Chemistry 11th Thermodynamics

CHAPTER
4
DPP
NEET
Chemistry by-
ADIL SIR
2 DPP CHEMICAL THERMODYNAMICS
EXCERCISE - 1 : OBJECTIVE QUESTIONS

AIIMS QUESTIONS (D) none of these
1. Which of the following is not a state function?
9. For which reaction from the following ∆S will be
[AIIMS 2002]
maximum [AIIMS 2006]
(A) Internal energy (B) Enthalpy
(A) Ca(s) + 1/2 O2(g) → CaO(s)
(C) Work (D) Entropy
(B) CaCO3(s) → CaO(s) + CO2(g)
2. Among them intensive property is [AIIMS 2002] (C) C(s) + O2(g) → CO2(g)
(A) mass (B) volume (D) N2(g) + O2(g) → 2NO(g)
(C) surface (D) enthalpy
10. The occurrence of reaction is impossible if
3. At constant T and P, which one of the following [AIIMS 2006]
statements is correct for the reaction, (A) ∆H is +ve; ∆S is also +ve but ∆H < T∆S
1 (B) ∆H is –ve; ∆S is also –ve but ∆H < T∆S
CO(g) + O (g) → CO2(g), [AIIMS 2003] (C) ∆H is –ve; ∆S is +ve
2 2
(A) ÄH is independent of the physical state of the (D) ∆H is +ve; ∆S is –ve
reactants of that compound
11. Which of the following is true for the reaction H2O(l)
(B) ∆H > ÄE
H2O(g) at 100°C and 1 atmosphere
(C) ∆H > ÄE
[AIIMS 2007]
(D) ∆H = ÄE
(A) ∆E = 0 (B) ∆H = 0
4. For the reaction of one mole of zinc dust with one (C) ∆H = ∆E (D) ∆H = T∆S
mole of sulphuric acid in a bomb calorimeter, ∆U and
12. Following data is known about melting of compound
w correspond to [AIIMS 2003]
AB. ∆H = 9.2 kJ mol–1, ∆S = 0.008 kJ K–1mol–1. Its
(A) ∆U < 0, w = 0 (B) ∆U = 0, w = 0
melting point is [AIIMS 2007]
(C) ∆U > 0, w = 0 (D) ∆U < 0, w > 0
(A) 736 K (B) 1050 K
5. Which of the following expressions represents the first (C) 1150 K (D) 1150°C
law of thermodynamics? [AIIMS 2004]
13. One mole of an ideal gas is allowed to expand
(A) ∆E = – q + W (B) ∆E = q – W
reversibly and adiabatically from a temperature of
(C) ∆E = q + W (D) ∆E = – q – W
27°C. If the work done during the process is 3 kJ, the
6. The relation between change in internal energy (∆E), final temperature will be equal to (Cv = 20 JK–1)
change in enthalpy (∆H) and work done (W) is [AIIMS 2007]
represented as [AIIMS 2004] (A) 150 K (B) 100 K
(A) ∆H = ∆E + W (B) W = ∆E – ∆H (C) 26.85°C (D) 295 K
(C) ∆E = W – ∆E (D) ∆E = ∆H + W
14. Equal volumes of monoatomic and diatomic gases at
7. Work done during isothermal expansion of one mole same initial temperature and pressure are mixed. The
of an ideal gas from 10 atm to 1 atm at 300 K is (Gas ratio of specific heats of the mixture (Cp/Cv) will be
constant = 2) [AIIMS 2005] [AIIMS 2008]
(A) 938.8 cal. (B) 1138.8 cal. (A) 1 (B) 2
(C) 1381.8 cal. (D) 1581.8 cal. (C) 1.67 (D) 1.5
8. Internal energy is [AIIMS 2005] 15. Which one of the following has greater than zero
(A) partly potential and partly kinetic [AIIMS 2008]
(B) totally kinetic (A) CaO + CO2(g) CaCO3(s)
(C) totally potential (B) NaCl(aq) NaCl(s)
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CHEMISTRY 3
(C) NaNO3(s) Na+(aq) + NO3(aq) value of ∆H for the ionisation of CH3COOH?
(D) N2(g) + 3H2(g) 2NH3(g) [AIIMS 2012]
(A) + 5.3 kJ/mol (B) + 6.2 kJ/mol
16. In which of the following neutralization reactions, the
(C) + 8.2 kJ/mol (D) + 9.3 kJ/mol
heat of neutralization will be highest? [AIIMS 2008]
(A) NH4OH and CH3COOH 23. The enthalpy of combustion of C6H6(l) is – 3250 kJ.
(B) NH4OH and HCl When 0.39 g of benzene is burnt excess of oxygen in
(C) NaOH and CH3COOH an open vessel, the amount of heat evolved is
(D) NaOH and HCl [AIIMS 2013]
(A) 16.25 J (B) 16.25 kJ
17. The heat of neutralization of a strong acid and a strong
(C) 32.5 J (D) 32.5 kJ
alkali is 57.0 kJ mol–1. The heat released when 0.5
mole of HNO3 solution is mixed with 0.2 mole of KOH 24. One gram sample of NH4NO3 is decomposed in a
is [AIIMS 2009] bomb calorimeter. The temperature of the calorimeter
(A) 57.0 kJ (B) 11.4 kJ increases by 6.12 K. The heat capacity of the system
(C) 28.5 kJ (D) 34.9 kJ is 1.23 kJ/g/deg. What is the molar heat of
decomposition for NH4NO3? [AIIMS 2013]
18. If enthalpies of formation of C2H4(g), CO2(g) and
(A) – 7.53 kJ/ mol (B) – 398.1 kJ/mol
H2O(l) at 25°C and 1 atm pressure be 52, – 394 and
(C) – 16.1 kJ/mol (D) – 602 kJ/mol
– 286 kJ mol–1 respectively, the enthalpy of combustion
of C2H4(g) will be [AIIMS 2009] 25. How many energy is released when 6 mole of octane
–1
(A) + 1412 kJ mol (B) – 1412 kJ mol–1 is burnt in air? Given f for CO2(g), H2O(g) and C8H18(l)
(C) + 141.2 kJ mol–1 (D) – 141.2 kJ mol–1 respectively are – 490, – 240 and + 160 kJ/mol
[AIIMS 2014]
19. Combustion of glucose takes place according to the
(A) – 6.2 kJ (B) – 37.4 kJ
equation, C6H12O6 + 6O2 → 6CO2 + 6H2O, ∆H = – 72
(C) – 35.5 kJ (D) – 20.0 kJ
kcal. How much energy will be required for the
production of 1.6 g glucose (Molecular mass of 26. In an isobaric process, the ratio of heat supplied to the
glucose = 180 g) [AIIMS 2010] system (dQ) and work done by the system (dW) for
–1
(A) + 1412 kJ mol (B) – 1412 kJ mol–1 diatomic gas is [AIIMS 2014]
(C) + 141.2 kJ mol–1 (D) – 141.2 kJ mol–1 (A) 1 : 1 (B) 7 : 2
(C) 7 : 5 (D) 5 : 7
20. Ozone is prepared by passing silent electric discharge
through oxygen. In this reaction [AIIMS 2011] NEET QUESTIONS
(A) energy is given out
27. When 1 mol gas is heated at constant volume tem-
(B) energy is absorbed
perature is raised from 298 to 308 K. Heat supplied to
(C) oxygen is loaded with energy
the gas is 500 J. Then which statement is correct :
(D) oxygen is dissociated
[NEET 2001]
21. When 4 g of iron is burnt to ferric oxide at constant (A) q = –W = 500 J, ∆U = 0
pressure, 29.28 kJ of heat is evolved. What is the (B) q = ∆U = 500J, W = 0
enthalpy of formation of ferric oxide (At. wt. of Fe = (C) q = W = 500 J, ∆U = 0
56) [AIIMS 2012] (D) ∆U = 0, q = W = – 500 J
(A) – 81.98 kJ (B) – 819.8 kJ
28. PbO2 → PbO, ∆G298 < 0
(C) – 40.99 kJ (D) + 819.8 kJ
SnO2 → SnO, ∆G298 > 0
22. Enthalpy of neutralization of acetic acid by NaOH is Most probable oxidation state of Pb & Sn will be :
– 50.6 kJ/mol and the heat of neutralization of a strong [NEET 2001]
4+ 4+
acid with a strong base is – 55.9 kJ/mol. What is the (A) Pb , Sn (B) Pb , Sn2+
4+

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(C) Pb2+, Sn2+ (D) Pb2+, Sn4+ 37. What is the entropy change (in JK–1 mol–1) when one
mole of ice is converted into water at 0°C?
29. Change in enthalpy for reaction
(The enthalpy change for the conversion of ice to
2H2O2(l) → 2H2O(l) + O2(g)
liquid water is 6.0 kJ mol–1 at 0°C) [NEET 2003]
If heat of formation of H2O2(l) and H2O(l) are – 188
(A) 20.13 (B) 2.013
and – 286 kJ/mol respectively is [NEET 2001]
(C) 2.198 (D) 21.98
(A) – 196 kJ/mol (B) + 196 kJ/mol
(C) + 948 kJ/mol (D) – 948 kJ/mol 38. For which one of the following equations is ∆H°reaction
equal to ∆Hf° for the product [NEET 2003]
1
30. Enthalpy of CH4 + O2 → CH3OH is negative. If (A) N2(g) + O3(g) → N2O3(g)
2
enthalpy of combustion of CH4 and CH3OH are x and (B) CH4(g) + 2Cl2(g) → CH2Cl2(l) + 2HCl(g)
y respectively, then which relation is correct? (C) Xe(g) + 2F2(g) → XeF4(g)
[NEET 2001] (D) 2CO(g) + O2(g) → 2CO2(g)
(A) x > y (B) x < y
39. For reaction,
(C) x = y (D) x ≥ y
C3H8(g) + 5O2 → 3CO2(g) + 4H2O(l)
31. The unit of entropy is [NEET 2002] at constant temperature, ∆H – ∆U is [NEET 2003]
(A) J K–1 mol–1 (B) kJ mol–1
–1
(A) + RT (B) – 3 RT
(C) kJ mol–1 (D) J–1 K–1 mol–1 (C) + 3 RT (D) – RT
32. In closed insulated container, a liquid is stirred with a 40. The densities of graphite and diamond at 298 K are
padle to increase the temperature, which of the 2.25 and 3.31 g cm–3, respectively. If the standard free
following is true? [NEET 2002] energy difference (∆G°) is equal to 1895 J mol–1, the
(A) ∆U + W ≠ 0, q = 0 (B) ∆U + W = 0, q ≠ 0 pressure at which graphite will be transformed into
(C) ∆U + Q, W = q ≠ 0 (D) W = 0, ∆U = q ≠ 0 diamond at 298 K is [NEET 2003]
6
(A) 9.92 × 10 pa (B) 9.92 × 105 pa
33. Two moles of ideal gas at 27°C temperature is
(C) 9.92 × 108 pa (D) 9.92 × 107 pa
expanded reversibly from 2 litre to 20 litre. Find
entropy change (R = 2 cal/mol K). [NEET 2002] 41. For which one of the following equations is ∆H°react
(A) 92.1 (B) 0 equal to ∆H°f for the product ? [NEET 2003]
(C) 4 (D) 9.2 (A) Xe(g) + 2F2(g) → XeF4(g)
(B) 2CO(g) + 2O2(g) → 2CO2(g)
34. Heat of combustion ∆H° for C(s), H2(g) and CH4(g)
(C) N2(g) + O3(g) → N2O3(g)
are – 94, – 68 and – 213 kcal/mol. The ∆H° for C(s) +
(D) CH4(g) + 2Cl2(g) → 2CH2Cl2(l) + 2HCl(g)
2H2(g) → ∆CH4(g) is [NEET 2002]
(A) – 17 kcal (B) – 111 kcal 42. Formation of solution from two components can be
(C) – 170 kcal (D) – 85 kcal considered as
(i) Pure solvent → separated solvent molecules, ∆H1
35. Which reaction is not feasible? [NEET 2002]
(ii) Pure solute → separated solute molecules, ∆H2
(A) 2KI + Br2 → 2KBr + I2
(iii) Separated solvent and solute molecules →
(B) 2KBr + I2 → 2KI + Br2
solution, ∆H3
(C) 2KBr + Cl2 → 2KCl + Br2
Solution so formed will be ideal if [NEET 2003]
(D) 2H2O + 2F2 → 4HF + O2
(A) ∆Hsoln = ∆H1 + ∆H2 + ∆H3
36. The molar heat capacity of water at constant pressure (B) ∆Hsoln = ∆H1 + ∆H2 – ∆H3
P, is 75 JK–1 mol–1. When 1.0 kJ of heat is supplied to (C) ∆Hsoln = ∆H1 – ∆H2 – ∆H3
100 g of water which is free to expand, the increase (D) ∆Hsoln = ∆H3 – ∆H1 – ∆H2
in temperature of water is [NEET 2003]
(A) 1.2 K (B) 2.4 K 43. Considering entropy (S) as a thermodynamic
(C) 4.8 K (D) 6.6 K parameter, the criterion for the spontaneity of any

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CHEMISTRY 5
process is [NEET 2004] 50. Identify the correct statement for change of Gibbs
(A) ∆Ssystem – ∆Ssurrounding be + ve energy for a system (ÄGsystem) at constant temperature
(B) ∆Ssystem + ∆Ssurrounding BE + ve and pressure: [NEET 2006]
(C) ∆Ssystem be zero (A) if ÄGsystem = 0, the system is still moving in
(D) ∆Ssurroundings be zero particular direction
(B) if ÄGsystem = –ve, the process in not spontaneous
44. Standard enthalpy and standard entropy changes for
(C) If ÄGsystem = + ve, the process is spontaneous
the oxidation of ammonia at 298 K are – 382.64 kJ (D) If ÄGsystem = 0, the system has attained equilibrium
mol–1 and – 145.6 JK–1 mol–1, respectively. Standard
Gibbs energy change for the same reaction at 298 K is 51. The enthalpy and entropy change for the reaction:
[NEET 2004] Br2(l) + Cl2(g) → 2BrCl(g)
(A) – 221.1 kJ mol–1 (B) – 339.3 kJ mol–1 are 30 kJ mol–1 and 105 JK–1 mol–1 respectively. The
(C) – 439.3 kJ mol–1 (D) – 523.2 kJ mol–1 temperature at which the reaction will be in equilibrium
is: [NEET 2006]
45. The work done during the expansion of a gas from a (A) 450 K (B) 300 K
volume of 4 dm3 to 6 dm3 against a constant external (C) 285.7 K (D) 273 K
pressure of 3 atm is (1 atm-L = 101.32 J)
[NEET 2004] 52. Assume each reaction is carried out in an open
(A) – 6 J (B) – 608 J container. For which reaction will ∆H = ∆U ?
(C) + 304 J (D) – 304 J [NEET 2006]
(A) H2(g) + Br2(g) → 2HBr(g)
46. The bond energies of H–H, Br–Br and H–Br are 433, (B) C(s) + 2H2O(g) → 2H2(g) + CO2(g)
192 and 364 kJ mol–1 respectively. The ∆H for the (C) PCl5(g) → PCl3(g) + Cl2(g)
reaction (D) 2CO(g) + O2(g) → 2CO2(g)
H2(g) +Br2(g) → 2 HBr(g) is [NEET 2004]
(A) – 261 kJ (B) + 103 kJ 53. The enthalpy of combustion of H2, of cyclohexene
(C) + 261 kJ (D) – 103 kJ (C6H10) and cyclohexan (C6H12) are – 241, – 3800 and
– 3920 kJ mol–1. respectively. Heat of hydrogenation
47. The absolute enthalpy of neutralization of the reaction, of cyclohexane is [NEET 2006]
MgO(s) + 2HCl(aq) → MgCl2(aq) + H2O(l) will be (A) – 121 kJ mol –1
(B) + 121 kJ mol–1
[NEET 2005] (C) + 242 kJ mol–1 (D) – 242 kJ mol–1
(A) Greater than – 57.33 kJ mol–1
(B) Less than – 57.33 kJ mol–1 54. The enthalpy of hydrogenation of cyclohexene is
(C) – 57.33 kJ mol–1 – 119.5 kJ mol–1. If resonance energy of benzene is
(D) 57.33 kJ mol–1 – 150.4 kJ mol–1, its enthalpy of hydrogenation would
be [NEET 2006]
48. A reaction occurs spontaneously if - [NEET 2005] (A) – 269.9 kJ mol–1 (B) – 358.5 kJ mol–1
(A) T∆S > ∆H and ∆H is +ve and ∆S are –ve (C) – 508.9 kJ mol–1 (D) – 208.1 kJ mol–1
(B) T∆S = ∆H and both ∆H and ∆S are +ve
(C) T∆S < ∆H and both ∆H and ∆S are +ve 55. Identify the correct statement regarding a spontaneous
(D) T∆S > ∆H and both ∆H and ∆S are +ve process. [NEET 2007]
(A) Lowering of energy is the only criterion for
49. Which of the following pairs of a chemical reaction is spontaneity.
certain to result in a spontaneous reaction? (B) For a spontaneous process in an isolated system,
[NEET 2005] the change in entropy is positive.
(A) Exothermic and decrasing disorder (C) Endothermic processes are never spontaneous.
(B) Endothermic and increasing disorder (D) Exothermic processes are always spontaneous.
(C) Exothermic and increasing disorder
(D) Endothermic and decreasing disorder 56. Given that bond energies of H–H and Cl–Cl are 430

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kJ mol–1 and 240 kJ mol–1 respectively and ∆H for will be spontaneous at [NEET 2009]
HCl is – 90 kJ mol–1. Bond enthalpy of HCl is : (A) 510 K (B) 710 K
[NEET 2007] (C) 910 K (D) 1110 K
(A) 245 kJ mol–1 (B) 290 kJ mol–1
63. The energy absorbed by each molecule (A2) of a
(C) 380 kJ mol–1 (4) 425 kJ mol–1
substance is 4.4 × 10–19 J and bond energy per molecule
57. Consider the following reactions : is 4.0 × 10–19 J. The kinetic energy of the molecule per
(i) H+(aq) + OH–(aq) → H2O(l); atom will be : [NEET 2009]
∆H = –X1 kJ mol–1 (A) 4.0 × 10 J –20
(B) 2.0 × 10–20 J
1 (C) 2.2 × 10–19 J (D) 4 × 10–19 J
(ii) H2(g) + O (g) → H2O(l);
2 2 64. From the following bond energies :
∆H = –X2 kJ mol–1 H — H bond energy : 431.37 kJ mol–1
(iii) CO2(g) + H2(g) → CO(g) + H2O(l); C = C bond energy : 606.10 kJ mol–1
∆H = –X3 kJ mol–1 C — C bond energy : 336.49 kJ mol–1
5 C — H bond energy : 410.50 kJ mol–1
(iv) C2H2(g) + O (g) → 2CO2(g) + H2O(l);
2 2 Enthalpy for the reaction
∆H = +X4 kJ mol–1
Enthalpy of formation of H2O(l) is [NEET 2007]
(A) – x2 kJ mol–1 (B) + x3 kJ mol–1
(C) – x4 kJ mol–1 (D) + x1 kJ mol–1
58. Which of the following are not state functions? will be [NEET 2009]
[NEET 2008] (A) 553.0 kJ mol–1 (B) 1523.6 kJ mol–1
I. q + w II. q (C) – 243.6 kJ mol–1 (D) – 120.0 kJ mol–1
III. w IV. H - TS 65. Standard entropies of X2, Y2 and XY3 are 60, 40 and 50
(A) II, III and IV (B) I, II and III J K1 mol1 respectively. For the reaction
(C) II and III (D) I and IV
1 3
X + Y → XY3, ∆H = 30 kJ,
59. For the gas phase reaction, [NEET 2008] 2 2 2 2
PCl5(g) → PCl3(g) + Cl2(g) to be at equilibrium, the temperature should be
Which of the following conditions ar correct? [NEET 2010]
(A) ∆H > 0 and ∆S > 0 (B) ∆H < 0 and ∆S < 0 (A) 750 K (B) 1000 K
(C) ∆H > 0 and ∆S < 0 (D) ∆H = 0 and ∆S < 0 (C) 1250 K (D) 500 K
60. Bond dissociation enthalpy of H2, Cl2 and HCl are 66. For an endothermic reaction, energy of activation is
434, 242 and 431 kJ mol–1 respectively. Enthalpy of Ea and enthalpy of reaction is ∆H (both of these in kJ/
formation of HCl is [NEET 2008] mol). Minimum value of Ea will be [NEET 2010]
(A) – 93 kJ mol–1 (B) 245 kJ mol–1 (A) less than ∆H (B) equal to ∆H
(C) 93 kJ mol–1 (D) – 245 kJ mol–1 (C) more than ∆H (D) equal to zero
61. At 27°C latent heat of fusion of a compound is 2930 67. The moles of an ideal gas expanded spontaneously
J/mol. Entropy change during fusion is [NEET 2009] into vacuum. The work done will be [NEET 2010]
(A) 9.77 J/mol K (B) 10.77 J/mol K (A) Infinite (B) 3 joules
(C) 9.07 J/mol K (D) 0.977 J/mol K (C) 9 joules (D) zero
62. The values of ∆H and ∆S for the reaction, 68. For vaporization of water at 1 atmospheric pressure
C(graphite) + CO2(g) → 2CO(g) the values of ∆H and ∆S are 40.63 kJ mol–1 and 108.8
are 170 kJ and 170 JK–1 respectively. This reaction JK–1 mol–1, respectively. The temperature when Gibbs

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CHEMISTRY 7
energy change (∆G) for this transformation will be 74. Consider the following processes :
zero is [NEET 2010] H (kJ/mol)
(A) 273.4 K (B) 393.4 K 1/2A → B + 150
(C) 373.4 K (D) 293.4 K 3B → 2C + D – 125
E + A → 2D + 350
69. The following two reactions are known
For B + D → E + 2C, ∆H will be [NEET 2011]
Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g);
(A) 525 kJ/mol (B) – 175 kJ/mol
∆H = – 26.8 kJ
(C) – 325 kJ/mol (D) 325 kJ/mol
FeO(s) + CO(g) → Fe(s) + 3CO2(g);
∆H = – 16.5 kJ 75. Standard enthalpy of vaporisation ∆vap. HΘ for water
The value of ∆H for the following reaction at 100°C is 40.66 kJ mol–1. The internal energy of
Fe2O3(s) + CO(g) → 2FeO(s) + CO2(g) vaporization of water at 100°C (in kJ mol–1) is
[NEET 2010] [NEET 2012]
(A) + 10.3 kJ (B) – 43.3 kJ (A) + 43.76 (B) + 40.66
(C) 10.3 kJ (D) – 6.2 (C) + 37.56 (D) – 43.76
70. Match List-I (Equations) with List-II (Type of 76. The enthalpy of fusion of water is 1.435 kcal/mol. The
processes) and select the correct option. molar entropy change for the melting of ice at 0°C is
List-I List-II [NEET 2012]
Equations Type of processes (A) 5.260 cal/(mol K) (B) 0.526 cal/(mol K)
(a) Kp > Q (i) Non- spontaneous (C) 10.52 cal/(mol K) (D) 21.04 cal/(mol K)
(b) ∆G° < RT ln Q (ii) Equilibrium
77. In which of the following reactions, standard reaction
(c) Kp = Q (iii) Spontaneous and
entropy change (ÄS°) is positive and standard Gibb’s
endothermic energy (ÄG°) decreases sharply with increasing
(d) T > ∆H/∆S (iv) Spontaneous temperature? [NEET 2012]
[NEET 2010]
(A) Mg(s) + 1/2O2(g)  → MgO(s)
(A) a-(i), b-(ii), c-(iii), d-(iv)
(B) C(graphite) + O2(g) CO2(g)
(B) a-(iii), b-(iv), c-(ii), d-(i)
(C) C(graphite) + O2(g) CO2(g)
(C) a-(iv), b-(i), c-(ii), d-(iii) (D) CO(g) + O2(g) CO2(g)
(D) a-(ii), b-(i), c-(iv), d-(iii)
78. Equal volumes of two monoatomic gases, A and B, at
71. Which of the following is the correct option for the the same temperature and pressure are mixed. The ratio
free expansion of an ideal gas under adiabatic of specific heats (CP /CV) of the mixture will be
condition? [NEET 2011, 2020] [NEET 2012]
(A) q = 0, ∆T < 0, w ≠ 0 (B) q = 0, ∆T ≠ 0, w = 0 (A) 0.83 (B) 1.50
(C) q ≠ 0, ∆T = 0, w = 0 (D) q = 0, ∆T = 0, w = 0 (C) 3.3 (D) 1.67
72. Enthalpy change for the reaction, 79. A reaction having equal energies of activation for
4H(g) → 2H2(g) is – 869.6 kJ forward and reverse reactions has- [NEET 2013]
The dissociation energy of H – H bond is (A) ∆G = 0 (B) ÄH = 0
[NEET 2011] (C) ∆H = ÄG = ∆S = 0 (D) ∆S = 0
(A) + 217.4 kJ (B) – 434.8 kJ
(C) – 869.6 kJ (D) + 434.8 kJ 80. Three thermochemical equations are given below
(i) C(graphite) + O2(g) CO2(g); ∆rH° = x kJ mol–1
73. If the enthalpy change for the transition of liquid water
1
to steam is 30 kJ mol–1 at 27°C, the entropy change (ii) C(graphite) + O CO(g); ∆rH° = y kJ mol–1
2 2(g)
for the process would be [NEET 2011]
–1 –1
(A) 10 J mol K (B) 1.0 J mol–1 K–1
(C) 0.1 J mol–1 K–1 (D) 100 J mol–1 K–1
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1 (A) – 630 kJ (B) – 3.15 kJ

(iii) CO(g) + O CO2(g); ∆rH° = z kJ mol–1 (C) – 315 kJ (D) + 315 kJ
2 2(g)
Based on the above equations, find out which of the 86. The correct thermodynamic conditions for the spon-
relationship given below is correct.- [NEET 2013] taneous reaction at all temperature is :
(A) z = x + y (B) x = y + z [NEET 2016 Phase-I]
(C) y = 2z – x (D) x = y – z (A) ∆H < 0 and ∆S < 0 (B) ∆H < 0 and ∆S = 0
81. When 5 litres of a gas mixture of methane and propane (C) ∆H > 0 and ∆S < 0 (D) ∆H < 0 and ∆S > 0
is perfectly combusted at 0°C and 1 atmosphere, 16 87. For a sample of perfect gas when its pressure is
litres of oxygen at the same temperature and pressure changed isothermally from pi to pf, the entropy change
is consumed, The amount of heat released from this is given by [NEET 2016 Phase-II]
combustion in kJ (∆Hcomb. (CH4) = 890 kJ mol–1, ∆Hcomb.
 pf   p 
(C3H8) = 2220 kJ mol–1) is [NEET 2013] (A) ∆S = nR ln  
 (B) ∆S = nR ln  i 
 pf 
(A) 38 (B) 317  pi   
(C) 477 (D) 32
 pf   p 
(C) ∆S = nRT ln  
 (D) ∆S = RT ln  i 
82. Which of the following statements is correct for the  pi 
 pf 
 
spontaneous adsorption of gas? [NEET 2014]
(A) ÄS is negative and therefore ÄH should be highly 88. A gas is allowed to expand in a well insulated container
positive against a constant external pressure of 2.5 atm from
(B) ÄS is negative and therefore ÄH should be highly an initial volume of 2.50 L to a final volume of 4.50
negative L. The change in internal energy ∆U of the gas in joules
(C) ÄS is positive and therefore ÄH should be highly will be : [NEET 2017]
negative (A) 1135.25 J (B) – 500 J
(D) ÄS is positive and therefore ÄH should be highly (C) – 505 J (D) + 505 J
positive
89. For a given reaction, ∆H = 35.5 kJ mol–1 and ∆S =
83. For the reaction : [NEET 2014] 83.6K–1 mol –1. The reaction is spontaneous at :
X2O4(l) → 2XO2(g) (Assume that ∆H and ∆S do not vary with temperatuer)
∆U = 2.1 cal, ∆S = 20 cal K–1 at 300 K [NEET 2017]
(A) 2.7 kcal (B) – 2.7 kcal (A) T < 425 K (B) T > 425 K
(C) 9.3 kcal (D) – 9.3 kcal (C) all temperatures (D) T > 298 K
84. Given 90. The bond dissociation energies of X2, Y2 and XY are in
the ratio of 1 : 0.5 : 1. ∆H for the formation of XY is .
200 kJ mol–1. The bond dissociation energy of X2 will
be : [NEET 2018]
–1
(A) 200 kJ mol (B) 400 kJ mol–1
(C) 800 kJ mol–1 (D) 100 kJ mol–1
The enthalpy of hydrogenation of these compounds
will be the order of as [NEET 2015] 91. Under isothermal condition, a gas at 300 K expands
(A) II > III > I (B) II > I > III from 0.1 L to 0.25 L against a constant external
(C) I > II > III (D) III > II > I pressure of 2 bar. The work done by the gas is [Given
that 1 L bar = 100 J] [NEET 2019]
85. The heat of combustion of carbon to CO2 is – 393.5
(A) 25 J (B) 30 J
kJ/mol. The heat released upon the formation of 35.2
(C) – 30 J (D) 5 kJ
g of CO2 from carbon and oxygen gas is
[NEET 2015 Re] 92. In which case change in entropy is negative?
[NEET 2019]
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CHEMISTRY 9
(A) Sublimation of solid to gas 100. Which amongst the following options is the correct
(B) 2H(g) → H2(g) relation between change in enthalpy and change in
(C) Evaporation of water internal energy? [NEET 2023]
(D) Expansion of a gas at temperature (A) ∆Η = ∆U + ∆ngRT (B) ∆Η – ∆U = – ∆nRT
(C) ∆Η + ∆U = ∆nR (D) ∆Η = ∆U – ∆ngRT
93. For the reaction, 2Cl(g) → Cl2(g), the correct option
is: [NEET 2020] 101. Consider the following reaction:- [NEET 2023]
(A) ∆rH > 0 and ∆rS < 0 (B) ∆rH < 0 and ∆rS > 0 2H2(g) + O2(g) → 2H2O (g) ∆ r H° = − 483.6 kJ
(C) ∆rH < 0 and ∆rS < 0 (D) ∆rH > 0 and ∆rS > 0 What is the enthalpy change for decomposition of one
94. For irreversible expansion of an ideal gas under mole of water? (Choose the right option).
isothermal condition, the correct option is : (A) 120.9 kJ (B) 241.82 kJ
[NEET 2021] (C) 18 kJ (D) 100 kJ
(A) ∆U ≠ 0, ∆Stotal = 0 (B) ∆U = 0, ∆Stotal = 0
(C) ∆U ≠ 0, ∆Stotal ≠ 0 (D) ∆U = 0, ∆Stotal ≠ 0
95. Which one among the following is the correct option

for right relationship between CP and CV for one mole
of ideal gas? [NEET 2021]
(A) CV = RCP (B) CP + CV = R
(C) CP – CV = R (D) CP = RCV
96. Which of the following p-V curve represents maximum

work done? [NEET 2022]
(A) CV = RCP (B) CP + CV = R
(C) CP – CV = R (D) CP = RCV
97. One mole of an ideal gas at 300 K is expanded

isothermally from 1 L to 10 L volume.
∆U for this process is :
(Use R = 8.314 J k–1 mol–1) [NEET Phase II 2022]
(A) 0J (B) 1260 J
(C) 2520 J (D) 5040 J
98. A vessel contains 3.2 g of dioxygen gas at STP (273.15

K and 1 atm pressure). The gas is now transferred to
another vessel at constant temperature, where pressure
becomes one third of the original pressure. The volume
of new vessel in L is : (Given : molar volume at STP is
22.4 L) [NEET Phase II 2022]
(A) 67.2 (B) 6.72
(C) 2.24 (D) 22.4
99. The equilibrium concentrations of the species in the

reaction A + B C + D are 2, 3, 10 and 6 mol L–
1
, respectively at 300 K. ∆G0 for the reaction is
(R = 2 cal/mol K) [NEET 2023]
(A) – 137.26 (B) – 1381.8 cal
(C) – 13.73 cal (D) 1372.60 cal

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EXCERCISE - 2 : ASSERTION & REASON

Direction : In the following questions, a statement of assertion 3. Assertion : When egg is boiled, the entropy increases.
is followed by a statement of reason. Mark the correct choice Reason : Albumin protein is solidified on boiling the
as : egg due to denaturation.
(A) Both assertion and reason are true and the reason
4. Assertion : Every substance has finite entropy even at
is correct explanation of assertion.
absolute zero.
(B) Both assertion and reason are true and the reason 3. D
Reason : Perfectly crystalline solids have zero entropy
is not correct explanation of assertion.
at absolute zero.
(C) Assertion is true but reason is false.
(D) Assertion is false, reason is true. 5. Assertion : If there is no residual orientational disorder,
(E) If both Assertion and Reason are false. the entropy of substance will be zero at 0 K. 4. B
Reason : Entropy is extensive property.
1. A 1. Assertion : In case of CO and NO molecules in solid
state; there is randomness even at 0 K. 6. Assertion : Combustion of all organic compounds is
Reason : Owing to dipole moment, CO and NO the an exothermic reaction.
entropy is not zero even at 0 K. Reason : The entalpies of all elements in their standard5. B
state are zero.
2. A 2. Assertion : Steam has greater entropy than same
6B
amount of water.
Reason : Entropy of a substance in different physical
state lies in following sequence.
Solid < Liquid < Gas

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Chemistry 11th Thermodynamics

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CHAPTER

EXCERCISE - 1 : OBJECTIVE QUESTIONS

Office :- Near T.B. Hospital, K.P. College Road, Pratapgarh

Office :- Near T.B. Hospital, K.P. College Road, Pratapgarh

Office :- Near T.B. Hospital, K.P. College Road, Pratapgarh

Office :- Near T.B. Hospital, K.P. College Road, Pratapgarh

Office :- Near T.B. Hospital, K.P. College Road, Pratapgarh

1 (A) – 630 kJ (B) – 3.15 kJ

95. Which one among the following is the correct option

96. Which of the following p-V curve represents maximum

97. One mole of an ideal gas at 300 K is expanded

98. A vessel contains 3.2 g of dioxygen gas at STP (273.15

99. The equilibrium concentrations of the species in the

Office :- Near T.B. Hospital, K.P. College Road, Pratapgarh

EXCERCISE - 2 : ASSERTION & REASON

Office :- Near T.B. Hospital, K.P. College Road, Pratapgarh

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