CA Vs tine w a badh neac ?

"Jnteyal metod
Nethod

-d CA
dt dt clope
-ln dCa luk t aluCA
dt

Ji(c:) dei

X3-%2
 w abdh at ?
Dynlial mettod
metlhod

1.
beeutiat melead.
-d CA
dt dt
- ln dCa luk t ox luCA
dt

gaphial matiad
di(c)
 kt for
CAo -|5
1-ktt
Kt
t
-tk
tk k
A | t
plalappept
. find ceNeck
cquatien. deid wgate
he ion
KiActseactio ohdeeof yuusa
bial) and Hit
CAn ttf
QAt dt
dCA
2at lt t
dCA
to t dt
CACA, 2At 4 3C+Ao
Cas Cas
CAConc.
t time
to
metlhod Numeninl
 ksoyut y mbig , PFRCsTR ia Seriea paulel not
paellel
Meactee, Auto Aeacto
Hal lite mettod -
tyala A

tyli G,
tyla CA2

(a-1)k
+
C

IwiialAate mesd:

PFR

R
R’ hatio

A CSTR a
 Keacko Deig fo multbipl hactimu
i) Sexius eactim
i) fanalat heacin
ii) Seriea- farallel actirn

farallel uactien
R (a)
A

s k, - f(T,c)
melu
kfomed(b) dee /dt =-dCe
S
dls<at d Cs

at

at lou C.
(csTA)
ceneentain
PCR.
’ maunteiu d
-’ eme ti
conettttim, cenesion ate.
mantai
pessure.

CS TR,
’ mamtai bigt con
 A+ B
(a-41)
R
CA

Eb /RT
Ko
ko

fes bigken halio te ed

6y >Ep net louw tenpatuu

b, eb

b ) b

Bartlh

A tB A

A
Flow B
CA

Ce

CSTR ceie

to
 5 O.3
’R + T dCe dCr k, CA Ce
AB dt dt
0-5
dCs
dt dt

Ara)
2 >5
5 >> 3>I>4

al factinne gield ( )
moles R dle
mola A disapped -dea

Cef ACR
- ACA
Caf
dCR k,CA
-dCA -A Kc+Kyc

PER
CAo

Cs TR
conatt
(A)
=

m
 seien
Colulate

-ACA

CAe

CRL

CR,
CAo

4
Ce caTR

CA
CAf

PER
 fFR

Chu
dle
Stu) dt
ds
dt
(%12, (A) -2
2) CsTR b) PPR
) suitable uacte
da
dt
(·5

CA
Ca t CA2

90/ cemwn
coMcenaisn R m
4, = -

Ca

Cao-af CA
|0-|

dca dCa
+CA

0-1894
 -0|894 x9
= ||705

Csf (- $,4) (a, s)

t 7.295

(A)

CRr 9x0-s
9x(t-0:s)
Cst
d CA A

08720
CRr = 9x 0872 7-85
Cag
Series heactim
AA k,AK
K,Ca k,Ca
consla velme
syaton
dt
A. k,t
k;t

k e-kt -kyt
CAo -e
-k,tk, CR,mr
Cone
C
CR, max
CA ) tmax
t’

()
ky-kË

2 0
(+k,am)(ekyr-) dn

Copt
Jk k

ke

(:
 ARs

PER Ce, mar 2. ME R CR, mar

Autoaaiyic uacte
> R t R

= kCA CR - d(Nav)
dt
taku a bateh neactor! Lotawt valme
Vavabl wol
ytim

-dcA
dt
kca lChu-)
t
dCA
-f Ca (ao-a)
k dt

at t = t CA =

dA
dt
k Caj XA (l- X)
9
dXA
dt
dxA
X(-) klaodt
deA
Alope = k
 - \A

RegdeAReacrn
Fay V
PER V
output
= Vb
Ao
Ve fas Recycle stan
XA=0
Reycle Ratio,R vellume o uid netmiy to acher uit
elume he

Vo

at pent A -

total = Vo t+ Rv

cemaent may balamce

(1+R)(1-XA) |tR(I-XA)
R

fos PER
V
d XA
CAb (-a)
dXA
(-9t4) VoV(tR)
Cao (a)
 -MA

K R

Cao lomell
A+R R+R (-AA) = ke,Ca
Va L mw

a) nd dhu Ruyleaat whi uill muuee

neacta aded ad duitne His

Sze ste cit Aeaeto alo R5
Re3 R=5 R2

dd
V,()Cho

V V R+1
fAo K CAo R(I-A)
R 0 43

Examplu 7IT
 (vr) d dt UA(T-1J
dH
(a)V--
bH) +
(T-T) UAQ=
balamer?
sulau cuall HI (2) () put
aea
ttet 2) A -
CA CA
CA ilet
Jacket
Accummuli =
sutlet
Jackel CAo MER
Ws Vo
Julet
also
censtant
A’R
-E;; F
-UA(T-) Loalls HT
H
=pv,cql. H,
.Output pvcpT Reactor HoR Tnput
Hal d)
bande) (Heat esloss Heat c)
stiming teonpeatu
do due vaniatien
Endotlenmie i) Heat a)neasm
Tcomstamt
deign Nan-Isthumal
aeact
 ’> fe(1,-T) + (-) V(- AHa)- UA(T-) =0
T-To ()-A (1-4)
T- To
()(a) - UA (T-T)
1-1, = t-AHR
lpck,e CA UAL (T- Te) -9)

celue (2) and (9) sinulknoualy to

gee T and CA

Batol heacto
mass balance
trb.t. comynent Jacket

4 - (-A)V = dA
Jactel
-ta = - I d NA
dt

balane
.o- UAct-To) +(-MA) V(-aHa) = dH
dT
= (-n) V(- AH) - UA (T-T)
Jt
dT
()-ate) - UAe (T-Te) - )
dt
 euih
Book solumae
at
Aeaeto met hat at
what at
melL 2
loL V> mo) keal r-20
-I ’R Comsdu
A
-Te) (T dz
+udT
(T-Te)
=o (-AHa)- AzA
vRaz Tz7-T,)+(-Ha) pUAC¢( >
aHA) +UR,
Az
(-A)DHe) (T-Te)
+
dT
(sHa) +)v -To) (TazUe, -
balanee
dz
lim
AAZ
Calz -
A
V
4, -0 -(4)
AV Zt0Z
TlztAZ Tlz
Caltaz
blamce masCompont
ORoz(T-) Q- Reacke: flow Plug
 Heat (-HA) VtoHe)
ge
Hedt neleasd UA (T-Te)
Heat - Heat med,
g
CSTR F k al1- XA)v (- AH)
- 2kead min
CA

dCA dCA
kCA K CAo
CA
-A
-kt -Da
CA = A, e
-kt Az
Q (-are) vk Cae Va Ve

Q= (-AHa V:k Ca, e

Batch eato
-dA = (-a) -

K C
dt
-kt
CA
-Kt

Adabati Reactoe
AHR
UA
T-To =
Pv (T-Te)

ebe s
cbe
 T-1,-AHe (Ca,Ca)
-AHRACA
Battl actes
ebe dt -AHR(-MA) - (00 (7-)

cbe - | dNA dCA

dt dt
dT deA

dI = - AHe

T-T. -(ate\(ca-au)

PPR
ebe
-dMe (-a)-ue (T-Te)

cbe 2

d2

dT dea
A
dT da AT

al adialatie seacto
thyt balamce eqn is same
 T-T = AHR

T-7

GA -CA = A, XA
T-1, JXA

exahee
Eudolienic
= T, t J
T t J
( )
for exofmic T<o fo endothemic

place ad'abatle heacto.

Caider A ’R takiny
z-20 kcal mo l000 cal L Cal T.00k

380K

MR Cao-CA CAo - CA
(-Aa) k, e-ER(TtJKA) CA
KMER size

ke (I-x)
XA XA
PFR dXA

(-Ma)
CAo koe

Batlo Jeplae T ith t ie PPR

 CA

[estR
CA

Excthuic neactin
CSTRa > PERad PFR iaelaol
iacunel

Maltigle steady sati i

?

T-1 =(EaH(-M) -0A

UA (T-Te)

T-T = AHe (a-Ga ) - (T-T)

- (- AHeCAXA UAc
(T-Te)

T-I, JXA - U7 (T-Te)

= T-o + Uk(T - T)
 PI i bet

Cmb CAo XA
k Ca k(I-)

I+ k

|-0| XA=

stable

To T'

Rsdnt time disthibution

Heactes
Ruasrns nen desli
cuad
(in CSTR) chert cuitig
constant (eek)

Stimalus Respomne lechique

Trar Experimnt RTD epoimnt
sheuld be inent, slald hae ded'eak reaetenaphyul
chould net
pleputiu mituu
tectabl , empltiy seluse
absobeol debel
t shoud be consese. it hold nt e absertesl
 Add thacu,t o

dateter

X= &t)

ple
X(4) v(t) -u(t -t)
t0 t

3) step ouput
t=0

4) Ramp wput X(H at

t=0

s) Sunuscidal X(t) A uuwt

RTD {unctinns
t ’ seidenee tin
E(t)’ eit olisbibution RTD fumctim
Ft) ’ Cumlatiu tesidenee timu outubutim unctin.
raction baces meleeulea w the sutlet stuam
whih has hem t to
t+dt time.
t
E )dt Fly= E(t) dt C(t)
t
 q) mole
C(H mel m3 V.c ) =qlt)

E(t) dt = v. (m's)· c) (mol /m3) " dt ()

(stal meles of thaen
time

E(t) dt = a C(t) t E(t) = c(t) C(t} [T]

’
C(Hdt Co

n-ideal eaeto

T- moclel the eactos as deal and accont cove ction acte

for the duiatin
RTD genra CH vs t dala Et) vet data
* Caleutate Et), Flt),t s and o (vaulanc)
*Comnpane the esult obtaved itt tat for ideal eaete.

T - lae Models (mio ot macro models )

modelo
(pufened)
mawmw miednesd moolal
+ y Haeo miuny models Tanke wseieu ( TIS) odt (N)
peramebi modela ’ Aial despessum mmodal. Da
> two panamete models
 Vo
or t G/ Acc.

d(v(a)

vC()
dt

dt
(Vw)
-t

E(t) dt VC)dl v 20.t

dt

6() =

F) - 6)At f)

| -e-t/e