Thermodynamics

ENGR. CHRISTIAN BLAS

 ISOMETRIC PROCESS
A. P,V AND T (V=C)

P1 P2
=
T1 T2

B. NON FLOW WORK

Wn = PdV ; where: dV=0 @ V=C

Wn = 0
 ISOMETRIC PROCESS
D. STEADY FLOW WORK G. HEAT TRANSFERRED
2 Q = U + Wn
Ws = - VdP = V (P1-P2) Wn = 0 V =C
1
Q = U
E. CHANGE IN INTERNAL ENERGY
U = m Cv T H. CHANGE IN ENTROPY

F. CHANGE IN ENTHALPY from : dS = dQ

T
H = m Cp T
S = m Cv ln T2
T1
 ISOBARIC PROCESS
A. P,V AND T (P=C)

V1 V2
=
T1 T2

B. NON FLOW WORK

2
Wn = PdV
1
Wn = P(V2-V1)
 ISOBARIC PROCESS
D. STEADY FLOW WORK
G. HEAT TRANSFERRED
2 Q = U + Wn
Ws = - VdP ; where: dP=0 @P=C Q = U + H
1
Ws=0 Q = H

H. CHANGE IN ENTROPY
E. CHANGE IN INTERNAL ENERGY
U = m Cv T from : dS = dQ
T
F. CHANGE IN ENTHALPY
S = m Cp ln T2
H = m Cp T T1
 ISOTHERMAL PROCESS
A. P,V AND T (T=C)
D. STEADY FLOW WORK
P1 V1 = P2 V2
2
Ws = - VdP ; where: V= C/P
B. NON FLOW WORK 1
2
Ws = -P1 V1 ln (V2/V1)
Wn = PdV ; where P =c/v Ws = -mRT1 ln (V2/V1)
1
Wn = P1 V1 ln (V2/V1)
Wn = mRT ln (V2/V1) Ws = Wn
 ISOTHERMAL PROCESS
G. HEAT TRANSFERRED
E. CHANGE IN INTERNAL ENERGY Q = U + Wn
U = 0 Q = Wn (for U=0)
F. CHANGE IN ENTHALPY
H = 0
H. CHANGE IN ENTROPY

from : dS = dQ
T

S = m Cp ln V2
V1
 ISENTROPIC PROCESS k
A. P,V AND T (S=C OR PV = C )
k k
P1 V1 = P2 V2 PRESSURE-VOLUME
D. STEADY FLOW WORK
T1 k-1
= V2 2
TEMPERATURE-VOLUME C
T2 V1 Ws = - VdP ; where: V= P k
k-1
T1 P1 k
1
= TEMPERATURE-PRESSURE
T2 P2
Ws = k(P2V2-P1V1)
B. NON FLOW WORK 1-k
2 = kmR(T2-T1)
C
Wn = PdV; where P = V k 1-k
1
Wn = P2V2-P1V1 = mR(T2-T1) Ws=kWn
1-k 1-k
 ISENTROPIC PROCESS
G. HEAT TRANSFERRED
E. CHANGE IN INTERNAL ENERGY
Q = 0
U = m Cv T =-Wn Q = U + Wn
F. CHANGE IN ENTHALPY U = - Wn

H = m Cp T H. CHANGE IN ENTROPY

S = 0
 POLYTROPIC PROCESS
n
A. P,V AND T (PV = C )
n n
P1 V1 = P2 V2 PRESSURE-VOLUME
D. STEADY FLOW WORK
T1 n-1
= V2 2
TEMPERATURE-VOLUME C
T2 V1 Ws = - VdP ; where: V= P n
n-1
T1 P1 n
1
= TEMPERATURE-PRESSURE
T2 P2
Ws = n(P2V2-P1V1)
B. NON FLOW WORK 1-n
2 = nmR(T2-T1)
C
Wn = PdV; where P = V n 1-
1
Wn = P2V2-P1V1 = mR(T2-T1) Ws=nWn
1-n 1-n
 POLYTROPIC PROCESS
G. HEAT TRANSFERRED
E. CHANGE IN INTERNAL ENERGY Q = m Cn T
U = m Cv T k-n
where; Cn = Cv
F. CHANGE IN ENTHALPY 1-n

H = m Cp T H. CHANGE IN ENTROPY

from : dS = dQ
T

S = m Cn ln T2
T1