Professional Documents
Culture Documents
Relevance of Modeling
Laser-Material Interactions
in the Industrial Context
© Fraunhofer ILT
Nonlinear Dynamics of Laser-Processing NLD 2
Story:
Laser and Flame
as technical tools for processing
RQ:
What is the most important difference between
Laser and Flame
for material processing?
13
Nonlinear Dynamics of Laser-Processing NLD 3
Research Question:
Why model reduction is important
?
LASER
Research Hypothesis:
Story:
Laser and Flame
energy density flow of the source
transferred to the material surface and after absorption named heat flux q
𝑒𝑛𝑒𝑟𝑔𝑦 𝑒𝑛𝑒𝑟𝑔𝑦
𝑞𝐴 = ∙ 𝑣𝑒𝑙𝑜𝑐𝑖𝑡𝑦 =
𝑣𝑜𝑙𝑢𝑚𝑒 𝑎𝑟𝑒𝑎 ∙ 𝑡𝑖𝑚𝑒
Nonlinear Dynamics of Laser-Processing NLD 5
Laser
”preset” heat source
with intensity 𝐼 𝑊𝑚−2
𝑞𝐴 = 𝜇𝐴 𝜇 𝐼
absorbed
heat flux 𝜇 ≔ cos 𝜗 projection
𝐴 𝜇 = 1 − 𝑅 𝜇 degree of absoprtion
Nonlinear Dynamics of Laser-Processing NLD 6
Flame
”self-adaptive” heat source/sink
with flame temperature 𝑇𝑓𝑙𝑎𝑚𝑒 [K]
𝑞𝐴 = 𝛼 𝑇𝑓𝑙𝑎𝑚𝑒 − 𝑇𝑚𝑎𝑡𝑒𝑟𝑖𝑎𝑙
absorbed temperature
heat flux difference
Nonlinear Dynamics of Laser-Processing NLD 7
Laser Flame
𝑞𝐴 = 𝜇𝐴 𝜇 𝐼 𝑞𝐴 = 𝛼 𝑇𝑓𝑙𝑎𝑚𝑒 − 𝑇𝑚𝑎𝑡𝑒𝑟𝑖𝑎𝑙
Story:
Laser and Flame
as technical tools for processing
RQ:
What is the reasoning to search for simplicity
by model reduction?
Nonlinear Dynamics of Laser-Processing NLD 9
Morse-Smale Complex
significant pathes
single beam ps-ablation - metal foil
Story:
Inertial Manifold
𝜕𝜃 𝜕 2 𝜃
= , 𝜃 = 𝜃 𝑥, 𝑡 , 𝑥 ∈ 0, ℎ , 𝑡 > 0
𝜕𝑡 𝜕𝑥 2
𝑥
ℎ
spectral amplitude 𝜃 = 0, 𝜃 = 1, 𝜃 = 𝑓(𝑥)
𝑥=0 𝑥=ℎ 𝑡=0
𝜃 𝑥, 𝑡 = 𝜃0 (𝑥)+𝜃1 (𝑥, 𝑡)
spectral number
𝑘
𝜃 𝑥, 𝑡 = 𝜃0 (𝑥)+𝜃1 (𝑥, 𝑡)
𝜕𝜃1 𝜕 2 𝜃1
= , 𝜃1 = 𝜃1 𝑥, 𝑡 , 𝑥 ∈ 0, ℎ , 𝑡 > 0
𝜕𝑡 𝜕𝑥 2
𝜃1 =0, 𝜃1 = 0, 𝜃1 = 𝑓 𝑥 − 𝜃0 (𝑥)
𝑥=0 𝑥=ℎ 𝑡=0
𝜃1 𝑥, 𝑡 = 𝑢 𝑡 𝑣 𝑥 ,
𝑢 𝑡 ∝ 𝑒 −𝜆𝑘 𝑡 , 𝑣 𝑥 ∝ sin 𝜆𝑘 𝑥 ,
𝜆𝑘 ℎ = 𝜋𝑘 , 𝑘 = {0,1, … }
Nonlinear Dynamics of Laser-Processing NLD 12
𝜃 𝑥, 𝑡 = 𝜃0 (𝑥)+𝜃1 (𝑥, 𝑡)
𝜕𝜃1 𝜕 2 𝜃1
= , 𝜃1 = 𝜃1 𝑥, 𝑡 , 𝑥 ∈ 0, ℎ , 𝑡 > 0
𝜕𝑡 𝜕𝑥 2
𝜃1 =0, 𝜃1 = 0, 𝜃1 = 𝑓 𝑥 − 𝜃0 (𝑥)
𝑥=0 𝑥=ℎ 𝑡=0
𝜃1 𝑥, 𝑡 = 𝒖 𝒕 𝑣 𝑥 ,
𝒖 𝒕 ∝ 𝒆−𝝀𝒌 𝒕 , 𝑣 𝑥 ∝ sin 𝜆𝑘 𝑥 ,
𝜆𝑘 ℎ = 𝜋𝑘 , 𝑘 = {0,1, … }
Nonlinear Dynamics of Laser-Processing NLD 13
Diffusion
𝜕𝜃 𝜕 2 𝜃
= , 𝜃 = 𝜃 𝑥, 𝑡 , 𝑥 ∈ 0, ℎ , 𝑡 > 0
𝜕𝑡 𝜕𝑥 2
𝜃 =0, 𝜃 =1, 𝜃 =𝑓 𝑥
𝑥=0 𝑥=ℎ 𝑡=0
∞
𝑥
𝜃 𝑥, 𝑡 = 𝜃0 (𝑥)+𝜃1 (𝑥, 𝑡) = + 𝑎𝑘 𝑒 −𝜆𝑘 𝑡 sin 𝜆𝑘 𝑥
ℎ
𝑘=1
𝑎𝑘
𝜃 2
𝜋𝑘
𝜆𝑘 =
ℎ
𝑥 𝑘
ℎ
Nonlinear Dynamics of Laser-Processing NLD 14
Morse-Smale Complex
significant pathes
single beam ps-ablation - metal foil
14
Nonlinear Dynamics of Laser-Processing NLD 16
Paramatric Interpolation
2. Mathematical Model Reduction
„ Digital Guess“
of sparse data
•
Applicability
• Singular Perturbation
Model Reduction
Buckingham‘s Pi-Theorem
Time scale separation – Inertial Manifold / Central Manifold
Singular perturbation theory
Principal Component Analysis PCA
Proper Orthogonal Decomposition POD
Buckingham‘s 𝚷-Theorem
Example Pendulum
𝚽 𝑹𝟏 , … , 𝑹𝒏 = 𝟎 𝚿 𝚷𝟏 , … , 𝜫𝒑 = 𝟎 , 𝒑 ≤ 𝒏
𝒈 𝑻𝟐 𝒄
𝚽 𝑻, 𝑴, 𝑳, 𝒈 = 𝟎 , 𝒏 = 𝟒 𝚿 𝚷𝟏 = 𝟎 , 𝒑 = 𝟏 , 𝚷𝟏 = ( 𝑳 )
𝑇 oscillation period
Edgar Buckingham
Ψ 𝛱1 = 0 discrete zero‘s
𝐿
𝑳
𝑻 = 𝒂𝒎 , 𝑎𝑚 = 2𝜋 by calibration
𝑀 𝒈
𝑔
Nonlinear Dynamics of Laser-Processing NLD 21
Unit 𝑭𝒊 [𝑭𝒊 ]
More ex pertis e?
Mass 𝐹1 𝑘𝑔 More unders tading?
Length 𝐹2 𝑚
Time 𝐹3 𝑠
Temperature 𝐹4 𝐾
Nonlinear Dynamics of Laser-Processing NLD 23
𝑅𝑗 𝒗(𝑅𝑗 ) [𝑅𝑗 ]
0 0 0 1 1
𝑅1 𝑟0 𝑚 1 1 2 −2 −2
𝑎𝑖𝑗 =
𝑅2 𝑣0 𝑚𝑠 −1 0 −1 −1 −3 −3
𝑅3 𝜅 𝑚2 𝑠 −1 0 0 0 0 0
𝑅4 𝑃𝑙𝑜𝑠𝑠 𝑘𝑔 𝑚2 𝑠 −3 𝑟 = 𝑟𝑎𝑛𝑘 𝑎𝑖𝑗 = 3
𝑅5 𝑃𝑠𝑑 = 𝑑 𝜆 𝑇𝑚 − 𝑇𝑎 2 −3
𝑘𝑔 𝑚 𝑠 𝑝=𝑛−𝑟 =5−3=2
𝑃𝑙𝑜𝑠𝑠 𝑟0 𝑣0
Π1 , Π2 = , 𝑃𝑒 , 𝑃𝑒 =
𝑑 𝜆 𝑇𝑚 −𝑇𝑎 𝜅
𝜸
𝑷𝒆
𝑷𝒍𝒐𝒔𝒔 = 𝑷𝒔𝒅 , 𝜸 = 𝟎. 𝟑
𝟐
Nonlinear Dynamics of Laser-Processing NLD 24
𝜸
𝑷𝒆
𝑷𝒍𝒐𝒔𝒔 = 𝑷𝒔𝒅 , 𝜸 = 𝟎. 𝟑
𝟐
WidthRatio norm
0
Reference
Model
P1 0 1
WidthRatio
P2
Sparse Raw Data Dense Raw Data Significant Pathes Principal Components
Machine Data Digitial Guess „spidernet“ in 𝑃1 , 𝑃2 of Morse Smale Complex
Comprehensive Simulation Data Interpolation high dimensional parameter space highest persistance level
Nonlinear Dynamics of Laser-Processing NLD 26
Hasso Plattner
Institute of Design at Stanford
?
empathize and define
Strength
Paramatric Interpolation
2. Mathematical Model Reduction
„ Digital Guess“
of sparse data
applicability – uneconomic, unexplored
Morse-Smale Complex
significant pathes
single beam ps-ablation - metal foil
20
Nonlinear Dynamics of Laser-Processing NLD 31
20 µm 80 µm 200 µm 8 mm length
2 µs 100 µs 1 ms time
𝜕𝑇
= 𝜅∆𝑇 , 𝑇 = 𝑇 𝑥, 𝑡 , 𝑥 ∈ Ω(𝑡)
𝜕𝑡
𝐼 𝑥, 𝑡 = 𝐼0 𝑡 𝑓 𝑥 − 𝑣𝑡, 𝑡
0<𝑓<1 melting front Γ𝑚 (t):
𝑞𝐴 − 𝜆𝛻𝑇 = 𝜌𝐻𝑚 𝑣𝑏 , 𝑥 ∈ Γ𝑚 (t)
𝑇 = 𝑇𝑚 , 𝑥 ∈ Γ𝑚 (t)
sheet surface and cut surface:
𝑞𝐴 − 𝜆𝛻𝑇 = 0 , 𝑥 ∈ Γ+ 𝑡 \Γ𝑚 (𝑡)
bottom sheet surface Γ− (t):
𝛻𝑇 ∙ 𝒏 = 0 , 𝑥 ∈ Γ− (𝑡)
outer boundary:
𝑇𝑥 ∞ = 𝑇𝑎 , 𝑥 ∈ Ω(𝑡)
𝑞𝐴 = 𝐴 𝑒𝑧 ∙ 𝑛 𝐼(𝑥, 𝑡)(−𝑒𝑧 ∙ 𝑛)
Nonlinear Dynamics of Laser-Processing NLD 35
Lengths: 𝛿 Velocities:
Convection-diffusion-equation with external sources
Length scales:
Time scales:
Nonlinear Dynamics of Laser-Processing NLD 36
Smallness parameters
𝜅
𝛿= ≪ 𝑤0 ≪ 𝑑:
𝑣𝑜
𝑥 = 𝛿 𝜉,
𝑦 = 𝑤0 𝜂,
𝑧 = 𝑑 𝜁,
𝛿2
𝑡= 𝜏
𝜅
2 2
𝜕𝜃 𝜕𝜃 𝜕 2 𝜃 𝛿 𝜕2𝜃 𝛿 𝜕2𝜃
= + 2+ +
𝜕𝜏 𝜕𝜉 𝜕𝜉 𝑤0 𝜕𝜂2 𝑑 𝜕𝜁 2
Nonlinear Dynamics of Laser-Processing NLD 37
2 2
Motion Equation and 𝜕𝜃 𝜕𝜃 𝜕 2 𝜃 𝛿 𝜕2𝜃 𝛿 𝜕2𝜃
= + + +
smallness parameters: 𝜕𝜏 𝜕𝜉 𝜕𝜉 2 𝑤0 𝜕𝜂2 𝑑 𝜕𝜁 2
Structure of Solution:
1D 2D 3D
𝑄(𝜏)
depth
One-Phase Problem
infinite dimensional PDE-system
𝑤02
𝑇 = 𝑇𝑚 − 𝑇𝑎 𝜃 + 𝑇𝑎 , 𝑥 = 𝑤0 𝜉 , 𝑡= 𝜏, 𝑎 𝑡 = 𝑤0 𝐴(𝜏)
𝜅 1D
𝜕𝜃 𝜕 2 𝜃
= , 𝜉 ∈ [𝐴 𝜏 , +∞)
𝜕𝜏 𝜕𝜉 2
Heating phase Melting phase
𝜕𝐴(𝜏)
= 0, 𝜃 =0 𝜃 = 1, 𝜃 =0
𝜕𝜏 𝜉 ∞ 𝜉=𝐴(𝜏) 𝜉 ∞
𝜕𝜃 𝜕𝜃 𝑑𝐴(𝜏)
𝛾 𝜏)𝑓(𝐴 𝜏 − 𝑃𝑒 𝜏 + =0 𝛾 𝜏)𝑓(𝐴 𝜏 − 𝑃𝑒 𝜏 + = ℎ𝑚 >0
𝜕𝜉 𝜉=𝐴(𝜏)
𝜕𝜉 𝜉=𝐴(𝜏)
𝑑𝜏
𝑑𝐴(𝜏)
𝜃 𝜉, 𝜏 = exp(−𝑃𝑒 𝜉 − 𝐴 𝜏 , 𝑃𝑒
𝑑𝜏 𝑡 ∞
Nonlinear Dynamics of Laser-Processing NLD 39
𝑑𝑇
𝜌𝑐 = 𝛻 ∙ 𝜆𝛻𝑇
𝑑𝑡
𝑑𝑇 𝑑
𝜌𝑐 =𝛻∙ − 𝑯
𝑑𝑡 𝑑𝑡
𝑤02
𝑯 = 𝜌𝑐 𝑇𝑚 − 𝑇𝑎 𝑤0 𝒉 , 𝑇 = 𝑇𝑚 − 𝑇𝑎 𝜃 + 𝑇𝑎 , 𝑥 = 𝑤0 𝜉 , 𝑡 = 𝜏
𝜅
M.A. Biot, Variational Principles in Heat Transfer, Oxford University Press, Oxford (1970)
Nonlinear Dynamics of Laser-Processing NLD 40
𝑑 𝑑
𝛻𝜃 + 𝒉=𝟎 𝛻𝜃 + 𝒉 ∙ 𝛿𝒉𝑑𝑽 = 𝟎 Fourier‘s Law
𝑑𝜏 𝛀 𝑑𝜏
1 𝑑
𝛿 Ω
𝜃 2 𝑑𝑉 + Ω 𝑑𝜏
𝒉 ∙ 𝛿𝒉 𝑑𝑉 = − 𝜕Ω
𝜃𝒏 ∙ 𝛿𝒉 𝑑𝐴
2
1
𝑉= 𝜃 2 𝑑𝑉
2 Ω
𝑑𝑉 𝑑𝐷 1 𝑑
2
𝜃=𝜃 𝑄1 , … , 𝑄𝑛 , 𝜉, 𝜏 : + = 𝐹𝑖 𝐷=
2 𝑑𝜏
ℎ 𝑑𝑉
𝑑𝑄𝑖 𝑑𝑄𝑖 Ω
𝑑𝒉
𝐹𝑖 = 𝜃𝒏 ∙ 𝑑𝐴
𝜕Ω 𝑑𝑄𝑖
M.A. Biot, Variational Principles in Heat Transfer, Oxford University Press, Oxford (1970)
Nonlinear Dynamics of Laser-Processing NLD 41
1D
Attractor
𝜉 = 𝐴(𝜏)
Tem perature
𝜃 𝜉, 𝜏 = 1 ∙ exp(−𝑃𝑒(𝜉 − 𝐴 𝜏 )
depth
Inertial Manifold
spanned by 3 dynamical parameters 𝜃𝑠 𝜏 , 𝑄 𝜏 , 𝐴(𝜏)
𝜉−𝐴(𝜏)
𝜃 𝜉, 𝜏 = 𝜃𝑠 (𝜏) ∙ exp(− ) + 𝜃1 (𝜉, 𝜏)
𝑄(𝜏)
1
0 < 𝜃𝑠 (𝜏) ≤ 1 𝑄 𝜏 𝜃1 (𝜉, 𝜏) spectral corrections
𝑡 ∞ 𝑃𝑒
Nonlinear Dynamics of Laser-Processing NLD 42
𝜉−𝐴(𝜏)
Ansatz: 𝜃 𝜉, 𝜏 = 𝜃𝑠 (𝜏) ∙ exp(− ) + 𝜃1 (𝜉, 𝜏)
𝑄(𝜏)
∞ 𝜉−𝐴(𝜏)
𝜃 = −𝛻𝒉: ℎ 𝑄, 𝜉, 𝜏 = 𝜉
𝜃 𝜉 ′ , 𝜏 𝑑𝜉 ′ = 𝜃𝑠 (𝜏)𝑄(𝜏) exp(− )
𝑄(𝜏)
∞
ℎ 𝑄, 𝜉 = 𝐴(𝜏), 𝜏 = 𝐴(𝜏)
𝜃 𝜉 ′ , 𝜏 𝑑𝜉 ′ = 𝜃𝑠 (𝜏)𝑄(𝜏)
M.A. Biot, Variational Principles in Heat Transfer, Oxford University Press, Oxford (1970)
Nonlinear Dynamics of Laser-Processing NLD 43
Variational equations
𝜉 − 𝐴(𝜏) ∞ 𝜉−𝐴(𝜏)
𝜃 𝜉, 𝜏 = 𝜃𝑠 (𝜏)exp(− ) ℎ 𝑄, 𝜉, 𝜏 = 𝜉
𝜃 𝜉 ′ , 𝜏 𝑑𝜉 ′ = 𝜃𝑠 (𝜏)𝑄(𝜏) exp(− )
𝑄(𝜏) 𝑄(𝜏)
𝑏1 = 3 5
𝑑𝑉 𝑑𝐷
+ = 𝐹𝑖
𝑑𝑄 𝑑𝑄
3d-Inertial Manifold
1 𝜃𝑆
𝑄 = 𝑏1 −𝐴−𝑄
𝑄 𝜃𝑆
𝑇𝑠 (𝑡) − 𝑇𝑎 𝑎(𝑡)
𝜃𝑠 𝜏 = 𝐴 𝜏 =
𝑇𝑚 − 𝑇𝑎 𝑤0
𝛿 (𝑡) 𝛿 (𝑡)
Q𝜏 = 𝑤0
Q𝜏 = 𝑤0
Schulz, International Journal of Heat and Mass Transfer, 40(12) pp.13-28, 1997
Nonlinear Dynamics of Laser-Processing NLD 45
Schulz, International Journal of Heat and Mass Transfer, 40(12) pp.13-28, 1997
Nonlinear Dynamics of Laser-Processing NLD 46
temperature distribution
0 temperature 1
Nonlinear Dynamics of Laser-Processing NLD 47
Morse-Smale Complex
significant pathes
single beam ps-ablation - metal foil
20
Nonlinear Dynamics of Laser-Processing NLD 51
51
Phase: uncharged
Gauss
Phase: charged
Left-hand Donut
Seite 52
Nonlinear Dynamics of Laser-Processing NLD 53
Nonlinear Dynamics of Laser-Processing NLD 54
RingG20A27.avi
DGM Discontinuous Galerkin Method
Nonlinear Dynamics of Laser-Processing NLD 55
Ablation
glass, metal, composite
Simulation
ps-filamentation – glass
Nonlinear Dynamics of Laser-Processing NLD 57
Simulation Experiment
pulse parameters
pulse energy
spot diameter
repetition rate
…
pattern parameters
spot distribution
energy distribution
…
Nonlinear Dynamics of Laser-Processing NLD 58
Tas k
Minimize damage
PICOSECOND
0 m e
2
GLASS
crit 2
0
CUTTING
e
free electron density
Nonlinear Dynamics of Laser-Processing NLD 59
𝜔𝐿 2 𝑚 𝑒 𝜖 0 Reflectivity 𝑅 𝜌(𝑡)
𝜌𝑐𝑟𝑖𝑡 =
𝑒2 t e
2
P t
m e 0
refractive index 𝑛 𝜌(𝑡)
Reflectivity R
0 n , : collision time
2
0
P : plasma - frequency
Glass Cutting: 0 m e 0
2
crit 2
e
ablation
or
filamentation?
Page 60
Nonlinear Dynamics of Laser-Processing NLD 61
I c I rec diff
k 2
t
Nonlinear Dynamics of Laser-Processing NLD 62
t
Intensity
Beam Propagation Model
E 2
2 ik 0 E k 0 ( 1) E
z
2
( ( I )), I 0 cn 0 E 0
Nonlinear Dynamics of Laser-Processing NLD 63
ablation
threshold
intensity-based
ablation
threshold
fluence-based
Page 63
Nonlinear Dynamics of Laser-Processing NLD 64
2
E E k c 0 n2 E E k ee ( r , , z ) E
2
2 ik
z
2
(I ) 𝜔𝐿 2 𝑚 𝑒 𝜖 0
0 c1 n2 I
c1 𝜌𝑐𝑟𝑖𝑡 =
𝑒2
4 n 0
2
0
w 2 crit
Kerr-self-focusing
plasma de-focusing
built up
length
plasma
Tow nes beam
2
Pthreshold
4 n 0 n 2 filam entation
no filam entation ablation
ablation
1 n0 (I )
I threshold 2 2 n2 I filam entation
w 0
n2k 2 crit no ablation
no filam entation
no ablation
below Pcrit
n 2 I c1 (
2
)
w0
above Pcrit
Filamentation peak power threshold:
Marburger, 1975
Nonlinear Dynamics of Laser-Processing NLD 66
__ Diffraction-Kerr equilibrium
__ Plasma-Kerr equilibrium
beam power
Defocssing by
Plas m a
Fosussing by
Kerr effect
Defocssing by
Diffraction
beam radius
Page 66
Nonlinear Dynamics of Laser-Processing NLD 67
Morse-Smale Complex
significant pathes
single beam ps-ablation - metal foil
the goal:
enabling v alue
by skilled developers
Morse-Smale
Complex
Source:
Visual exploration of high dimensional
scalar functions, Gerber
Nonlinear Dynamics of Laser-Processing NLD 70
Model Validation
relativ e error CS T
3.58%-5.8%
Cus tom ized S im ulation Tool
𝑰 𝟐 Fast & Frugal Simulation
𝒅𝒛
= 𝑰𝒕𝒉
− 𝟏 𝒊𝒇 𝑰 ≥ 𝑰𝒕𝒉
𝒅𝒙 calculation tim e < 1 s econd
𝟎 𝒊𝒇 𝑰 < 𝑰𝒕𝒉
S im ulation:
Entry diameter:
650 µm
Ex perim ent:
Mean value hole
entry diameter :
669 ± 26 µm
S im ulation:
Exit diameter:
510 µm
Ex perim ent:
Mean value hole
exit diameter:
497 ± 19 µm
Page 7
Nonlinear Dynamics of Laser-Processing NLD 72
CST
Customer
Simulation App
Simulation: Experiment:
Customer Simulation App
Beam Distribution
Model Validation
relativ e error
0.83%-2.16%
Patent pending
Nonlinear Dynamics of Laser-Processing NLD 73
Additive Manufacturing
from cutting and welding to build-up
Data Ex ploration
additiv e m anufacturing
cutting
Know -How
Know -How
surrogate „plas tic s train“
fast instead of comprehensive process
m ov ing
Know -How
beam
Know -How avoid
pore formation by Cus tom er S im ulation App
avoid feedback Em ulator (=„Nachahmer“)
ripple formation by
s hadow ing Digital S hadow
Nonlinear Dynamics of Laser-Processing NLD 74
Portable
high performance
metamodel tools
Portable
interactive and fast
simulation tools
Detailed
comprehensive
simulation Further laser processes
Page 16
Nonlinear Dynamics of Laser-Processing NLD Internet of Production 75
Tools Methods
Digital Gues s
Digital S hadow
Tools Methods
Digital Gues s
Interactiv e
com m unication Calibration
Digital S hadow
?
Nonlinear Dynamics of Laser-Processing NLD 79
Acknowledgements
Clus ter of Ex cellence: Integrativ e Production Technology for high-w age Countries
Nonlinear Dynamics of Laser-Processing NLD 80
or contact:
Prof. Dr. rer. nat. Wolfgang Schulz