26.2.1 - Open-Response - Multiple Choice QP

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Redox II
Question Paper
Level A Level
Subject Chemistry
Exam Board Edexcel
Topic Redox II
Sub Topic
Booklet Question Paper
Paper Type Open-Response 1
Time Allowed: 64 minutes
Score: /53
Percentage: /100
Grade Boundaries:
A* A B C D E U
>85% 777.5% 70% 62.5% 57.5% 45% <45%

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1 Vanadium exists in different oxidation states which can be interconverted using

suitable oxidising and reducing agents.
(a) Use relevant standard electrode potential values, on page 14 of the Data Booklet,
9
to complete the table below in which two E values are missing.
(1)
9
Half-equation E /V
V2+(aq) + 2e− U V(s)
V3+(aq) + e− U V2+(aq)
VO2+(aq) + 2H+(aq) + e− U V3+(aq) + H2O(l) +0.34
I2(aq) + 2e− U 2I−(aq) +0.54
VO2+(aq) + 2H+(aq) + e− U VO2+(aq) + H2O(l) +1.00

(b) The standard electrode potential of V3+(aq) + e− U V2+(aq) is measured using the
apparatus below.
V
hydrogen gas
B
platinum electrode A
solution
containing H+(aq) C
(i) Identify, by name or formula, the substances needed in the salt bridge and the
right-hand half-cell to measure the standard electrode potential.
(3)
A Salt bridge containing a solution of
. . . . . . . .................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............................................................................................................................................ . . . .. . . . . . . . . . . . . . . . . . . . . .
B Electrode made of
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C Solution containing
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(ii) State the three standard conditions needed for this measurement.
(2)
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3 . . ................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . .. . . . . . . . . . . . . . . . . .
*(c) A solution containing iodide ions, I−, was added to an acidified solution
containing vanadium(V) ions, VO2+.
Predict the oxidation state of the vanadium ions left at the end of the reaction.
9
Justify your prediction by calculating the Ecell for any relevant reaction(s).
Write the ionic equation for any reaction(s) occurring. State symbols are not required.
(5)
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(Total for Question = 11 marks)

2 This question is about vanadium and its ions.
(a) Consider the data below.
Standard electrode potential

Electrode system
E9/ V
V2+(aq)|V(s) –1.18
V3+(aq), V2+(aq)|Pt –0.26
(i) Draw a labelled diagram showing how to set up a cell, using the two electrode
systems in the table above, in order to measure E c9ell.
Include standard conditions in your labelling.
(3)
(ii) Write an equation for the reaction in this cell. State symbols are not required.
(2)
(b) (i) Complete the table below with the missing standard electrode potentials.
Use the table starting on page 14 of your Data Booklet.
(1)
Standard electrode potential

Electrode system
E9/ V
[VO2+(aq) + 2H+(aq)], [V3+(aq) + H2O(l)]|Pt
[VO2+(aq) + 2H+(aq)], [VO2+(aq) + H2O(l)]|Pt
I2(aq),2I–(aq)|Pt +0.54
[2H+(aq) + O2(g)], [H2O2(aq)]|Pt +0.68
(ii) The colours of the different oxidation states of vanadium are shown below.
Oxidation state Colour

+5 yellow
+4 blue
+3 green
+2 violet
For each of the following experiments, A and B, calculate the E 9 value for the
proposed reaction. Use your answers to predict whether or not a reaction occurs in
each case.
Give the formula of the vanadium product formed where a reaction occurs
and give one observation you would make in each experiment.
(6)
Experiment A: Hydrogen peroxide is added to an aqueous solution containing VO+2 ions.
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Experiment B: An aqueous solution of potassium iodide is added to an aqueous

solution containing VO2+ ions.
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(c) An experiment was carried out to determine the percentage purity of a sample of
ammonium vanadate(V), NH4VO3.
An impure sample of ammonium vanadate(V) with mass 0.150 g was dissolved
in dilute sulfuric acid. This produced a solution containing VO2+ ions. Excess zinc
powder was added to the solution, and this reduced the VO2+ ions to V2+ ions.
The solution containing V2+ ions was titrated with potassium manganate(VII) of
concentration 0.0200 mol dm–3. The manganate(VII) ions oxidized the V2+ back to
VO2+. The volume of potassium manganate(VII) required was 35.50 cm3.
(i) The manganate(VII) ions react as shown:
MnO4– + 8H+ + 5e– ĺ Mn2+ + 4H2O

Show, by writing the appropriate half equation or otherwise, that 5 mol V2+
react with 3 mol MnO4–.
(1)
(ii) Calculate the number of moles of manganate(VII) ions used in the titration.
(1)
(iii) Calculate the number of moles of VO2+ in the original solution, and hence
the percentage purity of the sample of NH4VO3. Give your answer to three
significant figures.
Molar mass of NH4VO3 = 116.9 g mol–1.

(3)
(Total for Question = 17 marks)

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26.2.1 - Open-Response - Multiple Choice QP

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1 Vanadium exists in different oxidation states which can be interconverted using

V2+(aq) + 2e− U V(s)

VO2+(aq) + 2H+(aq) + e− U V3+(aq) + H2O(l) +0.34

I2(aq) + 2e− U 2I−(aq) +0.54

VO2+(aq) + 2H+(aq) + e− U VO2+(aq) + H2O(l) +1.00

A Salt bridge containing a solution of

(Total for Question = 11 marks)

2 This question is about vanadium and its ions.

(a) Consider the data below.

Standard electrode potential

Standard electrode potential

Oxidation state Colour

Experiment A: Hydrogen peroxide is added to an aqueous solution containing VO+2 ions.

Experiment B: An aqueous solution of potassium iodide is added to an aqueous

MnO4– + 8H+ + 5e– ĺ Mn2+ + 4H2O

Molar mass of NH4VO3 = 116.9 g mol–1.

(Total for Question = 17 marks)

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