, change the underline word/s to make the statement correct. Write your
answers on a separate sheet of paper.
1. Alcohols have the general formula R-O-R', with R's being the alkyl groups.
2. The polarity of the carbonyl group makes aldehydes inherently polar, meaning
the electrons that make up the C=O bond are drawn closer to the oxygen than to
the carbon.
3. Ether molecules are miscible in water because like alcohols, the oxygen atom of
ether can also form hydrogen bonds with a water molecule.
4. Alcohols generally have lower boiling points in comparison to aldehydes and
ethers having equal molecular masses because of the presence of
intermolecular hydrogen bonding between hydroxyl groups of alcohol molecules.
5. Aldehydes with greater than five carbons are soluble in water and have lower
boiling points compared to alcohols of similar size.
For you to generalize the lesson, complete the table of comparison (among
the given organic compounds in this module) and the short paragraph below. Write
your answers on a separate sheet of paper.
Table of Comparison Among Alcohols, Ethers and Aldehydes
Intermolecular Soluble
Example
Hydrogen in Water
Type of Functional
Suffix Bonding (Yes/No)
Compound Group Structural Molecular IUPAC
(Present/
Formula Formula Name
Absent)
18
What I Can Do
The scoring rubric below will be used in assessing your brochure or leaflet.
Category 4 3 2 1
You used some
You used much of You used your You did not use
of your own
your own ideas and own ideas and your own ideas
Use of ideas and
imagination in imagination in and imagination
Creativity imagination in
designing the designing the in designing the
designing the
brochure. brochure. brochure.
brochure.
The brochure The brochure The brochure did
The brochure
includes some includes little or not include
includes many
relevant very few relevant relevant
Content relevant
information information information
information
regarding the regarding the regarding the
regarding the topic.
topic. topic. topic.
Much time and Some time and Very little time
No additional
effort went into the effort went into and effort went
Time and effort went into
planning and the planning and into the planning
Effort designing the
designing the designing the and designing
brochure.
brochure. brochure. the brochure.
Title is incom-
The title is catchy, A title is provided
plete and partial-
Title creative and related that relates to No title provided.
ly relates to the
to the topic. the topic.
topic.
19
Assessment
Read the following questions and answer each by writing the CAPITAL letter that
corresponds to your BEST response. Write your answers on a separate sheet of
paper.
4. What two functional groups can be found at the end of a carbon chain?
A. alcohol and aldehyde C. alcohol and ether
B. aldehyde and ether D. no correct response
A. Propane C. Propanal
B. Propanone D. Propanoic acid
7. Which of the following families of organic compound is the least soluble in water?
A. The ethers C. The aldehydes
B. The alcohols D. no correct response
20
8. Which of the following is a tertiary alcohol?
A. C.
B. D.
A. B. . C. D.
21
Additional Activities
Name the following compounds using the IUPAC system. Write your answers on a
separate sheet of paper.
1.
2.
3.
4.
5.
6.
7.
22
For inquiries or feedback, please write or call:
Department of Education, Schools Division of Bulacan
Curriculum Implementation Division
Learning Resource Management and Development System (LRMDS)
Capitol Compound, Guinhawa St., City of Malolos, Bulacan
Email address: lrmdsbulacan@deped.gov.ph