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Practice Paper
➢ Section – I : This section contains 20 multiple choice questions with one correct answers. A correct
answer carries 4 marks and wrong answer will attract a penalty of 1 mark.
➢ Section – II : This contains 10 numerical type questions for which the answer should be rounded off
to nearest integer. Candidates have to attempt any five questions out of ten questions in this
section. A correct answer carries 4 marks and wrong answer will attract a penalty of 1 mark.
In Section II, Out of 10 questions, Only 5 questions are to be answered. If you answered more than 5
questions in Section II, the first 5 questions answered will be evaluated.
4. Darken the appropriate bubble using a pen in the OMR sheet provided to you. Once entered, the
answer cannot be changed. Any corrections or modifications will automatically draw a penalty of
1 mark
5. No clarification will be entertained during the examination. Doubts in the paper can be reported
to the coordinator after the exam
6. If the details in the OMR Sheet are not filled, If the OMR sheet is mutilated, torn, white Ink used,
the circles filled and scratched, then the OMR sheet will not be graded
Useful Data
At. Wt.:
N = 14; O = 16; H = 1; S = 32; Cl = 35.5; Mn = 55; Na = 23; C = 12; Ag = 108; K = 39; Fe = 56; Pb = 207
Physical Constants:
h = 6.626 10−34 Js , N a = 6.022 1023 mol-1 , c = 2.998 108 m s-1 , me = 9.110−31 kg , R = 8.314 J mol-1 K -1
JEE Main Section
Chemistry
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 4 marks. A wrong
answer carries a penalty of 1 mark. 20 x 4 = 80
1. Select the correct option
EtONa / EtOH
Br (P) Product (Major)
Path (I)
Ph Me
EtOH
(Q) Product (Major)
Path (II)
Br Cl F Br
(a) ( I ) > ( II ) > ( III ) > ( IV ) (b) ( III ) > ( I ) > ( IV ) > ( II )
(c) ( IV ) > ( III ) > ( I ) > ( II ) (d) ( III ) > ( I ) > ( II ) > ( IV )
CH 3 CH 3
CH3 CH3
(c) CH 3 Br ROH (d) Br RONa OR
CH 3 CH2
CH3
Zn / ZnSO4 CuSO4 / Cu
−2.4 10−4 Volt /degree, calculate the enthalpy change of the cell reaction.
(a) −21.52 kJ (b) −13.83 kJ (c) +21.52 kJ (d) −28.82 kJ
6. A first order reaction, A → Products and a second order reaction, 2B → Products have a half – life of
30 min when the initial concentrations in each case are 3 mol L−1. The number of mol of A and B
remaining after 90 minutes after the start of the reaction is ( X ) and (Y ) respectively. The value of
(Y / X ) is -----
(a) 4.5 (b) 3.8 (c) 2.0 (d) 3.0
7. Bicyclohexane was found to undergo two parallel first order rearrangements. At 730 K , the first order
rate constant for the formation of cyclohexene was measured as 1.2 10−4 s −1 , and for the formation of
methylcyclopentene the rate constant was 4.0 10−5 s −1. What is the ratio of percentage distribution of
cyclohexene to methylcyclopentene?
(a) 8 (b) 3 (c) 4 (d) None of these
8. A first order reaction has a half-life of 1 hrs at 500 K . A catalyst lowers the activation energy of the
reaction by 30 kJ/mol. What is the time required to complete 75% of the reaction in presence of the
9. Atomic mass of thorium is 232 and its atomic number is 90. During the course of its radioactive
disintegration 5 and 4 particles are emitted. What is the atomic mass and atomic number of the final
atom?
(a) 208, 90 (b) 208,82 (c) 212, 72 (d) 212,82
O O
O
OH
(c) H (d)
CH3
O CH3
H3C D
Heat
B
OH OH
D D
H3C H3C
(a) (b)
CH2 CH3
H3C
OD OH
CH3
H3C H3C D
CH3
H3C
COOH
CH 2 OH
(1) SOCl2 +
H
CH 2 OH -
(1) NH2 NH 2 /OH
(2) H2 , Pd/BaSO4
O S T
R
+
(2) H3 O
COOH CHO
(a) (b)
O
CH3 CHO
(c) (d)
O O
Br OH Br
COOH COOH
(a) (b)
OH O OH
Br
CH3
(c) (d)
Br
Br
17. Match the species in Column-I that can react (oxidise, reduce, give ppt.) species in Column-II.
Column-I Column-II
A. Fe 2+ p. Cr2O72−
B. C2O42− q. CrO42 −
C. Pb 2 + r. 3−
Fe ( CN )
6
D. Ag + s. MnO4−
E. SO2 t. S 2O32−
(a) (A-r, s; B-p, q; C-q; D-s, t ; E-p, s) (b) (A-q, r, t; B-p, q; C-r; D-q, t ; E-q, s)
(c) (A-p, r, s; B-p, s; C-q; D-q, t ; E-p, s) (d) (A-p, s; B-p, t; C-p; D-q, r ; E-q, t)
18. Among the elements of group 17, fluorine is the most reactive owing to its
(a) electronegativity
(b) small size
(c) extremely high oxidising power and low dissociation energy of F-F bond
(d) all the above factors are responsible for high reactivity of fluorine
(a) Na2 SO4 (b) Na2 S 4O6 (c) NaCl (d) NaOH
Section II
This contains 10 numerical type questions for which the answer should be rounded off to nearest integer.
Candidates have to attempt any five questions out of ten questions in this section. A correct answer carries
4 marks and wrong answer will attract a penalty of 1 mark. 5 x 4 = 20
21. Two litre solution of a buffer mixture containing 1M NaH 2 PO4 and 1M Na2 HPO4 is placed in two
compartments (one litre in each) of an electrolytic cell the platinum electrodes are inserted in each
compartment and 1.2 amp current is passed for 201min . Assuming electrolysis of water only at each
compartment. The pH in cathode compartment is ( X ) and that at anode is (Y ) after passage of above
of water from which the above solution is made is 6.0 10−8 S cm −1. Calculate the molar conductivity of
oxalate ion, given molar conductivity of Ag + ion at infinite dilution is 62 S cm 2 mol−1 and solubility
23. Two weak acid solutions HA1 and HA2 each with same concentration and having pK a values 2 and 4 are
placed in contact with hydrogen electrode (1 atm and 25C are interconnected through a salt bridge.
silver iodide. Calculate the number of methoxy groups present in the ether.
(Mol. Mass of ether = 162)
26. The oxidation number of Mn in the product of alkaline oxidative fusion of MnO2 is
27. Calculate the magnetic moment of a divalent ion in aqueous solution if its atomic number is 25
28. Question:
O
CO 2Et
+
H3O
A; Product
EtO2C
O
Degree of unsaturation of the cyclic product is
29. What is the molecular weight of a compound that undergoes an aldol self-condensation reaction to
result in a - hydroxy ketone with a molecular weight of 144 ?
80 torr and total pressure at the end of 20 minutes is 120 torr. The time needed for 75% decomposition
Mathematics
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 4 marks. A wrong
answer carries a penalty of 1 mark. 20 x 4 = 80
−1 18
7 −10 17 4 −6
31. If 3 A + 4 B ' = ,2 B − 3 A ' = , then B =
0 6 31 −5 −7
1 −3 1 3 1 −4
1 −2 3
(a) −1 0 (b) −1 0 (c) (d) −2 2
2 4 2 4 −4 2 5 3 5
32. The values of x for which the formula 2sin −1 x = − sin −1 2 x 1 − x 2 is true, is
1 3 3 1 1
(a) ( −1,0 ) (b) ,1 (c) − , (d) − ,
2 2 2 2 2
33. The unit vectors perpendicular to the plane determined by the vectors a = 4iˆ + 3 ˆj − kˆ and b = 2iˆ − 6 ˆj − 3kˆ
are
x −3 y −8 z −3 x+3 y +7 z −6
34. The shortest distance between the lines = = and = = is
3 −1 −1 −3 2 4
136 156
(a) (b) 2 30 (c) 5 30 (d)
94 94
x +1 y − 2 z +1
35. The perpendicular distance from the point (1,0,2 ) onto the line = = is
3 −2 −1
3 3 3 3
(a) (b) 2 (c) 3 (d) 4
2 2 2 2
36. If R be the relation on the set R of all real numbers defined by aRb if and only if a − b 1 . Then R is
(a) ( −, −1 (b) (1, ) (c) ( 0,1) (d) ( −, −1)
1 1
− +
38. If f ( x) = xe x x , x 0 then f ( x ) is
0 , x=0
(a) a1a2 + c1c2 = 1 (b) a1a2 + b1b2 = 1 (c) a1a2 + b1b2 = 0 (d) a1a2 + c1c2 = −1
x2 + x + 2
41. The function f : R → R given by f ( x ) = , is
x2 + x + 1
(a) one-one and onto (b) one-one but not onto
(c) onto but not one-one (d) neither one-one nor onto
−1
1 − tan 1 tan b −a
42. If = , then
tan 1 − tan 1 a b
i −i 1 −1 6
43. If A = and B = −1 1 , then A equals
−i i
1 b 1 b
44. tan + cos−1 + tan − cos −1 =
4 2 a 4 2 a
a b 2b 2a
(a) (b) (c) (d)
b a a b
( ) ( )
45. If 6sin x y 2 + 8cos x y 2 = 10 , then
dy
dx
=
(a)
( )
6sin( x y 2 ) + 8cos x y 2
(b)
y2
6cos ( x y 2 ) − 8sin ( x y 2 ) x
y2 −y
(c) − (d)
x 2x
2 1 0 x
47. If x 4 −1 1 0 2 4 = 0, then absolute value of difference of possible values of x is
0 2 4 −1
−2 2
(a) (b) (c) 1 (d) −1
3 3
2
50. Let a = iˆ − 2 ˆj + 3kˆ if b is a vector such that a b = b and a − b = 6 , then b = _____
Section II
This contains 10 numerical type questions for which the answer should be rounded off to nearest integer.
Candidates have to attempt any five questions out of ten questions in this section. A correct answer carries
4 marks and wrong answer will attract a penalty of 1 mark. 5 x 4 = 20
3 6
51. If sin −1 x + sin −1 y + sin −1 z = , then the value of x100 + y100 + z100 − 101 101 101 is __________
2 x +y +z
1/ x 2
1 + 5x2
53. If lim = e then =
x →0 1 + 3 x 2
2x − 3 −1
54. Let f be a real – valued invertible function such that f = 5 x − 2, x 2. then the value of f (13)
x−2
is ______
x 5
55. If sin −1 + cosec−1 = , then x =
5 3 2
2k − 5 =
1 2 x
58. If x N and 2 x 3 = O , then x =
−3 0 8
59. If the line joining the points ( k , 1, 3) , ( 2, 4, 8 ) is parallel to the line joining the points ( −2, 1, −4 ) ,
( 3, 10, l ) , then ( l − 6k ) =
60. Number of onto functions from a set of five elements to a set of two elements is
Physics
Section I
Multiple Choice Questions with one correct answer. A correct answer carries 4 marks. A wrong
answer carries a penalty of 1 mark. 20 x 4 = 80
d
61. The plates of a parallel plate capacitor are separated by a distance d . A dielectric slab of thickness t =
4
of dielectric constant k1 = 2 is inserted in the space between the plates of the capacitor and the remaining
space is filled with a dielectric slab of dielectric constant k2 = 4 . Area of both dielectric plates is same as
that of the plates of capacitor. If Q is the charge on the capacitor and area of plates is A each, then
62. A capacitor of capacitance C 0 , which is charged to potential 2V0 , is connected across a capacitor of
capacitance 3C0 , charged to potential 4V0 , such that oppositely charged plates are connected to each
63. Light ( = 5000 Å ) illuminates a single slit whose width is 0.1 mm . What is the distance between two
nearest dark lines on either side of the central maximum if the diffraction pattern is viewed on a screen
that is 1.5 m from the slit?
64. In a Young’s double slit experiment, the two slits act as coherent sources of waves of equal amplitude A
and wavelength . In another experiment with the same arrangement, the two slits are made to act as
incoherent sources of waves of same amplitude and wavelength.
(a) In the first case, if the intensity at the midpoint of the screen (symmetric with respect to the
I
sources) is I1 and in the second case it is I 2 , then 1 = 2
I2
(b) In the first case, if the intensity at a point Q on the screen is one-fourth of that at the central
maximum, then in the second case also this relationship holds true
(c) In the first case, if the intensity at a point P on the screen is one-third of that at the central
maximum, then in the second case also this relationship holds true
(d) In the first case, if the phase difference between waves reaching a point R on the screen is 1 ,
65. While conducting the Young’s double slit experiment, a student replaced the two slits with a large,
opaque plate in the x-y plane containing two small holes that act as two coherent point sources ( S1 , S 2 )
emitting light of wavelength 600 nm . The student mistakenly placed the screen parallel to the x-z plane
(for z 0 ) at a distance D = 3 m from the mid-point of S1S 2 as shown schematically in the figure. The
distance between the sources d = 0.6006 mm . The origin O is at the intersection of the screen and the
line joining S1S 2 . Which of the following is true about the intensity pattern on the screen?
z
Screen
O
y
S1 S2
d x
D
(a) No fringes are formed
(b) Point O will be bright
(c) Hyperbolic bright and dark bands form, with foci symmetrically placed about O in the x-
direction
(d) Number of fringes formed around O (excluding the point O ) will be 500
C 2C
A C B
2C C
(a) 1.1 μF (b) 2.8 μF (c) 3.5 μF (d) 7 μF
68. For an electron to move in a circular path in an environment of purely uniform electric field
(a) It must be released from rest
(b) It must have an initial velocity at an angle of 45º to the direction of electric field
(c) It must have an initial velocity perpendicular to the direction of electric field
(d) Circular motion cannot be achieved
69. Time period of a simple pendulum of a certain length and having a positively charged bob oscillating
near Earth’s surface in a region devoid of electric field is T . How can the time period be decreased?
(a) By applying a uniform electric field acting upwards keeping the charge unchanged
(b) By applying a uniform electric field acting downwards keeping the charge unchanged
(c) By reducing the positive charge on the bob and applying a uniform electric field acting upwards
(d) By making the charge of the bob negative and applying a uniform electric field acting
downwards
70. The electric field in a region is given by E = 3E0iˆ + 4 E0 ˆj with E0 = 20 N C−1 . The electric flux of this field
maximum kinetic energy TA eV and de- Broglie wavelength A . The maximum kinetic energy of
photoelectrons liberated from another metal B by photons of energy 4.70 eV is TB = (TA − 1.50 ) eV . If
the de Broglie wavelength of these photoelectrons is B = 2 A, then which is the incorrect statement?
(a) the work function of A is 2.25 eV (b) the work function of B is 4.20 eV
72. Two identical non-relativistic particles A and B move at right angles to each other, having de Broglie
wavelengths 1 and 2 , respectively. The de Broglie wavelength of each particle in their centre of mass
frame of reference is
212 12
(a) 2 12 + 22 (b) 12 + 22 (c) (d)
12 + 22 12 + 22
73. Three different media - A, B and C - have refractive indices for a specific colour of light as
5 6 7
A = ; B = ; C = respectively. For which pair of media is critical angle least?
4 5 6
(a) A, B only (b) A, C only
(c) B, C only (d) It is least and equal for A, B and A, C
74. A horizontal ray of light passes through a prism of refractive index 1.5 whose apex angle is 4 and then
strikes a vertical mirror M as shown in the figure. In order to have a total deviation for the ray equal to
180 , the angle through which the mirror should be rotated is
M
4
75. The same size images are formed by a convex lens when the object is placed at 20 cm or at 10 cm from
76. Nine wires each of resistance r are connected to make a prism as shown. Find the equivalent resistance
of the arrangement across: (i) AD (ii) AB
C
E
D B
F
A
10r 3r 3r 10r 5r 2r 2r 5r
(a) ; (b) ; (c) ; (d) ;
3 5 5 3 6 3 3 6
2
77. A thread carrying a uniform negative charge per unit length = − ( 0 ) has the configuration as
3
shown. Assuming the curvature radius R to be considerbly less than the length of the thread, find the
magnitude of the electric field strength at O .
x
O
R
2 3k 6k 2k 2 2k
(a) (b) (c) (d)
R R 3R 3R
78. Find the electric potential energy of the system of charges as shown in the figure below.
+q a +q
−q −q
1 − 2q 2 1 −q 2 1 −q 2 1 q2
(a) (b) (c) (d)
4 0 a 4 0 a 8 0 a 8 0 a
79. In the circuit shown below, the readings of the voltmeter (ideal) and the ammeter (ideal) respectively
will be
10 i1
V1 A1
10 V
(a) V1 =10V, A1 =1A (b) V1 = 0V, A1 = 0 A (c) V1 =10V, A1 = 0A (d) V1 = 0V, A1 =1A
80. Radiation force experienced by a spherical body exposed to radiation of intensity I = 1Wm −2 (assuming
I
R
Section II
This contains 10 numerical type questions for which the answer should be rounded off to nearest integer.
Candidates have to attempt any five questions out of ten questions in this section. A correct answer carries
4 marks and wrong answer will attract a penalty of 1 mark. 5 x 4 = 20
C KC K 2C K 3C To infinity
B
82. A battery of emf 24 V and internal resistance R is connected to a resistance network as shown in the
figure. The value of R (in ohms) for which the thermal power dissipated in it is maximum is _______ .
1 6
2 10
6
12
83. A non-conducting solid sphere of radius R is charged uniformly. Electrostatic potential at a point, P , is
0.7 times of its value at the centre. Distance of P from the centre of the sphere is 3R / N . N is equal to
__________.
84. A converging lens and a diverging mirror are placed at a separation of 15 cm . The focal length of the lens
is 20 cm and that of the mirror is 40 cm . A point source is placed between the lens and the mirror so that
the light, after getting reflected by the mirror and then getting transmitted by the lens, comes out parallel
to the principal axis. The distance of the point source from the lens is ________ cm.
85. A point object is placed at a distance of 15 cm from a convex lens. The image is formed on the other side
at a distance of 30 cm from the lens. When a concave lens is placed in contact with the convex lens, the
image shifts away further by 20 cm . Focal length of the concave lens (absolute value) is _________ cm.
86. A wire has a resistance of 12 . It is bent in the form of a circle. The effective resistance between two
________cm.
88. In the circuit, given below, potential difference across the capacitor of 3 μF is _________ volts.
2 μF
3 μF
e d
5 μF
f c
4 μF
a + −
b
6V
89. The electrostatic potential energy ( in J ) of a system consisting of two charges 7 μC and 7 μC placed at
in the figure. If 0.2 mV/cm is the potential gradient, then resistance of the potentiometer wire is
_________ .
2V 490
B
J
G