REVISION JEE (Main + Advanced) 2023

LEADER + ENTHUSIAST COURSE

CLASS TEST # 01
INORGANIC CHEMISTRY TIME : 30 MIN.
Single Correct
1. Find the pair of species having the same shape but different hybridization of the central
atom?
(A) [SnCl3] ! , XeO3 (B) XeO2F2, SF4

(C) XeF2, NO2Å (D) BrF3 , XeOF2

2. Select the CORRECT order of bond angle?

(A) NH3 < NH!2 < CH4 (B) CO2 = NO2Å < NO!2

(C) SO3–2 < SO4–2 < SO2 (D) BF3 < BCl3 < BBr3

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3. Borazine shows a close similarity with benzene and therefore also named as inorganic benzene.
Which of the following statement(s) is/are INCORRECT for benzene and borazine?
(A) Both are planar
(B) Both are aromatic
(C) Both are isoelectronic species
(D) Both have 2pp - 2pp type of coordinate bond.

4. Identify the chemical specie(s), which is/are polar as well as planar.

(A) SnCl2 (B) XeF6
(C) BF3 (D) XeF2

5. With respect to valence bond theory, the CORRECT statement is

(A) Bond energy order is H2 > F2

(B) Number of lone pair of electron order is I3Å > I3!

(C) s % character order in lone pair of electron(s) is OCl2 > OF2

(D) Bond angle order is SCl2 > OCl2

6. Which of the following set of order is INCORRECT for their indicated properties?
(A) Bond length of O–F ; O2F2 > OF2
(B) Lewis acidic strength ; BCl3 > BF3
(C) Basic strength ; N(CH3)3 < N(SiH3)3
(D) pp–pp back bond strength ; BF3 > BCl3

Inorganic / Revision Class Test # 01 E-1 / 4

 JEE (Main + Advanced) 2023
LEADER + ENTHUSIAST COURSE

7. Observe the following conversion and structure of B2H6 (Diborane)

2BH3(g) ¾® B2H6(g)

H l1 l2 H H
q1 B q2 B
H H H

The correct statement is :

(A) l1 > l2
(B) q1 > q2
(C) B2H6 consists 3c–2e bond and is a planar species

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(D) The hybridisation state of Boron atom in B2H6 is not changed as compared to monomeric
form of BH3
8. Which of the following acid/base reaction is most difficult to proceed in forward direction ?
(A) BCl3 + NMe 3 ¾® Cl3B¬NMe3
(B) BF 3 + NH3 ¾® F3B¬NH3
(C) NH3 + H2O ¾® NH4+ + OH–
(D) PH 3 + H2O ¾® PH4+ + OH–
9. Which of the following species is having highest p% character in the orbital occupied by bond
pair as compared to orbital occupied by lone pair ?

(A) NH3 (B) PH3 (C) AsH3 (D) CH3-

10. Which of the following species has bond angle ³ 120°, w.r.t. underlined atom?
(A) O(CH3) 2 (B) N(CH3) 3 (C) N(SiH3)3 (D) P(SiH3)3
11. The CORRECT order of indicated bond length is :-
(A) dC–Cl ; CF3–Cl > CH3–Cl (B) dC–H ; CF3–H < Cl3C–H
(C) dN–N ; H2N–NH2 < F2N–NF2 (D) dO–O ; O2F2 > H2O2
One or more than one Correct
12. Which of the following statement is/are CORRECT?
(A) In NSF3 both p-bonds are pp-dp type.
(B) The ratio of s-bonds to p-bond in SO3 and SO2 are identical.
(C) [ICl4]! & [XeF5]! are planar.

(D) Cl2O6(s) exist as ClOÅ2 & ClO!4

13. Select the CORRECT order of bond energy?

(A) H–F < H–Cl < H–Br (B) 3pp-3pp < 3dp-3dp
(C) Cl2 > Br2 > F2 (D) O2 < O3(O–O)

E-2 / 4 Inorganic / Revision Class Test # 01

 JEE (Main + Advanced) 2023
LEADER + ENTHUSIAST COURSE

14. Which of the following option is/are CORRECT about

F
q2
F
O S q1
q3 F
F

(A) q2 > q1 > q3

(B) d x2 -y2 orbital involved in hybridization

(C) maximum number of atoms in plane are 4.

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(D) S–F(axial) bond length < S–F(eq.) bond length

15. Consider the following reaction and choose CORRECT statements

room temperature
3B2H6 + 6NH3 3 mole ionic product (A)

Heat

Product (B) + Flammable gas (C)

(A) Product (B) contain aromatic character.

(B) Boiling point of product (C) is less than Helium.
(C) All Boron in product (A) are sp3 hybridised.
(D) In product (B), 2pp–3pp type back bond present.

16. Which of the following is example of cyclic silicate?

(A) dioptase Cu6Si6O18.6H2O (B) Crocidolite Na2Fe5(OH)2[(Si4O11)]2
(C) Serpentine Al2(OH)2Si4O10 (D) Catapleite Na2ZrSi3O9.H2O

17. In which of the following odd electron species single electron is present in hybrid orbital.
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(A) NO2 (B) CF3

(C) ClO3 (D) ClO2

18. Identify the pair(s) in which first chemical species has greater % s-character on lone pair of
central atom than second one.
(A) (NH3, NF3) (B) (PF3, PH3)
(C) (SnCl2, SnCl3–) (D) (SbH3, PH3)

Inorganic / Revision Class Test # 01 E-3 / 4

 JEE (Main + Advanced) 2023
LEADER + ENTHUSIAST COURSE

Matrix Match Type

1. Column-I Column-II
(Treatment of reactant with excess
water at room temperature) (Reaction Characteristics)

(A) H2O
XeF4 ¾¾¾ ® (P) Disproportination reaction

H2O
(B) XeF6 ¾¾¾ ® (Q) One of the product is oxygen gas

H2O
(C) SF6 ¾¾¾ ® (R) Complete hydrolysis

H2O
(D) N 2O4 ¾¾¾ ® (S) Inert towards hydrolysis

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(T) One of the product is monobasic oxyacid
Numb Type
1. Identify the pair in which the specified bond length of first is greater than second.
PCl3F2 , PF3Cl2 : B LP–Cleq
SO2Cl2 , SO2F2 : B LS=O
BF3 , BCl3 : B LB–X X = F/Cl

NO3- , NO2- : B LN–O

O3 , O2 : B LO–O
CO , CO2 : B LC–O
2. Find the total number of chemical specie(s) in which effective pp – dp type of back bonding is
observed.
N(SiH3)3 , O(SiH3)2 , :CCl2 , P(CH3)3 , N(GeH3)3 , B(OMe)3 , B(OEt)3 , SiF4 , P(SiH3)3
3. Write sum of basicity of oxy acid formed by hydrolysis of

Hydrolysis
PCl 3 ¾¾¾¾ ¾® oxy acid + hydra acid
(I)

Hydrolysis
SF4 ¾¾¾¾ ¾® oxy acid + hydra acid
( II)

Hydrolysis
BrF5 ¾¾¾¾ ¾® oxy acid + hydra acid
(III)

E-4 / 4 Inorganic / Revision Class Test # 01